Ni–V system

30 accepted literature values from 2 paper(s) (experimental 14, model 16); 6 calculated phase diagram(s). 5 further extracted value(s) not accepted by the reader-agreement checks are only in the JSON/CSV.

Data: JSON · CSV · interactive explorer · interactive phase diagram · phases (12) · papers (bibliography) · Markdown

Accepted values by evidence class
Evidence classValues
experimental14
model16
Accepted values by property group
Property groupValues
invariant reaction24
phase transition6

Calculated phase diagrams

Binary phase diagrams calculated with pycalphad 0.11.2 from the SGTE binary collection (Hallstedt 2025, CC BY 4.0). Evidence class: model.

Assessments with a calculated phase diagram
TDB fileAssessmentSHA-256Links
NiV-01Wat.tdbA. Watson, F.H. Hayes, J. Alloys Compd., 320, 199-206(2001). doi:10.1016/S0925-8388(00)01472-9cd99dd38bf6fcab8c72cb4c1623eccb56a6377ca7b6984ec6ac5c5f023de394cviewer · TDB · JSON
NiV-10Kab.tdbE.G. Kabanova, V.N. Kuznetsov, G.P. Zhmurko, Russ. J. Phys. Chem., 84, 755-59(2010). doi:10.1134/S0036024410050080328d1c8d6ac9314a111139be3b2225af4295df8fa685ced097d18a3bd50f761eviewer · TDB · JSON
NiV-18Pan.tdbY. Pan, Y. Du, J. Lv, T. Liang, F. Luo, Thermochim. Acta, 661, 137-46(2018). doi:10.1016/j.tca.2018.01.02018c5215f577364d8da9340202710b6a96b70a423328eb2df76a3390115bbae02viewer · TDB · JSON
NiV-19Noo-simple.tdbM. Noori, B. Hallstedt, Calphad, 65, 273-81(2019). doi:10.1016/j.calphad.2019.03.010280f505b819a27e37c999be738c4ea0c63e8e2dde3830ca95cecac085f263116viewer · TDB · JSON
NiV-19Zou.tdbL. Zou, C. Guo, C. Li, Z. Du, Calphad, 64, 97-114(2019). doi:10.1016/j.calphad.2018.11.006cab38dd7f44a0129b6362909d523c4ec4378a014b4ed1037f5783713c15cbd66viewer · TDB · JSON
NiV-98Kor-LB.tdbJ. Korb, K. Hack, COST 507, Final report round 2, 1998.7b4eb525c523269030efb73f6ed579c4d2e480001cba28f6e676c9927ed5ca4eviewer · TDB · JSON
Calculated three-phase invariants (model, mole fraction of the second component)
TDB fileT (K)Phases at the invariant
NiV-01Wat.tdb1553.16LIQUID (x(V) 0.61788) + SIGMA_OLD (x(V) 0.66897) + BCC_A2 (x(V) 0.75906)
NiV-01Wat.tdb1478.21FCC_A1 (x(V) 0.419) + LIQUID (x(V) 0.4973) + SIGMA_OLD (x(V) 0.56006)
NiV-01Wat.tdb1173.28NI3V_D022 (x(V) 0.26632) + FCC_A1 (x(V) 0.30366) + NI2V (x(V) 0.33333)
NiV-01Wat.tdb1173SIGMA_OLD (x(V) 0.71918) + NIV3_A15 (x(V) 0.775) + BCC_A2 (x(V) 0.89888)
NiV-01Wat.tdb1173SIGMA_OLD (x(V) 0.71917) + NIV3_A15 (x(V) 0.775) + BCC_A2 (x(V) 0.89884)
