Ni–V system
30 accepted literature values from 2 paper(s) (experimental 14, model 16); 6 calculated phase diagram(s). 5 further extracted value(s) not accepted by the reader-agreement checks are only in the JSON/CSV.
Data: JSON · CSV · interactive explorer · interactive phase diagram · phases (12) · papers (bibliography) · Markdown
| Evidence class | Values |
|---|---|
| experimental | 14 |
| model | 16 |
| Property group | Values |
|---|---|
| invariant reaction | 24 |
| phase transition | 6 |
Calculated phase diagrams
Binary phase diagrams calculated with pycalphad 0.11.2 from the SGTE binary collection (Hallstedt 2025, CC BY 4.0). Evidence class: model.
| TDB file | Assessment | SHA-256 | Links |
|---|---|---|---|
| NiV-01Wat.tdb | A. Watson, F.H. Hayes, J. Alloys Compd., 320, 199-206(2001). doi:10.1016/S0925-8388(00)01472-9 | cd99dd38bf6fcab8c72cb4c1623eccb56a6377ca7b6984ec6ac5c5f023de394c | viewer · TDB · JSON |
| NiV-10Kab.tdb | E.G. Kabanova, V.N. Kuznetsov, G.P. Zhmurko, Russ. J. Phys. Chem., 84, 755-59(2010). doi:10.1134/S0036024410050080 | 328d1c8d6ac9314a111139be3b2225af4295df8fa685ced097d18a3bd50f761e | viewer · TDB · JSON |
| NiV-18Pan.tdb | Y. Pan, Y. Du, J. Lv, T. Liang, F. Luo, Thermochim. Acta, 661, 137-46(2018). doi:10.1016/j.tca.2018.01.020 | 18c5215f577364d8da9340202710b6a96b70a423328eb2df76a3390115bbae02 | viewer · TDB · JSON |
| NiV-19Noo-simple.tdb | M. Noori, B. Hallstedt, Calphad, 65, 273-81(2019). doi:10.1016/j.calphad.2019.03.010 | 280f505b819a27e37c999be738c4ea0c63e8e2dde3830ca95cecac085f263116 | viewer · TDB · JSON |
| NiV-19Zou.tdb | L. Zou, C. Guo, C. Li, Z. Du, Calphad, 64, 97-114(2019). doi:10.1016/j.calphad.2018.11.006 | cab38dd7f44a0129b6362909d523c4ec4378a014b4ed1037f5783713c15cbd66 | viewer · TDB · JSON |
| NiV-98Kor-LB.tdb | J. Korb, K. Hack, COST 507, Final report round 2, 1998. | 7b4eb525c523269030efb73f6ed579c4d2e480001cba28f6e676c9927ed5ca4e | viewer · TDB · JSON |
| TDB file | T (K) | Phases at the invariant |
|---|---|---|
| NiV-01Wat.tdb | 1553.16 | LIQUID (x(V) 0.61788) + SIGMA_OLD (x(V) 0.66897) + BCC_A2 (x(V) 0.75906) |
| NiV-01Wat.tdb | 1478.21 | FCC_A1 (x(V) 0.419) + LIQUID (x(V) 0.4973) + SIGMA_OLD (x(V) 0.56006) |
| NiV-01Wat.tdb | 1173.28 | NI3V_D022 (x(V) 0.26632) + FCC_A1 (x(V) 0.30366) + NI2V (x(V) 0.33333) |
| NiV-01Wat.tdb | 1173 | SIGMA_OLD (x(V) 0.71918) + NIV3_A15 (x(V) 0.775) + BCC_A2 (x(V) 0.89888) |
| NiV-01Wat.tdb | 1173 | SIGMA_OLD (x(V) 0.71917) + NIV3_A15 (x(V) 0.775) + BCC_A2 (x(V) 0.89884) |
| NiV-01Wat.tdb | 1156.68 | NI2V (x(V) 0.33333) + FCC_A1 (x(V) 0.37505) + SIGMA_OLD (x(V) 0.53199) |
| NiV-01Wat.tdb | 1156.68 | NI2V (x(V) 0.33333) + FCC_A1 (x(V) 0.37506) + SIGMA_OLD (x(V) 0.53199) |
| NiV-01Wat.tdb | 931.9 | SIGMA_D8B (x(V) 0.67006) + SIGMA_OLD (x(V) 0.72522) + NIV3_A15 (x(V) 0.775) |
