# Sb–Zn system

> Sb–Zn system: 256 accepted literature values (invariant reaction 108, formation 98, activity / EMF / Gibbs energy 20, phase transition 20) and 7 calculated phase diagram(s) from ORCHID, each value with evidence class, source, page and quote.

HTML: https://data.orchid-project.org/systems/SB-ZN.html · Markdown: https://data.orchid-project.org/systems/SB-ZN.md

256 accepted literature values from 4 paper(s) (experimental 134, model 113, unspecified 9); 7 calculated phase diagram(s). 7 further extracted value(s) not accepted by the reader-agreement checks are only in the JSON/CSV.

Data: [JSON](https://data.orchid-project.org/literature/systems/SB-ZN.json) · [CSV](https://data.orchid-project.org/systems/SB-ZN.csv) · [interactive explorer](https://orchid-project.org/data-explorer/#SB-ZN) · [interactive phase diagram](https://orchid-project.org/phase-diagrams/#SB-ZN/SbZn-00Liu-LB.json) · [phases (24)](https://data.orchid-project.org/phases/pages/SB-ZN.html) · [papers (bibliography)](https://data.orchid-project.org/bibliography/pages/systems/SB-ZN.html) · [Markdown](https://data.orchid-project.org/systems/SB-ZN.md)

Table: Accepted values by evidence class

| Evidence class | Values |
|---|---:|
| experimental | 134 |
| model | 113 |
| unspecified | 9 |

Table: Accepted values by property group

| Property group | Values |
|---|---:|
| invariant reaction | 108 |
| phase transition | 20 |
| phase equilibrium | 5 |
| formation | 98 |
| activity / EMF / Gibbs energy | 20 |
| crystal structure | 5 |

## Calculated phase diagrams

Binary phase diagrams calculated with pycalphad 0.11.2 from the SGTE binary collection (Hallstedt 2025, CC BY 4.0). Evidence class: model.

Table: Assessments with a calculated phase diagram

| TDB file | Assessment | SHA-256 | Links |
|---|---|---|---|
| SbZn-00Liu-LB.tdb | X.J. Liu, C.P. Wang, I. Ohnuma, R. Kainuma, K. Ishida, J. Phase Equilib., 21, 432-42(2000). [doi:10.1361/105497100770339608](https://doi.org/10.1361/105497100770339608) | `82e256183b64ede758f561d12adf389cd0adaf9e5af88286ee4e56800f4147b0` | [viewer](https://orchid-project.org/phase-diagrams/#SB-ZN/SbZn-00Liu-LB.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/SbZn-00Liu-LB.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/SbZn-00Liu-LB.json) |
| SbZn-07Li.tdb | J.-B. Li, M.-C. Record, J.-C. Tedenac, J. Alloys Compd., 438, 171-77(2007). [doi:10.1016/j.jallcom.2006.08.035](https://doi.org/10.1016/j.jallcom.2006.08.035) | `6e6072cc45a32d331379e105afb36e76a0030c9d5cb3c31db974f889a8e8b865` | [viewer](https://orchid-project.org/phase-diagrams/#SB-ZN/SbZn-07Li.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/SbZn-07Li.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/SbZn-07Li.json) |
| SbZn-09Liu.tdb | Y. Liu, J.-C. Tedenac, Calphad, 33, 684-94(2009). [doi:10.1016/j.calphad.2009.08.006](https://doi.org/10.1016/j.calphad.2009.08.006) | `187d17f544e9280e613de51174c62279fc8f67fa2b09c2b1f13ea8ad6d3fca00` | [viewer](https://orchid-project.org/phase-diagrams/#SB-ZN/SbZn-09Liu.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/SbZn-09Liu.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/SbZn-09Liu.json) |
| SbZn-18Wan.tdb | W. Wang, L. Yang, N. Wang, H. Zhang, Y. Jia, J. Electron. Mater., 47, 261-71(2018). [doi:10.1007/s11664-017-5757-5](https://doi.org/10.1007/s11664-017-5757-5) | `8427f99df3872e4ef2032d36f2e36d657b353866ea955f9534f84743f37fabf6` | [viewer](https://orchid-project.org/phase-diagrams/#SB-ZN/SbZn-18Wan.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/SbZn-18Wan.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/SbZn-18Wan.json) |
| SbZn-22Zha.tdb | J. Zhang, Y. Yuan, Thermochim. Acta, 716, 179327(2022). [doi:10.1016/j.tca.2022.179327](https://doi.org/10.1016/j.tca.2022.179327) | `7c5dd94e653096cdc663fdd27557d7ed5e13124c2593bd414b3a987fe55bb960` | [viewer](https://orchid-project.org/phase-diagrams/#SB-ZN/SbZn-22Zha.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/SbZn-22Zha.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/SbZn-22Zha.json) |
| SbZn-23Zha.tdb | J. Zhang, Y. Yuan, Calphad, 80, 102525(2023). [doi:10.1016/j.calphad.2022.102525](https://doi.org/10.1016/j.calphad.2022.102525) | `be7f7a4bc8316cfda617d82173ad3f8dcd68c6c2a480b956d7a03bce6a8227fc` | [viewer](https://orchid-project.org/phase-diagrams/#SB-ZN/SbZn-23Zha.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/SbZn-23Zha.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/SbZn-23Zha.json) |
| SbZn-97Zab.tdb | L.A. Zabdyr, Calphad, 21, 349-58(1997). [doi:10.1016/S0364-5916(97)00036-9](https://doi.org/10.1016/S0364-5916%2897%2900036-9) | `dab5acfd3e531488e5eda71b7f049ae232c4bfc05a529186bd55ad9df7a15274` | [viewer](https://orchid-project.org/phase-diagrams/#SB-ZN/SbZn-97Zab.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/SbZn-97Zab.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/SbZn-97Zab.json) |

Table: Calculated three-phase invariants (model, mole fraction of the second component)

