# Ni–Sb system

> Ni–Sb system: 118 accepted literature values (invariant reaction 114, formation 4) and 4 calculated phase diagram(s) from ORCHID, each value with evidence class, source, page and quote.

HTML: https://data.orchid-project.org/systems/NI-SB.html · Markdown: https://data.orchid-project.org/systems/NI-SB.md

118 accepted literature values from 3 paper(s) (experimental 94, model 24); 4 calculated phase diagram(s). 3 further extracted value(s) not accepted by the reader-agreement checks are only in the JSON/CSV.

Data: [JSON](https://data.orchid-project.org/literature/systems/NI-SB.json) · [CSV](https://data.orchid-project.org/systems/NI-SB.csv) · [interactive explorer](https://orchid-project.org/data-explorer/#NI-SB) · [interactive phase diagram](https://orchid-project.org/phase-diagrams/#NI-SB/NiSb-08Cao.json) · [phases (10)](https://data.orchid-project.org/phases/pages/NI-SB.html) · [papers (bibliography)](https://data.orchid-project.org/bibliography/pages/systems/NI-SB.html) · [Markdown](https://data.orchid-project.org/systems/NI-SB.md)

Table: Accepted values by evidence class

| Evidence class | Values |
|---|---:|
| experimental | 94 |
| model | 24 |

Table: Accepted values by property group

| Property group | Values |
|---|---:|
| invariant reaction | 114 |
| formation | 4 |

## Calculated phase diagrams

Binary phase diagrams calculated with pycalphad 0.11.2 from the SGTE binary collection (Hallstedt 2025, CC BY 4.0). Evidence class: model.

Table: Assessments with a calculated phase diagram

| TDB file | Assessment | SHA-256 | Links |
|---|---|---|---|
| NiSb-08Cao.tdb | Z. Cao, Y. Takaku, I. Ohnuma, R. Kainuma, H. Zhu, K. Ishida, Rare. Met., 27, 384-92(2008). [doi:10.1016/S1001-0521(08)60150-3](https://doi.org/10.1016/S1001-0521%2808%2960150-3) | `c50b9c6a21205dfe003993046d9f6f8fb89c4dae10d9a17fa254d5d30d9c234f` | [viewer](https://orchid-project.org/phase-diagrams/#NI-SB/NiSb-08Cao.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/NiSb-08Cao.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/NiSb-08Cao.json) |
| NiSb-08Zha.tdb | Y. Zhang, C. Li, Z. Du, C. Guo, Calphad, 32, 378-88(2008). [doi:10.1016/j.calphad.2008.02.001](https://doi.org/10.1016/j.calphad.2008.02.001) | `1ab705f632704a07ca1d24342fe42a159b30c1cb1d9a36f53a2a635650fcb54d` | [viewer](https://orchid-project.org/phase-diagrams/#NI-SB/NiSb-08Zha.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/NiSb-08Zha.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/NiSb-08Zha.json) |
| NiSb-13Cao.tdb | Z. Cao, W. Xie, K. Wang, G. Du, Z. Qiao, J. Electron. Mater., 42, 2615-29(2013). [doi:10.1007/s11664-013-2599-7](https://doi.org/10.1007/s11664-013-2599-7) | `57b2cd3fde2a42568c0dc120447c0ef6c036e6012c6926687146837ecfc0881b` | [viewer](https://orchid-project.org/phase-diagrams/#NI-SB/NiSb-13Cao.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/NiSb-13Cao.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/NiSb-13Cao.json) |
| NiSb-14Kro.tdb | A. Kroupa, R. Mishra, D. Rajamohan, H. Flandorfer, A. Watson, H. Ipser, Calphad, 45, 151-66(2014). [doi:10.1016/j.calphad.2013.11.007](https://doi.org/10.1016/j.calphad.2013.11.007) | `15754b2a707f1c85565c5582ceabba72e7076f88c69108ed0d113b8e2ee9d407` | [viewer](https://orchid-project.org/phase-diagrams/#NI-SB/NiSb-14Kro.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/NiSb-14Kro.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/NiSb-14Kro.json) |

Table: Calculated three-phase invariants (model, mole fraction of the second component)