| NiV-01Wat.tdb | 931.9 | SIGMA_D8B (x(V) 0.67006) + SIGMA_OLD (x(V) 0.72524) + NIV3_A15 (x(V) 0.775) |
| NiV-01Wat.tdb | 917.44 | NI2V (x(V) 0.33333) + SIGMA_OLD (x(V) 0.55061) + SIGMA_D8B (x(V) 0.66582) |
| NiV-01Wat.tdb | 853.27 | SIGMA_D8B (x(V) 0.67078) + NIV3_A15 (x(V) 0.775) + BCC_A2 (x(V) 0.96148) |
| NiV-01Wat.tdb | 853.27 | SIGMA_D8B (x(V) 0.67078) + NIV3_A15 (x(V) 0.775) + BCC_A2 (x(V) 0.96149) |
| NiV-01Wat.tdb | 796.38 | NI2V (x(V) 0.33333) + SIGMA_D8B#2 (x(V) 0.46679) + SIGMA_D8B (x(V) 0.66635) |
| NiV-01Wat.tdb | 796.38 | NI2V (x(V) 0.33333) + SIGMA_D8B#2 (x(V) 0.46679) + SIGMA_D8B (x(V) 0.66635) |
| NiV-01Wat.tdb | 584.06 | NI3V_D022 (x(V) 0.24996) + NI2V (x(V) 0.33333) + SIGMA_D8B (x(V) 0.46666) |
| NiV-01Wat.tdb | 584.06 | NI3V_D022 (x(V) 0.24996) + NI2V (x(V) 0.33333) + SIGMA_D8B (x(V) 0.46666) |
| NiV-10Kab.tdb | 1516.12 | LIQUID (x(V) 0.59463) + SIGMA_OLD (x(V) 0.67689) + BCC_A2 (x(V) 0.74945) |
| NiV-10Kab.tdb | 1459.93 | FCC_A1 (x(V) 0.46504) + LIQUID (x(V) 0.52125) + SIGMA_OLD (x(V) 0.64611) |
| NiV-10Kab.tdb | 1186.78 | NI3V_D022 (x(V) 0.26775) + FCC_A1 (x(V) 0.3156) + NI2V (x(V) 0.33333) |
| NiV-10Kab.tdb | 1186.78 | NI3V_D022 (x(V) 0.26776) + FCC_A1 (x(V) 0.31568) + NI2V (x(V) 0.33333) |
| NiV-10Kab.tdb | 1167.47 | NI2V (x(V) 0.33333) + FCC_A1 (x(V) 0.37117) + SIGMA_OLD (x(V) 0.60493) |
| NiV-10Kab.tdb | 1167.47 | NI2V (x(V) 0.33333) + FCC_A1 (x(V) 0.3712) + SIGMA_OLD (x(V) 0.60494) |
| NiV-10Kab.tdb | 623.1 | NI3V_D022 (x(V) 0.25052) + NI2V (x(V) 0.33333) + SIGMA_OLD (x(V) 0.60313) |
| NiV-10Kab.tdb | 623.1 | NI3V_D022 (x(V) 0.25052) + NI2V (x(V) 0.33333) + SIGMA_OLD (x(V) 0.60313) |
| NiV-10Kab.tdb | 472.27 | FCC_A1#2 (x(V) 0.01896) + FCC_A1 (x(V) 0.04674) + NI3V_D022 (x(V) 0.24241) |
| NiV-18Pan.tdb | 1549.12 | LIQUID (x(V) 0.62906) + SIGMA_D8B (x(V) 0.67925) + BCC_A2 (x(V) 0.76038) |
| NiV-18Pan.tdb | 1476.86 | FCC_A1 (x(V) 0.42685) + LIQUID (x(V) 0.50564) + SIGMA_D8B (x(V) 0.55568) |
| NiV-18Pan.tdb | 1178.99 | NI3V_D022 (x(V) 0.26683) + FCC_A1 (x(V) 0.30789) + NI2V (x(V) 0.33333) |
| NiV-18Pan.tdb | 1168.37 | SIGMA_D8B (x(V) 0.74223) + NI2V7_A15 (x(V) 0.77778) + BCC_A2 (x(V) 0.89629) |
| NiV-18Pan.tdb | 1168.37 | SIGMA_D8B (x(V) 0.74224) + NI2V7_A15 (x(V) 0.77778) + BCC_A2 (x(V) 0.89631) |
| NiV-18Pan.tdb | 1157.4 | NI2V (x(V) 0.33333) + FCC_A1 (x(V) 0.36745) + SIGMA_D8B (x(V) 0.53203) |
| NiV-18Pan.tdb | 1157.4 | NI2V (x(V) 0.33333) + FCC_A1 (x(V) 0.36743) + SIGMA_D8B (x(V) 0.53203) |
| NiV-19Noo-simple.tdb | 1552.4 | LIQUID (x(V) 0.63262) + SIGMA_D8B (x(V) 0.68257) + BCC_A2 (x(V) 0.74834) |
| NiV-19Noo-simple.tdb | 1477.9 | FCC_A1 (x(V) 0.41453) + LIQUID (x(V) 0.50291) + SIGMA_D8B (x(V) 0.55914) |