| TDB file | T (K) | Phases at the invariant |
|---|---:|---|
| SbZn-00Liu-LB.tdb | 833.76 | LIQUID (x(Zn) 0.55978) + SB17ZN23_H (x(Zn) 0.575) + SB2ZN3 (x(Zn) 0.6) |
| SbZn-00Liu-LB.tdb | 833.76 | LIQUID (x(Zn) 0.55947) + SB17ZN23_H (x(Zn) 0.575) + SB2ZN3 (x(Zn) 0.6) |
| SbZn-00Liu-LB.tdb | 833.76 | LIQUID (x(Zn) 0.55944) + SB17ZN23_H (x(Zn) 0.575) + SB2ZN3 (x(Zn) 0.6) |
| SbZn-00Liu-LB.tdb | 819.27 | LIQUID (x(Zn) 0.47725) + SBZN_BE (x(Zn) 0.5) + SB17ZN23_H (x(Zn) 0.575) |
| SbZn-00Liu-LB.tdb | 819.27 | LIQUID (x(Zn) 0.47724) + SBZN_BE (x(Zn) 0.5) + SB17ZN23_H (x(Zn) 0.575) |
| SbZn-00Liu-LB.tdb | 819.27 | LIQUID (x(Zn) 0.47679) + SBZN_BE (x(Zn) 0.5) + SB17ZN23_H (x(Zn) 0.575) |
| SbZn-00Liu-LB.tdb | 801.01 | SBZN_BE (x(Zn) 0.5) + SB9ZN11 (x(Zn) 0.55) + SB17ZN23_H (x(Zn) 0.575) |
| SbZn-00Liu-LB.tdb | 779.6 | RHOMBOHEDRAL_A7 (x(Zn) 0.01694) + LIQUID (x(Zn) 0.3137) + SBZN_BE (x(Zn) 0.5) |
| SbZn-00Liu-LB.tdb | 779.6 | RHOMBOHEDRAL_A7 (x(Zn) 0.01691) + LIQUID (x(Zn) 0.31341) + SBZN_BE (x(Zn) 0.5) |
| SbZn-00Liu-LB.tdb | 764.91 | SB9ZN11 (x(Zn) 0.55) + SB17ZN23_L (x(Zn) 0.575) + SB17ZN23_H (x(Zn) 0.575) |
| SbZn-00Liu-LB.tdb | 764.91 | SB17ZN23_L (x(Zn) 0.575) + SB17ZN23_H (x(Zn) 0.575) + SB2ZN3 (x(Zn) 0.6) |
| SbZn-00Liu-LB.tdb | 764.56 | SBZN_BE (x(Zn) 0.5) + SB9ZN11 (x(Zn) 0.55) + SB17ZN23_L (x(Zn) 0.575) |
| SbZn-00Liu-LB.tdb | 727.92 | SB2ZN3 (x(Zn) 0.6) + SB19ZN31 (x(Zn) 0.62) + LIQUID (x(Zn) 0.92753) |
| SbZn-00Liu-LB.tdb | 727.92 | SB2ZN3 (x(Zn) 0.6) + SB19ZN31 (x(Zn) 0.62) + LIQUID (x(Zn) 0.9269) |
| SbZn-00Liu-LB.tdb | 712.64 | SB17ZN23_L (x(Zn) 0.575) + SB2ZN3 (x(Zn) 0.6) + SB19ZN31 (x(Zn) 0.62) |
| SbZn-00Liu-LB.tdb | 682.87 | SB19ZN31 (x(Zn) 0.62) + LIQUID (x(Zn) 0.97829) + HCP_A3 (x(Zn) 1) |
| SbZn-00Liu-LB.tdb | 682.87 | SB19ZN31 (x(Zn) 0.62) + LIQUID (x(Zn) 0.97837) + HCP_A3 (x(Zn) 1) |
| SbZn-00Liu-LB.tdb | 681.25 | SB17ZN23_L (x(Zn) 0.575) + SB19ZN31 (x(Zn) 0.62) + HCP_A3 (x(Zn) 1) |
| SbZn-00Liu-LB.tdb | 489.61 | SBZN_BE (x(Zn) 0.5) + SB17ZN23_L (x(Zn) 0.575) + HCP_A3 (x(Zn) 1) |
| SbZn-07Li.tdb | 835.73 | SB3ZN4_PRIME (x(Zn) 0.558) + LIQUID (x(Zn) 0.5719) + SB2ZN3_ZETA (x(Zn) 0.595) |
| SbZn-07Li.tdb | 835.73 | SB3ZN4_PRIME (x(Zn) 0.558) + LIQUID (x(Zn) 0.57141) + SB2ZN3_ZETA (x(Zn) 0.595) |
| SbZn-07Li.tdb | 816.67 | LIQUID (x(Zn) 0.46662) + SBZN_BE (x(Zn) 0.5) + SB3ZN4_PRIME (x(Zn) 0.558) |
| SbZn-07Li.tdb | 816.67 | LIQUID (x(Zn) 0.46659) + SBZN_BE (x(Zn) 0.5) + SB3ZN4_PRIME (x(Zn) 0.558) |
| SbZn-07Li.tdb | 802.06 | SB3ZN4_PRIME (x(Zn) 0.558) + SB3ZN4_DELTA (x(Zn) 0.559) + SB2ZN3_ZETA (x(Zn) 0.595) |
| SbZn-07Li.tdb | 801.5 | SBZN_BE (x(Zn) 0.5) + SB3ZN4_PRIME (x(Zn) 0.558) + SB3ZN4_DELTA (x(Zn) 0.559) |
| SbZn-07Li.tdb | 773.52 | RHOMBOHEDRAL_A7 (x(Zn) 0) + LIQUID (x(Zn) 0.31487) + SBZN_BE (x(Zn) 0.5) |
| SbZn-07Li.tdb | 773.52 | RHOMBOHEDRAL_A7 (x(Zn) 0) + LIQUID (x(Zn) 0.31449) + SBZN_BE (x(Zn) 0.5) |
| SbZn-07Li.tdb | 767.62 | SB3ZN4_DELTA (x(Zn) 0.559) + SB3ZN4_EPS (x(Zn) 0.57143) + SB2ZN3_ZETA (x(Zn) 0.595) |
| SbZn-07Li.tdb | 767.25 | SBZN_BE (x(Zn) 0.5) + SB3ZN4_DELTA (x(Zn) 0.559) + SB3ZN4_EPS (x(Zn) 0.57143) |
| SbZn-07Li.tdb | 733.19 | SB2ZN3_ZETA (x(Zn) 0.595) + SB2ZN3_ETA (x(Zn) 0.6) + LIQUID (x(Zn) 0.96082) |
| SbZn-07Li.tdb | 714.93 | SB3ZN4_EPS (x(Zn) 0.57143) + SB2ZN3_ZETA (x(Zn) 0.595) + SB2ZN3_ETA (x(Zn) 0.6) |
| SbZn-07Li.tdb | 686.73 | SB2ZN3_ETA (x(Zn) 0.6) + LIQUID (x(Zn) 0.9874) + HCP_A3 (x(Zn) 1) |
| SbZn-07Li.tdb | 677.96 | SB3ZN4_EPS (x(Zn) 0.57143) + SB2ZN3_ETA (x(Zn) 0.6) + HCP_A3 (x(Zn) 1) |
| SbZn-09Liu.tdb | 836.8 | SB3ZN4_PRIME (x(Zn) 0.558) + LIQUID (x(Zn) 0.58784) + SB2ZN3_ZETA (x(Zn) 0.595) |
| SbZn-09Liu.tdb | 836.8 | SB3ZN4_PRIME (x(Zn) 0.558) + LIQUID (x(Zn) 0.58719) + SB2ZN3_ZETA (x(Zn) 0.595) |
| SbZn-09Liu.tdb | 823.82 | LIQUID (x(Zn) 0.48179) + SBZN_BE (x(Zn) 0.49602) + SB3ZN4_PRIME (x(Zn) 0.558) |
| SbZn-09Liu.tdb | 802.76 | SB3ZN4_PRIME (x(Zn) 0.558) + SB3ZN4_DELTA (x(Zn) 0.559) + SB2ZN3_ZETA (x(Zn) 0.595) |
| SbZn-09Liu.tdb | 778.39 | RHOMBOHEDRAL_A7 (x(Zn) 0) + LIQUID (x(Zn) 0.30887) + SBZN_BE (x(Zn) 0.4902) |
| SbZn-09Liu.tdb | 766.7 | SB3ZN4_DELTA (x(Zn) 0.559) + SB3ZN4_EPS (x(Zn) 0.56556) + SB2ZN3_ZETA (x(Zn) 0.595) |
| SbZn-09Liu.tdb | 730.98 | SB2ZN3_ZETA (x(Zn) 0.595) + SB2ZN3_ETA (x(Zn) 0.6) + LIQUID (x(Zn) 0.96464) |
| SbZn-09Liu.tdb | 717.39 | SB3ZN4_EPS (x(Zn) 0.56921) + SB2ZN3_ZETA (x(Zn) 0.595) + SB2ZN3_ETA (x(Zn) 0.6) |
| SbZn-09Liu.tdb | 689.75 | SB2ZN3_ETA (x(Zn) 0.6) + LIQUID (x(Zn) 0.98718) + HCP_A3 (x(Zn) 0.99423) |
| SbZn-09Liu.tdb | 680.58 | SB3ZN4_EPS (x(Zn) 0.56996) + SB2ZN3_ETA (x(Zn) 0.6) + HCP_A3 (x(Zn) 0.9947) |
| SbZn-18Wan.tdb | 839.67 | SB3ZN4_PRIME (x(Zn) 0.558) + LIQUID (x(Zn) 0.58101) + SB2ZN3_ZETA (x(Zn) 0.595) |
| SbZn-18Wan.tdb | 839.67 | SB3ZN4_PRIME (x(Zn) 0.558) + LIQUID (x(Zn) 0.57998) + SB2ZN3_ZETA (x(Zn) 0.595) |
| SbZn-18Wan.tdb | 819.08 | LIQUID (x(Zn) 0.42983) + SBZN_BE (x(Zn) 0.5) + SB3ZN4_PRIME (x(Zn) 0.558) |
| SbZn-18Wan.tdb | 819.08 | LIQUID (x(Zn) 0.42981) + SBZN_BE (x(Zn) 0.5) + SB3ZN4_PRIME (x(Zn) 0.558) |
| SbZn-18Wan.tdb | 805.03 | SB3ZN4_PRIME (x(Zn) 0.558) + SB3ZN4_GAMMA (x(Zn) 0.559) + SB2ZN3_ZETA (x(Zn) 0.595) |
| SbZn-18Wan.tdb | 797.97 | SBZN_BE (x(Zn) 0.5) + SB3ZN4_PRIME (x(Zn) 0.558) + SB3ZN4_GAMMA (x(Zn) 0.559) |
| SbZn-18Wan.tdb | 779.35 | RHOMBOHEDRAL_A7 (x(Zn) 0) + LIQUID (x(Zn) 0.27802) + SBZN_BE (x(Zn) 0.5) |
| SbZn-18Wan.tdb | 779.35 | RHOMBOHEDRAL_A7 (x(Zn) 0) + LIQUID (x(Zn) 0.27762) + SBZN_BE (x(Zn) 0.5) |
| SbZn-18Wan.tdb | 768.92 | SB3ZN4_GAMMA (x(Zn) 0.559) + SB3ZN4_BETA (x(Zn) 0.57143) + SB2ZN3_ZETA (x(Zn) 0.595) |
| SbZn-18Wan.tdb | 765.05 | SBZN_BE (x(Zn) 0.5) + SB3ZN4_GAMMA (x(Zn) 0.559) + SB3ZN4_BETA (x(Zn) 0.57143) |
| SbZn-18Wan.tdb | 731.02 | SB2ZN3_ZETA (x(Zn) 0.595) + SB2ZN3_ETA (x(Zn) 0.6) + LIQUID (x(Zn) 0.95764) |
| SbZn-18Wan.tdb | 713.82 | SB3ZN4_BETA (x(Zn) 0.57143) + SB2ZN3_ZETA (x(Zn) 0.595) + SB2ZN3_ETA (x(Zn) 0.6) |
| SbZn-18Wan.tdb | 687.14 | SB2ZN3_ETA (x(Zn) 0.6) + LIQUID (x(Zn) 0.98824) + HCP_A3 (x(Zn) 1) |
| SbZn-18Wan.tdb | 677.06 | SB3ZN4_BETA (x(Zn) 0.57143) + SB2ZN3_ETA (x(Zn) 0.6) + HCP_A3 (x(Zn) 1) |
| SbZn-22Zha.tdb | 851.57 | SB3ZN4_PRIME (x(Zn) 0.55128) + LIQUID (x(Zn) 0.57247) + SB2ZN3_ZETA (x(Zn) 0.59267) |
| SbZn-22Zha.tdb | 851.57 | SB3ZN4_PRIME (x(Zn) 0.55128) + LIQUID (x(Zn) 0.57192) + SB2ZN3_ZETA (x(Zn) 0.59267) |
| SbZn-22Zha.tdb | 851.57 | SB3ZN4_PRIME (x(Zn) 0.55128) + LIQUID (x(Zn) 0.57191) + SB2ZN3_ZETA (x(Zn) 0.59267) |
| SbZn-22Zha.tdb | 838.84 | LIQUID (x(Zn) 0.46549) + SBZN_BE (x(Zn) 0.49731) + SB3ZN4_PRIME (x(Zn) 0.55128) |
| SbZn-22Zha.tdb | 810.41 | SB3ZN4_PRIME (x(Zn) 0.55128) + SB3ZN4_GAMMA (x(Zn) 0.55696) + SB2ZN3_ZETA (x(Zn) 0.59267) |
| SbZn-22Zha.tdb | 806.7 | SBZN_BE (x(Zn) 0.49837) + SB3ZN4_PRIME (x(Zn) 0.55128) + SB3ZN4_GAMMA (x(Zn) 0.55696) |
| SbZn-22Zha.tdb | 795.32 | SB3ZN4_GAMMA (x(Zn) 0.55696) + SB3ZN4_BETA (x(Zn) 0.56342) + SB2ZN3_ZETA (x(Zn) 0.59267) |
| SbZn-22Zha.tdb | 785.12 | SBZN_BE (x(Zn) 0.49869) + SB3ZN4_GAMMA (x(Zn) 0.55696) + SB3ZN4_BETA (x(Zn) 0.56327) |
| SbZn-22Zha.tdb | 783.88 | RHOMBOHEDRAL_A7 (x(Zn) 3.100e-4) + LIQUID (x(Zn) 0.28468) + SBZN_BE (x(Zn) 0.49328) |
| SbZn-22Zha.tdb | 757.55 | SB2ZN3_ZETA (x(Zn) 0.59267) + SB2ZN3_ETA (x(Zn) 0.6) + LIQUID (x(Zn) 0.90866) |
| SbZn-22Zha.tdb | 757.55 | SB2ZN3_ZETA (x(Zn) 0.59267) + SB2ZN3_ETA (x(Zn) 0.6) + LIQUID (x(Zn) 0.90832) |
| SbZn-22Zha.tdb | 705.74 | SB3ZN4_BETA (x(Zn) 0.56482) + SB2ZN3_ZETA (x(Zn) 0.59267) + SB2ZN3_ETA (x(Zn) 0.6) |
| SbZn-22Zha.tdb | 686.72 | SB2ZN3_ETA (x(Zn) 0.6) + LIQUID (x(Zn) 0.98429) + HCP_A3 (x(Zn) 0.99719) |
| SbZn-22Zha.tdb | 677.42 | SB3ZN4_BETA (x(Zn) 0.56498) + SB2ZN3_ETA (x(Zn) 0.6) + HCP_A3 (x(Zn) 0.99743) |
| SbZn-22Zha.tdb | 677.42 | SB3ZN4_BETA (x(Zn) 0.56498) + SB2ZN3_ETA (x(Zn) 0.6) + HCP_A3 (x(Zn) 0.99743) |
| SbZn-23Zha.tdb | 851.61 | SB3ZN4_PRIME (x(Zn) 0.55128) + LIQUID (x(Zn) 0.56832) + SB2ZN3_ZETA (x(Zn) 0.59267) |
| SbZn-23Zha.tdb | 838.2 | LIQUID (x(Zn) 0.46461) + SBZN_BE (x(Zn) 0.49733) + SB3ZN4_PRIME (x(Zn) 0.55128) |
| SbZn-23Zha.tdb | 810.41 | SB3ZN4_PRIME (x(Zn) 0.55128) + SB3ZN4_GAMMA (x(Zn) 0.55696) + SB2ZN3_ZETA (x(Zn) 0.59267) |
| SbZn-23Zha.tdb | 806.7 | SBZN_BE (x(Zn) 0.49837) + SB3ZN4_PRIME (x(Zn) 0.55128) + SB3ZN4_GAMMA (x(Zn) 0.55696) |
| SbZn-23Zha.tdb | 795.32 | SB3ZN4_GAMMA (x(Zn) 0.55696) + SB3ZN4_BETA (x(Zn) 0.56342) + SB2ZN3_ZETA (x(Zn) 0.59267) |
| SbZn-23Zha.tdb | 785.12 | SBZN_BE (x(Zn) 0.49869) + SB3ZN4_GAMMA (x(Zn) 0.55696) + SB3ZN4_BETA (x(Zn) 0.56327) |
| SbZn-23Zha.tdb | 782.91 | RHOMBOHEDRAL_A7 (x(Zn) 3.100e-4) + LIQUID (x(Zn) 0.28523) + SBZN_BE (x(Zn) 0.49331) |
| SbZn-23Zha.tdb | 752.1 | SB2ZN3_ZETA (x(Zn) 0.59267) + SB2ZN3_ETA (x(Zn) 0.6) + LIQUID (x(Zn) 0.92858) |
| SbZn-23Zha.tdb | 703.48 | SB3ZN4_BETA (x(Zn) 0.56484) + SB2ZN3_ZETA (x(Zn) 0.59267) + SB2ZN3_ETA (x(Zn) 0.6) |
| SbZn-23Zha.tdb | 686.86 | SB2ZN3_ETA (x(Zn) 0.6) + LIQUID (x(Zn) 0.98461) + HCP_A3 (x(Zn) 0.99718) |
| SbZn-23Zha.tdb | 678.13 | SB3ZN4_BETA (x(Zn) 0.56498) + SB2ZN3_ETA (x(Zn) 0.6) + HCP_A3 (x(Zn) 0.99741) |
| SbZn-23Zha.tdb | 678.13 | SB3ZN4_BETA (x(Zn) 0.56498) + SB2ZN3_ETA (x(Zn) 0.6) + HCP_A3 (x(Zn) 0.99741) |
| SbZn-97Zab.tdb | 835.16 | SB3ZN4_HT (x(Zn) 0.57143) + LIQUID (x(Zn) 0.58812) + SB2ZN3_HT (x(Zn) 0.6) |
| SbZn-97Zab.tdb | 835.16 | SB3ZN4_HT (x(Zn) 0.57143) + LIQUID (x(Zn) 0.58767) + SB2ZN3_HT (x(Zn) 0.6) |
| SbZn-97Zab.tdb | 812.5 | LIQUID (x(Zn) 0.46885) + SBZN_BE (x(Zn) 0.5) + SB3ZN4_HT (x(Zn) 0.57143) |
| SbZn-97Zab.tdb | 781.52 | RHOMBOHEDRAL_A7 (x(Zn) 0) + LIQUID (x(Zn) 0.32899) + SBZN_BE (x(Zn) 0.5) |
| SbZn-97Zab.tdb | 781.52 | RHOMBOHEDRAL_A7 (x(Zn) 0) + LIQUID (x(Zn) 0.32893) + SBZN_BE (x(Zn) 0.5) |
| SbZn-97Zab.tdb | 766 | SBZN_BE (x(Zn) 0.5) + SB3ZN4_HT (x(Zn) 0.57143) + SB3ZN4_LT (x(Zn) 0.57143) |
| SbZn-97Zab.tdb | 766 | SB3ZN4_LT (x(Zn) 0.57143) + SB3ZN4_HT (x(Zn) 0.57143) + SB2ZN3_HT (x(Zn) 0.6) |
| SbZn-97Zab.tdb | 719.86 | SB3ZN4_LT (x(Zn) 0.57143) + SB2ZN3_LT (x(Zn) 0.6) + SB2ZN3_HT (x(Zn) 0.6) |
| SbZn-97Zab.tdb | 719.86 | SB2ZN3_LT (x(Zn) 0.6) + SB2ZN3_HT (x(Zn) 0.6) + LIQUID (x(Zn) 0.96109) |
| SbZn-97Zab.tdb | 683.38 | SB2ZN3_LT (x(Zn) 0.6) + LIQUID (x(Zn) 0.98046) + HCP_A3 (x(Zn) 1) |
| SbZn-97Zab.tdb | 676.1 | SB3ZN4_LT (x(Zn) 0.57143) + SB2ZN3_LT (x(Zn) 0.6) + HCP_A3 (x(Zn) 1) |
| SbZn-97Zab.tdb | 338.81 | SBZN_BE (x(Zn) 0.5) + SB3ZN4_LT (x(Zn) 0.57143) + HCP_A3 (x(Zn) 1) |

Convex hulls: [Materials Project DFT hull](https://data.orchid-project.org/hulls/dft-mp/SB/SB-ZN.json) · [OQMD DFT hull](https://data.orchid-project.org/hulls/dft-oqmd/SB/SB-ZN.json) · [CALPHAD hull SbZn-00Liu-LB](https://data.orchid-project.org/hulls/calphad-sgte/SB/SB-ZN--SbZn-00Liu-LB.json) · [CALPHAD hull SbZn-07Li](https://data.orchid-project.org/hulls/calphad-sgte/SB/SB-ZN--SbZn-07Li.json) · [CALPHAD hull SbZn-09Liu](https://data.orchid-project.org/hulls/calphad-sgte/SB/SB-ZN--SbZn-09Liu.json) · [CALPHAD hull SbZn-18Wan](https://data.orchid-project.org/hulls/calphad-sgte/SB/SB-ZN--SbZn-18Wan.json) · [CALPHAD hull SbZn-22Zha](https://data.orchid-project.org/hulls/calphad-sgte/SB/SB-ZN--SbZn-22Zha.json) · [CALPHAD hull SbZn-97Zab](https://data.orchid-project.org/hulls/calphad-sgte/SB/SB-ZN--SbZn-97Zab.json)