| TDB file | T (K) | Phases at the invariant |
|---|---:|---|
| NiSb-08Cao.tdb | 1371.88 | FCC_A1 (x(Sb) 0.10338) + LIQUID (x(Sb) 0.18871) + NI3SB_D03 (x(Sb) 0.25493) |
| NiSb-08Cao.tdb | 1364.23 | NI3SB_D03 (x(Sb) 0.28151) + LIQUID (x(Sb) 0.35709) + NISB_B81 (x(Sb) 0.43752) |
| NiSb-08Cao.tdb | 978.37 | FCC_A1 (x(Sb) 0.08518) + NI3SB_D0A (x(Sb) 0.25) + NI3SB_D03 (x(Sb) 0.2575) |
| NiSb-08Cao.tdb | 978.37 | FCC_A1 (x(Sb) 0.08518) + NI3SB_D0A (x(Sb) 0.25) + NI3SB_D03 (x(Sb) 0.2575) |
| NiSb-08Cao.tdb | 901.22 | NISB_B81 (x(Sb) 0.54003) + NISB2_C18 (x(Sb) 0.66667) + LIQUID (x(Sb) 0.95581) |
| NiSb-08Cao.tdb | 893.5 | NISB2_C18 (x(Sb) 0.66667) + LIQUID (x(Sb) 0.96097) + RHOMBOHEDRAL_A7 (x(Sb) 1) |
| NiSb-08Cao.tdb | 893.5 | NISB2_C18 (x(Sb) 0.66667) + LIQUID (x(Sb) 0.96113) + RHOMBOHEDRAL_A7 (x(Sb) 1) |
| NiSb-08Cao.tdb | 846.28 | NI3SB_D03 (x(Sb) 0.27897) + NI5SB2_LT (x(Sb) 0.283) + NISB_B81 (x(Sb) 0.4405) |
| NiSb-08Cao.tdb | 821.68 | NI3SB_D0A (x(Sb) 0.25) + NI3SB_D03 (x(Sb) 0.2712) + NI5SB2_LT (x(Sb) 0.283) |
| NiSb-08Zha.tdb | 1372.46 | FCC_A1 (x(Sb) 0.08566) + LIQUID (x(Sb) 0.18235) + NI3SB_D03 (x(Sb) 0.25842) |
| NiSb-08Zha.tdb | 1349.08 | NI3SB_D03 (x(Sb) 0.29052) + LIQUID (x(Sb) 0.36791) + NISB_B81 (x(Sb) 0.46682) |
| NiSb-08Zha.tdb | 989.25 | FCC_A1 (x(Sb) 0.08167) + NI3SB_D0A (x(Sb) 0.24568) + NI3SB_D03 (x(Sb) 0.26106) |
| NiSb-08Zha.tdb | 892.34 | NISB_B81 (x(Sb) 0.54254) + NISB2_C18 (x(Sb) 0.66667) + LIQUID (x(Sb) 0.95817) |
| NiSb-08Zha.tdb | 890.32 | NISB2_C18 (x(Sb) 0.66667) + LIQUID (x(Sb) 0.95923) + RHOMBOHEDRAL_A7 (x(Sb) 1) |
| NiSb-08Zha.tdb | 890.32 | NISB2_C18 (x(Sb) 0.66667) + LIQUID (x(Sb) 0.95925) + RHOMBOHEDRAL_A7 (x(Sb) 1) |
| NiSb-08Zha.tdb | 869.35 | NI5SB2_LT (x(Sb) 0.28547) + NI3SB_D03 (x(Sb) 0.29054) + NISB_B81 (x(Sb) 0.46552) |
| NiSb-08Zha.tdb | 802.63 | NI3SB_D0A (x(Sb) 0.24944) + NI3SB_D03 (x(Sb) 0.27216) + NI5SB2_LT (x(Sb) 0.27704) |
| NiSb-13Cao.tdb | 1372.46 | FCC_A1 (x(Sb) 0.08566) + LIQUID (x(Sb) 0.18235) + NI3SB_D03 (x(Sb) 0.25842) |
| NiSb-13Cao.tdb | 1347.72 | NI3SB_D03 (x(Sb) 0.29225) + LIQUID (x(Sb) 0.36911) + NISB_B81 (x(Sb) 0.4626) |
| NiSb-13Cao.tdb | 989.25 | FCC_A1 (x(Sb) 0.08167) + NI3SB_D0A (x(Sb) 0.24568) + NI3SB_D03 (x(Sb) 0.26106) |
| NiSb-13Cao.tdb | 898.01 | NISB_B81 (x(Sb) 0.54484) + NISB2_C18 (x(Sb) 0.66667) + LIQUID (x(Sb) 0.95504) |
| NiSb-13Cao.tdb | 890.32 | NISB2_C18 (x(Sb) 0.66667) + LIQUID (x(Sb) 0.95923) + RHOMBOHEDRAL_A7 (x(Sb) 1) |
| NiSb-13Cao.tdb | 890.32 | NISB2_C18 (x(Sb) 0.66667) + LIQUID (x(Sb) 0.95936) + RHOMBOHEDRAL_A7 (x(Sb) 1) |
| NiSb-13Cao.tdb | 855.45 | NI5SB2_LT (x(Sb) 0.28554) + NI3SB_D03 (x(Sb) 0.29252) + NISB_B81 (x(Sb) 0.46336) |
| NiSb-13Cao.tdb | 802.63 | NI3SB_D0A (x(Sb) 0.24944) + NI3SB_D03 (x(Sb) 0.27216) + NI5SB2_LT (x(Sb) 0.27704) |
| NiSb-14Kro.tdb | 1366.73 | FCC_A1 (x(Sb) 0.08706) + LIQUID (x(Sb) 0.18464) + BCC_A2 (x(Sb) 0.24453) |
| NiSb-14Kro.tdb | 1349.63 | BCC_A2 (x(Sb) 0.28986) + LIQUID (x(Sb) 0.36784) + NISB_B81 (x(Sb) 0.46568) |
| NiSb-14Kro.tdb | 988.84 | FCC_A1 (x(Sb) 0.08166) + NI3SB_D0A (x(Sb) 0.24568) + BCC_A2 (x(Sb) 0.25676) |
| NiSb-14Kro.tdb | 892.34 | NISB_B81 (x(Sb) 0.54254) + NISB2_C18 (x(Sb) 0.66667) + LIQUID (x(Sb) 0.95817) |
| NiSb-14Kro.tdb | 890.32 | NISB2_C18 (x(Sb) 0.66667) + LIQUID (x(Sb) 0.95923) + RHOMBOHEDRAL_A7 (x(Sb) 1) |
| NiSb-14Kro.tdb | 890.32 | NISB2_C18 (x(Sb) 0.66667) + LIQUID (x(Sb) 0.95925) + RHOMBOHEDRAL_A7 (x(Sb) 1) |
| NiSb-14Kro.tdb | 856.98 | NI5SB2_LT (x(Sb) 0.28548) + BCC_A2 (x(Sb) 0.28966) + NISB_B81 (x(Sb) 0.46549) |
| NiSb-14Kro.tdb | 803.04 | NI3SB_D0A (x(Sb) 0.24944) + BCC_A2 (x(Sb) 0.27208) + NI5SB2_LT (x(Sb) 0.27704) |

Convex hulls: [Materials Project DFT hull](https://data.orchid-project.org/hulls/dft-mp/NI/NI-SB.json) · [OQMD DFT hull](https://data.orchid-project.org/hulls/dft-oqmd/NI/NI-SB.json) · [CALPHAD hull NiSb-08Cao](https://data.orchid-project.org/hulls/calphad-sgte/NI/NI-SB--NiSb-08Cao.json) · [CALPHAD hull NiSb-08Zha](https://data.orchid-project.org/hulls/calphad-sgte/NI/NI-SB--NiSb-08Zha.json) · [CALPHAD hull NiSb-13Cao](https://data.orchid-project.org/hulls/calphad-sgte/NI/NI-SB--NiSb-13Cao.json)

## Invariant reactions (literature)

Table: Invariant reactions reported in the literature for the Ni–Sb system (114)