| NiV-19Noo-simple.tdb | 1193.01 | NI3V_D022 (x(V) 0.26465) + FCC_A1 (x(V) 0.32612) + NI2V (x(V) 0.33333) |
| NiV-19Noo-simple.tdb | 1193.01 | NI3V_D022 (x(V) 0.26466) + FCC_A1 (x(V) 0.32617) + NI2V (x(V) 0.33333) |
| NiV-19Noo-simple.tdb | 1173.29 | SIGMA_D8B (x(V) 0.75047) + NIV3_A15 (x(V) 0.77105) + BCC_A2 (x(V) 0.90196) |
| NiV-19Noo-simple.tdb | 1151.47 | NI2V (x(V) 0.33333) + FCC_A1 (x(V) 0.38517) + SIGMA_D8B (x(V) 0.54356) |
| NiV-19Noo-simple.tdb | 1151.47 | NI2V (x(V) 0.33333) + FCC_A1 (x(V) 0.38515) + SIGMA_D8B (x(V) 0.54355) |
| NiV-19Noo-simple.tdb | 678.03 | FCC_A1 (x(V) 0.1105) + NI8V (x(V) 0.11111) + NI3V_D022 (x(V) 0.22869) |
| NiV-19Noo-simple.tdb | 539.04 | NI2V (x(V) 0.33333) + SIGMA_D8B (x(V) 0.62473) + NIV3_A15 (x(V) 0.75) |
| NiV-19Noo-simple.tdb | 539.04 | NI2V (x(V) 0.33333) + SIGMA_D8B (x(V) 0.62473) + NIV3_A15 (x(V) 0.75) |
| NiV-19Noo-simple.tdb | 539.04 | NI2V (x(V) 0.33333) + SIGMA_D8B (x(V) 0.62474) + NIV3_A15 (x(V) 0.75) |
| NiV-19Zou.tdb | 1553 | LIQUID (x(V) 0.6178) + SIGMA_D8B (x(V) 0.68003) + BCC_A2 (x(V) 0.75898) |
| NiV-19Zou.tdb | 1474.18 | FCC_A1 (x(V) 0.41304) + LIQUID (x(V) 0.49306) + SIGMA_D8B (x(V) 0.54693) |
| NiV-19Zou.tdb | 1175.05 | NI3V_D022 (x(V) 0.27095) + FCC_A1 (x(V) 0.30913) + NI2V (x(V) 0.33333) |
| NiV-19Zou.tdb | 1172.99 | SIGMA_D8B (x(V) 0.72983) + NIV3_A15 (x(V) 0.75) + BCC_A2 (x(V) 0.895) |
| NiV-19Zou.tdb | 1172.99 | SIGMA_D8B (x(V) 0.72983) + NIV3_A15 (x(V) 0.75) + BCC_A2 (x(V) 0.89504) |
| NiV-19Zou.tdb | 1163.73 | NI2V (x(V) 0.33333) + FCC_A1 (x(V) 0.36877) + SIGMA_D8B (x(V) 0.54108) |
| NiV-98Kor-LB.tdb | 1485.68 | FCC_A1 (x(V) 0.44308) + LIQUID (x(V) 0.50143) + SIGMA_OLD (x(V) 0.57803) |
| NiV-98Kor-LB.tdb | 1175.55 | NI3V_D022 (x(V) 0.25) + FCC_A1 (x(V) 0.3127) + NI2V (x(V) 0.33333) |
| NiV-98Kor-LB.tdb | 1175.54 | NI3V_D022 (x(V) 0.25) + FCC_A1 (x(V) 0.31284) + NI2V (x(V) 0.33333) |
| NiV-98Kor-LB.tdb | 1171.92 | SIGMA_OLD (x(V) 0.72741) + NI2V7_A15 (x(V) 0.77778) + BCC_A2 (x(V) 0.92245) |
| NiV-98Kor-LB.tdb | 1150.88 | NI2V (x(V) 0.33333) + FCC_A1 (x(V) 0.36843) + SIGMA_OLD (x(V) 0.55376) |
| NiV-98Kor-LB.tdb | 929.7 | NI2V (x(V) 0.33333) + SIGMA_D8B (x(V) 0.56716) + SIGMA_OLD (x(V) 0.58054) |
| NiV-98Kor-LB.tdb | 929.7 | NI2V (x(V) 0.33333) + SIGMA_D8B (x(V) 0.56701) + SIGMA_OLD (x(V) 0.58036) |
| NiV-98Kor-LB.tdb | 386.07 | FCC_A1 (x(V) 0.14327) + NI3V_D022 (x(V) 0.25) + NI2V (x(V) 0.33333) |
| NiV-98Kor-LB.tdb | 386.07 | FCC_A1 (x(V) 0.14325) + NI3V_D022 (x(V) 0.25) + NI2V (x(V) 0.33333) |
Convex hulls: Materials Project DFT hull · OQMD DFT hull · CALPHAD hull NiV-01Wat · CALPHAD hull NiV-10Kab · CALPHAD hull NiV-18Pan · CALPHAD hull NiV-19Zou · CALPHAD hull NiV-98Kor-LB
Invariant reactions (literature)
| T (K) | Reaction / phases | Compositions (mole fraction) | Class | Source | Location | Quote |