## Invariant reactions (literature)

Table: Invariant reactions reported in the literature for the Sb–Zn system (108)

| T (K) | Reaction / phases | Compositions (mole fraction) | Class | Source | Location | Quote |
|---:|---|---|---|---|---|---|
| 863.15 | congruent melting: L ↔ β-Zn9Sb7 | L: Zn 0.571; β-Zn9Sb7: Zn 0.571 | experimental | [1] Zhang 2022; _cites Dobryden 1983_ | Table 7, p. 12, row 20; `ORC-7RFWQASPU5` |  |
| 858.15 | congruent melting: L ↔ β-Zn3Sb2 | L: Zn 0.6; β-Zn3Sb2: Zn 0.6 | experimental | [1] Zhang 2022; _cites Dobryden 1983_ | Table 7, p. 12, row 3; `ORC-POSG52LJIJ` |  |
| 854.15 | congruent melting: L ↔ β-Zn3Sb2 | L: Zn 0.593; β-Zn3Sb2: Zn 0.593 | experimental | [1] Zhang 2022; _cites Lo 2017_ [doi](https://doi.org/10.1021/acs.chemmater.7b01214) | Table 7, p. 12, row 5; `ORC-KWH2QWJO3R` |  |
| 854.15 | congruent melting: L ↔ β-Zn9Sb7 | L: Zn 0.548; β-Zn9Sb7: Zn 0.548 | experimental | [1] Zhang 2022; _cites He 2015_ [doi](https://doi.org/10.1039/c5dt03509k) | Table 7, p. 12, row 21; `ORC-L6H5PQASW6` |  |
| 853.15 | L + β-Zn9Sb7 ↔ SbZn | β-Zn9Sb7: Zn 0.571; SbZn: Zn 0.5 | experimental | [1] Zhang 2022; _cites Dobryden 1983_ | Table 7, p. 12, row 30; `ORC-7J43QH2VQV` |  |
| 852.65 | congruent melting: L ↔ β-Zn3Sb2 | L: Zn 0.593; β-Zn3Sb2: Zn 0.593 | model | [1] Zhang 2022 | Table 7, p. 12, row 6; `ORC-INOYOR2USG` |  |
| 852.45 | congruent melting: L ↔ β-Zn9Sb7 | L: Zn 0.551; β-Zn9Sb7: Zn 0.551 | model | [1] Zhang 2022 | Table 7, p. 12, row 22; `ORC-42C4HFQX3Y` |  |
| 851.55 | L ↔ β-Zn9Sb7 + β-Zn3Sb2 | L: Zn 0.572; β-Zn9Sb7: Zn 0.551; β-Zn3Sb2: Zn 0.593 | model | [1] Zhang 2022 | Table 7, p. 12, row 27; `ORC-YVO3FNJKLJ` |  |
| 848.15 | L ↔ β-Zn9Sb7 + β-Zn3Sb2 | β-Zn9Sb7: Zn 0.548; β-Zn3Sb2: Zn 0.593 | experimental | [1] Zhang 2022; _cites Lo 2018_ [doi](https://doi.org/10.1039/c8dt02521e) | Table 7, p. 12, row 26; `ORC-BBNKFL77W4` |  |
| 842.15 | L + β-Zn9Sb7 ↔ SbZn | β-Zn9Sb7: Zn 0.548; SbZn: Zn 0.5 | experimental | [1] Zhang 2022; _cites Lo 2018_ [doi](https://doi.org/10.1039/c8dt02521e) | Table 7, p. 12, row 32; `ORC-TO733BRX5U` |  |
| 841.15 | congruent melting: L ↔ β-Zn3Sb2 | L: Zn 0.596; β-Zn3Sb2: Zn 0.596 | experimental | [1] Zhang 2022; _cites Adjadj 2007_ [doi](https://doi.org/10.1016/j.jallcom.2006.04.051) | Table 7, p. 12, row 4; `ORC-3XMOCGOFNR` |  |
| 841.15 | congruent melting: L ↔ β-Zn3Sb2 | L: Zn 0.558; β-Zn3Sb2: Zn 0.558 | experimental | [1] Zhang 2022; _cites Izard 2001_ [doi](https://doi.org/10.1016/s0364-5916%2802%2900008-1) | Table 7, p. 12, row 1; `ORC-CRQ2QQ7PRZ` |  |
| 841.15 | congruent melting: L ↔ β-Zn9Sb7 | L: Zn 0.558; β-Zn9Sb7: Zn 0.558 | experimental | [1] Zhang 2022; _cites Izard 2001_ [doi](https://doi.org/10.1016/s0364-5916%2802%2900008-1) | Table 7, p. 12, row 19; `ORC-RECCULIHI3` |  |
| 839.15 | congruent melting: L ↔ β-Zn9Sb7 | L: Zn 0.57; β-Zn9Sb7: Zn 0.57 | experimental | [1] Zhang 2022; _cites Adjadj 2007_ [doi](https://doi.org/10.1016/j.jallcom.2006.04.051) | Table 7, p. 12, row 18; `ORC-4RUN5E7U2M` |  |
| 839.15 | L ↔ β-Zn9Sb7 + β-Zn3Sb2 | L: Zn 0.559; β-Zn9Sb7: Zn 0.558; β-Zn3Sb2: Zn 0.595 | experimental | [1] Zhang 2022; _cites Izard 2001_ [doi](https://doi.org/10.1016/s0364-5916%2802%2900008-1) | Table 7, p. 12, row 24; `ORC-HCRSEBKFSJ` |  |
| 839.15 | congruent melting: L ↔ β-Zn3Sb2 | L: Zn 0.6; β-Zn3Sb2: Zn 0.6 | experimental | [1] Zhang 2022; _cites Zabdyr 1993_ [doi](https://doi.org/10.1016/0364-5916%2893%2990005-v) | Table 7, p. 12, row 2; `ORC-HSUV7ZAJKQ` |  |
| 839 | eutectic: L -> δ'Sb3Zn4 + ξSb2Zn3 | L: Zn 0.559; δ'Sb3Zn4: Zn 0.558; ξSb2Zn3: Zn 0.595 | experimental | [2] Li 2007; _cites Izard 2001_ [doi](https://doi.org/10.1016/s0364-5916%2802%2900008-1) | Table 2, p. 3, row 15; `ORC-BKR5IDQHJG` |  |
| 838.85 | L + β-Zn9Sb7 ↔ SbZn | L: Zn 0.465; β-Zn9Sb7: Zn 0.551; SbZn: Zn 0.5 | model | [1] Zhang 2022 | Table 7, p. 12, row 34; `ORC-I5ZHDN223U` |  |
| 836.15 | L ↔ β-Zn9Sb7 + β-Zn3Sb2 | β-Zn9Sb7: Zn 0.57; β-Zn3Sb2: Zn 0.596 | experimental | [1] Zhang 2022; _cites Adjadj 2007_ [doi](https://doi.org/10.1016/j.jallcom.2006.04.051) | Table 7, p. 12, row 25; `ORC-SNDKJIJXCS` |  |
| 836 | eutectic: L -> δ'Sb3Zn4 + ξSb2Zn3 | L: Zn 0.572; δ'Sb3Zn4: Zn 0.558; ξSb2Zn3: Zn 0.595 | model | [2] Li 2007 | Table 2, p. 3, row 16; `ORC-TLKFOCNFXR` |  |
| 835.65 | L ↔ β-Zn9Sb7 + β-Zn3Sb2 | L: Zn 0.577; β-Zn9Sb7: Zn 0.571; β-Zn3Sb2: Zn 0.6 | experimental | [1] Zhang 2022; _cites Takei 1927_ | Table 7, p. 12, row 23; `ORC-IKSVBONJ2L` |  |
| 835.65 | eutectic: L -> δ'Sb3Zn4 + ξSb2Zn3 | L: Zn 0.577; δ'Sb3Zn4: Zn 0.571; ξSb2Zn3: Zn 0.6 | unspecified | [2] Li 2007; _cites Zabdyr 1993_ [doi](https://doi.org/10.1016/0364-5916%2893%2990005-v) | Table 2, p. 3, row 14; `ORC-IONXM4SCMG` |  |
| 834.15 | peritectic: L + ξSb2Zn3 -> δSb3Zn4 | L: Zn 0.559; ξSb2Zn3: Zn 0.6; δSb3Zn4: Zn 0.575 | model | [2] Li 2007; _cites Liu 2000_ [doi](https://doi.org/10.1361/105497100770339608) | Table 2, p. 3, row 13; `ORC-SVDL2U4QUW` |  |
| 820.15 | L + β-Zn9Sb7 ↔ SbZn | L: Zn 0.47; β-Zn9Sb7: Zn 0.558; SbZn: Zn 0.5 | experimental | [1] Zhang 2022; _cites Izard 2001_ [doi](https://doi.org/10.1016/s0364-5916%2802%2900008-1) | Table 7, p. 12, row 31; `ORC-RHKBUNPC33` |  |
| 820 | peritectic: L + δ'Sb3Zn4 -> βSbZn | L: Zn 0.47; δ'Sb3Zn4: Zn 0.558; βSbZn: Zn 0.5 | experimental | [2] Li 2007; _cites Izard 2001_ [doi](https://doi.org/10.1016/s0364-5916%2802%2900008-1) | Table 2, p. 3, row 8; `ORC-UZTW5UH2CE` |  |
| 819.15 | L + β-Zn9Sb7 ↔ SbZn | L: Zn 0.477; β-Zn9Sb7: Zn 0.575; SbZn: Zn 0.5 | model | [1] Zhang 2022; _cites Liu 2000_ [doi](https://doi.org/10.1361/105497100770339608) | Table 7, p. 12, row 33; `ORC-DVDIQFDOQ4` |  |
| 819.15 | peritectic: L + δSb3Zn4 -> βSbZn | L: Zn 0.477; δSb3Zn4: Zn 0.575; βSbZn: Zn 0.5 | model | [2] Li 2007; _cites Liu 2000_ [doi](https://doi.org/10.1361/105497100770339608) | Table 2, p. 3, row 7; `ORC-SAEALQEAUH` |  |
| 817.65 | L + β-Zn9Sb7 ↔ SbZn | β-Zn9Sb7: Zn 0.57; SbZn: Zn 0.5 | experimental | [1] Zhang 2022; _cites Adjadj 2007_ [doi](https://doi.org/10.1016/j.jallcom.2006.04.051) | Table 7, p. 12, row 29; `ORC-KLKL5ZVMOC` |  |
| 817 | peritectic: L + δ'Sb3Zn4 -> βSbZn | L: Zn 0.466; δ'Sb3Zn4: Zn 0.558; βSbZn: Zn 0.5 | model | [2] Li 2007 | Table 2, p. 3, row 9; `ORC-6ZN6OUDZGP` |  |
| 814.95 | L + β-Zn9Sb7 ↔ SbZn | L: Zn 0.474; β-Zn9Sb7: Zn 0.572; SbZn: Zn 0.5 | experimental | [1] Zhang 2022; _cites Takei 1927_ | Table 7, p. 12, row 28; `ORC-IPLLYKPYTH` |  |
| 814.95 | peritectic: L + δSb3Zn4 -> βSbZn | L: Zn 0.474; δSb3Zn4: Zn 0.572; βSbZn: Zn 0.5 | unspecified | [2] Li 2007; _cites Zabdyr 1993_ [doi](https://doi.org/10.1016/0364-5916%2893%2990005-v) | Table 2, p. 3, row 6; `ORC-JJZ5HJHXVJ` |  |
| 812.15 | β-Zn9Sb7 + β-Zn3Sb2 ↔ α-Zn9Sb7 | β-Zn9Sb7: Zn 0.548; β-Zn3Sb2: Zn 0.593; α-Zn9Sb7: Zn 0.5625 | experimental | [1] Zhang 2022; _cites Lo 2018_ [doi](https://doi.org/10.1039/c8dt02521e) | Table 7, p. 12, row 41; `ORC-CKNHCYTV5I` |  |
| 810.4 | β-Zn9Sb7 + β-Zn3Sb2 ↔ α-Zn9Sb7 | β-Zn9Sb7: Zn 0.551; β-Zn3Sb2: Zn 0.593; α-Zn9Sb7: Zn 0.5625 | model | [1] Zhang 2022 | Table 7, p. 12, row 42; `ORC-YCMBOPFZHH` |  |
| 809.15 | β-Zn9Sb7 ↔ α-Zn9Sb7 + SbZn | β-Zn9Sb7: Zn 0.548; α-Zn9Sb7: Zn 0.5625; SbZn: Zn 0.5 | experimental | [1] Zhang 2022; _cites Lo 2018_ [doi](https://doi.org/10.1039/c8dt02521e) | Table 7, p. 12, row 44; `ORC-CZIMIXCCJ5` |  |
| 806.65 | β-Zn9Sb7 ↔ α-Zn9Sb7 + SbZn | β-Zn9Sb7: Zn 0.551; α-Zn9Sb7: Zn 0.5625; SbZn: Zn 0.5 | model | [1] Zhang 2022 | Table 7, p. 12, row 45; `ORC-QNFPEXGQIS` |  |
| 805.15 | β-Zn9Sb7 + β-Zn3Sb2 ↔ α-Zn9Sb7 | β-Zn9Sb7: Zn 0.558; β-Zn3Sb2: Zn 0.595; α-Zn9Sb7: Zn 0.559 | experimental | [1] Zhang 2022; _cites Izard 2001_ [doi](https://doi.org/10.1016/s0364-5916%2802%2900008-1) | Table 7, p. 12, row 40; `ORC-TV6FO7ONC2` |  |