NiV-01Wat.tdb1156.68NI2V (x(V) 0.33333) + FCC_A1 (x(V) 0.37505) + SIGMA_OLD (x(V) 0.53199)
NiV-01Wat.tdb1156.68NI2V (x(V) 0.33333) + FCC_A1 (x(V) 0.37506) + SIGMA_OLD (x(V) 0.53199)
NiV-01Wat.tdb931.9SIGMA_D8B (x(V) 0.67006) + SIGMA_OLD (x(V) 0.72522) + NIV3_A15 (x(V) 0.775)
NiV-01Wat.tdb931.9SIGMA_D8B (x(V) 0.67006) + SIGMA_OLD (x(V) 0.72524) + NIV3_A15 (x(V) 0.775)
NiV-01Wat.tdb917.44NI2V (x(V) 0.33333) + SIGMA_OLD (x(V) 0.55061) + SIGMA_D8B (x(V) 0.66582)
NiV-01Wat.tdb853.27SIGMA_D8B (x(V) 0.67078) + NIV3_A15 (x(V) 0.775) + BCC_A2 (x(V) 0.96148)
NiV-01Wat.tdb853.27SIGMA_D8B (x(V) 0.67078) + NIV3_A15 (x(V) 0.775) + BCC_A2 (x(V) 0.96149)
NiV-01Wat.tdb796.38NI2V (x(V) 0.33333) + SIGMA_D8B#2 (x(V) 0.46679) + SIGMA_D8B (x(V) 0.66635)
NiV-01Wat.tdb796.38NI2V (x(V) 0.33333) + SIGMA_D8B#2 (x(V) 0.46679) + SIGMA_D8B (x(V) 0.66635)
NiV-01Wat.tdb584.06NI3V_D022 (x(V) 0.24996) + NI2V (x(V) 0.33333) + SIGMA_D8B (x(V) 0.46666)
NiV-01Wat.tdb584.06NI3V_D022 (x(V) 0.24996) + NI2V (x(V) 0.33333) + SIGMA_D8B (x(V) 0.46666)
NiV-10Kab.tdb1516.12LIQUID (x(V) 0.59463) + SIGMA_OLD (x(V) 0.67689) + BCC_A2 (x(V) 0.74945)
NiV-10Kab.tdb1459.93FCC_A1 (x(V) 0.46504) + LIQUID (x(V) 0.52125) + SIGMA_OLD (x(V) 0.64611)
NiV-10Kab.tdb1186.78NI3V_D022 (x(V) 0.26775) + FCC_A1 (x(V) 0.3156) + NI2V (x(V) 0.33333)
NiV-10Kab.tdb1186.78NI3V_D022 (x(V) 0.26776) + FCC_A1 (x(V) 0.31568) + NI2V (x(V) 0.33333)
NiV-10Kab.tdb1167.47NI2V (x(V) 0.33333) + FCC_A1 (x(V) 0.37117) + SIGMA_OLD (x(V) 0.60493)
NiV-10Kab.tdb1167.47NI2V (x(V) 0.33333) + FCC_A1 (x(V) 0.3712) + SIGMA_OLD (x(V) 0.60494)
NiV-10Kab.tdb623.1NI3V_D022 (x(V) 0.25052) + NI2V (x(V) 0.33333) + SIGMA_OLD (x(V) 0.60313)
NiV-10Kab.tdb623.1NI3V_D022 (x(V) 0.25052) + NI2V (x(V) 0.33333) + SIGMA_OLD (x(V) 0.60313)
NiV-10Kab.tdb472.27FCC_A1#2 (x(V) 0.01896) + FCC_A1 (x(V) 0.04674) + NI3V_D022 (x(V) 0.24241)
NiV-18Pan.tdb1549.12LIQUID (x(V) 0.62906) + SIGMA_D8B (x(V) 0.67925) + BCC_A2 (x(V) 0.76038)
NiV-18Pan.tdb1476.86FCC_A1 (x(V) 0.42685) + LIQUID (x(V) 0.50564) + SIGMA_D8B (x(V) 0.55568)
NiV-18Pan.tdb1178.99NI3V_D022 (x(V) 0.26683) + FCC_A1 (x(V) 0.30789) + NI2V (x(V) 0.33333)
NiV-18Pan.tdb1168.37SIGMA_D8B (x(V) 0.74223) + NI2V7_A15 (x(V) 0.77778) + BCC_A2 (x(V) 0.89629)
NiV-18Pan.tdb1168.37SIGMA_D8B (x(V) 0.74224) + NI2V7_A15 (x(V) 0.77778) + BCC_A2 (x(V) 0.89631)
NiV-18Pan.tdb1157.4NI2V (x(V) 0.33333) + FCC_A1 (x(V) 0.36745) + SIGMA_D8B (x(V) 0.53203)
NiV-18Pan.tdb1157.4NI2V (x(V) 0.33333) + FCC_A1 (x(V) 0.36743) + SIGMA_D8B (x(V) 0.53203)