|---|---|---|---|---|---|---|
| 1553.15 | L + bcc-(V) = σ | L: V 0.615; bcc-(V): V 0.76; σ: V 0.67 | experimental | [1] Pan 2018 cites Stevens 1970 doi | Table 3, p. 6, row 4 report | |
| 1553 | peritectic: L + bcc -> σ | L: V 0.615; bcc: V 0.76; σ: V 0.67 | experimental | [2] Kabanova 2010 cites Smith 1982 | Table 1, p. 3, row 3 report | |
| 1551 | peritectic: L + bcc -> σ | L: V 0.6118; bcc: V 0.7643; σ: V 0.649 | model | [2] Kabanova 2010 | Table 1, p. 3, row 4 report | |
| 1549.15 | L + bcc-(V) = σ | L: V 0.629; bcc-(V): V 0.76; σ: V 0.68 | model | [1] Pan 2018 | Table 3, p. 6, row 3 report | |
| 1477.15 | L = fcc-(Ni) + σ | L: V 0.506; fcc-(Ni): V 0.427; σ: V 0.556 | model | [1] Pan 2018 | Table 3, p. 6, row 1 report | |
| 1476.5 | eutectic: L -> fcc + σ | L: V 0.485; fcc: V 0.4305; σ: V 0.5901 | model | [2] Kabanova 2010 | Table 1, p. 3, row 2 report | |
| 1475.15 | L = fcc-(Ni) + σ | L: V 0.51; fcc-(Ni): V 0.43; σ: V 0.55 | experimental | [1] Pan 2018 cites Stevens 1970 doi | Table 3, p. 6, row 2 report | |
| 1475 | eutectic: L -> fcc + σ | L: V 0.512; fcc: V 0.43; σ: V 0.56 | experimental | [2] Kabanova 2010 cites Smith 1982 | Table 1, p. 3, row 1 report | |
| 1325.15 | polymorphic: fcc-(Ni) = Ni3V | fcc-(Ni): V 0.247; Ni3V: V 0.247 | model | [1] Pan 2018 | Table 3, p. 6, row 11 report | |
| 1318.15 | polymorphic: fcc-(Ni) = Ni3V | fcc-(Ni): V 0.25; Ni3V: V 0.25 | experimental | [1] Pan 2018 cites Stevens 1970 doi | Table 3, p. 6, row 12 report | |
| 1206.15 | polymorphic: fcc-(Ni) = Ni2V | fcc-(Ni): V 0.333; Ni2V: V 0.333 | model | [1] Pan 2018 | Table 3, p. 6, row 13 report | |
| 1195.15 | polymorphic: fcc-(Ni) = Ni2V | fcc-(Ni): V 0.333; Ni2V: V 0.333 | experimental | [1] Pan 2018 cites Stevens 1970 doi | Table 3, p. 6, row 14 report | |
| 1183 | eutectoid: fcc -> Ni3V + Ni2V | fcc: V 0.323; Ni3V: V 0.283; Ni2V: V 0.333 | model | [2] Kabanova 2010 | Table 1, p. 3, row 10 report | |
| 1181.15 | fcc-(Ni) = Ni3V + Ni2V | fcc-(Ni): V 0.325; Ni3V: V 0.285; Ni2V: V 0.33 | experimental | [1] Pan 2018 cites Stevens 1970 doi | Table 3, p. 6, row 6 report | |
| 1181 | eutectoid: fcc -> Ni3V + Ni2V | fcc: V 0.325; Ni3V: V 0.285; Ni2V: V 0.33 | experimental | [2] Kabanova 2010 cites Smith 1982 | Table 1, p. 3, row 9 report | |
| 1178.5 | eutectoid: fcc -> Ni2V + σ | fcc: V 0.3675; Ni2V: V 0.333; σ: V 0.5732 | model | [2] Kabanova 2010 | Table 1, p. 3, row 12 report | |
| 1177.15 | fcc-(Ni) = Ni3V + Ni2V | fcc-(Ni): V 0.31; Ni3V: V 0.267; Ni2V: V 0.333 | model | [1] Pan 2018 | Table 3, p. 6, row 5 report | |
| 1175 | peritectoid: σ + bcc -> NiV3 | σ: V 0.7274; bcc: V 0.892; NiV3: V 0.75 | model | [2] Kabanova 2010 | Table 1, p. 3, row 14 report | |
