Si–W system

78 accepted literature values from 3 paper(s) (experimental 58, model 20); 4 calculated phase diagram(s). 3 further extracted value(s) not accepted by the reader-agreement checks are only in the JSON/CSV.

Data: JSON · CSV · interactive explorer · interactive phase diagram · phases (7) · papers (bibliography) · Markdown

Accepted values by evidence class
Evidence class	Values
experimental	58
model	20

Accepted values by property group
Property group	Values
invariant reaction	39
phase transition	24
formation	11
crystal structure	4

Calculated phase diagrams

Binary phase diagrams calculated with pycalphad 0.11.2 from the SGTE binary collection (Hallstedt 2025, CC BY 4.0). Evidence class: model.

Assessments with a calculated phase diagram
TDB file	Assessment	SHA-256	Links
SiW-03Che-LB.tdb	P.-Y. Chevalier, E. Fischer, unpublished, 2003.	`980d470108b9356014b6a28aedaff9d818a3785bf4b9d86044bce6c3fb688023`	viewer · TDB · JSON
SiW-09Guo.tdb	Z. Guo, W. Yuan, Y. Sun, Z. Cai, Z. Qiao, J. Phase Equilib. Diffus., 30, 564-70(2009). doi:10.1007/s11669-009-9579-x	`5f6d911f9b50695896885bab52759251967d3aeb5536938d44554d602e33a85f`	viewer · TDB · JSON
SiW-13Li.tdb	Y. Li, C. Li, Z. Du, C. Guo, Calphad, 43, 112-23(2013). doi:10.1016/j.calphad.2013.04.004	`6cb14cc0019fd85687d871a41d2eadee3ed10a9f84d075558c911dca731f1d55`	viewer · TDB · JSON
SiW-89Vah.tdb	C. Vahlas, P.-Y. Chevalier, E. Blanquet, Calphad, 13, 273-92(1989). doi:10.1016/0364-5916(89)90007-2	`1b97c566f7b1735ce36c841c697dde9e201aeb64f8c5c00322f49c792b83ab23`	viewer · TDB · JSON