| T (K) | Reaction / phases | Compositions (mole fraction) | Class | Source | Location | Quote |
|---:|---|---|---|---|---|---|
| 1444 | congruent melting: L \<-> Ni3Sb_HT | L: Sb 0.285; Ni3Sb_HT: Ni 0.75, Sb 0.25 | experimental | [1] CAO 2008; _cites Panteleimonov 1964_ | Table 3, p. 6, row 12; `ORC-ET7ZISA7SU` |  |
| 1443 | congruent melting: L ↔ (βNi5Sb2) | L: Sb 0.29; (βNi5Sb2): Sb 0.29 | experimental | [2] Zhang 2008; _cites Eremenko 1951_ | Table 3, p. 4, row 21; `ORC-3T6BRDCB7T` |  |
| 1443 | congruent melting: L ↔ (βNi5Sb2) | L: Sb 0.29; (βNi5Sb2): Sb 0.29 | experimental | [2] Zhang 2008; _cites Panteleimonov 1964_ | Table 3, p. 4, row 22; `ORC-DYZ5ZUNZFE` |  |
| 1443 | congruent melting: L \<-> Ni3Sb_HT | L: Sb 0.283; Ni3Sb_HT: Ni 0.75, Sb 0.25 | experimental | [1] CAO 2008; _cites Lossew 1906_ | Table 3, p. 6, row 10; `ORC-L4L6P6SX74` |  |
| 1443 | congruent melting: L ↔ (βNi5Sb2) | L: Sb 0.283; (βNi5Sb2): Sb 0.283 | experimental | [2] Zhang 2008; _cites Lossew 1906_ [doi](https://doi.org/10.1002/zaac.19060490107) | Table 3, p. 4, row 19; `ORC-N6LGBAW2UY` |  |
| 1443 | congruent melting: L \<-> Ni3Sb_HT | L: Sb 0.267; Ni3Sb_HT: Ni 0.75, Sb 0.25 | model | [1] CAO 2008 | Table 3, p. 6, row 14; `ORC-TVLJITCI3F` |  |
| 1438 | congruent melting: L \<-> NiSb | L: Sb 0.475; NiSb: Ni 0.5, Sb 0.5 | model | [1] CAO 2008 | Table 3, p. 6, row 32; `ORC-ZSGIICVIEU` |  |
| 1435 | congruent melting: L ↔ (βNi5Sb2) | L: Sb 0.293; (βNi5Sb2): Sb 0.293 | experimental | [2] Zhang 2008; _cites Shibata 1939_ | Table 3, p. 4, row 20; `ORC-QTTGSTRO2T` |  |
| 1435 | congruent melting: L \<-> Ni3Sb_HT | L: Sb 0.279; Ni3Sb_HT: Ni 0.75, Sb 0.25 | experimental | [1] CAO 2008; _cites Shibata 1939_ | Table 3, p. 6, row 11; `ORC-U44E4V3IYT` |  |
| 1434 | congruent melting: L ↔ (βNi3Sb) | L: Sb 0.2627; (βNi3Sb): Sb 0.2627 | experimental | [2] Zhang 2008 | Table 3, p. 4, row 25; `ORC-2NNDACOZ73` |  |
| 1434 | congruent melting: L ↔ (βNi5Sb2) | L: Sb 0.279; (βNi5Sb2): Sb 0.279 | model | [2] Zhang 2008; _cites Cha 1991_ | Table 3, p. 4, row 24; `ORC-6SI33UL42Y` |  |
| 1434 | congruent melting: L ↔ (βNi3Sb) | L: Sb 0.279; (βNi3Sb): Sb 0.279 | experimental | [2] Zhang 2008; _cites Feschotte 1989_ [doi](https://doi.org/10.1016/0022-5088%2889%2990235-x) | Table 3, p. 4, row 23; `ORC-IF3KLL3CFX` |  |
| 1434 | congruent melting: L \<-> Ni3Sb_HT | L: Sb 0.279; Ni3Sb_HT: Ni 0.75, Sb 0.25 | experimental | [1] CAO 2008; _cites Feschotte 1989_ | Table 3, p. 6, row 13; `ORC-VU4YOPPQ4Q` |  |
| 1432 | congruent melting: L ↔ (γNiSb) | L: Sb 0.47; γNiSb: Sb 0.47 | experimental | [2] Zhang 2008; _cites Leubolt 1986_ [doi](https://doi.org/10.1002/zaac.19865330226) | Table 3, p. 5, row 3; `ORC-PAJDW7T2UN` |  |
| 1432 | congruent melting: L \<-> NiSb | L: Sb 0.47; NiSb: Ni 0.5, Sb 0.5 | experimental | [1] CAO 2008; _cites Leubolt 1986_ | Table 3, p. 6, row 30; `ORC-ZMIHMY6Y5T` |  |
| 1431 | congruent melting: L ↔ (γNiSb) | L: Sb 0.4965; γNiSb: Sb 0.4965 | experimental | [2] Zhang 2008; _cites Lossew 1906_ [doi](https://doi.org/10.1002/zaac.19060490107) | Table 3, p. 5, row 1; `ORC-5S6MBF7ZKY` |  |
| 1431 | congruent melting: L \<-> NiSb | L: Sb 0.497; NiSb: Ni 0.5, Sb 0.5 | experimental | [1] CAO 2008; _cites Lossew 1906_ | Table 3, p. 6, row 27; `ORC-Q4QNG5BRF4` |  |
| 1426 | congruent melting: L \<-> NiSb | L: Sb 0.494; NiSb: Ni 0.5, Sb 0.5 | experimental | [1] CAO 2008; _cites Shibata 1939_ | Table 3, p. 6, row 28; `ORC-I5CQ76DA5H` |  |
| 1426 | congruent melting: L ↔ (γNiSb) | L: Sb 0.484; γNiSb: Sb 0.484 | experimental | [2] Zhang 2008; _cites Shibata 1939_ | Table 3, p. 5, row 2; `ORC-SQPZ2RKOFQ` |  |
| 1420 | congruent melting: L ↔ (γNiSb) | L: Sb 0.4838; γNiSb: Sb 0.4838 | model | [2] Zhang 2008 | Table 3, p. 5, row 6; `ORC-7X3EUOIVW4` |  |
| 1420 | congruent melting: L ↔ (γNiSb) | L: Sb 0.489; γNiSb: Sb 0.489 | model | [2] Zhang 2008; _cites Cha 1991_ | Table 3, p. 5, row 5; `ORC-KMCNXSVRCB` |  |
| 1420 | congruent melting: L ↔ (γNiSb) | L: Sb 0.489; γNiSb: Sb 0.489 | experimental | [2] Zhang 2008; _cites Feschotte 1989_ [doi](https://doi.org/10.1016/0022-5088%2889%2990235-x) | Table 3, p. 5, row 4; `ORC-SY4JJPG7YI` |  |
| 1420 | congruent melting: L \<-> NiSb | L: Sb 0.489; NiSb: Ni 0.5, Sb 0.5 | experimental | [1] CAO 2008; _cites Feschotte 1989_ | Table 3, p. 6, row 31; `ORC-TPLHOVXKZE` |  |
| 1413 | congruent melting: L \<-> NiSb | L: Sb 0.47; NiSb: Ni 0.5, Sb 0.5 | experimental | [1] CAO 2008; _cites Chen 1978_ | Table 3, p. 6, row 29; `ORC-FG7V6JNBW7` |  |
| 1375 | eutectic: L ↔ (αNi) + (βNi5Sb2) | (βNi5Sb2): Ni 0.714286, Sb 0.285714 | experimental | [2] Zhang 2008; _cites Panteleimonov 1964_ | Table 3, p. 4, row 6; `ORC-D4BQZABKZB` |  |