| 1173.15 | σ + bcc-(V) = Ni2V7 | σ: V 0.735; bcc-(V): V 0.895; Ni2V7: V 0.778 | experimental | [1] Pan 2018 cites Stevens 1970 doi | Table 3, p. 6, row 10 report | |
| 1173.15 | σ + bcc-(V) = Ni2V7 | σ: V 0.742; bcc-(V): V 0.895; Ni2V7: V 0.778 | model | [1] Pan 2018 | Table 3, p. 6, row 9 report | |
| 1173 | peritectoid: σ + bcc -> NiV3 | σ: V 0.735; bcc: V 0.895; NiV3: V 0.778 | experimental | [2] Kabanova 2010 cites Smith 1982 | Table 1, p. 3, row 13 report | |
| 1163.15 | fcc-(Ni) = Ni2V + σ | fcc-(Ni): V 0.385; Ni2V: V 0.33; σ: V 0.55 | experimental | [1] Pan 2018 cites Stevens 1970 doi | Table 3, p. 6, row 8 report | |
| 1163 | eutectoid: fcc -> Ni2V + σ | fcc: V 0.365; Ni2V: V 0.33; σ: V 0.56 | experimental | [2] Kabanova 2010 cites Smith 1982 | Table 1, p. 3, row 11 report | |
| 1155.15 | fcc-(Ni) = Ni2V + σ | fcc-(Ni): V 0.367; Ni2V: V 0.333; σ: V 0.532 | model | [1] Pan 2018 | Table 3, p. 6, row 7 report |
Other properties
Phase transition (6)
| Property | Value | T (K) | Phases / composition | Class | Source | Location | Quote |
|---|---|---|---|---|---|---|---|
| Phase transition | 1192 K | 1192 | other: fcc -> Ni2V fcc: V 0.333; Ni2V: V 0.333 | model | [2] Kabanova 2010 | Table 1, p. 3, row 8 report | |
| Phase transition | 1195 K | 1195 | fcc + Ni3V | model | [2] Kabanova 2010 cites Smith 1982 | p. 3 report | The Ni3V phase was, however, exper imentally ascertained to be formed in the Ni-V sys tem by the ordering of fcc solid solution based on nickel at 1195 K [1]. |
| Phase transition | 1195 K | 1195 | other: fcc -> Ni2V fcc: V 0.333; Ni2V: V 0.333 | experimental | [2] Kabanova 2010 cites Smith 1982 | Table 1, p. 3, row 7 report | |
| Phase transition | 1303.5 K | 1303.5 | other: fcc -> Ni3V fcc: V 0.258; Ni3V: V 0.258 | model | [2] Kabanova 2010 | Table 1, p. 3, row 6 report | |
| Phase transition | 1318 K | 1318 | other: fcc -> Ni3V fcc: V 0.25; Ni3V: V 0.25 | experimental | [2] Kabanova 2010 cites Smith 1982 | Table 1, p. 3, row 5 report | |
| Phase transition | 6011 K | 6011 | phase separation of the liquid phase | model | [1] Pan 2018 | p. 6 report | According to the present calculation, there are phase decompositions of the Ni2V phase at 291 K and a phase separation of the liquid phase at 6011 K, as can be seen in Fig. 2. |
Sources
Reporting papers the values were read from (a value cited from another work names that work in its row).
- Yafei Pan, Yong Du, Jian Lv, Tongxiang Liang, Fenghua Luo, Reassessment of the Ni–V system and a new thermodynamic modeling of the Mo–Ni–V system, Thermochimica Acta 661, 137-146 (2018). doi:10.1016/j.tca.2018.01.020
- E. G. Kabanova, V. N. Kuznetsov, G. P. Zhmurko, Thermodynamic modeling of phase equilibria in the Ni-V system, Russ. J. Phys. Chem. 84, 755-759 (2010). doi:10.1134/s0036024410050080