Calculated three-phase invariants (model, mole fraction of the second component)
TDB file	T (K)	Phases at the invariant
SiW-03Che-LB.tdb	2535.87	SI3W5_D8M (x(W) 0.625) + LIQUID (x(W) 0.65046) + BCC_A2 (x(W) 0.93612)
SiW-03Che-LB.tdb	2535.87	SI3W5_D8M (x(W) 0.625) + LIQUID (x(W) 0.65049) + BCC_A2 (x(W) 0.93613)
SiW-03Che-LB.tdb	2301.46	SI2W_C11B (x(W) 0.33333) + LIQUID (x(W) 0.4442) + SI3W5_D8M (x(W) 0.625)
SiW-03Che-LB.tdb	2301.46	SI2W_C11B (x(W) 0.33333) + LIQUID (x(W) 0.44445) + SI3W5_D8M (x(W) 0.625)
SiW-03Che-LB.tdb	1671.14	DIAMOND_A4 (x(W) 0) + LIQUID (x(W) 0.02879) + SI2W_C11B (x(W) 0.33333)
SiW-03Che-LB.tdb	1671.13	DIAMOND_A4 (x(W) 0) + LIQUID (x(W) 0.02842) + SI2W_C11B (x(W) 0.33333)
SiW-09Guo.tdb	2484.59	SI3W5_D8M (x(W) 0.625) + LIQUID (x(W) 0.71224) + BCC_A2 (x(W) 0.94521)
SiW-09Guo.tdb	2484.59	SI3W5_D8M (x(W) 0.625) + LIQUID (x(W) 0.71226) + BCC_A2 (x(W) 0.94522)
SiW-09Guo.tdb	2284.02	SI2W_C11B (x(W) 0.33333) + LIQUID (x(W) 0.46847) + SI3W5_D8M (x(W) 0.625)
SiW-09Guo.tdb	2284.02	SI2W_C11B (x(W) 0.33333) + LIQUID (x(W) 0.46856) + SI3W5_D8M (x(W) 0.625)
SiW-09Guo.tdb	1660.94	DIAMOND_A4 (x(W) 0) + LIQUID (x(W) 0.04416) + SI2W_C11B (x(W) 0.33333)
SiW-09Guo.tdb	1660.93	DIAMOND_A4 (x(W) 0) + LIQUID (x(W) 0.0438) + SI2W_C11B (x(W) 0.33333)
SiW-13Li.tdb	2352.03	SI3W5_D8M (x(W) 0.6217) + LIQUID (x(W) 0.66752) + BCC_A2 (x(W) 0.96066)
SiW-13Li.tdb	2230.71	SI2W_C11B (x(W) 0.33333) + LIQUID (x(W) 0.46164) + SI3W5_D8M (x(W) 0.59955)
SiW-13Li.tdb	1666.92	DIAMOND_A4 (x(W) 0) + LIQUID (x(W) 0.03509) + SI2W_C11B (x(W) 0.33333)
SiW-13Li.tdb	1666.92	DIAMOND_A4 (x(W) 0) + LIQUID (x(W) 0.03487) + SI2W_C11B (x(W) 0.33333)
SiW-89Vah.tdb	2353.53	SI3W5_D8M (x(W) 0.625) + LIQUID (x(W) 0.6687) + BCC_A2 (x(W) 0.96946)
SiW-89Vah.tdb	2353.53	SI3W5_D8M (x(W) 0.625) + LIQUID (x(W) 0.66872) + BCC_A2 (x(W) 0.96946)
SiW-89Vah.tdb	2213.37	SI2W_C11B (x(W) 0.33333) + LIQUID (x(W) 0.47439) + SI3W5_D8M (x(W) 0.625)
SiW-89Vah.tdb	2213.37	SI2W_C11B (x(W) 0.33333) + LIQUID (x(W) 0.47441) + SI3W5_D8M (x(W) 0.625)
SiW-89Vah.tdb	1662.09	DIAMOND_A4 (x(W) 0) + LIQUID (x(W) 0.04134) + SI2W_C11B (x(W) 0.33333)
SiW-89Vah.tdb	1662.09	DIAMOND_A4 (x(W) 0) + LIQUID (x(W) 0.04132) + SI2W_C11B (x(W) 0.33333)

Convex hulls: Materials Project DFT hull · OQMD DFT hull · CALPHAD hull SiW-03Che-LB · CALPHAD hull SiW-09Guo · CALPHAD hull SiW-89Vah

Invariant reactions (literature)