| 1375 | eutectic: L ↔ (αNi) + (βNi5Sb2) | L: Sb 0.213; (βNi5Sb2): Ni 0.714286, Sb 0.285714 | experimental | [2] Zhang 2008; _cites Eremenko 1951_ | Table 3, p. 4, row 5; `ORC-NGEKZOFIG5` |  |
| 1373 | eutectic: L ↔ (αNi) + (βNi5Sb2) | (αNi): Sb 0.0367; (βNi5Sb2): Ni 0.714286, Sb 0.285714 | experimental | [2] Zhang 2008; _cites Lossew 1906_ [doi](https://doi.org/10.1002/zaac.19060490107) | Table 3, p. 4, row 3; `ORC-3PSLNX5PLO` |  |
| 1373 | L \<-> fcc(Ni)+Ni3Sb_HT | L: Sb 0.205; fcc(Ni): Sb 0.038; Ni3Sb_HT: Sb 0.267 | experimental | [1] CAO 2008; _cites Lossew 1906_ | Table 3, p. 6, row 1; `ORC-MAA6BKKVUV` |  |
| 1372 | eutectic: L ↔ (αNi) + (βNi3Sb) | L: Sb 0.1823; (αNi): Sb 0.085665; (βNi3Sb): Sb 0.2584 | experimental | [2] Zhang 2008 | Table 3, p. 4, row 10; `ORC-F2UQTFIX7C` |  |
| 1371 | L \<-> fcc(Ni)+Ni3Sb_HT | L: Sb 0.189; fcc(Ni): Sb 0.104; Ni3Sb_HT: Sb 0.255 | model | [1] CAO 2008 | Table 3, p. 6, row 4; `ORC-YPNCDJUXEN` |  |
| 1370 | eutectic: L ↔ (αNi) + (βNi5Sb2) | L: Sb 0.2133; (αNi): Sb 0.084; (βNi5Sb2): Ni 0.714286, Sb 0.285714 | experimental | [2] Zhang 2008; _cites Shibata 1939_ | Table 3, p. 4, row 4; `ORC-6GWMEZLOKQ` |  |
| 1370 | eutectic: L ↔ (αNi) + (βNi3Sb) | L: Sb 0.23; (αNi): Sb 0.085; (βNi3Sb): Sb 0.252 | experimental | [2] Zhang 2008; _cites Feschotte 1989_ [doi](https://doi.org/10.1016/0022-5088%2889%2990235-x) | Table 3, p. 4, row 8; `ORC-IDRMWPTBU6` |  |
| 1370 | eutectic: L ↔ (αNi) + (βNi5Sb2) | L: Sb 0.23; (αNi): Sb 0.09; (βNi5Sb2): Sb 0.252 | model | [2] Zhang 2008; _cites Cha 1991_ | Table 3, p. 4, row 9; `ORC-KC6NDD5AE2` |  |
| 1370 | eutectic: L ↔ (αNi) + (βNi5Sb2) | (αNi): Sb 0.094; (βNi5Sb2): Ni 0.714286, Sb 0.285714 | experimental | [2] Zhang 2008; _cites Naud 1972_ [doi](https://doi.org/10.1016/0025-5408%2872%2990207-3) | Table 3, p. 4, row 7; `ORC-ONN7SO2PHH` |  |
| 1370 | L \<-> fcc(Ni)+Ni3Sb_HT | L: Sb 0.216; fcc(Ni): Sb 0.084; Ni3Sb_HT: Sb 0.236 | experimental | [1] CAO 2008; _cites Shibata 1939_ | Table 3, p. 6, row 2; `ORC-T4BFHO4O72` |  |
| 1370 | L \<-> fcc(Ni)+Ni3Sb_HT | L: Sb 0.23; fcc(Ni): Sb 0.09; Ni3Sb_HT: Sb 0.252 | experimental | [1] CAO 2008; _cites Feschotte 1989_ | Table 3, p. 6, row 3; `ORC-XN4IWPS5C4` |  |
| 1364 | L \<-> Ni3Sb_HT+NiSb | L: Sb 0.357; Ni3Sb_HT: Sb 0.281; NiSb: Sb 0.437 | model | [1] CAO 2008 | Table 3, p. 6, row 26; `ORC-NUPRXYXIVC` |  |
| 1353 | eutectic: L ↔ (βNi5Sb2) + (γNiSb) | L: Sb 0.35; (βNi5Sb2): Ni 0.714286, Sb 0.285714; (γNiSb): Ni 0.5, Sb 0.5 | experimental | [2] Zhang 2008; _cites Panteleimonov 1964_ | Table 3, p. 4, row 49; `ORC-3HPPXTTPLP` |  |
| 1353 | eutectic: L ↔ (βNi5Sb2) + (γNiSb) | L: Sb 0.35; (βNi5Sb2): Ni 0.714286, Sb 0.285714; (γNiSb): Ni 0.5, Sb 0.5 | experimental | [2] Zhang 2008; _cites Eremenko 1951_ | Table 3, p. 4, row 48; `ORC-5WRDQ65JAW` |  |
| 1349 | eutectic: L ↔ (βNi3Sb) + (γNiSb) | L: Sb 0.3667; (βNi3Sb): Sb 0.2885; (γNiSb): Sb 0.46 | experimental | [2] Zhang 2008 | Table 3, p. 4, row 54; `ORC-IM4RSEL7LT` |  |
| 1348 | eutectic: L ↔ (βNi5Sb2) + (γNiSb) | (βNi5Sb2): Ni 0.714286, Sb 0.285714; (γNiSb): Ni 0.5, Sb 0.5 | experimental | [2] Zhang 2008; _cites Leubolt 1986_ [doi](https://doi.org/10.1002/zaac.19865330226) | Table 3, p. 4, row 51; `ORC-2OVKJEIJMI` |  |
| 1348 | L \<-> Ni3Sb_HT+NiSb | Ni3Sb_HT: Ni 0.75, Sb 0.25; NiSb: Ni 0.5, Sb 0.5 | experimental | [1] CAO 2008; _cites Leubolt 1986_ | Table 3, p. 6, row 24; `ORC-Z5Q64LVGDK` |  |
| 1345 | eutectic: L ↔ (βNi3Sb) + (γNiSb) | L: Sb 0.35; (βNi3Sb): Sb 0.288; (γNiSb): Sb 0.43 | experimental | [2] Zhang 2008; _cites Feschotte 1989_ [doi](https://doi.org/10.1016/0022-5088%2889%2990235-x) | Table 3, p. 4, row 52; `ORC-A4LYJZZRRF` |  |
| 1345 | L \<-> Ni3Sb_HT+NiSb | L: Sb 0.35; Ni3Sb_HT: Sb 0.288; NiSb: Sb 0.43 | experimental | [1] CAO 2008; _cites Feschotte 1989_ | Table 3, p. 6, row 25; `ORC-DPFIFNCJ55` |  |
| 1345 | eutectic: L ↔ (βNi5Sb2) + (γNiSb) | L: Sb 0.3467; (βNi5Sb2): Sb 0.283; (γNiSb): Sb 0.4965 | experimental | [2] Zhang 2008; _cites Lossew 1906_ [doi](https://doi.org/10.1002/zaac.19060490107) | Table 3, p. 4, row 46; `ORC-JT4C3GAE7B` |  |
| 1345 | L \<-> Ni3Sb_HT+NiSb | L: Sb 0.347; Ni3Sb_HT: Sb 0.283; NiSb: Sb 0.42 | experimental | [1] CAO 2008; _cites Lossew 1906_ | Table 3, p. 6, row 22; `ORC-LWJ63WWAT4` |  |
| 1345 | eutectic: L ↔ (βNi5Sb2) + (γNiSb) | L: Sb 0.37; (βNi5Sb2): Sb 0.288; (γNiSb): Sb 0.43 | model | [2] Zhang 2008; _cites Cha 1991_ | Table 3, p. 4, row 53; `ORC-YOAGEFAZ3G` |  |
| 1343 | eutectic: L ↔ (βNi5Sb2) + (γNiSb) | L: Sb 0.37; (βNi5Sb2): Ni 0.714286, Sb 0.285714; (γNiSb): Ni 0.5, Sb 0.5 | experimental | [2] Zhang 2008; _cites Shibata 1939_ | Table 3, p. 4, row 47; `ORC-4QBROO7KLS` |  |