| 805 | peritectoid: δ'Sb3Zn4 + ξSb2Zn3 -> δSb3Zn4 | δ'Sb3Zn4: Zn 0.558; ξSb2Zn3: Zn 0.595; δSb3Zn4: Zn 0.559 | experimental | [2] Li 2007; _cites Izard 2001_ [doi](https://doi.org/10.1016/s0364-5916%2802%2900008-1) | Table 2, p. 3, row 24; `ORC-DOVBM6HEHY` |  |
| 803.15 | β-Zn9Sb7 ↔ α-Zn9Sb7 + SbZn | β-Zn9Sb7: Zn 0.558; α-Zn9Sb7: Zn 0.559; SbZn: Zn 0.5 | experimental | [1] Zhang 2022; _cites Izard 2001_ [doi](https://doi.org/10.1016/s0364-5916%2802%2900008-1) | Table 7, p. 12, row 43; `ORC-MLDVXASA7P` |  |
| 802 | peritectoid: δ'Sb3Zn4 + ξSb2Zn3 -> δSb3Zn4 | δ'Sb3Zn4: Zn 0.558; ξSb2Zn3: Zn 0.595; δSb3Zn4: Zn 0.559 | model | [2] Li 2007 | Table 2, p. 3, row 25; `ORC-GXNSCKQCDO` |  |
| 801.5 | eutectoid: δ'Sb3Zn4 -> βSbZn + δSb3Zn4 | δ'Sb3Zn4: Zn 0.558; βSbZn: Zn 0.5; δSb3Zn4: Zn 0.559 | model | [2] Li 2007 | Table 2, p. 3, row 23; `ORC-TL6NSAVXNY` |  |
| 801.15 | peritectoid: βSbZn + δSb3Zn4 -> γSb5Zn6 | βSbZn: Zn 0.5; δSb3Zn4: Zn 0.575; γSb5Zn6: Zn 0.55 | model | [2] Li 2007; _cites Liu 2000_ [doi](https://doi.org/10.1361/105497100770339608) | Table 2, p. 3, row 21; `ORC-EZE2HKAW47` |  |
| 798 | eutectoid: δ'Sb3Zn4 -> βSbZn + δSb3Zn4 | δ'Sb3Zn4: Zn 0.558; βSbZn: Zn 0.5; δSb3Zn4: Zn 0.559 | experimental | [2] Li 2007; _cites Izard 2001_ [doi](https://doi.org/10.1016/s0364-5916%2802%2900008-1) | Table 2, p. 3, row 22; `ORC-F32ZZ675WH` |  |
| 795.35 | β-Zn3Sb2 + α-Zn9Sb7 ↔ β-Zn13Sb10 | β-Zn3Sb2: Zn 0.593; α-Zn9Sb7: Zn 0.5625; β-Zn13Sb10: Zn 0.5652 | model | [1] Zhang 2022 | Table 7, p. 12, row 48; `ORC-WM54CTZZCV` |  |
| 788.15 | β-Zn3Sb2 + α-Zn9Sb7 ↔ β-Zn13Sb10 | β-Zn3Sb2: Zn 0.593; α-Zn9Sb7: Zn 0.5625; β-Zn13Sb10: Zn 0.5652 | experimental | [1] Zhang 2022; _cites Lo 2018_ [doi](https://doi.org/10.1039/c8dt02521e) | Table 7, p. 12, row 47; `ORC-URWIXU3EQQ` |  |
| 785.15 | β-Zn3Sb2 + α-Zn9Sb7 ↔ β-Zn13Sb10 | β-Zn3Sb2: Zn 0.595; α-Zn9Sb7: Zn 0.559; β-Zn13Sb10: Zn 0.571 | experimental | [1] Zhang 2022; _cites Izard 2001_ [doi](https://doi.org/10.1016/s0364-5916%2802%2900008-1) | Table 7, p. 12, row 46; `ORC-DGU3SHLKMZ` |  |
| 785.11 | α-Zn9Sb7 ↔ β-Zn13Sb10 + SbZn | α-Zn9Sb7: Zn 0.5625; β-Zn13Sb10: Zn 0.5652; SbZn: Zn 0.5 | model | [1] Zhang 2022 | Table 7, p. 12, row 51; `ORC-PR5ZXM2QSF` |  |
| 783.85 | L ↔ SbZn + Rho(Sb) | L: Zn 0.285; SbZn: Zn 0.5; Rho(Sb): Zn 0 | model | [1] Zhang 2022 | Table 7, p. 12, row 39; `ORC-YT5W2VYSP7` |  |
| 783.15 | α-Zn9Sb7 ↔ β-Zn13Sb10 + SbZn | α-Zn9Sb7: Zn 0.5625; β-Zn13Sb10: Zn 0.5652; SbZn: Zn 0.5 | experimental | [1] Zhang 2022; _cites Lo 2018_ [doi](https://doi.org/10.1039/c8dt02521e) | Table 7, p. 12, row 50; `ORC-UC2HC47S2O` |  |
| 782.15 | L ↔ SbZn + Rho(Sb) | L: Zn 0.31; SbZn: Zn 0.5; Rho(Sb): Zn 0 | experimental | [1] Zhang 2022; _cites Izard 2001_ [doi](https://doi.org/10.1016/s0364-5916%2802%2900008-1) | Table 7, p. 12, row 37; `ORC-XEX4PXBJQ4` |  |
| 782 | eutectic: L -> Sb + βSbZn | L: Zn 0.31; Sb: Zn 0; βSbZn: Zn 0.5 | experimental | [2] Li 2007; _cites Izard 2001_ [doi](https://doi.org/10.1016/s0364-5916%2802%2900008-1) | Table 2, p. 3, row 4; `ORC-C7DGYJ5TSU` |  |
| 780.15 | L ↔ SbZn + Rho(Sb) | L: Zn 0.313; SbZn: Zn 0.5; Rho(Sb): Zn 0 | model | [1] Zhang 2022; _cites Liu 2000_ [doi](https://doi.org/10.1361/105497100770339608) | Table 7, p. 12, row 38; `ORC-5RGUKS4OCA` |  |
| 780.15 | eutectic: L -> Sb + βSbZn | L: Zn 0.313; Sb: Zn 0.02; βSbZn: Zn 0.5 | model | [2] Li 2007; _cites Liu 2000_ [doi](https://doi.org/10.1361/105497100770339608) | Table 2, p. 3, row 3; `ORC-USLQXBESNL` |  |
| 779.65 | L ↔ SbZn + Rho(Sb) | SbZn: Zn 0.5; Rho(Sb): Zn 0 | experimental | [1] Zhang 2022; _cites Takei 1927_ | Table 7, p. 12, row 35; `ORC-7GTG4YDB6Y` |  |
| 779.15 | L ↔ SbZn + Rho(Sb) | L: Zn 0.318; SbZn: Zn 0.489; Rho(Sb): Zn 0 | experimental | [1] Zhang 2022; _cites Adjadj 2007_ [doi](https://doi.org/10.1016/j.jallcom.2006.04.051) | Table 7, p. 12, row 36; `ORC-BVHZRB4LN4` |  |
| 779.05 | eutectic: L -> Sb + βSbZn | L: Zn 0.371; Sb: Zn 0; βSbZn: Zn 0.5 | unspecified | [2] Li 2007; _cites Zabdyr 1993_ [doi](https://doi.org/10.1016/0364-5916%2893%2990005-v) | Table 2, p. 3, row 2; `ORC-WP4KKZ27O4` |  |
| 774 | eutectic: L -> Sb + βSbZn | L: Zn 0.315; Sb: Zn 0; βSbZn: Zn 0.5 | model | [2] Li 2007 | Table 2, p. 3, row 5; `ORC-34YPBUFYLB` |  |
| 767.6 | peritectoid: δSb3Zn4 + ξSb2Zn3 -> εSb3Zn4 | δSb3Zn4: Zn 0.559; ξSb2Zn3: Zn 0.595; εSb3Zn4: Zn 0.5714 | model | [2] Li 2007 | Table 2, p. 3, row 32; `ORC-D4OEUGFCGV` |  |
| 767.3 | eutectoid: δSb3Zn4 -> βSbZn + εSb3Zn4 | δSb3Zn4: Zn 0.559; βSbZn: Zn 0.5; εSb3Zn4: Zn 0.5714 | model | [2] Li 2007 | Table 2, p. 3, row 29; `ORC-TV2JZQR5HQ` |  |
| 767.15 | α-Zn9Sb7 ↔ β-Zn13Sb10 + SbZn | α-Zn9Sb7: Zn 0.559; β-Zn13Sb10: Zn 0.571; SbZn: Zn 0.5 | experimental | [1] Zhang 2022; _cites Izard 2001_ [doi](https://doi.org/10.1016/s0364-5916%2802%2900008-1) | Table 7, p. 12, row 49; `ORC-WF4B46RVKL` |  |
| 767 | peritectoid: δSb3Zn4 + ξSb2Zn3 -> εSb3Zn4 | δSb3Zn4: Zn 0.559; ξSb2Zn3: Zn 0.595; εSb3Zn4: Zn 0.565 | experimental | [2] Li 2007; _cites Izard 2001_ [doi](https://doi.org/10.1016/s0364-5916%2802%2900008-1) | Table 2, p. 3, row 31; `ORC-PT5MBNSXNX.0ccca9` |  |
| 767 | eutectoid: δSb3Zn4 -> βSbZn + εSb3Zn4 | δSb3Zn4: Zn 0.559; βSbZn: Zn 0.5; εSb3Zn4: Zn 0.565 | experimental | [2] Li 2007; _cites Izard 2001_ [doi](https://doi.org/10.1016/s0364-5916%2802%2900008-1) | Table 2, p. 3, row 28; `ORC-PT5MBNSXNX.fc92ac` |  |
| 764.85 | eutectoid: δSb3Zn4 -> εSb3Zn4 + ξSb2Zn3 | δSb3Zn4: Zn 0.575; εSb3Zn4: Zn 0.575; ξSb2Zn3: Zn 0.6 | model | [2] Li 2007; _cites Liu 2000_ [doi](https://doi.org/10.1361/105497100770339608) | Table 2, p. 3, row 30; `ORC-VLK6WEMKLE` |  |
| 764.55 | eutectoid: γSb5Zn6 -> βSbZn + εSb3Zn4 | γSb5Zn6: Zn 0.55; βSbZn: Zn 0.5; εSb3Zn4: Zn 0.575 | model | [2] Li 2007; _cites Liu 2000_ [doi](https://doi.org/10.1361/105497100770339608) | Table 2, p. 3, row 26; `ORC-Q53SA5CCRT` |  |
| 763.15 | L + β-Zn3Sb2 ↔ α-Zn3Sb2 | β-Zn3Sb2: Zn 0.593; α-Zn3Sb2: Zn 0.6 | experimental | [1] Zhang 2022; _cites Lo 2018_ [doi](https://doi.org/10.1039/c8dt02521e) | Table 7, p. 12, row 16; `ORC-PL4CRWKXXN` |  |
| 757.55 | L + β-Zn3Sb2 ↔ α-Zn3Sb2 | L: Zn 0.9086; β-Zn3Sb2: Zn 0.593; α-Zn3Sb2: Zn 0.6 | model | [1] Zhang 2022 | Table 7, p. 12, row 17; `ORC-HISBCAMRNP` |  |
| 733.2 | peritectic: ξSb2Zn3 + L -> ηSb2Zn3 | ξSb2Zn3: Zn 0.595; L: Zn 0.961; ηSb2Zn3: Zn 0.6 | model | [2] Li 2007 | Table 2, p. 3, row 39; `ORC-MYZKDNE3G5` |  |
| 733.15 | L + β-Zn3Sb2 ↔ α-Zn3Sb2 | β-Zn3Sb2: Zn 0.596; α-Zn3Sb2: Zn 0.6 | experimental | [1] Zhang 2022; _cites Adjadj 2007_ [doi](https://doi.org/10.1016/j.jallcom.2006.04.051) | Table 7, p. 12, row 15; `ORC-HEB43VA2PM` |  |
| 731.15 | L + β-Zn3Sb2 ↔ α-Zn3Sb2 | L: Zn 0.897; β-Zn3Sb2: Zn 0.595; α-Zn3Sb2: Zn 0.6 | experimental | [1] Zhang 2022; _cites Izard 2001_ [doi](https://doi.org/10.1016/s0364-5916%2802%2900008-1) | Table 7, p. 12, row 14; `ORC-XFXCOA2DU4` |  |
| 731 | peritectic: ξSb2Zn3 + L -> ηSb2Zn3 | ξSb2Zn3: Zn 0.595; L: Zn 0.897; ηSb2Zn3: Zn 0.6 | experimental | [2] Li 2007; _cites Izard 2001_ [doi](https://doi.org/10.1016/s0364-5916%2802%2900008-1) | Table 2, p. 3, row 38; `ORC-IIVHPUFUJY` |  |
| 728.15 | L + β-Zn3Sb2 ↔ α-Zn3Sb2 | L: Zn 0.928; β-Zn3Sb2: Zn 0.6; α-Zn3Sb2: Zn 0.62 | experimental | [1] Zhang 2022; _cites Liu 2000_ [doi](https://doi.org/10.1361/105497100770339608) | Table 7, p. 12, row 13; `ORC-KLOR3GK3PS` |  |
| 728.15 | peritectic: ξSb2Zn3 + L -> ηSb2Zn3 | ξSb2Zn3: Zn 0.6; L: Zn 0.928; ηSb2Zn3: Zn 0.62 | model | [2] Li 2007; _cites Liu 2000_ [doi](https://doi.org/10.1361/105497100770339608) | Table 2, p. 3, row 37; `ORC-XIOBGSGZ4N` |  |
| 715 | eutectoid: ξSb2Zn3 -> εSb3Zn4 + ηSb2Zn3 | ξSb2Zn3: Zn 0.595; εSb3Zn4: Zn 0.5714; ηSb2Zn3: Zn 0.6 | model | [2] Li 2007 | Table 2, p. 3, row 36; `ORC-G7ZAP5YU6U` |  |