Invariant reactions reported in the literature for the Si–W system (39)
T (K)	Reaction / phases	Compositions (mole fraction)	Class	Source	Location
2643	(L)+bcc->Si3W5	L: W 0.58; bcc: W 0.92; Si3W5: W 0.625	experimental	[1] Vahlas 1989 cites ref. 58	Table 8, p. 15, row 28 report
2594	congruent melting: L <-> W5Si3	W5Si3: Si 0.375	model	[2] Guo 2009	Table 5, p. 5, row 4 report
2593	congruent melting: L <-> W5Si3	W5Si3: Si 0.375	experimental	[2] Guo 2009 cites Maksimov 1969	Table 5, p. 5, row 5 report
2523	eutectic: (L)->Si3W5+bcc	L: W 0.8; Si3W5: W 0.625; bcc: W 0.95	experimental	[1] Vahlas 1989 cites ref. 18	Table 8, p. 15, row 30 report
2483	eutectic: (L)->Si3W5+bcc	L: W 0.79; Si3W5: W 0.625; bcc: W 0.94	experimental	[1] Vahlas 1989 cites ref. 48	Table 8, p. 15, row 31 report
2460	L <-> (W) + W5Si3	L: Si 0.281; (W): Si 0.055; W5Si3: Si 0.375	model	[2] Guo 2009	Table 5, p. 5, row 1 report
2453	eutectic: L->Bcc+W5Si3	W5Si3: W 0.625	experimental	[3] Li 2013 cites Maksimov 1969	Table 2, p. 3, row 3 report
2453	eutectic: (L)->Si3W5+bcc	L: W 0.68; Si3W5: W 0.625; bcc: W 0.95	experimental	[1] Vahlas 1989 cites ref. 49	Table 8, p. 15, row 32 report
2453	L <-> (W) + W5Si3	L: Si 0.315; (W): Si 0.055; W5Si3: Si 0.375	experimental	[2] Guo 2009 cites Maksimov 1969	Table 5, p. 5, row 2 report
2433	congruent melting: L <-> WSi2	WSi2: Si 0.667	model	[2] Guo 2009	Table 5, p. 5, row 10 report
2433	congruent melting: L <-> WSi2	WSi2: Si 0.667	experimental	[2] Guo 2009 cites Maksimov 1969	Table 5, p. 5, row 11 report
2368	congruent melting: L <-> W5Si3	W5Si3: Si 0.375	experimental	[2] Guo 2009 cites Yu 1973	Table 5, p. 5, row 6 report
2362	eutectic: (L)->Si3W5+bcc	L: W 0.671; Si3W5: W 0.625; bcc: W 0.97	model	[1] Vahlas 1989	Table 8, p. 15, row 29 report
2358	eutectic: (L)->Si3W5+bcc	L: W 0.68; Si3W5: W 0.625; bcc: W 0.96	experimental	[1] Vahlas 1989 cites ref. 51	Table 8, p. 15, row 33 report
2358	eutectic: L->Bcc+W5Si3	W5Si3: W 0.625	experimental	[3] Li 2013 cites Kocherzhinskii 1973	Table 2, p. 3, row 8 report
2358	L <-> (W) + W5Si3	L: Si 0.32; (W): Si 0.05; W5Si3: Si 0.375	experimental	[2] Guo 2009 cites Yu 1973	Table 5, p. 5, row 3 report
2343	eutectic: (L)->Si2W+Si3W5	L: W 0.43; Si2W: W 0.333333; Si3W5: W 0.625	experimental	[1] Vahlas 1989 cites ref. 47	Table 8, p. 15, row 18 report
2333	eutectic: (L)->Si2W+Si3W5	L: W 0.41; Si2W: W 0.333333; Si3W5: W 0.625	experimental	[1] Vahlas 1989 cites ref. 18	Table 8, p. 15, row 19 report
2293	congruent melting: L <-> WSi2	WSi2: Si 0.667	experimental	[2] Guo 2009 cites Yu 1973	Table 5, p. 5, row 12 report
2284	L <-> W5Si3 + WSi2	L: Si 0.532; W5Si3: Si 0.375; WSi2: Si 0.667	model	[2] Guo 2009	Table 5, p. 5, row 7 report