| 1343 | L \<-> Ni3Sb_HT+NiSb | L: Sb 0.37; Ni3Sb_HT: Sb 0.299; NiSb: Sb 0.432 | experimental | [1] CAO 2008; _cites Shibata 1939_ | Table 3, p. 6, row 23; `ORC-FDLPCXSWQB` |  |
| 1343 | eutectic: L ↔ (βNi5Sb2) + (γNiSb) | (βNi5Sb2): Ni 0.714286, Sb 0.285714; (γNiSb): Ni 0.5, Sb 0.5 | experimental | [2] Zhang 2008; _cites Naud 1972_ [doi](https://doi.org/10.1016/0025-5408%2872%2990207-3) | Table 3, p. 4, row 50; `ORC-VZBQWNANXE` |  |
| 1163 | polymorphic: (βNi5Sb2) ↔ (β'Ni5Sb2) | (βNi5Sb2): Ni 0.714286, Sb 0.285714 | experimental | [2] Zhang 2008; _cites Panteleimonov 1964_ | Table 3, p. 4, row 27; `ORC-ZQRS43OH5C` |  |
| 989 | peritectoid: (αNi) + (βNi3Sb) ↔ (δNi3Sb) | (αNi): Sb 0.08167; (βNi3Sb): Sb 0.261; (δNi3Sb): Sb 0.2456 | experimental | [2] Zhang 2008 | Table 3, p. 4, row 18; `ORC-U3TXECA5OB` |  |
| 988 | fcc(Ni)+Ni3Sb_HT \<-> Ni3Sb | fcc(Ni): Sb 0.09; Ni3Sb_HT: Sb 0.25; Ni3Sb: Sb 0.237 | experimental | [1] CAO 2008; _cites Feschotte 1989_ | Table 3, p. 6, row 6; `ORC-J4IZLJWBKW` |  |
| 988 | peritectoid: (αNi) + (βNi3Sb) ↔ (δNi3Sb) | (βNi3Sb): Sb 0.257; (δNi3Sb): Sb 0.237 | experimental | [2] Zhang 2008; _cites Feschotte 1989_ [doi](https://doi.org/10.1016/0022-5088%2889%2990235-x) | Table 3, p. 4, row 16; `ORC-MUNOM5TPMU` |  |
| 988 | fcc(Ni)+Ni3Sb_HT \<-> Ni3Sb | fcc(Ni): Sb 0.09; Ni3Sb_HT: Sb 0.257; Ni3Sb: Sb 0.237 | experimental | [1] CAO 2008; _cites Nash 1991_ | Table 3, p. 6, row 8; `ORC-NHFAZMJ4L7` |  |
| 988 | peritectoid: (αNi) + (βNi5Sb2) ↔ (δNi3Sb) | (αNi): Sb 0.09; (βNi5Sb2): Sb 0.257; (δNi3Sb): Sb 0.237 | model | [2] Zhang 2008; _cites Cha 1991_ | Table 3, p. 4, row 17; `ORC-ZRLHF5AJSN` |  |
| 987 | fcc(Ni)+Ni3Sb_HT \<-> Ni3Sb | fcc(Ni): Sb 0.086; Ni3Sb_HT: Sb 0.258; Ni3Sb: Sb 0.25 | model | [1] CAO 2008 | Table 3, p. 6, row 9; `ORC-XR2OCOXRZB` |  |
| 982 | peritectoid: (αNi) + (βNi5Sb2) ↔ δNi3Sb | (αNi): Sb 0.094; (βNi5Sb2): Ni 0.714286, Sb 0.285714; δNi3Sb: Ni 0.75, Sb 0.25 | experimental | [2] Zhang 2008; _cites Naud 1972_ [doi](https://doi.org/10.1016/0025-5408%2872%2990207-3) | Table 3, p. 4, row 15; `ORC-T4ZGXC4CRN` |  |
| 973 | peritectoid: (αNi) + (βNi5Sb2) ↔ (δNi13Sb4) | (βNi5Sb2): Ni 0.714286, Sb 0.285714 | experimental | [2] Zhang 2008; _cites Panteleimonov 1964_ | Table 3, p. 4, row 14; `ORC-F2G2544N7Z` |  |
| 971 | fcc(Ni)+Ni3Sb_HT \<-> Ni3Sb | fcc(Ni): Sb 0.081; Ni3Sb_HT: Sb 0.25; Ni3Sb: Sb 0.25 | experimental | [1] CAO 2008; _cites Shibata 1939_ | Table 3, p. 6, row 5; `ORC-J75RGU5EGL` |  |
| 971 | peritectoid: (αNi) + (βNi5Sb2) ↔ (δNi3Sb) | (αNi): Sb 0.084; (βNi5Sb2): Sb 0.25; (δNi3Sb): Ni 0.75, Sb 0.25 | experimental | [2] Zhang 2008; _cites Shibata 1939_ | Table 3, p. 4, row 12; `ORC-WRF5DAGLOZ` |  |
| 958 | fcc(Ni)+Ni3Sb_HT \<-> Ni3Sb | Ni3Sb_HT: Ni 0.75, Sb 0.25; Ni3Sb: Ni 0.75, Sb 0.25 | experimental | [1] CAO 2008; _cites Elbakkouri 1986_ | Table 3, p. 6, row 7; `ORC-UACVWMPDGR` |  |
| 950 | peritectoid: (αNi) + (βNi5Sb2) ↔ δNi4Sb | (αNi): Sb 0.0376; (βNi5Sb2): Ni 0.714286, Sb 0.285714; δNi4Sb: Sb 0.2 | experimental | [2] Zhang 2008; _cites Lossew 1906_ [doi](https://doi.org/10.1002/zaac.19060490107) | Table 3, p. 4, row 11; `ORC-HUFSBGFW3T` |  |
| 932 | peritectoid: (αNi) + (βNi5Sb2) ↔ (δNi3Sb) | (βNi5Sb2): Ni 0.714286, Sb 0.285714; (δNi3Sb): Ni 0.75, Sb 0.25 | experimental | [2] Zhang 2008; _cites Eremenko 1951_ | Table 3, p. 4, row 13; `ORC-J3L23KBDJE` |  |
| 901 | L+NiSb \<-> NiSb2 | L: Sb 0.956; NiSb: Sb 0.54; NiSb2: Sb 0.667 | model | [1] CAO 2008 | Table 3, p. 6, row 37; `ORC-5FOUOTUEJF` |  |
| 899 | peritectic: L + (γNiSb) ↔ ζNiSb2 | γNiSb: Ni 0.5, Sb 0.5; ζNiSb2: Ni 0.333333, Sb 0.666667 | experimental | [2] Zhang 2008; _cites Naud 1972_ [doi](https://doi.org/10.1016/0025-5408%2872%2990207-3) | Table 3, p. 5, row 9; `ORC-TRBQ545ENB` |  |
| 899 | peritectic: L + (γNiSb) ↔ ζNiSb2 | L: Sb 0.95; γNiSb: Ni 0.5, Sb 0.5; ζNiSb2: Ni 0.333333, Sb 0.666667 | experimental | [2] Zhang 2008; _cites Shibata 1939_ | Table 3, p. 5, row 8; `ORC-Z5KMP4J57A` |  |
| 897 | L+NiSb \<-> NiSb2 | NiSb: Ni 0.5, Sb 0.5; NiSb2: Ni 0.333333, Sb 0.666667 | experimental | [1] CAO 2008; _cites Leubolt 1986_ | Table 3, p. 6, row 36; `ORC-46IP44UVYD` |  |
| 897 | peritectic: L + (γNiSb) ↔ ζNiSb2 | γNiSb: Ni 0.5, Sb 0.5; ζNiSb2: Ni 0.333333, Sb 0.666667 | experimental | [2] Zhang 2008; _cites Leubolt 1986_ [doi](https://doi.org/10.1002/zaac.19865330226) | Table 3, p. 5, row 11; `ORC-PTPJZ6BPJB` |  |
| 894 | peritectic: L + (γNiSb) ↔ (ζNiSb2) | L: Sb 0.97; γNiSb: Sb 0.52; ζNiSb2: Sb 0.665 | model | [2] Zhang 2008; _cites Cha 1991_ | Table 3, p. 5, row 13; `ORC-3EBLBJWETI` |  |