| 714.15 | β-Zn3Sb2 ↔ β-Zn13Sb10 + α-Zn3Sb2 | β-Zn3Sb2: Zn 0.595; β-Zn13Sb10: Zn 0.571; α-Zn3Sb2: Zn 0.6 | experimental | [1] Zhang 2022; _cites Izard 2001_ [doi](https://doi.org/10.1016/s0364-5916%2802%2900008-1) | Table 7, p. 12, row 57; `ORC-YRKZTONJTW` |  |
| 714 | eutectoid: ξSb2Zn3 -> εSb3Zn4 + ηSb2Zn3 | ξSb2Zn3: Zn 0.595; εSb3Zn4: Zn 0.57; ηSb2Zn3: Zn 0.6 | experimental | [2] Li 2007; _cites Izard 2001_ [doi](https://doi.org/10.1016/s0364-5916%2802%2900008-1) | Table 2, p. 3, row 35; `ORC-ZPSEB47FOV` |  |
| 713.15 | eutectoid: ξSb2Zn3 -> εSb3Zn4 + ηSb2Zn3 | ξSb2Zn3: Zn 0.6; εSb3Zn4: Zn 0.575; ηSb2Zn3: Zn 0.62 | model | [2] Li 2007; _cites Liu 2000_ [doi](https://doi.org/10.1361/105497100770339608) | Table 2, p. 3, row 34; `ORC-FHBQ4AMLGF` |  |
| 713.15 | β-Zn3Sb2 ↔ β-Zn13Sb10 + α-Zn3Sb2 | β-Zn3Sb2: Zn 0.6; β-Zn13Sb10: Zn 0.575; α-Zn3Sb2: Zn 0.62 | model | [1] Zhang 2022; _cites Liu 2000_ [doi](https://doi.org/10.1361/105497100770339608) | Table 7, p. 12, row 59; `ORC-M3X6PTESKT` |  |
| 705.75 | β-Zn3Sb2 ↔ β-Zn13Sb10 + α-Zn3Sb2 | β-Zn3Sb2: Zn 0.593; β-Zn13Sb10: Zn 0.5652; α-Zn3Sb2: Zn 0.6 | model | [1] Zhang 2022 | Table 7, p. 12, row 60; `ORC-LWXVLXPSD4` |  |
| 698.15 | β-Zn3Sb2 ↔ β-Zn13Sb10 + α-Zn3Sb2 | β-Zn3Sb2: Zn 0.593; β-Zn13Sb10: Zn 0.5652; α-Zn3Sb2: Zn 0.6 | experimental | [1] Zhang 2022; _cites Lo 2018_ [doi](https://doi.org/10.1039/c8dt02521e) | Table 7, p. 12, row 58; `ORC-U4QHXEULDT` |  |
| 689.75 | L ↔ α-Zn3Sb2 + Hcp(Zn) | L: Zn 0.9872; α-Zn3Sb2: Zn 0.6; Hcp(Zn): Zn 0.9942 | model | [1] Zhang 2022; _cites Liu 2009_ [doi](https://doi.org/10.1016/j.calphad.2009.08.006) | Table 7, p. 12, row 11; `ORC-4YIYLNWD23` |  |
| 687.97 | quasi-peritectic: L + η-Sb2Zn3 -> ε-Sb3Zn4 + (Zn) | L: Sb 0.013, Zn 0.983; (Zn): Sb 0.006, Zn 0.994; ε: Sb 0.43, Zn 0.565 | model | [3] Liu 2009 | Table 8, p. 11, row 4; `ORC-PS3WQ4HIWL` |  |
| 687.15 | L ↔ α-Zn3Sb2 + Hcp(Zn) | L: Zn 0.987; α-Zn3Sb2: Zn 0.608; Hcp(Zn): Zn 1 | experimental | [1] Zhang 2022; _cites Adjadj 2007_ [doi](https://doi.org/10.1016/j.jallcom.2006.04.051) | Table 7, p. 12, row 8; `ORC-7LXH6USAN4` |  |
| 687 | eutectic: L -> ηSb2Zn3 + Zn | L: Zn 0.9875; ηSb2Zn3: Zn 0.6; Zn: Zn 1 | model | [2] Li 2007 | Table 2, p. 3, row 47; `ORC-PCWLYXRUPB` |  |
| 686.95 | L ↔ α-Zn3Sb2 + Hcp(Zn) | L: Zn 0.984; α-Zn3Sb2: Zn 0.6; Hcp(Zn): Zn 1 | model | [1] Zhang 2022 | Table 7, p. 12, row 12; `ORC-LJ665SWECY` |  |
| 686.15 | L ↔ α-Zn3Sb2 + Hcp(Zn) | L: Zn 0.978; α-Zn3Sb2: Zn 0.6; Hcp(Zn): Zn 1 | experimental | [1] Zhang 2022; _cites Izard 2001_ [doi](https://doi.org/10.1016/s0364-5916%2802%2900008-1) | Table 7, p. 12, row 7; `ORC-WJL7OE3KYY` |  |
| 686 | eutectic: L -> ηSb2Zn3 + Zn | L: Zn 0.978; ηSb2Zn3: Zn 0.6; Zn: Zn 1 | experimental | [2] Li 2007; _cites Izard 2001_ [doi](https://doi.org/10.1016/s0364-5916%2802%2900008-1) | Table 2, p. 3, row 46; `ORC-KT2GC4QVFN` |  |
| 684.65 | eutectic: L -> ηSb2Zn3 + Zn | L: Zn 0.983; ηSb2Zn3: Zn 0.6; Zn: Zn 1 | unspecified | [2] Li 2007; _cites Zabdyr 1993_ [doi](https://doi.org/10.1016/0364-5916%2893%2990005-v) | Table 2, p. 3, row 44; `ORC-4NSZIO35TU` |  |
| 684.65 | L ↔ α-Zn3Sb2 + Hcp(Zn) | L: Zn 0.983; α-Zn3Sb2: Zn 0.6; Hcp(Zn): Zn 1 | experimental | [1] Zhang 2022; _cites Takei 1927_ | Table 7, p. 12, row 10; `ORC-AVOXIQLKU5` |  |
| 683.15 | α-Zn3Sb2 ↔ β-Zn13Sb10 + Hcp(Zn) | α-Zn3Sb2: Zn 0.6; β-Zn13Sb10: Zn 0.5652; Hcp(Zn): Zn 1 | experimental | [1] Zhang 2022; _cites Lo 2018_ [doi](https://doi.org/10.1039/c8dt02521e) | Table 7, p. 12, row 55; `ORC-A5O44X26OX` |  |
| 682.15 | eutectic: L -> ηSb2Zn3 + Zn | L: Zn 0.978; ηSb2Zn3: Zn 0.62; Zn: Zn 1 | model | [2] Li 2007; _cites Liu 2000_ [doi](https://doi.org/10.1361/105497100770339608) | Table 2, p. 3, row 45; `ORC-53FKLBZLO7` |  |
| 682.15 | L ↔ α-Zn3Sb2 + Hcp(Zn) | L: Zn 0.978; α-Zn3Sb2: Zn 0.62; Hcp(Zn): Zn 1 | experimental | [1] Zhang 2022; _cites Liu 2000_ [doi](https://doi.org/10.1361/105497100770339608) | Table 7, p. 12, row 9; `ORC-NBJBC4U5WB` |  |
| 681.15 | α-Zn3Sb2 ↔ β-Zn13Sb10 + Hcp(Zn) | α-Zn3Sb2: Zn 0.62; β-Zn13Sb10: Zn 0.575; Hcp(Zn): Zn 1 | experimental | [1] Zhang 2022; _cites Liu 2000_ [doi](https://doi.org/10.1361/105497100770339608) | Table 7, p. 12, row 54; `ORC-6ODN3GR3SC` |  |
| 681.15 | eutectoid: ηSb2Zn3 -> εSb3Zn4 + Zn | ηSb2Zn3: Zn 0.62; εSb3Zn4: Zn 0.575; Zn: Zn 1 | model | [2] Li 2007; _cites Liu 2000_ [doi](https://doi.org/10.1361/105497100770339608) | Table 2, p. 3, row 41; `ORC-NIA7YV7L4D` |  |
| 678.25 | eutectoid: ηSb2Zn3 -> εSb3Zn4 + Zn | ηSb2Zn3: Zn 0.6; εSb3Zn4: Zn 0.571; Zn: Zn 1 | unspecified | [2] Li 2007; _cites Zabdyr 1993_ [doi](https://doi.org/10.1016/0364-5916%2893%2990005-v) | Table 2, p. 3, row 40; `ORC-BJPO6F7BXK` |  |
| 678.25 | α-Zn3Sb2 ↔ β-Zn13Sb10 + Hcp(Zn) | α-Zn3Sb2: Zn 0.6; β-Zn13Sb10: Zn 0.571; Hcp(Zn): Zn 1 | experimental | [1] Zhang 2022; _cites Adjadj 2007_ [doi](https://doi.org/10.1016/j.jallcom.2006.04.051) | Table 7, p. 12, row 52; `ORC-RJFDUBZFOA` |  |
| 678 | eutectoid: ηSb2Zn3 -> εSb3Zn4 + Zn | ηSb2Zn3: Zn 0.6; εSb3Zn4: Zn 0.5714; Zn: Zn 1 | model | [2] Li 2007 | Table 2, p. 3, row 43; `ORC-NLUNVWGWKJ` |  |
| 677.45 | α-Zn3Sb2 ↔ β-Zn13Sb10 + Hcp(Zn) | α-Zn3Sb2: Zn 0.6; β-Zn13Sb10: Zn 0.5652; Hcp(Zn): Zn 1 | model | [1] Zhang 2022 | Table 7, p. 12, row 56; `ORC-4H4DJ4RW5Z` |  |
| 677.15 | α-Zn3Sb2 ↔ β-Zn13Sb10 + Hcp(Zn) | α-Zn3Sb2: Zn 0.6; β-Zn13Sb10: Zn 0.57; Hcp(Zn): Zn 1 | experimental | [1] Zhang 2022; _cites Izard 2001_ [doi](https://doi.org/10.1016/s0364-5916%2802%2900008-1) | Table 7, p. 12, row 53; `ORC-ORFXMYD5KZ` |  |
| 677 | eutectoid: ηSb2Zn3 -> εSb3Zn4 + Zn | ηSb2Zn3: Zn 0.6; εSb3Zn4: Zn 0.57; Zn: Zn 1 | experimental | [2] Li 2007; _cites Izard 2001_ [doi](https://doi.org/10.1016/s0364-5916%2802%2900008-1) | Table 2, p. 3, row 42; `ORC-YTZNLBFFD6` |  |
| 256.15 | polymorphic: β-Zn13Sb10 ↔ α-Zn13Sb10 | β-Zn13Sb10: Zn 0.5652; α-Zn13Sb10: Zn 0.5652 | experimental | [1] Zhang 2022; _cites Mozharivskyj 2004_ [doi](https://doi.org/10.1021/cm035274a) | Table 7, p. 12, row 62; `ORC-QV7SINT6UG` |  |
| 256.15 | polymorphic: α-Zn13Sb10 ↔ β-Zn13Sb10 | α-Zn13Sb10: Zn 0.5652; β-Zn13Sb10: Zn 0.5652 | experimental | [1] Zhang 2022; _cites Mozharivskyj 2004_ [doi](https://doi.org/10.1021/cm035274a) | Table 7, p. 12, row 61; `ORC-YVMYB3LTN2` |  |
| 253.85 | α-Zn13Sb10 + SbZn ↔ β-Zn13Sb10 | α-Zn13Sb10: Zn 0.5652; SbZn: Zn 0.5; β-Zn13Sb10: Zn 0.5652 | model | [1] Zhang 2022 | Table 7, p. 12, row 68; `ORC-HT7O3JZL7Z` |  |
| 253.85 | α-Zn13Sb10 ↔ β-Zn13Sb10 + Hcp(Zn) | α-Zn13Sb10: Zn 0.5652; β-Zn13Sb10: Zn 0.5652; Hcp(Zn): Zn 1 | model | [1] Zhang 2022 | Table 7, p. 12, row 67; `ORC-MGXNSP3G4O` |  |
| 253.85 | polymorphic: β-Zn13Sb10 ↔ α-Zn13Sb10 | β-Zn13Sb10: Zn 0.5652; α-Zn13Sb10: Zn 0.5652 | model | [1] Zhang 2022 | Table 7, p. 12, row 63; `ORC-VAM2DLED66` |  |
| 234.35 | α-Zn13Sb10 ↔ α'-Zn13Sb10 + SbZn | α-Zn13Sb10: Zn 0.5652; SbZn: Zn 0.5 | model | [1] Zhang 2022 | Table 7, p. 12, row 70; `ORC-AP4YR6ZTS4` |  |
| 234.35 | α-Zn13Sb10 + Hcp(Zn) ↔ α'-Zn13Sb10 | α-Zn13Sb10: Zn 0.5652; Hcp(Zn): Zn 1 | model | [1] Zhang 2022 | Table 7, p. 12, row 69; `ORC-CSC2U6SA66` |  |
| 234.35 | polymorphic: α-Zn13Sb10 ↔ α'-Zn13Sb10 | α-Zn13Sb10: Zn 0.5652 | model | [1] Zhang 2022 | Table 7, p. 12, row 66; `ORC-R2SF3CPC4R` |  |
| 232.15 | polymorphic: α-Zn13Sb10 ↔ α'-Zn13Sb10 | α-Zn13Sb10: Zn 0.5652 | experimental | [1] Zhang 2022; _cites Mozharivskyj 2004_ [doi](https://doi.org/10.1021/cm035274a) | Table 7, p. 12, row 65; `ORC-JRB2NYZYXS` |  |
| 232.15 | polymorphic: α'-Zn13Sb10 ↔ α-Zn13Sb10 | α'-Zn13Sb10: Zn 0.5652 | experimental | [1] Zhang 2022; _cites Mozharivskyj 2004_ [doi](https://doi.org/10.1021/cm035274a) | Table 7, p. 12, row 64; `ORC-S6YNVBCDSP` |  |