2283	L <-> W5Si3 + WSi2	L: Si 0.593; W5Si3: Si 0.4; WSi2: Si 0.667	experimental	[2] Guo 2009 cites Maksimov 1969	Table 5, p. 5, row 8 report
2283	eutectic: (L)->Si2W+Si3W5	L: W 0.405; Si2W: W 0.333333; Si3W5: W 0.625	experimental	[1] Vahlas 1989 cites ref. 53	Table 8, p. 15, row 22 report
2283	eutectic: (L)->Si2W+Si3W5	L: W 0.405; Si2W: W 0.333333; Si3W5: W 0.625	experimental	[1] Vahlas 1989 cites ref. 48	Table 8, p. 15, row 20 report
2283	eutectic: L->W5Si3+WSi2	W5Si3: W 0.625; WSi2: W 0.333333	experimental	[3] Li 2013 cites Maksimov 1969	Table 2, p. 3, row 4 report
2213	eutectic: L->W5Si3+WSi2	W5Si3: W 0.625; WSi2: W 0.333333	experimental	[3] Li 2013 cites Kocherzhinskii 1973	Table 2, p. 3, row 9 report
2213	eutectic: (L)->Si2W+Si3W5	L: W 0.475; Si2W: W 0.333333; Si3W5: W 0.625	model	[1] Vahlas 1989	Table 8, p. 15, row 17 report
2213	L <-> W5Si3 + WSi2	L: Si 0.53; W5Si3: Si 0.375; WSi2: Si 0.667	experimental	[2] Guo 2009 cites Yu 1973	Table 5, p. 5, row 9 report
2213	eutectic: (L)->Si2W+Si3W5	L: W 0.47; Si2W: W 0.333333; Si3W5: W 0.625	experimental	[1] Vahlas 1989 cites ref. 51	Table 8, p. 15, row 21 report
1673	eutectic: (L)->Si(dia)+Si2W	L: W 0.008; Si(dia): W 0; Si2W: W 0.333333	experimental	[1] Vahlas 1989 cites ref. 18	Table 8, p. 15, row 7 report
1673	eutectic: (L)->Si(dia)+Si2W	L: W 0.026; Si(dia): W 0; Si2W: W 0.333333	experimental	[1] Vahlas 1989 cites ref. 51	Table 8, p. 15, row 9 report
1673	L <-> Si + WSi2	L: Si 0.974; Si: Si 1; WSi2: Si 0.667	experimental	[2] Guo 2009 cites Yu 1973	Table 5, p. 5, row 15 report
1673	eutectic: L->WSi2+Si	WSi2: W 0.333333; Si: W 0	experimental	[3] Li 2013 cites Kocherzhinskii 1973	Table 2, p. 3, row 10 report
1666	L <-> Si + WSi2	L: Si 0.956; Si: Si 1; WSi2: Si 0.667	model	[2] Guo 2009	Table 5, p. 5, row 13 report
1663	L <-> Si + WSi2	L: Si 0.992; Si: Si 1; WSi2: Si 0.667	experimental	[2] Guo 2009 cites Maksimov 1969	Table 5, p. 5, row 14 report
1663	eutectic: (L)->Si(dia)+Si2W	L: W 0.017; Si(dia): W 0; Si2W: W 0.333333	experimental	[1] Vahlas 1989 cites ref. 49	Table 8, p. 15, row 8 report
1663	eutectic: L->WSi2+Si	WSi2: W 0.333333; Si: W 0	experimental	[3] Li 2013 cites Maksimov 1969	Table 2, p. 3, row 5 report
1663	eutectic: (L)->Si(dia)+Si2W	L: W 0.001; Si(dia): W 0; Si2W: W 0.333333	experimental	[1] Vahlas 1989 cites ref. 48	Table 8, p. 15, row 6 report
1661	eutectic: (L)->Si(dia)+Si2W	L: W 0.014; Si(dia): W 0; Si2W: W 0.333333	experimental	[1] Vahlas 1989 cites ref. 53	Table 8, p. 15, row 10 report
1661	eutectic: (L)->Si(dia)+Si2W	L: W 0.043; Si(dia): W 0; Si2W: W 0.333333	model	[1] Vahlas 1989	Table 8, p. 15, row 5 report