| 894 | peritectic: L + (γNiSb) ↔ ζNiSb2 | L: Sb 0.96; γNiSb: Sb 0.5354; ζNiSb2: Sb 0.6667 | model | [2] Zhang 2008 | Table 3, p. 5, row 14; `ORC-MOJDUA2DQK` |  |
| 894 | peritectic: L + (γNiSb) ↔ ζNiSb2 | L: Sb 0.97; γNiSb: Sb 0.52; ζNiSb2: Sb 0.662 | experimental | [2] Zhang 2008; _cites Feschotte 1989_ [doi](https://doi.org/10.1016/0022-5088%2889%2990235-x) | Table 3, p. 5, row 10; `ORC-TII4ARV3KU` |  |
| 894 | L \<-> NiSb2+rhomb (Sb) | L: Sb 0.961; NiSb2: Sb 0.667; rhomb (Sb): Sb 1 | model | [1] CAO 2008 | Table 3, p. 6, row 41; `ORC-TT34KUEN7M` |  |
| 894 | L+NiSb \<-> NiSb2 | L: Sb 0.96; NiSb: Sb 0.52; NiSb2: Sb 0.662 | experimental | [1] CAO 2008; _cites Feschotte 1989_ | Table 3, p. 6, row 35; `ORC-ZLNX4UV5OL` |  |
| 890 | eutectic: L ↔ ζNiSb2 + εSb | L: Sb 0.96; ζNiSb2: Sb 0.6667; εSb: Sb 1 | model | [2] Zhang 2008 | Table 3, p. 5, row 20; `ORC-77PUKOHGRN` |  |
| 889 | L+NiSb \<-> NiSb2 | L: Sb 0.95; NiSb: Sb 0.535; NiSb2: Sb 0.713 | experimental | [1] CAO 2008; _cites Shibata 1939_ | Table 3, p. 6, row 34; `ORC-6PCZB3L3JA` |  |
| 889 | eutectic: L ↔ ζNiSb2 + (εSb) | L: Sb 0.96; ζNiSb2: Sb 0.714 | experimental | [2] Zhang 2008; _cites Shibata 1939_ | Table 3, p. 5, row 16; `ORC-EW5XBBDWSM` |  |
| 889 | eutectic: L ↔ ζNiSb2 + (εSb) | ζNiSb2: Ni 0.333333, Sb 0.666667 | experimental | [2] Zhang 2008; _cites Naud 1972_ [doi](https://doi.org/10.1016/0025-5408%2872%2990207-3) | Table 3, p. 5, row 17; `ORC-SVSJTQ5TFM` |  |
| 889 | L \<-> NiSb2+rhomb (Sb) | L: Sb 0.97; NiSb2: Sb 0.722; rhomb (Sb): Sb 0.995 | experimental | [1] CAO 2008; _cites Shibata 1939_ | Table 3, p. 6, row 39; `ORC-XLU4KGGSYU` |  |
| 885 | congruent transformation: (βNi3Sb) ↔ (θNi5Sb2) | (βNi3Sb): Ni 0.75, Sb 0.25; (θNi5Sb2): Sb 0.285 | experimental | [2] Zhang 2008 | Table 3, p. 4, row 30; `ORC-MEAK7VLJRB` |  |
| 885 | L+NiSb \<-> NiSb2 | L: Sb 0.941; NiSb: Sb 0.42; NiSb2: Sb 0.552 | experimental | [1] CAO 2008; _cites Lossew 1906_ | Table 3, p. 6, row 33; `ORC-MWNBZZBHAK` |  |
| 885 | peritectic: L + (γNiSb) ↔ (ζNi4Sb5) | L: Sb 0.9456; γNiSb: Sb 0.4965; ζNi4Sb5: Sb 0.5522; (ζNi4Sb5): Sb 0.5522 | experimental | [2] Zhang 2008; _cites Lossew 1906_ [doi](https://doi.org/10.1002/zaac.19060490107) | Table 3, p. 5, row 7; `ORC-Z3OVAODWTL` |  |
| 884 | eutectic: L ↔ ζNi4Sb5 + (εSb) | L: Sb 0.9456; ζNi4Sb5: Sb 0.5522 | experimental | [2] Zhang 2008; _cites Lossew 1906_ [doi](https://doi.org/10.1002/zaac.19060490107) | Table 3, p. 5, row 15; `ORC-DI3JIDPXWI` |  |
| 884 | L \<-> NiSb2+rhomb (Sb) | L: Sb 0.946; NiSb2: Sb 0.552; rhomb (Sb): Sb 1 | experimental | [1] CAO 2008; _cites Lossew 1906_ | Table 3, p. 6, row 38; `ORC-IRERM2S7K5` |  |
| 883 | peritectic: L + (γNiSb) ↔ ζNiSb2 | γNiSb: Ni 0.5, Sb 0.5; ζNiSb2: Ni 0.333333, Sb 0.666667 | experimental | [2] Zhang 2008; _cites Kjekshus 1977_ [doi](https://doi.org/10.3891/acta.chem.scand.31a-0517) | Table 3, p. 5, row 12; `ORC-YKDUJ7QB42` |  |
| 882 | L \<-> NiSb2+rhomb (Sb) | L: Sb 0.97; NiSb2: Sb 0.665; rhomb (Sb): Sb 0.998 | experimental | [1] CAO 2008; _cites Feschotte 1989_ | Table 3, p. 6, row 40; `ORC-JMNU4Z6R73` |  |
| 882 | eutectic: L ↔ ζNiSb2 + (εSb) | L: Sb 0.98; ζNiSb2: Sb 0.666; εSb: Sb 0.999; (εSb): Sb 0.999 | experimental | [2] Zhang 2008; _cites Feschotte 1989_ [doi](https://doi.org/10.1016/0022-5088%2889%2990235-x) | Table 3, p. 5, row 18; `ORC-SHFXN44LXS` |  |
| 873 | congruent transformation: (βNi3Sb) ↔ (θNi5Sb2) | (βNi3Sb): Ni 0.75, Sb 0.25; (θNi5Sb2): Sb 0.283 | experimental | [2] Zhang 2008; _cites Feschotte 1989_ [doi](https://doi.org/10.1016/0022-5088%2889%2990235-x) | Table 3, p. 4, row 28; `ORC-454SQJIA5Q` |  |
| 873 | congruent transformation: (βNi5Sb2) ↔ (θNi7Sb3) | (βNi5Sb2): Ni 0.714286, Sb 0.285714; (θNi7Sb3): Sb 0.283 | model | [2] Zhang 2008; _cites Cha 1991_ | Table 3, p. 4, row 29; `ORC-Z3FPCKA3F6` |  |
| 865 | polymorphic: (βNi5Sb2) ↔ (β'Ni5Sb2) + (γNiSb) | (βNi5Sb2): Ni 0.714286, Sb 0.285714; (γNiSb): Ni 0.5, Sb 0.5 | experimental | [2] Zhang 2008; _cites Leubolt 1986_ [doi](https://doi.org/10.1002/zaac.19865330226) | Table 3, p. 4, row 35; `ORC-22HD4ATQNL` |  |
| 865 | Ni3Sb_HT+NiSb \<-> Ni7Sb3 | Ni3Sb_HT: Ni 0.75, Sb 0.25; NiSb: Ni 0.5, Sb 0.5; Ni7Sb3: Ni 0.717, Sb 0.283 | experimental | [1] CAO 2008; _cites Leubolt 1986_ | Table 3, p. 6, row 16; `ORC-IRSWHVFQPW` |  |
| 861 | peritectoid: (β'Ni5Sb2) + (γNiSb) ↔ (θNi7Sb3) | (β'Ni5Sb2): Ni 0.714286, Sb 0.285714; (γNiSb): Ni 0.5, Sb 0.5; (θNi7Sb3): Sb 0.3 | experimental | [2] Zhang 2008; _cites Shibata 1939_ | Table 3, p. 4, row 31; `ORC-PVM2IOM6HP` |  |