NiV-19Noo-simple.tdb1552.4LIQUID (x(V) 0.63262) + SIGMA_D8B (x(V) 0.68257) + BCC_A2 (x(V) 0.74834)
NiV-19Noo-simple.tdb1477.9FCC_A1 (x(V) 0.41453) + LIQUID (x(V) 0.50291) + SIGMA_D8B (x(V) 0.55914)
NiV-19Noo-simple.tdb1193.01NI3V_D022 (x(V) 0.26465) + FCC_A1 (x(V) 0.32612) + NI2V (x(V) 0.33333)
NiV-19Noo-simple.tdb1193.01NI3V_D022 (x(V) 0.26466) + FCC_A1 (x(V) 0.32617) + NI2V (x(V) 0.33333)
NiV-19Noo-simple.tdb1173.29SIGMA_D8B (x(V) 0.75047) + NIV3_A15 (x(V) 0.77105) + BCC_A2 (x(V) 0.90196)
NiV-19Noo-simple.tdb1151.47NI2V (x(V) 0.33333) + FCC_A1 (x(V) 0.38517) + SIGMA_D8B (x(V) 0.54356)
NiV-19Noo-simple.tdb1151.47NI2V (x(V) 0.33333) + FCC_A1 (x(V) 0.38515) + SIGMA_D8B (x(V) 0.54355)
NiV-19Noo-simple.tdb678.03FCC_A1 (x(V) 0.1105) + NI8V (x(V) 0.11111) + NI3V_D022 (x(V) 0.22869)
NiV-19Noo-simple.tdb539.04NI2V (x(V) 0.33333) + SIGMA_D8B (x(V) 0.62473) + NIV3_A15 (x(V) 0.75)
NiV-19Noo-simple.tdb539.04NI2V (x(V) 0.33333) + SIGMA_D8B (x(V) 0.62473) + NIV3_A15 (x(V) 0.75)
NiV-19Noo-simple.tdb539.04NI2V (x(V) 0.33333) + SIGMA_D8B (x(V) 0.62474) + NIV3_A15 (x(V) 0.75)
NiV-19Zou.tdb1553LIQUID (x(V) 0.6178) + SIGMA_D8B (x(V) 0.68003) + BCC_A2 (x(V) 0.75898)
NiV-19Zou.tdb1474.18FCC_A1 (x(V) 0.41304) + LIQUID (x(V) 0.49306) + SIGMA_D8B (x(V) 0.54693)
NiV-19Zou.tdb1175.05NI3V_D022 (x(V) 0.27095) + FCC_A1 (x(V) 0.30913) + NI2V (x(V) 0.33333)
NiV-19Zou.tdb1172.99SIGMA_D8B (x(V) 0.72983) + NIV3_A15 (x(V) 0.75) + BCC_A2 (x(V) 0.895)
NiV-19Zou.tdb1172.99SIGMA_D8B (x(V) 0.72983) + NIV3_A15 (x(V) 0.75) + BCC_A2 (x(V) 0.89504)
NiV-19Zou.tdb1163.73NI2V (x(V) 0.33333) + FCC_A1 (x(V) 0.36877) + SIGMA_D8B (x(V) 0.54108)
NiV-98Kor-LB.tdb1485.68FCC_A1 (x(V) 0.44308) + LIQUID (x(V) 0.50143) + SIGMA_OLD (x(V) 0.57803)
NiV-98Kor-LB.tdb1175.55NI3V_D022 (x(V) 0.25) + FCC_A1 (x(V) 0.3127) + NI2V (x(V) 0.33333)
NiV-98Kor-LB.tdb1175.54NI3V_D022 (x(V) 0.25) + FCC_A1 (x(V) 0.31284) + NI2V (x(V) 0.33333)
NiV-98Kor-LB.tdb1171.92SIGMA_OLD (x(V) 0.72741) + NI2V7_A15 (x(V) 0.77778) + BCC_A2 (x(V) 0.92245)
NiV-98Kor-LB.tdb1150.88NI2V (x(V) 0.33333) + FCC_A1 (x(V) 0.36843) + SIGMA_OLD (x(V) 0.55376)
NiV-98Kor-LB.tdb929.7NI2V (x(V) 0.33333) + SIGMA_D8B (x(V) 0.56716) + SIGMA_OLD (x(V) 0.58054)
NiV-98Kor-LB.tdb929.7NI2V (x(V) 0.33333) + SIGMA_D8B (x(V) 0.56701) + SIGMA_OLD (x(V) 0.58036)
NiV-98Kor-LB.tdb386.07FCC_A1 (x(V) 0.14327) + NI3V_D022 (x(V) 0.25) + NI2V (x(V) 0.33333)
NiV-98Kor-LB.tdb386.07FCC_A1 (x(V) 0.14325) + NI3V_D022 (x(V) 0.25) + NI2V (x(V) 0.33333)