Formation enthalpies

Literature values in kJ/mol-atom where the per-atom basis is known. DFT columns: the lowest-energy entry at the same composition (Materials Project 2026.04.13, OQMD v1.8; different energy references, never averaged), from dft_parity.json.

Enthalpies of formation, Si–W system (11)
Phase	Value	T (K)	Class	Source	Location
W5Si3	-145 kJ/mol (basis unstated)		model	[3] Li 2013 cites Vahlas 1989 doi	Table 3, p. 3, row 6 report
W5Si3	-138 kJ/mol (basis unstated)	298.15	experimental	[3] Li 2013 cites Kematick 1993 doi	Table 3, p. 3, row 4 report
W5Si3	-136 kJ/mol (basis unstated)		model	[3] Li 2013	Table 3, p. 3, row 7 report
W5Si3	-135 kJ/mol (basis unstated)	298.15	experimental	[3] Li 2013 cites Chart 1975 doi	Table 3, p. 3, row 3 report
W5Si3	-133 kJ/mol (basis unstated) ± 25	298.15	experimental	[3] Li 2013 cites Fujiwara 2005 doi	Table 3, p. 3, row 5 report
WSi2	-93.7 kJ/mol (basis unstated)	298.15	experimental	[3] Li 2013 cites Robinson 1955	Table 3, p. 3, row 2 report
WSi2	-93 kJ/mol (basis unstated)		model	[3] Li 2013 cites Vahlas 1989 doi	Table 3, p. 3, row 6 report
WSi2	-92.7 kJ/mol (basis unstated)	298.15	experimental	[3] Li 2013 cites Chart 1975 doi	Table 3, p. 3, row 3 report
WSi2	-82 kJ/mol (basis unstated) ± 6	298.15	experimental	[3] Li 2013 cites Fujiwara 2005 doi	Table 3, p. 3, row 5 report
WSi2	-81 kJ/mol (basis unstated)		model	[3] Li 2013	Table 3, p. 3, row 7 report
WSi2	-79.6 kJ/mol (basis unstated)	298.15	experimental	[3] Li 2013 cites Kematick 1993 doi	Table 3, p. 3, row 4 report

Other properties

Phase transition (24)

Phase transition, Si–W system
Property	Value	T (K)	Phases / composition	Class	Source	Location
Phase transition	1685 K	1685	Si(dia)->Si(L) Si(dia): W 0	experimental	[1] Vahlas 1989 cites ref. 1	Table 8, p. 15, row 3 report
Phase transition	1687 K	1687	Si(dia)->Si(L) Si(dia): W 0	model	[1] Vahlas 1989	Table 8, p. 15, row 1 report
Phase transition	1687 K	1687	Si(dia)->Si(L) Si(dia): W 0	experimental	[1] Vahlas 1989 cites ref. 3	Table 8, p. 15, row 2 report
Phase transition	1693 K	1693	Si(dia)->Si(L) Si(dia): W 0	experimental	[1] Vahlas 1989 cites ref. 51	Table 8, p. 15, row 4 report
Phase transition	2275 K	2275	Si2W->L Si2W: W 0.333	model	[1] Vahlas 1989	Table 8, p. 15, row 11 report
Phase transition	2293 K	2293	Si2W Si2W: W 0.333333; L: W 0.333333	experimental	[3] Li 2013 cites Kocherzhinskii 1973	Table 2, p. 3, row 11 report
Phase transition	2293 K	2293	Si2W->L Si2W: W 0.333333	experimental	[1] Vahlas 1989 cites ref. 51	Table 8, p. 15, row 15 report
Phase transition	2368 K	2368	Si3W5 Si3W5: W 0.625; L: W 0.625	experimental	[3] Li 2013 cites Kocherzhinskii 1973	Table 2, p. 3, row 12 report
Phase transition	2368 K	2368	Si3W5->(L) Si3W5: W 0.625	experimental	[1] Vahlas 1989 cites ref. 51	Table 8, p. 15, row 27 report
Phase transition	2381 K	2381	Si3W5->(L) Si3W5: W 0.625	model	[1] Vahlas 1989	Table 8, p. 15, row 23 report
Phase transition	2433 K	2433	Si2W Si2W: W 0.333333; L: W 0.333333	experimental	[3] Li 2013 cites Maksimov 1969	Table 2, p. 3, row 6 report
Phase transition	2433 K	2433	Si2W->L Si2W: W 0.333333	experimental	[1] Vahlas 1989 cites ref. 49	Table 8, p. 15, row 14 report
Phase transition	2433 K	2433	Si2W->L Si2W: W 0.333333	experimental	[1] Vahlas 1989 cites ref. 53	Table 8, p. 15, row 16 report
Phase transition	2436 K	2436	Si2W->L Si2W: W 0.333333	experimental	[1] Vahlas 1989 cites ref. 48	Table 8, p. 15, row 13 report
Phase transition	2438 K	2438	Si2W Si2W: W 0.333333; L: W 0.333333	experimental	[3] Li 2013 cites Kieffer 1952	Table 2, p. 3, row 1 report
Phase transition	2438 K	2438	Si2W->L Si2W: W 0.333	experimental	[1] Vahlas 1989 cites ref. 18	Table 8, p. 15, row 12 report
Phase transition	2583 K	2583	Si3W5->(L) Si3W5: W 0.625	experimental	[1] Vahlas 1989 cites ref. 18	Table 8, p. 15, row 26 report
Phase transition	2593 K	2593	Si3W5 Si3W5: W 0.625; L: W 0.625	experimental	[3] Li 2013 cites Kieffer 1952	Table 2, p. 3, row 2 report
Phase transition	2593 K	2593	Si3W5 Si3W5: W 0.625; L: W 0.625	experimental	[3] Li 2013 cites Maksimov 1969	Table 2, p. 3, row 7 report
Phase transition	2593 K	2593	Si3W5->(L) Si3W5: W 0.625	experimental	[1] Vahlas 1989 cites ref. 47	Table 8, p. 15, row 24 report
Phase transition	2641 K	2641	Si3W5->(L) Si3W5: W 0.625	experimental	[1] Vahlas 1989 cites ref. 48	Table 8, p. 15, row 25 report
Phase transition	3680 K	3680	W(bcc)->(L) W(bcc): W 1	experimental	[1] Vahlas 1989 cites ref. 58	Table 8, p. 15, row 36 report
Phase transition	3695 K	3695	W(bcc)->(L) W(bcc): W 1	experimental	[1] Vahlas 1989 cites ref. 10	Table 8, p. 15, row 35 report
Phase transition	3695 K	3695	W(bcc)->(L) W(bcc): W 1	model	[1] Vahlas 1989	Table 8, p. 15, row 34 report