| 861 | peritectoid: (β'Ni5Sb2) + (γNiSb) ↔ (θNi7Sb3) | (β'Ni5Sb2): Ni 0.714286, Sb 0.285714; (γNiSb): Ni 0.5, Sb 0.5 | experimental | [2] Zhang 2008; _cites Naud 1972_ [doi](https://doi.org/10.1016/0025-5408%2872%2990207-3) | Table 3, p. 4, row 34; `ORC-TBRXMVGB3Q` |  |
| 857 | eutectoid: (βNi3Sb) ↔ θNi5Sb2 + (γNiSb) | (βNi3Sb): Sb 0.292; θNi5Sb2: Sb 0.285; (γNiSb): Sb 0.462 | experimental | [2] Zhang 2008 | Table 3, p. 4, row 38; `ORC-JY52GAWKKM` |  |
| 855 | eutectoid: (βNi3Sb) ↔ θNi5Sb2 + (γNiSb) | (βNi3Sb): Sb 0.288; θNi5Sb2: Sb 0.284; (γNiSb): Sb 0.465 | experimental | [2] Zhang 2008; _cites Feschotte 1989_ [doi](https://doi.org/10.1016/0022-5088%2889%2990235-x) | Table 3, p. 4, row 36; `ORC-6R2IITDQO6` |  |
| 855 | eutectoid: (βNi5Sb2) ↔ θNi7Sb3 + (γNiSb) | (βNi5Sb2): Sb 0.288; θNi7Sb3: Sb 0.284; (γNiSb): Sb 0.465 | model | [2] Zhang 2008; _cites Cha 1991_ | Table 3, p. 4, row 37; `ORC-HDM5DZ7P2Z` |  |
| 855 | Ni3Sb_HT+NiSb \<-> Ni7Sb3 | Ni3Sb_HT: Sb 0.288; NiSb: Sb 0.284; Ni7Sb3: Sb 0.465 | experimental | [1] CAO 2008; _cites Feschotte 1989_ | Table 3, p. 6, row 15; `ORC-JAEP7MHIVX` |  |
| 853 | polymorphic: (βNi5Sb2) ↔ (β'Ni5Sb2) | (βNi5Sb2): Ni 0.714286, Sb 0.285714 | experimental | [2] Zhang 2008; _cites Lossew 1906_ [doi](https://doi.org/10.1002/zaac.19060490107) | Table 3, p. 4, row 26; `ORC-ATBUOKCWC4` |  |
| 853 | Ni3Sb_HT+NiSb \<-> Ni7Sb3 | Ni3Sb_HT: Sb 0.279; NiSb: Sb 0.283; Ni7Sb3: Sb 0.44 | model | [1] CAO 2008 | Table 3, p. 6, row 17; `ORC-QL5C7SSGTA` |  |
| 833 | eutectoid: (βNi5Sb2) ↔ θNi5Sb2 + (γNiSb) | (βNi5Sb2): Sb 0.32; θNi5Sb2: Ni 0.714286, Sb 0.285714; (γNiSb): Ni 0.5, Sb 0.5 | experimental | [2] Zhang 2008; _cites Panteleimonov 1964_ | Table 3, p. 4, row 33; `ORC-ZMQKYBVGJV` |  |
| 829 | Ni3Sb_HT \<-> Ni3Sb+Ni7Sb3 | Ni3Sb_HT: Sb 0.271; Ni3Sb: Sb 0.25; Ni7Sb3: Sb 0.283 | model | [1] CAO 2008 | Table 3, p. 6, row 21; `ORC-36NYPSPVSY` |  |
| 820 | eutectoid: (βNi5Sb2) ↔ (θNi5Sb2) + (γNiSb) | (βNi5Sb2): Ni 0.714286, Sb 0.285714; (θNi5Sb2): Ni 0.714286, Sb 0.285714; (γNiSb): Ni 0.5, Sb 0.5 | experimental | [2] Zhang 2008; _cites Eremenko 1951_ | Table 3, p. 4, row 32; `ORC-Y5LKFOVMU3` |  |
| 808 | eutectoid: (β'Ni5Sb2) ↔ δNi3Sb + (θNi7Sb3) | (β'Ni5Sb2): Ni 0.714286, Sb 0.285714; δNi3Sb: Ni 0.75, Sb 0.25 | experimental | [2] Zhang 2008; _cites Naud 1972_ [doi](https://doi.org/10.1016/0025-5408%2872%2990207-3) | Table 3, p. 4, row 42; `ORC-GGZUNK2UYA` |  |
| 806 | Ni3Sb_HT \<-> Ni3Sb+Ni7Sb3 | Ni3Sb_HT: Sb 0.288; Ni3Sb: Sb 0.254; Ni7Sb3: Sb 0.293 | experimental | [1] CAO 2008; _cites Shibata 1939_ | Table 3, p. 6, row 18; `ORC-OLD4VSV5J3` |  |
| 806 | eutectoid: (β'Ni5Sb2) ↔ (δNi3Sb) + (θNi7Sb3) | (β'Ni5Sb2): Sb 0.283; (δNi3Sb): Ni 0.75, Sb 0.25 | experimental | [2] Zhang 2008; _cites Shibata 1939_ | Table 3, p. 4, row 39; `ORC-PYIN6ZQAOH` |  |
| 803 | Ni3Sb_HT \<-> Ni3Sb+Ni7Sb3 | Ni3Sb_HT: Sb 0.277; Ni3Sb: Sb 0.248; Ni7Sb3: Sb 0.28 | experimental | [1] CAO 2008; _cites Feschotte 1989_ | Table 3, p. 6, row 20; `ORC-4JSF5W36OM` |  |
| 803 | eutectoid: (βNi5Sb2) ↔ (δNi3Sb) + (θNi7Sb3) | (βNi5Sb2): Sb 0.277; (δNi3Sb): Sb 0.25; (θNi7Sb3): Sb 0.28 | model | [2] Zhang 2008; _cites Cha 1991_ | Table 3, p. 4, row 44; `ORC-6KACXGSPYD` |  |
| 803 | eutectoid: (βNi3Sb) ↔ (δNi3Sb) + (θNi5Sb2) | (βNi3Sb): Sb 0.272; (δNi3Sb): Sb 0.2494; (θNi5Sb2): Sb 0.277 | experimental | [2] Zhang 2008 | Table 3, p. 4, row 45; `ORC-ACE5WK67XM` |  |
| 803 | eutectoid: (βNi3Sb) ↔ (δNi3Sb) + (θNi5Sb2) | (βNi3Sb): Sb 0.277; (δNi3Sb): Sb 0.248; (θNi5Sb2): Sb 0.28 | experimental | [2] Zhang 2008; _cites Feschotte 1989_ [doi](https://doi.org/10.1016/0022-5088%2889%2990235-x) | Table 3, p. 4, row 43; `ORC-KJO6NPE6ZI` |  |
| 798 | eutectoid: (βNi5Sb2) ↔ (δNi13Sb4) + (θNi5Sb2) | (βNi5Sb2): Sb 0.2725; (θNi5Sb2): Ni 0.714286, Sb 0.285714 | experimental | [2] Zhang 2008; _cites Panteleimonov 1964_ | Table 3, p. 4, row 41; `ORC-AG6ZAJBBCM` |  |
| 798 | Ni3Sb_HT \<-> Ni3Sb+Ni7Sb3 | Ni3Sb_HT: Sb 0.267; Ni3Sb: Sb 0.241; Ni7Sb3: Sb 0.283 | experimental | [1] CAO 2008; _cites Panteleimonov 1964_ | Table 3, p. 6, row 19; `ORC-Z6N5PUMCTO` |  |
| 768 | eutectoid: (βNi5Sb2) ↔ δNi3Sb + (θNi5Sb2) | (βNi5Sb2): Ni 0.714286, Sb 0.285714; δNi3Sb: Ni 0.75, Sb 0.25; (θNi5Sb2): Ni 0.714286, Sb 0.285714 | experimental | [2] Zhang 2008; _cites Eremenko 1951_ | Table 3, p. 4, row 40; `ORC-ZREGLAIDMZ` |  |
| 733 | congruent transformation: (αNi) ↔ (α'Ni15Sb) | (αNi): Sb 0.063; (α'Ni15Sb): Sb 0.063 | model | [2] Zhang 2008; _cites Cha 1991_ | Table 3, p. 4, row 2; `ORC-L64KPRRFC7` |  |
| 733 | congruent transformation: (αNi) ↔ (α'Ni15Sb) | (αNi): Sb 0.0625; (α'Ni15Sb): Sb 0.0625 | experimental | [2] Zhang 2008; _cites Osawa 1940_ | Table 3, p. 4, row 1; `ORC-WYVXNXPT5R` |  |