## Formation enthalpies

Literature values in kJ/mol-atom where the per-atom basis is known. DFT columns: the lowest-energy entry at the same composition (Materials Project 2026.04.13, OQMD v1.8; different energy references, never averaged), from [dft_parity.json](https://data.orchid-project.org/literature/dft_parity.json).

Table: Enthalpies of formation, Sb–Zn system (58)

| Phase | Compound | Value | T (K) | Class | MP DFT (kJ/mol-atom) | OQMD DFT (kJ/mol-atom) | Source | Location | Quote |
|---|---|---:|---:|---|---:|---:|---|---|---|
| SbZn | [SbZn](https://data.orchid-project.org/compounds/SbZn.html) | -25.086 kJ/mol-atom | 804 | model | -11.964 (mp-aaaaabcz) | -3.464 (oqmd-2031988) | [2] Li 2007 | Table 4, p. 4, row 9; `ORC-GJR4EUMWYF.c040bc` |  |
| SbZn | [SbZn](https://data.orchid-project.org/compounds/SbZn.html) | -24.9572 kJ/mol-atom | 804.15 | model | -11.964 (mp-aaaaabcz) | -3.464 (oqmd-2031988) | [1] Zhang 2022 | Table 8, p. 14, row 12; `ORC-LUMCSKWV67.d3c06c` |  |
| SbZn | [SbZn](https://data.orchid-project.org/compounds/SbZn.html) | -20.011 kJ/mol-atom | 804 | experimental | -11.964 (mp-aaaaabcz) | -3.464 (oqmd-2031988) | [2] Li 2007; _cites DeWitt 1939_ [doi](https://doi.org/10.1021/ja01266a055) | Table 4, p. 4, row 10; `ORC-6KZI7KX5JB.0a3b52` |  |
| SbZn | [SbZn](https://data.orchid-project.org/compounds/SbZn.html) | -20.011 kJ/mol-atom | 804.15 | experimental | -11.964 (mp-aaaaabcz) | -3.464 (oqmd-2031988) | [1] Zhang 2022; _cites Seltz 1940_ [doi](https://doi.org/10.1149/1.3521200) | Table 8, p. 14, row 11; `ORC-KGYH6LY3EJ.84a3f9` |  |
| SbZn | [SbZn](https://data.orchid-project.org/compounds/SbZn.html) | -15.149 kJ/mol-atom | 750 | model | -11.964 (mp-aaaaabcz) | -3.464 (oqmd-2031988) | [2] Li 2007 | Table 4, p. 4, row 13; `ORC-K7LVIQZ7M5.1812cf` |  |
| SbZn | [SbZn](https://data.orchid-project.org/compounds/SbZn.html) | -15.102 kJ/mol-atom | 750.15 | model | -11.964 (mp-aaaaabcz) | -3.464 (oqmd-2031988) | [1] Zhang 2022 | Table 8, p. 14, row 10; `ORC-KRTUSQP322.d2235c` |  |
| SbZn | [SbZn](https://data.orchid-project.org/compounds/SbZn.html) | -15.052 kJ/mol-atom | 298.15 | experimental | -11.964 (mp-aaaaabcz) | -3.464 (oqmd-2031988) | [2] Li 2007; _cites Oelsen 1937_ | Table 4, p. 4, row 12; `ORC-27XO4HPAOZ.560330` |  |
| SbZn | [SbZn](https://data.orchid-project.org/compounds/SbZn.html) | -15.052 kJ/mol-atom | 298.15 | experimental | -11.964 (mp-aaaaabcz) | -3.464 (oqmd-2031988) | [1] Zhang 2022; _cites Oelsen 1937_ | Table 8, p. 14, row 2; `ORC-VZTUEMSCRU` |  |
| SbZn | [SbZn](https://data.orchid-project.org/compounds/SbZn.html) | -14.853 kJ/mol-atom | 298.15 | experimental | -11.964 (mp-aaaaabcz) | -3.464 (oqmd-2031988) | [2] Li 2007; _cites Hirayama 1963_ [doi](https://doi.org/10.1149/1.2425680) | Table 4, p. 4, row 6; `ORC-2MDAMARU3A.3ab478` |  |
| SbZn | [SbZn](https://data.orchid-project.org/compounds/SbZn.html) | -14.853 kJ/mol-atom | 298.15 | experimental | -11.964 (mp-aaaaabcz) | -3.464 (oqmd-2031988) | [1] Zhang 2022; _cites Hirayama 1963_ [doi](https://doi.org/10.1149/1.2425680) | Table 8, p. 14, row 3; `ORC-7EXHM5F5PH` |  |
| SbZn | [SbZn](https://data.orchid-project.org/compounds/SbZn.html) | -12.845 kJ/mol-atom | 298.15 | experimental | -11.964 (mp-aaaaabcz) | -3.464 (oqmd-2031988) | [2] Li 2007; _cites DeWitt 1939_ [doi](https://doi.org/10.1021/ja01266a055) | Table 4, p. 4, row 8; `ORC-5FM66R6W4S.2b6a0c` |  |
| SbZn | [SbZn](https://data.orchid-project.org/compounds/SbZn.html) | -12.845 kJ/mol-atom | 298.15 | experimental | -11.964 (mp-aaaaabcz) | -3.464 (oqmd-2031988) | [1] Zhang 2022; _cites Seltz 1940_ [doi](https://doi.org/10.1149/1.3521200) | Table 8, p. 14, row 1; `ORC-O5PVWPM5VG` |  |
| SbZn | [SbZn](https://data.orchid-project.org/compounds/SbZn.html) | -11.89 kJ/mol-atom | 750.15 | experimental | -11.964 (mp-aaaaabcz) | -3.464 (oqmd-2031988) | [1] Zhang 2022; _cites Zabdyr 1981_ | Table 8, p. 14, row 9; `ORC-UN32LPDZOH.9644de` |  |
| SbZn | [SbZn](https://data.orchid-project.org/compounds/SbZn.html) | -11.89 kJ/mol-atom | 750 | experimental | -11.964 (mp-aaaaabcz) | -3.464 (oqmd-2031988) | [2] Li 2007; _cites Zabdyr 1981_ | Table 4, p. 4, row 14; `ORC-UZ5GR3NBH7.4f3489` |  |
| SbZn | [SbZn](https://data.orchid-project.org/compounds/SbZn.html) | -11.4879 kJ/mol-atom | 298.15 | model | -11.964 (mp-aaaaabcz) | -3.464 (oqmd-2031988) | [1] Zhang 2022 | Table 8, p. 14, row 4; `ORC-L5MAOTGUXB.e42c9a` |  |
| SbZn | [SbZn](https://data.orchid-project.org/compounds/SbZn.html) | -11.4875 kJ/mol-atom | 420.15 | model | -11.964 (mp-aaaaabcz) | -3.464 (oqmd-2031988) | [1] Zhang 2022 | Table 8, p. 14, row 6; `ORC-ZFD2AE7PNV.b37398` |  |
| SbZn | [SbZn](https://data.orchid-project.org/compounds/SbZn.html) | -11.459 kJ/mol-atom | 298.15 | model | -11.964 (mp-aaaaabcz) | -3.464 (oqmd-2031988) | [2] Li 2007 | Table 4, p. 4, row 7; `ORC-UBYA6L7PJN.34975c` |  |
| SbZn | [SbZn](https://data.orchid-project.org/compounds/SbZn.html) | -11.455 kJ/mol-atom | 420 | model | -11.964 (mp-aaaaabcz) | -3.464 (oqmd-2031988) | [2] Li 2007 | Table 4, p. 4, row 1; `ORC-LAENHZK3Y6.a8b5fd` |  |
| SbZn | [SbZn](https://data.orchid-project.org/compounds/SbZn.html) | -11.455 kJ/mol-atom | 700 | model | -11.964 (mp-aaaaabcz) | -3.464 (oqmd-2031988) | [2] Li 2007 | Table 4, p. 4, row 3; `ORC-N4ABGBP2DJ.0ae061` |  |
| SbZn | [SbZn](https://data.orchid-project.org/compounds/SbZn.html) | -11.4395 kJ/mol-atom | 700.15 | model | -11.964 (mp-aaaaabcz) | -3.464 (oqmd-2031988) | [1] Zhang 2022 | Table 8, p. 14, row 8; `ORC-ZF4IE5PFSW.0ba69c` |  |
| SbZn | [SbZn](https://data.orchid-project.org/compounds/SbZn.html) | -10.9 kJ/mol-atom | 420.15 | experimental | -11.964 (mp-aaaaabcz) | -3.464 (oqmd-2031988) | [1] Zhang 2022; _cites Goryacheva 1997_ | Table 8, p. 14, row 5; `ORC-QB7KEQZ7NP.753ee0` |  |
| SbZn | [SbZn](https://data.orchid-project.org/compounds/SbZn.html) | -10.9 kJ/mol-atom | 420 | experimental | -11.964 (mp-aaaaabcz) | -3.464 (oqmd-2031988) | [2] Li 2007; _cites Goryacheva 1997_ | Table 4, p. 4, row 2; `ORC-YVLBOQ5WZM.2cc9d4` |  |
| SbZn | [SbZn](https://data.orchid-project.org/compounds/SbZn.html) | -9.517 kJ/mol-atom | 700.15 | experimental | -11.964 (mp-aaaaabcz) | -3.464 (oqmd-2031988) | [1] Zhang 2022; _cites Hultgren 1978_ | Table 8, p. 14, row 7; `ORC-WP35MO5EGA.5dfe3e` |  |
| SbZn | [SbZn](https://data.orchid-project.org/compounds/SbZn.html) | -9.517 kJ/mol-atom | 700 | model | -11.964 (mp-aaaaabcz) | -3.464 (oqmd-2031988) | [2] Li 2007; _cites Hulgren 1973_ | Table 4, p. 4, row 4; `ORC-ZHI4RONI5E.0b26c2` |  |
| α-Zn9Sb7 |  | -21.3989 kJ/mol-atom | 806.15 | model |  |  | [1] Zhang 2022 | Table 8, p. 14, row 16; `ORC-UQLMRPUW7V.8bd61b` |  |
| α-Zn9Sb7 |  | -12.6041 kJ/mol-atom | 800.15 | model |  |  | [1] Zhang 2022 | Table 8, p. 14, row 18; `ORC-WN6Q6YN6LT.acd3a4` |  |
| α-Zn9Sb7 |  | -12.379 kJ/mol-atom | 806.15 | experimental |  |  | [1] Zhang 2022; _cites Seltz 1940_ [doi](https://doi.org/10.1149/1.3521200) | Table 8, p. 14, row 15; `ORC-37FC3SIAD7.bccaa4` |  |
| α-Zn9Sb7 |  | -4.35 kJ/mol-atom | 800.15 | experimental |  |  | [1] Zhang 2022; _cites Zabdyr 1981_ | Table 8, p. 14, row 17; `ORC-HTTS63YOJG.aceeb6` |  |
| β(SbZn) | [SbZn](https://data.orchid-project.org/compounds/SbZn.html) | -11.89 kJ/mol-atom | 723.15 | experimental | -11.964 (mp-aaaaabcz) | -3.464 (oqmd-2031988) | [4] Liu 2000; _cites Zabdyr 1981_ | Table 2, p. 3, row 11; `ORC-WYL2GD26DJ.21e8e6` |  |
| β(SbZn) | [SbZn](https://data.orchid-project.org/compounds/SbZn.html) | -11.541 kJ/mol-atom |  | model | -11.964 (mp-aaaaabcz) | -3.464 (oqmd-2031988) | [4] Liu 2000 | Table 2, p. 3, row 10; `ORC-CFKGQIIWYF.4e66c7` |  |
| β(SbZn) | [SbZn](https://data.orchid-project.org/compounds/SbZn.html) | -9.517 kJ/mol-atom ± 0.627 | 700.15 | experimental | -11.964 (mp-aaaaabcz) | -3.464 (oqmd-2031988) | [4] Liu 2000; _cites Hultgren 1973_ | Table 2, p. 3, row 12; `ORC-LXX7M4I7II.8ceaee` |  |
| β-Zn13Sb10 | [Sb10Zn13](https://data.orchid-project.org/compounds/Sb10Zn13.html) | -10.7 kJ/mol-atom | 420.15 | experimental | -9.34 (mp-aaabgmhw) |  | [1] Zhang 2022; _cites Goryacheva 1997_ | Table 8, p. 14, row 19; `ORC-TIHVTPDIMR.d86e1c` |  |
| β-Zn13Sb10 | [Sb10Zn13](https://data.orchid-project.org/compounds/Sb10Zn13.html) | -9.6151 kJ/mol-atom | 420.15 | model | -9.34 (mp-aaabgmhw) |  | [1] Zhang 2022 | Table 8, p. 14, row 20; `ORC-RUE7NCC2QK.4625ea` |  |
| β-Zn13Sb10 | [Sb10Zn13](https://data.orchid-project.org/compounds/Sb10Zn13.html) | -9.607 kJ/mol-atom | 600.15 | model | -9.34 (mp-aaabgmhw) |  | [1] Zhang 2022 | Table 8, p. 14, row 22; `ORC-5FN2IJMMAY.0adc31` |  |
| β-Zn13Sb10 | [Sb10Zn13](https://data.orchid-project.org/compounds/Sb10Zn13.html) | -5.28 kJ/mol-atom | 600.15 | experimental | -9.34 (mp-aaabgmhw) |  | [1] Zhang 2022; _cites Zabdyr 1981_ | Table 8, p. 14, row 21; `ORC-EVZXBKPOLW.4a10f8` |  |
| β-Zn3Sb2 | [Sb2Zn3](https://data.orchid-project.org/compounds/Sb2Zn3.html) | -10.434 kJ/mol-atom | 800.15 | model |  | -1.685 (oqmd-994658) | [1] Zhang 2022 | Table 8, p. 14, row 24; `ORC-JVUQCUY4PL.cd2875` |  |
| β-Zn3Sb2 | [Sb2Zn3](https://data.orchid-project.org/compounds/Sb2Zn3.html) | -5.78 kJ/mol-atom | 800.15 | experimental |  | -1.685 (oqmd-994658) | [1] Zhang 2022; _cites Zabdyr 1981_ | Table 8, p. 14, row 23; `ORC-O44M4ZW6TJ.25c16b` |  |
| β-Zn9Sb7 |  | -20.551 kJ/mol-atom | 826.15 | experimental |  |  | [1] Zhang 2022; _cites Seltz 1940_ [doi](https://doi.org/10.1149/1.3521200) | Table 8, p. 14, row 13; `ORC-5XSEGZQBR3.c07b17` |  |
| β-Zn9Sb7 |  | -18.6235 kJ/mol-atom | 826.15 | model |  |  | [1] Zhang 2022 | Table 8, p. 14, row 14; `ORC-TVM3BDOS7V.3380af` |  |
| γ(Sb9Zn11) |  | -8.749 kJ/mol-atom |  | model |  |  | [4] Liu 2000 | Table 2, p. 3, row 13; `ORC-U6ELHFN72M.0869c4` |  |
| δ(Sb17Zn23) |  | -7.348 kJ/mol-atom |  | model |  |  | [4] Liu 2000 | Table 2, p. 3, row 14; `ORC-VLOMHAIR5Q.1b0fad` |  |
| δ(Sb17Zn23) |  | -4.35 kJ/mol-atom | 298.15 | experimental |  |  | [4] Liu 2000; _cites Zabdyr 1981_ | Table 2, p. 3, row 15; `ORC-QHEFWJN2FX.5cafc3` |  |
| δ(Sb4Zn6) | [Sb2Zn3](https://data.orchid-project.org/compounds/Sb2Zn3.html) | -5.78 kJ/mol-atom | 298.15 | experimental |  | -1.685 (oqmd-994658) | [4] Liu 2000; _cites Zabdyr 1981_ | Table 2, p. 3, row 19; `ORC-SEAEWZOJ7K.ef3226` |  |
| δ(Sb4Zn6) | [Sb2Zn3](https://data.orchid-project.org/compounds/Sb2Zn3.html) | -4.918 kJ/mol-atom |  | model |  | -1.685 (oqmd-994658) | [4] Liu 2000 | Table 2, p. 3, row 18; `ORC-OY2ENCQXV6.ca42e0` |  |
| δ-Sb3Zn4 | [Sb3Zn4](https://data.orchid-project.org/compounds/Sb3Zn4.html) | -17.878 kJ/mol-atom | 806 | model |  | 14.359 (oqmd-760143) | [2] Li 2007 | Table 4, p. 4, row 17; `ORC-R4WK4SK6PB.425011` |  |
| δ-Sb3Zn4 | [Sb3Zn4](https://data.orchid-project.org/compounds/Sb3Zn4.html) | -12.379 kJ/mol-atom | 806 | experimental |  | 14.359 (oqmd-760143) | [2] Li 2007; _cites DeWitt 1939_ [doi](https://doi.org/10.1021/ja01266a055) | Table 4, p. 4, row 18; `ORC-7VPUF5XRGG.2a862c` |  |
| δ-Sb3Zn4 | [Sb3Zn4](https://data.orchid-project.org/compounds/Sb3Zn4.html) | -10.707 kJ/mol-atom | 800 | model |  | 14.359 (oqmd-760143) | [2] Li 2007 | Table 4, p. 4, row 19; `ORC-THQ7S4MRBN.008989` |  |
| δ-Sb3Zn4 | [Sb3Zn4](https://data.orchid-project.org/compounds/Sb3Zn4.html) | -4.35 kJ/mol-atom | 800 | experimental |  | 14.359 (oqmd-760143) | [2] Li 2007; _cites Zabdyr 1981_ | Table 4, p. 4, row 20; `ORC-NZUTUZNKYH.3f1124` |  |
| δ′-Sb3Zn4 | [Sb3Zn4](https://data.orchid-project.org/compounds/Sb3Zn4.html) | -20.551 kJ/mol-atom | 826 | experimental |  | 14.359 (oqmd-760143) | [2] Li 2007; _cites DeWitt 1939_ [doi](https://doi.org/10.1021/ja01266a055) | Table 4, p. 4, row 16; `ORC-LJ7NTT3MZM.0521f9` |  |
| δ′-Sb3Zn4 | [Sb3Zn4](https://data.orchid-project.org/compounds/Sb3Zn4.html) | -16.028 kJ/mol-atom | 826 | model |  | 14.359 (oqmd-760143) | [2] Li 2007 | Table 4, p. 4, row 15; `ORC-I5P7YJ6ZTR.05380b` |  |
| ε(Sb17Zn23) |  | -7.731 kJ/mol-atom |  | model |  |  | [4] Liu 2000 | Table 2, p. 3, row 16; `ORC-XU6AY7QWWN.bae207` |  |
| ε(Sb17Zn23) |  | -5.28 kJ/mol-atom | 298.15 | experimental |  |  | [4] Liu 2000; _cites Zabdyr 1981_ | Table 2, p. 3, row 17; `ORC-SUB2ZPFKEO.9ee9a2` |  |
| ε-Sb3Zn4 | [Sb3Zn4](https://data.orchid-project.org/compounds/Sb3Zn4.html) | -10.7 kJ/mol-atom | 420 | experimental |  | 14.359 (oqmd-760143) | [2] Li 2007; _cites Goryacheva 1997_ | Table 4, p. 4, row 22; `ORC-GEOHQLQG2H.60a4e1` |  |
| ε-Sb3Zn4 | [Sb3Zn4](https://data.orchid-project.org/compounds/Sb3Zn4.html) | -9.378 kJ/mol-atom | 600 | model |  | 14.359 (oqmd-760143) | [2] Li 2007 | Table 4, p. 4, row 23; `ORC-7A2QTKMYRH.003111` |  |
| ε-Sb3Zn4 | [Sb3Zn4](https://data.orchid-project.org/compounds/Sb3Zn4.html) | -9.378 kJ/mol-atom | 420 | model |  | 14.359 (oqmd-760143) | [2] Li 2007 | Table 4, p. 4, row 21; `ORC-E76ESIXAL7.7546d1` |  |
| ε-Sb3Zn4 | [Sb3Zn4](https://data.orchid-project.org/compounds/Sb3Zn4.html) | -5.28 kJ/mol-atom | 600 | experimental |  | 14.359 (oqmd-760143) | [2] Li 2007; _cites Zabdyr 1981_ | Table 4, p. 4, row 24; `ORC-6OOPELOSIS.274e9e` |  |
| ξ-Sb2Zn3 | [Sb2Zn3](https://data.orchid-project.org/compounds/Sb2Zn3.html) | -9.839 kJ/mol-atom | 800 | model |  | -1.685 (oqmd-994658) | [2] Li 2007 | Table 4, p. 4, row 25; `ORC-XD2QFXBABL.a4f923` |  |
| ξ-Sb2Zn3 | [Sb2Zn3](https://data.orchid-project.org/compounds/Sb2Zn3.html) | -5.78 kJ/mol-atom | 800 | experimental |  | -1.685 (oqmd-994658) | [2] Li 2007; _cites Zabdyr 1981_ | Table 4, p. 4, row 26; `ORC-NNBDCYEADO.98dc51` |  |