Crystal structure (4)

Crystal structure, Si–W system
Property	Value	T (K)	Phases / composition	Class	Source	Location
Lattice a	9.59 Å	298.15	W5Si3 alloy: Si 0.375, W 0.625	model	[3] Li 2013 cites Daams 1991	Table 1, p. 2, row 8 report
Lattice a	3.22 Å	298.15	WSi2 alloy: Si 0.666667, W 0.333333	model	[3] Li 2013 cites Daams 1991	Table 1, p. 2, row 9 report
Lattice c	4.92 Å	298.15	W5Si3 alloy: Si 0.375, W 0.625	model	[3] Li 2013 cites Daams 1991	Table 1, p. 2, row 8 report
Lattice c	7.83 Å	298.15	WSi2 alloy: Si 0.666667, W 0.333333	model	[3] Li 2013 cites Daams 1991	Table 1, p. 2, row 9 report

Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

C. Vahlas, P.Y. Chevalier, E. Blanquet, A thermodynamic evaluation of four Si-M (M = Mo, Ta, Ti, W) binary systems, Calphad 13, 273-292 (1989). doi:10.1016/0364-5916(89)90007-2
Zhongnan Guo, Wenxia Yuan, Yu Sun, Zhoufei Cai, Zhiyu Qiao, Thermodynamic Assessment of the Si-Ta and Si-W Systems, J. Phase Equilib. Diffus. 30, 564-570 (2009). doi:10.1007/s11669-009-9579-x
Yan Li, Changrong Li, Zhenmin Du, Cuiping Guo, Thermodynamic optimization of the Nb–Si–W ternary system, Calphad 43, 112-123 (2013). doi:10.1016/j.calphad.2013.04.004

Please cite

R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23735569
R. Arróyave, J. Saal, D. Shin, ORCHID-Diagrams: calculated binary phase diagrams (version 2026.10), Zenodo (2026). doi:10.5281/zenodo.23735859
R. Arróyave, J. Saal, D. Shin, ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD) (version 2026.10), Zenodo (2026). doi:10.5281/zenodo.23735891
R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0). Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_phase_diagrams_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Diagrams: calculated binary phase diagrams}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735859},
  url       = {https://doi.org/10.5281/zenodo.23735859}
}

@misc{orchid_hulls_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD)}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735891},
  url       = {https://doi.org/10.5281/zenodo.23735891}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}