## Formation enthalpies

Literature values in kJ/mol-atom where the per-atom basis is known. DFT columns: the lowest-energy entry at the same composition (Materials Project 2026.04.13, OQMD v1.8; different energy references, never averaged), from [dft_parity.json](https://data.orchid-project.org/literature/dft_parity.json).

Table: Enthalpies of formation, Ni–Sb system (4)

| Phase | Compound | Value | T (K) | Class | MP DFT (kJ/mol-atom) | OQMD DFT (kJ/mol-atom) | Source | Location | Quote |
|---|---|---:|---:|---|---:|---:|---|---|---|
| ζ(NiSb) |  | -33.472 kJ/mol (basis unstated) | 298.15 | experimental |  |  | [3] Cao 2013; _cites Korber 1937_ | Table IV, p. 9, row 1; `ORC-ABDJTH4LAW` |  |
| ζ(NiSb) |  | -32.659 kJ/mol (basis unstated) | 1060 | model |  |  | [3] Cao 2013 | Table IV, p. 9, row 4; `ORC-QBMBSSVL7S` |  |
| ζ(NiSb) |  | -32.543 kJ/mol (basis unstated) ± 0.494 | 1060 | experimental |  |  | [3] Cao 2013; _cites Predel 1978_ [doi](https://doi.org/10.1016/0040-6031%2878%2985146-6) | Table IV, p. 9, row 3; `ORC-64UDB5YW55.8b29a9` |  |
| ζ(NiSb) |  | -32.171 kJ/mol (basis unstated) | 298.15 | model |  |  | [3] Cao 2013 | Table IV, p. 9, row 2; `ORC-GQGFCXOC6L` |  |

## Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

1. Z CAO, Y TAKAKU, I OHNUMA, R KAINUMA, H ZHU, K ISHIDA, Thermodynamic assessment of the Ni-Sb binary system, Rare Metals 27, 384-392 (2008). [doi:10.1016/s1001-0521(08)60150-3](https://doi.org/10.1016/s1001-0521%2808%2960150-3)
2. Yubi Zhang, Changrong Li, Zhenmin Du, Cuiping Guo, A thermodynamic assessment of Ni–Sb system, Calphad 32, 378-388 (2008). [doi:10.1016/j.calphad.2008.02.001](https://doi.org/10.1016/j.calphad.2008.02.001)
3. Zhanmin Cao, Wei Xie, Kunpeng Wang, Guangwei Du, Zhiyu Qiao, Thermodynamic Assessment of the In-Ni-Sb System and Predictions for Thermally Stable Contacts to InSb, Journal of Elec Materi 42, 2615-2629 (2013). [doi:10.1007/s11664-013-2599-7](https://doi.org/10.1007/s11664-013-2599-7)

## Please cite

- R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569
- R. Arróyave, J. Saal, D. Shin, ORCHID-Diagrams: calculated binary phase diagrams (version 2026.10), Zenodo (2026). https://doi.org/10.5281/zenodo.23735859
- R. Arróyave, J. Saal, D. Shin, ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD) (version 2026.10), Zenodo (2026). https://doi.org/10.5281/zenodo.23735891
- R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0).

Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

```bibtex
@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_phase_diagrams_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Diagrams: calculated binary phase diagrams}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735859},
  url       = {https://doi.org/10.5281/zenodo.23735859}
}

@misc{orchid_hulls_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD)}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735891},
  url       = {https://doi.org/10.5281/zenodo.23735891}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}
```

---

Derived data CC BY 4.0 ([licence](https://creativecommons.org/licenses/by/4.0/)): cite ORCHID ([CITATION.cff](https://data.orchid-project.org/CITATION.cff)) and the original sources. Quotes are short excerpts kept so that each value can be checked; they remain under the publishers' copyright and are not relicensed. Source papers, page images and full text are not redistributed. Field reference: [SCHEMA.md](https://data.orchid-project.org/literature/SCHEMA.md). Machine-readable guide: [llms.txt](https://data.orchid-project.org/llms.txt). Found an error? The report link of a value (Markdown: its id, ORC-..., in the Location column) opens a pre-filled GitHub issue, https://github.com/orchid-calphad/orchid-data/issues/new?template=report-value-error.yml&record_id=\<id>, carrying only the record id, source and value; [how to contribute](https://orchid-project.org/contribute/).