## Other properties

### Phase transition (20)

Table: Phase transition, Sb–Zn system

| Property | Value | T (K) | Phases / composition | Class | Source | Location | Quote |
|---|---:|---:|---|---|---|---|---|
| Phase transition | 682.15 K | 682.15 | eutectic: L -> η + (Zn); _alloy: Sb 0.166, Zn 0.834_ | experimental | [4] Liu 2000 | Table 5, p. 8, row 15; `ORC-CEK5USEOI5` |  |
| Phase transition | 682.15 K | 682.15 | eutectic: L -> η + (Zn); _alloy: Sb 0.236, Zn 0.764_ | experimental | [4] Liu 2000 | Table 5, p. 8, row 12; `ORC-FJKABKPUUF` |  |
| Phase transition | 682.15 K | 682.15 | eutectic: L -> η + (Zn); _alloy: Sb 0.276, Zn 0.724_ | experimental | [4] Liu 2000 | Table 5, p. 8, row 11; `ORC-K3YAMV7T2M` |  |
| Phase transition | 682.15 K | 682.15 | eutectic: L -> η + (Zn); _alloy: Sb 0.224, Zn 0.776_ | experimental | [4] Liu 2000 | Table 5, p. 8, row 13; `ORC-QOIDNA2KNQ` |  |
| Phase transition | 683.15 K | 683.15 | eutectic: L -> η + (Zn); _alloy: Sb 0.187, Zn 0.813_ | experimental | [4] Liu 2000 | Table 5, p. 8, row 14; `ORC-WOCE7Z454X` |  |
| Phase transition | 717.65 K | 717.65 | congruent transformation: ξSb2Zn3 -> ηSb2Zn3; _ξSb2Zn3: Zn 0.6; ηSb2Zn3: Zn 0.6_ | unspecified | [2] Li 2007; _cites Zabdyr 1993_ [doi](https://doi.org/10.1016/0364-5916%2893%2990005-v) | Table 2, p. 3, row 33; `ORC-CI6MM3X4UF` |  |
| Phase transition | 728.15 K | 728.15 | peritectic: ζ + L -> η; _alloy: Sb 0.276, Zn 0.724_ | experimental | [4] Liu 2000 | Table 5, p. 8, row 6; `ORC-AAROKHQYRP` |  |
| Phase transition | 728.15 K | 728.15 | peritectic: ζ + L -> η; _alloy: Sb 0.166, Zn 0.834_ | experimental | [4] Liu 2000 | Table 5, p. 8, row 10; `ORC-BHQXUMQFBQ` |  |
| Phase transition | 728.15 K | 728.15 | peritectic: ζ + L -> η; _alloy: Sb 0.224, Zn 0.776_ | experimental | [4] Liu 2000 | Table 5, p. 8, row 8; `ORC-FM2RBAZ6RQ` |  |
| Phase transition | 728.15 K | 728.15 | peritectic: ζ + L -> η; _alloy: Sb 0.236, Zn 0.764_ | experimental | [4] Liu 2000 | Table 5, p. 8, row 7; `ORC-PC6A76JUDU` |  |
| Phase transition | 728.15 K | 728.15 | peritectic: ζ + L -> η; _alloy: Sb 0.187, Zn 0.813_ | experimental | [4] Liu 2000 | Table 5, p. 8, row 9; `ORC-WN3ZAH5YOE` |  |
| Phase transition | 765.25 K | 765.25 | congruent transformation: δSb3Zn4 -> εSb3Zn4; _δSb3Zn4: Zn 0.571; εSb3Zn4: Zn 0.571_ | unspecified | [2] Li 2007; _cites Zabdyr 1993_ [doi](https://doi.org/10.1016/0364-5916%2893%2990005-v) | Table 2, p. 3, row 27; `ORC-N2WFMXG67Y` |  |
| Phase transition | 835.75 K | 835.75 | congruent melting: L -> δSb3Zn4; _L: Zn 0.571; δSb3Zn4: Zn 0.571_ | unspecified | [2] Li 2007; _cites Zabdyr 1993_ [doi](https://doi.org/10.1016/0364-5916%2893%2990005-v) | Table 2, p. 3, row 10; `ORC-6NL4J47C6E` |  |
| Phase transition | 836.15 K | 836.15 | congruent melting: L -> ξSb2Zn3; _L: Zn 0.6; ξSb2Zn3: Zn 0.6_ | model | [2] Li 2007; _cites Liu 2000_ [doi](https://doi.org/10.1361/105497100770339608) | Table 2, p. 3, row 18; `ORC-GKCB2EIZEM` |  |
| Phase transition | 836.2 K | 836.2 | congruent melting: L -> δ'Sb3Zn4; _L: Zn 0.558; δ'Sb3Zn4: Zn 0.558_ | model | [2] Li 2007 | Table 2, p. 3, row 12; `ORC-W3Y52BXABU` |  |
| Phase transition | 836.8 K | 836.8 | congruent melting: L -> ξSb2Zn3; _L: Zn 0.595; ξSb2Zn3: Zn 0.595_ | model | [2] Li 2007 | Table 2, p. 3, row 20; `ORC-B7TH2B4GZB` |  |
| Phase transition | 837.1 K | 837.1 | congruent melting: L -> ξSb2Zn3; _L: Zn 0.6; ξSb2Zn3: Zn 0.6_ | unspecified | [2] Li 2007; _cites Zabdyr 1993_ [doi](https://doi.org/10.1016/0364-5916%2893%2990005-v) | Table 2, p. 3, row 17; `ORC-KIWR7B7TVU` |  |
| Phase transition | 841 K | 841 | congruent melting: L -> δ'Sb3Zn4; _L: Zn 0.558; δ'Sb3Zn4: Zn 0.558_ | experimental | [2] Li 2007; _cites Izard 2001_ [doi](https://doi.org/10.1016/s0364-5916%2802%2900008-1) | Table 2, p. 3, row 11; `ORC-L7GOVUQOCC.b4b033` |  |
| Phase transition | 841 K | 841 | congruent melting: L -> ξSb2Zn3; _L: Zn 0.595; ξSb2Zn3: Zn 0.595_ | experimental | [2] Li 2007; _cites Izard 2001_ [doi](https://doi.org/10.1016/s0364-5916%2802%2900008-1) | Table 2, p. 3, row 19; `ORC-L7GOVUQOCC.506d75` |  |
| Phase transition | 903 K | 903 | congruent melting: L1 -> Sb; _L1: Zn 0; Sb: Zn 0_ | experimental | [2] Li 2007; _cites Izard 2001_ [doi](https://doi.org/10.1016/s0364-5916%2802%2900008-1) | Table 2, p. 3, row 1; `ORC-Z4J5WASV36` |  |

### Phase equilibrium (5)

Table: Phase equilibrium, Sb–Zn system

| Property | Value | T (K) | Phases / composition | Class | Source | Location | Quote |
|---|---:|---:|---|---|---|---|---|
| Phase composition |  | 776.15 | other: Liquidus line; _liquid: Sb 0.166, Zn 0.834_ | experimental | [4] Liu 2000 | Table 5, p. 8, row 5; `ORC-D2WAT6GQ7P` |  |
| Phase composition |  | 781.15 | other: Liquidus line; _liquid: Sb 0.187, Zn 0.813_ | experimental | [4] Liu 2000 | Table 5, p. 8, row 4; `ORC-RREESVNKC5` |  |
| Phase composition |  | 789.15 | other: Liquidus line; _liquid: Sb 0.224, Zn 0.776_ | experimental | [4] Liu 2000 | Table 5, p. 8, row 3; `ORC-55ZGMHHS7A` |  |
| Phase composition |  | 801.15 | other: Liquidus line; _liquid: Sb 0.236, Zn 0.764_ | experimental | [4] Liu 2000 | Table 5, p. 8, row 2; `ORC-VEOIU5YYQP` |  |
| Phase composition |  | 814.15 | other: Liquidus line; _liquid: Sb 0.276, Zn 0.724_ | experimental | [4] Liu 2000 | Table 5, p. 8, row 1; `ORC-RI7BJHNYHI` |  |

### Formation (40)

Table: Formation, Sb–Zn system

| Property | Value | T (K) | Phases / composition | Class | Source | Location | Quote |
|---|---:|---:|---|---|---|---|---|
| Gibbs energy of formation | -10.3364 kJ/mol-atom | 298.15 | SbZn; _alloy: Zn 0.5_ | model | [1] Zhang 2022 | Table 8, p. 14, row 4; `ORC-L5MAOTGUXB.332468` |  |
| Gibbs energy of formation | -9.508 kJ/mol-atom | 420 | SbZn; _alloy: Zn 0.5_ | model | [2] Li 2007 | Table 4, p. 4, row 1; `ORC-LAENHZK3Y6.4202a3` |  |
| Gibbs energy of formation | -9.7 kJ/mol-atom | 420 | SbZn; _alloy: Zn 0.5_ | experimental | [2] Li 2007; _cites Goryacheva 1997_ | Table 4, p. 4, row 2; `ORC-YVLBOQ5WZM.5e199a` |  |
| Gibbs energy of formation | -8.494 kJ/mol-atom | 420 | ε-Sb3Zn4; _alloy: Zn 0.571429_ | model | [2] Li 2007 | Table 4, p. 4, row 21; `ORC-E76ESIXAL7.c2b223` |  |
| Gibbs energy of formation | -8.8 kJ/mol-atom | 420 | ε-Sb3Zn4; _alloy: Zn 0.571429_ | experimental | [2] Li 2007; _cites Goryacheva 1997_ | Table 4, p. 4, row 22; `ORC-GEOHQLQG2H.b78abb` |  |
| Gibbs energy of formation | -9.7 kJ/mol-atom | 420.15 | SbZn; _alloy: Zn 0.5_ | experimental | [1] Zhang 2022; _cites Goryacheva 1997_ | Table 8, p. 14, row 5; `ORC-QB7KEQZ7NP.1ec8c7` |  |
| Gibbs energy of formation | -9.8384 kJ/mol-atom | 420.15 | SbZn; _alloy: Zn 0.5_ | model | [1] Zhang 2022 | Table 8, p. 14, row 6; `ORC-ZFD2AE7PNV.7dfc8a` |  |
| Gibbs energy of formation | -8.9298 kJ/mol-atom | 420.15 | β-Zn13Sb10; _alloy: Zn 0.565217_ | model | [1] Zhang 2022 | Table 8, p. 14, row 20; `ORC-RUE7NCC2QK.019adc` |  |
| Gibbs energy of formation | -8.8 kJ/mol-atom | 420.15 | β-Zn13Sb10; _alloy: Zn 0.565217_ | experimental | [1] Zhang 2022; _cites Goryacheva 1997_ | Table 8, p. 14, row 19; `ORC-TIHVTPDIMR.f1d784` |  |
| Gibbs energy of formation | -6.99 kJ/mol-atom | 600 | ε-Sb3Zn4; _alloy: Zn 0.571429_ | experimental | [2] Li 2007; _cites Zabdyr 1981_ | Table 4, p. 4, row 24; `ORC-6OOPELOSIS.eb17ad` |  |
| Gibbs energy of formation | -8.115 kJ/mol-atom | 600 | ε-Sb3Zn4; _alloy: Zn 0.571429_ | model | [2] Li 2007 | Table 4, p. 4, row 23; `ORC-7A2QTKMYRH.ceb081` |  |
| Gibbs energy of formation | -8.6373 kJ/mol-atom | 600.15 | β-Zn13Sb10; _alloy: Zn 0.565217_ | model | [1] Zhang 2022 | Table 8, p. 14, row 22; `ORC-5FN2IJMMAY.6d04a2` |  |
| Gibbs energy of formation | -6.99 kJ/mol-atom | 600.15 | β-Zn13Sb10; _alloy: Zn 0.565217_ | experimental | [1] Zhang 2022; _cites Zabdyr 1981_ | Table 8, p. 14, row 21; `ORC-EVZXBKPOLW.5b7b0c` |  |
| Gibbs energy of formation | -7.946 kJ/mol-atom | 700 | SbZn; _alloy: Zn 0.5_ | model | [2] Li 2007; _cites Hulgren 1973_ | Table 4, p. 4, row 4; `ORC-ZHI4RONI5E.2eb85c` |  |
| Gibbs energy of formation | -7.946 kJ/mol-atom | 700.15 | SbZn; _alloy: Zn 0.5_ | experimental | [1] Zhang 2022; _cites Hultgren 1978_ | Table 8, p. 14, row 7; `ORC-WP35MO5EGA.ea905b` |  |
| Gibbs energy of formation | -8.7714 kJ/mol-atom | 700.15 | SbZn; _alloy: Zn 0.5_ | model | [1] Zhang 2022 | Table 8, p. 14, row 8; `ORC-ZF4IE5PFSW.209bf2` |  |
| Gibbs energy of formation | -7.674 kJ/mol-atom | 750 | SbZn; _alloy: Zn 0.5_ | model | [2] Li 2007 | Table 4, p. 4, row 13; `ORC-K7LVIQZ7M5.af7241` |  |
| Gibbs energy of formation | -7.465 kJ/mol-atom | 750 | SbZn; _alloy: Zn 0.5_ | experimental | [2] Li 2007; _cites Zabdyr 1981_ | Table 4, p. 4, row 14; `ORC-UZ5GR3NBH7.257cf2` |  |
| Gibbs energy of formation | -8.2591 kJ/mol-atom | 750.15 | SbZn; _alloy: Zn 0.5_ | model | [1] Zhang 2022 | Table 8, p. 14, row 10; `ORC-KRTUSQP322.7e89f7` |  |
| Gibbs energy of formation | -7.465 kJ/mol-atom | 750.15 | SbZn; _alloy: Zn 0.5_ | experimental | [1] Zhang 2022; _cites Zabdyr 1981_ | Table 8, p. 14, row 9; `ORC-UN32LPDZOH.5dabc2` |  |
| Gibbs energy of formation | -7.126 kJ/mol-atom | 800 | δ-Sb3Zn4; _alloy: Zn 0.571429_ | experimental | [2] Li 2007; _cites Zabdyr 1981_ | Table 4, p. 4, row 20; `ORC-NZUTUZNKYH.b1f117` |  |
| Gibbs energy of formation | -7.2 kJ/mol-atom | 800 | δ-Sb3Zn4; _alloy: Zn 0.571429_ | model | [2] Li 2007 | Table 4, p. 4, row 19; `ORC-THQ7S4MRBN.80d8b3` |  |
| Gibbs energy of formation | -6.916 kJ/mol-atom | 800 | ξ-Sb2Zn3; _alloy: Zn 0.6_ | experimental | [2] Li 2007; _cites Zabdyr 1981_ | Table 4, p. 4, row 26; `ORC-NNBDCYEADO.2a8dfa` |  |
| Gibbs energy of formation | -7.131 kJ/mol-atom | 800 | ξ-Sb2Zn3; _alloy: Zn 0.6_ | model | [2] Li 2007 | Table 4, p. 4, row 25; `ORC-XD2QFXBABL.de3786` |  |
| Gibbs energy of formation | -7.126 kJ/mol-atom | 800.15 | α-Zn9Sb7; _alloy: Zn 0.5625_ | experimental | [1] Zhang 2022; _cites Zabdyr 1981_ | Table 8, p. 14, row 17; `ORC-HTTS63YOJG.2f0354` |  |
| Gibbs energy of formation | -7.7357 kJ/mol-atom | 800.15 | α-Zn9Sb7; _alloy: Zn 0.5625_ | model | [1] Zhang 2022 | Table 8, p. 14, row 18; `ORC-WN6Q6YN6LT.1b79e9` |  |
| Gibbs energy of formation | -7.5476 kJ/mol-atom | 800.15 | β-Zn3Sb2; _alloy: Zn 0.6_ | model | [1] Zhang 2022 | Table 8, p. 14, row 24; `ORC-JVUQCUY4PL.a464a3` |  |
| Gibbs energy of formation | -6.916 kJ/mol-atom | 800.15 | β-Zn3Sb2; _alloy: Zn 0.6_ | experimental | [1] Zhang 2022; _cites Zabdyr 1981_ | Table 8, p. 14, row 23; `ORC-O44M4ZW6TJ.030335` |  |
| Gibbs energy of formation | -8.115 kJ/mol-atom | 804 | SbZn; _alloy: Zn 0.5_ | experimental | [2] Li 2007; _cites DeWitt 1939_ [doi](https://doi.org/10.1021/ja01266a055) | Table 4, p. 4, row 10; `ORC-6KZI7KX5JB.3e7611` |  |
| Gibbs energy of formation | -8.233 kJ/mol-atom | 804 | SbZn; _alloy: Zn 0.5_ | model | [2] Li 2007 | Table 4, p. 4, row 9; `ORC-GJR4EUMWYF.7d9985` |  |
| Gibbs energy of formation | -8.115 kJ/mol-atom | 804.15 | SbZn; _alloy: Zn 0.5_ | experimental | [1] Zhang 2022; _cites Seltz 1940_ [doi](https://doi.org/10.1149/1.3521200) | Table 8, p. 14, row 11; `ORC-KGYH6LY3EJ.ae2d4a` |  |
| Gibbs energy of formation | -8.8837 kJ/mol-atom | 804.15 | SbZn; _alloy: Zn 0.5_ | model | [1] Zhang 2022 | Table 8, p. 14, row 12; `ORC-LUMCSKWV67.23262a` |  |
| Gibbs energy of formation | -7.903 kJ/mol-atom | 806 | δ-Sb3Zn4; _alloy: Zn 0.571429_ | experimental | [2] Li 2007; _cites DeWitt 1939_ [doi](https://doi.org/10.1021/ja01266a055) | Table 4, p. 4, row 18; `ORC-7VPUF5XRGG.1e6b0e` |  |
| Gibbs energy of formation | -7.982 kJ/mol-atom | 806 | δ-Sb3Zn4; _alloy: Zn 0.571429_ | model | [2] Li 2007 | Table 4, p. 4, row 17; `ORC-R4WK4SK6PB.aed88a` |  |
| Gibbs energy of formation | -7.903 kJ/mol-atom | 806.15 | α-Zn9Sb7; _alloy: Zn 0.5625_ | experimental | [1] Zhang 2022; _cites Seltz 1940_ [doi](https://doi.org/10.1149/1.3521200) | Table 8, p. 14, row 15; `ORC-37FC3SIAD7.ecb149` |  |
| Gibbs energy of formation | -8.6511 kJ/mol-atom | 806.15 | α-Zn9Sb7; _alloy: Zn 0.5625_ | model | [1] Zhang 2022 | Table 8, p. 14, row 16; `ORC-UQLMRPUW7V.000463` |  |
| Gibbs energy of formation | -7.947 kJ/mol-atom | 826 | δ′-Sb3Zn4; _alloy: Zn 0.571429_ | model | [2] Li 2007 | Table 4, p. 4, row 15; `ORC-I5P7YJ6ZTR.b53eb8` |  |
| Gibbs energy of formation | -8.032 kJ/mol-atom | 826 | δ′-Sb3Zn4; _alloy: Zn 0.571429_ | experimental | [2] Li 2007; _cites DeWitt 1939_ [doi](https://doi.org/10.1021/ja01266a055) | Table 4, p. 4, row 16; `ORC-LJ7NTT3MZM.f6971e` |  |
| Gibbs energy of formation | -8.032 kJ/mol-atom | 826.15 | β-Zn9Sb7; _alloy: Zn 0.5625_ | experimental | [1] Zhang 2022; _cites Seltz 1940_ [doi](https://doi.org/10.1149/1.3521200) | Table 8, p. 14, row 13; `ORC-5XSEGZQBR3.c2c961` |  |
| Gibbs energy of formation | -8.445 kJ/mol-atom | 826.15 | β-Zn9Sb7; _alloy: Zn 0.5625_ | model | [1] Zhang 2022 | Table 8, p. 14, row 14; `ORC-TVM3BDOS7V.b0b508` |  |