Convex hulls: Materials Project DFT hull · OQMD DFT hull · CALPHAD hull NiV-01Wat · CALPHAD hull NiV-10Kab · CALPHAD hull NiV-18Pan · CALPHAD hull NiV-19Zou · CALPHAD hull NiV-98Kor-LB

Invariant reactions (literature)

Invariant reactions reported in the literature for the Ni–V system (24)
T (K)Reaction / phasesCompositions (mole fraction)ClassSourceLocationQuote
1553.15L + bcc-(V) = σL: V 0.615; bcc-(V): V 0.76; σ: V 0.67experimental[1] Pan 2018
cites Stevens 1970 doi
Table 3, p. 6, row 4
report
1553peritectic: L + bcc -> σL: V 0.615; bcc: V 0.76; σ: V 0.67experimental[2] Kabanova 2010
cites Smith 1982
Table 1, p. 3, row 3
report
1551peritectic: L + bcc -> σL: V 0.6118; bcc: V 0.7643; σ: V 0.649model[2] Kabanova 2010Table 1, p. 3, row 4
report
1549.15L + bcc-(V) = σL: V 0.629; bcc-(V): V 0.76; σ: V 0.68model[1] Pan 2018Table 3, p. 6, row 3
report
1477.15L = fcc-(Ni) + σL: V 0.506; fcc-(Ni): V 0.427; σ: V 0.556model[1] Pan 2018Table 3, p. 6, row 1
report
1476.5eutectic: L -> fcc + σL: V 0.485; fcc: V 0.4305; σ: V 0.5901model[2] Kabanova 2010Table 1, p. 3, row 2
report
1475.15L = fcc-(Ni) + σL: V 0.51; fcc-(Ni): V 0.43; σ: V 0.55experimental[1] Pan 2018
cites Stevens 1970 doi
Table 3, p. 6, row 2
report
1475eutectic: L -> fcc + σL: V 0.512; fcc: V 0.43; σ: V 0.56experimental[2] Kabanova 2010
cites Smith 1982
Table 1, p. 3, row 1
report
1325.15polymorphic: fcc-(Ni) = Ni3Vfcc-(Ni): V 0.247; Ni3V: V 0.247model[1] Pan 2018Table 3, p. 6, row 11
report
1318.15polymorphic: fcc-(Ni) = Ni3Vfcc-(Ni): V 0.25; Ni3V: V 0.25experimental[1] Pan 2018
cites Stevens 1970 doi
Table 3, p. 6, row 12
report
1206.15polymorphic: fcc-(Ni) = Ni2Vfcc-(Ni): V 0.333; Ni2V: V 0.333model[1] Pan 2018Table 3, p. 6, row 13
report
1195.15polymorphic: fcc-(Ni) = Ni2Vfcc-(Ni): V 0.333; Ni2V: V 0.333experimental[1] Pan 2018
cites Stevens 1970 doi
Table 3, p. 6, row 14
report
1183eutectoid: fcc -> Ni3V + Ni2Vfcc: V 0.323; Ni3V: V 0.283; Ni2V: V 0.333model[2] Kabanova 2010Table 1, p. 3, row 10
report
1181.15fcc-(Ni) = Ni3V + Ni2Vfcc-(Ni): V 0.325; Ni3V: V 0.285; Ni2V: V 0.33experimental[1] Pan 2018
cites Stevens 1970 doi
Table 3, p. 6, row 6
report
1181eutectoid: fcc -> Ni3V + Ni2Vfcc: V 0.325; Ni3V: V 0.285; Ni2V: V 0.33experimental[2] Kabanova 2010
cites Smith 1982
Table 1, p. 3, row 9
report
1178.5eutectoid: fcc -> Ni2V + σfcc: V 0.3675; Ni2V: V 0.333; σ: V 0.5732model[2] Kabanova 2010Table 1, p. 3, row 12
report
1177.15fcc-(Ni) = Ni3V + Ni2Vfcc-(Ni): V 0.31; Ni3V: V 0.267; Ni2V: V 0.333model[1] Pan 2018Table 3, p. 6, row 5
report
1175peritectoid: σ + bcc -> NiV3σ: V 0.7274; bcc: V 0.892; NiV3: V 0.75model[2] Kabanova 2010Table 1, p. 3, row 14
report
1173.15σ + bcc-(V) = Ni2V7σ: V 0.735; bcc-(V): V 0.895; Ni2V7: V 0.778experimental[1] Pan 2018
cites Stevens 1970 doi
Table 3, p. 6, row 10
report
1173.15σ + bcc-(V) = Ni2V7σ: V 0.742; bcc-(V): V 0.895; Ni2V7: V 0.778model[1] Pan 2018Table 3, p. 6, row 9
report
1173peritectoid: σ + bcc -> NiV3σ: V 0.735; bcc: V 0.895; NiV3: V 0.778experimental[2] Kabanova 2010
cites Smith 1982
Table 1, p. 3, row 13
report
1163.15fcc-(Ni) = Ni2V + σfcc-(Ni): V 0.385; Ni2V: V 0.33; σ: V 0.55experimental[1] Pan 2018
cites Stevens 1970 doi
Table 3, p. 6, row 8
report
1163eutectoid: fcc -> Ni2V + σfcc: V 0.365; Ni2V: V 0.33; σ: V 0.56experimental[2] Kabanova 2010
cites Smith 1982
Table 1, p. 3, row 11
report
1155.15fcc-(Ni) = Ni2V + σfcc-(Ni): V 0.367; Ni2V: V 0.333; σ: V 0.532model[1] Pan 2018Table 3, p. 6, row 7
report

