# Si–B system

> Si–B system: 0 accepted literature values (none) and 4 calculated phase diagram(s) from ORCHID, each value with evidence class, source, page and quote.

HTML: https://data.orchid-project.org/systems/SI-B.html · Markdown: https://data.orchid-project.org/systems/SI-B.md

0 accepted literature values from 0 paper(s); 4 calculated phase diagram(s).

Data: [interactive phase diagram](https://orchid-project.org/phase-diagrams/#SI-B/SiB-01Tok.json) · [Markdown](https://data.orchid-project.org/systems/SI-B.md)

## Calculated phase diagrams

Binary phase diagrams calculated with pycalphad 0.11.2 from the SGTE binary collection (Hallstedt 2025, CC BY 4.0). Evidence class: model.

Table: Assessments with a calculated phase diagram

| TDB file | Assessment | SHA-256 | Links |
|---|---|---|---|
| SiB-01Tok.tdb | T. Tokunaga, K. Nishio, M. Hasebe, J. Phase Equilib., 22, 291-99(2001). [doi:10.1361/105497101770338798](https://doi.org/10.1361/105497101770338798) | `d151ee95b11739ecd759ac34e32862420c76cca0a61b1f7f5e13a7df880c39f4` | [viewer](https://orchid-project.org/phase-diagrams/#SI-B/SiB-01Tok.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/SiB-01Tok.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/SiB-01Tok.json) |
| SiB-03Tok.tdb | T. Tokunaga, K. Nishio, H. Ohtani, M. Hasebe, Mater. Trans. (JIM), 44, 1651-54(2003). [doi:10.2320/matertrans.44.1651](https://doi.org/10.2320/matertrans.44.1651) | `200e70443756318e9f28cbeaaee4f2806687cee6ada0a52c5f51fe26174c9b97` | [viewer](https://orchid-project.org/phase-diagrams/#SI-B/SiB-03Tok.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/SiB-03Tok.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/SiB-03Tok.json) |
| SiB-09Che.tdb | H.M. Chen, H.Y. Qi, F. Zheng, L.B. Liu, Z.P. Jin, J. Alloys Compd., 481, 182-89(2009). [doi:10.1016/j.jallcom.2009.03.044](https://doi.org/10.1016/j.jallcom.2009.03.044) | `306d09e27c26972d99b5d99f49e741e3ebcf540843c5418866e01d27f6bb8c1a` | [viewer](https://orchid-project.org/phase-diagrams/#SI-B/SiB-09Che.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/SiB-09Che.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/SiB-09Che.json) |
| SiB-95Lim-LB.tdb | S.-K. Lim, H.L. Lukas, "Hochleistungskeramik, Herstellung, Aufbau und Eigenschaften", G. Petzow, J. Tobolski, R. Telle (Eds.), VCH, Weinheim, 1995, pp. 605-16. [doi:10.1016/0364-5916(95)00014-6](https://doi.org/10.1016/0364-5916%2895%2900014-6) | `2706dcc211c225ff5ed1c6cb8a308106a1a1a9ad381905b7c4a33a6a19c483f4` | [viewer](https://orchid-project.org/phase-diagrams/#SI-B/SiB-95Lim-LB.json) · [TDB](https://orchid-project.org/data/databases/sgte-binary/SiB-95Lim-LB.tdb) · [JSON](https://data.orchid-project.org/phase-diagrams/sgte/SiB-95Lim-LB.json) |

Table: Calculated three-phase invariants (model, mole fraction of the second component)