### Activity / EMF / Gibbs energy (20)

Table: Activity / EMF / Gibbs energy, Sb–Zn system

| Property | Value | T (K) | Phases / composition | Class | Source | Location | Quote |
|---|---:|---:|---|---|---|---|---|
| Gibbs energy | -9.508 kJ/mol atom | 420 | SbZn; _alloy: Zn 0.5_ | model | [2] Li 2007 | Table 4, p. 4, row 1; `ORC-LAENHZK3Y6.95cc2b` |  |
| Gibbs energy | -9.7 kJ/mol atom | 420 | SbZn; _alloy: Zn 0.5_ | experimental | [2] Li 2007; _cites Goryacheva 1997_ | Table 4, p. 4, row 2; `ORC-YVLBOQ5WZM.8c8c0f` |  |
| Gibbs energy | -8.494 kJ/mol atom | 420 | ε-Sb3Zn4; _alloy: Zn 0.571429_ | model | [2] Li 2007 | Table 4, p. 4, row 21; `ORC-E76ESIXAL7.6898fa` |  |
| Gibbs energy | -8.8 kJ/mol atom | 420 | ε-Sb3Zn4; _alloy: Zn 0.571429_ | experimental | [2] Li 2007; _cites Goryacheva 1997_ | Table 4, p. 4, row 22; `ORC-GEOHQLQG2H.fbe9d1` |  |
| Gibbs energy | -6.99 kJ/mol atom | 600 | ε-Sb3Zn4; _alloy: Zn 0.571429_ | experimental | [2] Li 2007; _cites Zabdyr 1981_ | Table 4, p. 4, row 24; `ORC-6OOPELOSIS.803242` |  |
| Gibbs energy | -8.115 kJ/mol atom | 600 | ε-Sb3Zn4; _alloy: Zn 0.571429_ | model | [2] Li 2007 | Table 4, p. 4, row 23; `ORC-7A2QTKMYRH.5b6dd2` |  |
| Gibbs energy | -8210 kJ/mol atom | 700 | SbZn; _alloy: Zn 0.5_ | model | [2] Li 2007 | Table 4, p. 4, row 3; `ORC-N4ABGBP2DJ.3cf714` |  |
| Gibbs energy | -7.946 kJ/mol atom | 700 | SbZn; _alloy: Zn 0.5_ | model | [2] Li 2007; _cites Hulgren 1973_ | Table 4, p. 4, row 4; `ORC-ZHI4RONI5E.00f5f9` |  |
| Gibbs energy | -7.674 kJ/mol atom | 750 | SbZn; _alloy: Zn 0.5_ | model | [2] Li 2007 | Table 4, p. 4, row 13; `ORC-K7LVIQZ7M5.57d4c5` |  |
| Gibbs energy | -7.465 kJ/mol atom | 750 | SbZn; _alloy: Zn 0.5_ | experimental | [2] Li 2007; _cites Zabdyr 1981_ | Table 4, p. 4, row 14; `ORC-UZ5GR3NBH7.8c87f0` |  |
| Gibbs energy | -7.126 kJ/mol atom | 800 | δ-Sb3Zn4; _alloy: Zn 0.571429_ | experimental | [2] Li 2007; _cites Zabdyr 1981_ | Table 4, p. 4, row 20; `ORC-NZUTUZNKYH.6bdff7` |  |
| Gibbs energy | -7.2 kJ/mol atom | 800 | δ-Sb3Zn4; _alloy: Zn 0.571429_ | model | [2] Li 2007 | Table 4, p. 4, row 19; `ORC-THQ7S4MRBN.0af948` |  |
| Gibbs energy | -6.916 kJ/mol atom | 800 | ξ-Sb2Zn3; _alloy: Zn 0.6_ | experimental | [2] Li 2007; _cites Zabdyr 1981_ | Table 4, p. 4, row 26; `ORC-NNBDCYEADO.7e788a` |  |
| Gibbs energy | -7.131 kJ/mol atom | 800 | ξ-Sb2Zn3; _alloy: Zn 0.6_ | model | [2] Li 2007 | Table 4, p. 4, row 25; `ORC-XD2QFXBABL.6a5fa7` |  |
| Gibbs energy | -8.115 kJ/mol atom | 804 | SbZn; _alloy: Zn 0.5_ | experimental | [2] Li 2007; _cites DeWitt 1939_ [doi](https://doi.org/10.1021/ja01266a055) | Table 4, p. 4, row 10; `ORC-6KZI7KX5JB.6ded93` |  |
| Gibbs energy | -8.233 kJ/mol atom | 804 | SbZn; _alloy: Zn 0.5_ | model | [2] Li 2007 | Table 4, p. 4, row 9; `ORC-GJR4EUMWYF.0ff417` |  |
| Gibbs energy | -7.903 kJ/mol atom | 806 | δ-Sb3Zn4; _alloy: Zn 0.571429_ | experimental | [2] Li 2007; _cites DeWitt 1939_ [doi](https://doi.org/10.1021/ja01266a055) | Table 4, p. 4, row 18; `ORC-7VPUF5XRGG.29696a` |  |
| Gibbs energy | -7.982 kJ/mol atom | 806 | δ-Sb3Zn4; _alloy: Zn 0.571429_ | model | [2] Li 2007 | Table 4, p. 4, row 17; `ORC-R4WK4SK6PB.8c3dda` |  |
| Gibbs energy | -7.947 kJ/mol atom | 826 | δ′-Sb3Zn4; _alloy: Zn 0.571429_ | model | [2] Li 2007 | Table 4, p. 4, row 15; `ORC-I5P7YJ6ZTR.b1205e` |  |
| Gibbs energy | -8.032 kJ/mol atom | 826 | δ′-Sb3Zn4; _alloy: Zn 0.571429_ | experimental | [2] Li 2007; _cites DeWitt 1939_ [doi](https://doi.org/10.1021/ja01266a055) | Table 4, p. 4, row 16; `ORC-LJ7NTT3MZM.b711d1` |  |

### Crystal structure (5)

Table: Crystal structure, Sb–Zn system

| Property | Value | T (K) | Phases / composition | Class | Source | Location | Quote |
|---|---:|---:|---|---|---|---|---|
| Lattice a | 12.2282 not_printed ± 3.000e-4 | 298.15 | ε-Sb3Zn4; _alloy: Sb 0.428571, Zn 0.571429_ | model | [3] Liu 2009 | Table 1, p. 2, row 6; `ORC-FK6Z3C3SCW.432860` |  |
| Lattice a | 6.20393 not_printed ± 8.900e-5 | 298.15 | ω-SbZn; _alloy: Sb 0.5, Zn 0.5_ | model | [3] Liu 2009 | Table 1, p. 2, row 3; `ORC-U25VI6CN4W.6e154c` |  |
| Lattice b | 7.7408 not_printed ± 1.000e-4 | 298.15 | ω-SbZn; _alloy: Sb 0.5, Zn 0.5_ | model | [3] Liu 2009 | Table 1, p. 2, row 3; `ORC-U25VI6CN4W.e5403a` |  |
| Lattice c | 12.4067 not_printed ± 4.000e-4 | 298.15 | ε-Sb3Zn4; _alloy: Sb 0.428571, Zn 0.571429_ | model | [3] Liu 2009 | Table 1, p. 2, row 6; `ORC-FK6Z3C3SCW.814da9` |  |
| Lattice c | 8.0977 not_printed ± 1.000e-4 | 298.15 | ω-SbZn; _alloy: Sb 0.5, Zn 0.5_ | model | [3] Liu 2009 | Table 1, p. 2, row 3; `ORC-U25VI6CN4W.869a8d` |  |

## Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

1. Jiyuan Zhang, Yuan Yuan, A coupled experimental and thermodynamic assessment of the Mg-Bi-Sb and Zn-Bi-Sb ternary system and extrapolate to the Mg-Bi-Zn-Sb system, Thermochimica Acta 716, 179327 (2022). [doi:10.1016/j.tca.2022.179327](https://doi.org/10.1016/j.tca.2022.179327)
2. Jing-Bo Li, Marie-Christine Record, Jean-Claude Tedenac, A thermodynamic assessment of the Sb–Zn system, Journal of Alloys and Compounds 438, 171-177 (2007). [doi:10.1016/j.jallcom.2006.08.035](https://doi.org/10.1016/j.jallcom.2006.08.035)
3. Ya Liu, Jean-Claude Tedenac, Thermodynamic modeling of the Cd–Sb–Zn ternary system, Calphad 33, 684-694 (2009). [doi:10.1016/j.calphad.2009.08.006](https://doi.org/10.1016/j.calphad.2009.08.006)
4. X. J. Liu, C. P. Wang, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the phase diagrams of the Cu-Sb and Sb-Zn systems, JPE 21, 432-442 (2000). [doi:10.1361/105497100770339608](https://doi.org/10.1361/105497100770339608)

## Please cite

- R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569
- R. Arróyave, J. Saal, D. Shin, ORCHID-Diagrams: calculated binary phase diagrams (version 2026.10), Zenodo (2026). https://doi.org/10.5281/zenodo.23735859
- R. Arróyave, J. Saal, D. Shin, ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD) (version 2026.10), Zenodo (2026). https://doi.org/10.5281/zenodo.23735891
- R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0).

Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

```bibtex
@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_phase_diagrams_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Diagrams: calculated binary phase diagrams}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735859},
  url       = {https://doi.org/10.5281/zenodo.23735859}
}

@misc{orchid_hulls_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD)}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735891},
  url       = {https://doi.org/10.5281/zenodo.23735891}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}
```

---

Derived data CC BY 4.0 ([licence](https://creativecommons.org/licenses/by/4.0/)): cite ORCHID ([CITATION.cff](https://data.orchid-project.org/CITATION.cff)) and the original sources. Quotes are short excerpts kept so that each value can be checked; they remain under the publishers' copyright and are not relicensed. Source papers, page images and full text are not redistributed. Field reference: [SCHEMA.md](https://data.orchid-project.org/literature/SCHEMA.md). Machine-readable guide: [llms.txt](https://data.orchid-project.org/llms.txt). Found an error? The report link of a value (Markdown: its id, ORC-..., in the Location column) opens a pre-filled GitHub issue, https://github.com/orchid-calphad/orchid-data/issues/new?template=report-value-error.yml&record_id=\<id>, carrying only the record id, source and value; [how to contribute](https://orchid-project.org/contribute/).