Other properties

Phase transition (6)

Phase transition, Ni–V system
PropertyValueT (K)Phases / compositionClassSourceLocationQuote
Phase transition1192 K1192other: fcc -> Ni2V
fcc: V 0.333; Ni2V: V 0.333
model[2] Kabanova 2010Table 1, p. 3, row 8
report
Phase transition1195 K1195fcc + Ni3Vmodel[2] Kabanova 2010
cites Smith 1982
p. 3
report
The Ni3V phase was, however, exper imentally ascertained to be formed in the Ni-V sys tem by the ordering of fcc solid solution based on nickel at 1195 K [1].
Phase transition1195 K1195other: fcc -> Ni2V
fcc: V 0.333; Ni2V: V 0.333
experimental[2] Kabanova 2010
cites Smith 1982
Table 1, p. 3, row 7
report
Phase transition1303.5 K1303.5other: fcc -> Ni3V
fcc: V 0.258; Ni3V: V 0.258
model[2] Kabanova 2010Table 1, p. 3, row 6
report
Phase transition1318 K1318other: fcc -> Ni3V
fcc: V 0.25; Ni3V: V 0.25
experimental[2] Kabanova 2010
cites Smith 1982
Table 1, p. 3, row 5
report
Phase transition6011 K6011phase separation of the liquid phasemodel[1] Pan 2018p. 6
report
According to the present calculation, there are phase decompositions of the Ni2V phase at 291 K and a phase separation of the liquid phase at 6011 K, as can be seen in Fig. 2.

Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

  1. Yafei Pan, Yong Du, Jian Lv, Tongxiang Liang, Fenghua Luo, Reassessment of the Ni–V system and a new thermodynamic modeling of the Mo–Ni–V system, Thermochimica Acta 661, 137-146 (2018). doi:10.1016/j.tca.2018.01.020
  2. E. G. Kabanova, V. N. Kuznetsov, G. P. Zhmurko, Thermodynamic modeling of phase equilibria in the Ni-V system, Russ. J. Phys. Chem. 84, 755-759 (2010). doi:10.1134/s0036024410050080