| TDB file | T (K) | Phases at the invariant |
|---|---:|---|
| SiB-01Tok.tdb | 2305.08 | LIQUID (x(B) 0.91434) + SIB24 (x(B) 0.959) + BETA_RHOMBO_B (x(B) 0.96838) |
| SiB-01Tok.tdb | 2305.08 | LIQUID (x(B) 0.91445) + SIB24 (x(B) 0.959) + BETA_RHOMBO_B (x(B) 0.9684) |
| SiB-01Tok.tdb | 2127.06 | LIQUID (x(B) 0.63877) + SIB6 (x(B) 0.85714) + SIB24 (x(B) 0.959) |
| SiB-01Tok.tdb | 2127.06 | LIQUID (x(B) 0.63934) + SIB6 (x(B) 0.85714) + SIB24 (x(B) 0.959) |
| SiB-01Tok.tdb | 2127.06 | LIQUID (x(B) 0.6385) + SIB6 (x(B) 0.85714) + SIB24 (x(B) 0.959) |
| SiB-01Tok.tdb | 1661.99 | DIAMOND_A4 (x(B) 0.01591) + LIQUID (x(B) 0.10933) + SIB6 (x(B) 0.85714) |
| SiB-01Tok.tdb | 1661.98 | DIAMOND_A4 (x(B) 0.01588) + LIQUID (x(B) 0.10874) + SIB6 (x(B) 0.85714) |
| SiB-01Tok.tdb | 1542.98 | DIAMOND_A4 (x(B) 0.01063) + SIB3_D1G (x(B) 0.75) + SIB6 (x(B) 0.85714) |
| SiB-01Tok.tdb | 1542.98 | DIAMOND_A4 (x(B) 0.01062) + SIB3_D1G (x(B) 0.75) + SIB6 (x(B) 0.85714) |
| SiB-01Tok.tdb | 1542.98 | DIAMOND_A4 (x(B) 0.01062) + SIB3_D1G (x(B) 0.75) + SIB6 (x(B) 0.85714) |
| SiB-03Tok.tdb | 2303.42 | LIQUID (x(B) 0.92954) + SIB24 (x(B) 0.959) + BETA_RHOMBO_B (x(B) 0.9749) |
| SiB-03Tok.tdb | 2303.42 | LIQUID (x(B) 0.92956) + SIB24 (x(B) 0.959) + BETA_RHOMBO_B (x(B) 0.9749) |
| SiB-03Tok.tdb | 2129.74 | LIQUID (x(B) 0.64852) + SIB6 (x(B) 0.85714) + SIB24 (x(B) 0.959) |
| SiB-03Tok.tdb | 2129.74 | LIQUID (x(B) 0.64918) + SIB6 (x(B) 0.85714) + SIB24 (x(B) 0.959) |
| SiB-03Tok.tdb | 2129.74 | LIQUID (x(B) 0.64807) + SIB6 (x(B) 0.85714) + SIB24 (x(B) 0.959) |
| SiB-03Tok.tdb | 1667.16 | DIAMOND_A4 (x(B) 0.01895) + LIQUID (x(B) 0.09883) + SIB6 (x(B) 0.85714) |
| SiB-03Tok.tdb | 1667.16 | DIAMOND_A4 (x(B) 0.0189) + LIQUID (x(B) 0.09797) + SIB6 (x(B) 0.85714) |
| SiB-03Tok.tdb | 1545.28 | DIAMOND_A4 (x(B) 0.01283) + SIB3_D1G (x(B) 0.75) + SIB6 (x(B) 0.85714) |
| SiB-03Tok.tdb | 1545.28 | DIAMOND_A4 (x(B) 0.01282) + SIB3_D1G (x(B) 0.75) + SIB6 (x(B) 0.85714) |
| SiB-03Tok.tdb | 1545.28 | DIAMOND_A4 (x(B) 0.01281) + SIB3_D1G (x(B) 0.75) + SIB6 (x(B) 0.85714) |
| SiB-09Che.tdb | 2302.01 | LIQUID (x(B) 0.9118) + SIB24 (x(B) 0.96097) + BETA_RHOMBO_B (x(B) 0.97496) |
| SiB-09Che.tdb | 2121.42 | LIQUID (x(B) 0.64876) + SIB6 (x(B) 0.85714) + SIB24 (x(B) 0.94185) |
| SiB-09Che.tdb | 2121.41 | LIQUID (x(B) 0.64893) + SIB6 (x(B) 0.85714) + SIB24 (x(B) 0.94186) |
| SiB-09Che.tdb | 1635.39 | DIAMOND_A4 (x(B) 0.02376) + LIQUID (x(B) 0.12722) + SIB6 (x(B) 0.85714) |
| SiB-09Che.tdb | 1635.39 | DIAMOND_A4 (x(B) 0.02374) + LIQUID (x(B) 0.12712) + SIB6 (x(B) 0.85714) |
| SiB-09Che.tdb | 1555.2 | DIAMOND_A4 (x(B) 0.01614) + SIB3_D1G (x(B) 0.75) + SIB6 (x(B) 0.85714) |
| SiB-09Che.tdb | 1555.2 | DIAMOND_A4 (x(B) 0.01612) + SIB3_D1G (x(B) 0.75) + SIB6 (x(B) 0.85714) |
| SiB-09Che.tdb | 1555.2 | DIAMOND_A4 (x(B) 0.01611) + SIB3_D1G (x(B) 0.75) + SIB6 (x(B) 0.85714) |
| SiB-09Che.tdb | 1387.63 | SIB24 (x(B) 0.97581) + BETA_RHOMBO_B (x(B) 0.99994) + ALPHA_RHOMBO_B (x(B) 1) |
| SiB-09Che.tdb | 1387.63 | SIB24 (x(B) 0.97581) + BETA_RHOMBO_B (x(B) 0.99994) + ALPHA_RHOMBO_B (x(B) 1) |
| SiB-95Lim-LB.tdb | 2310.04 | LIQUID (x(B) 0.92552) + ALPHA_RHOMBO_B (x(B) 0.96691) + BETA_RHOMBO_B (x(B) 0.97862) |
| SiB-95Lim-LB.tdb | 2122.98 | LIQUID (x(B) 0.6212) + SIB6 (x(B) 0.86158) + ALPHA_RHOMBO_B (x(B) 0.94061) |
| SiB-95Lim-LB.tdb | 1657.56 | DIAMOND_A4 (x(B) 0.01059) + LIQUID (x(B) 0.08109) + SIB6 (x(B) 0.85438) |
| SiB-95Lim-LB.tdb | 1543.01 | DIAMOND_A4 (x(B) 0.00738) + SIB3_D1G (x(B) 0.73787) + SIB6 (x(B) 0.85457) |

## Please cite

- R. Arróyave, J. Saal, D. Shin, ORCHID-Diagrams: calculated binary phase diagrams (version 2026.10), Zenodo (2026). https://doi.org/10.5281/zenodo.23735859
- R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065

Also cite B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0).

Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

```bibtex
@misc{orchid_phase_diagrams_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Diagrams: calculated binary phase diagrams}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735859},
  url       = {https://doi.org/10.5281/zenodo.23735859}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}
```

---

Derived data CC BY 4.0 ([licence](https://creativecommons.org/licenses/by/4.0/)): cite ORCHID ([CITATION.cff](https://data.orchid-project.org/CITATION.cff)) and the original sources. Quotes are short excerpts kept so that each value can be checked; they remain under the publishers' copyright and are not relicensed. Source papers, page images and full text are not redistributed. Field reference: [SCHEMA.md](https://data.orchid-project.org/literature/SCHEMA.md). Machine-readable guide: [llms.txt](https://data.orchid-project.org/llms.txt). Found an error? The report link of a value (Markdown: its id, ORC-..., in the Location column) opens a pre-filled GitHub issue, https://github.com/orchid-calphad/orchid-data/issues/new?template=report-value-error.yml&record_id=\<id>, carrying only the record id, source and value; [how to contribute](https://orchid-project.org/contribute/).
