Sn–Zn system

8 accepted literature values from 2 paper(s) (experimental 6, model 2); 4 calculated phase diagram(s). 1 further extracted value(s) not accepted by the reader-agreement checks are only in the JSON/CSV.

Data: JSON · CSV · interactive explorer · interactive phase diagram · phases (6) · papers (bibliography) · Markdown

Accepted values by evidence class
Evidence class	Values
experimental	6
model	2

Accepted values by property group
Property group	Values
invariant reaction	8

Calculated phase diagrams

Binary phase diagrams calculated with pycalphad 0.11.2 from the SGTE binary collection (Hallstedt 2025, CC BY 4.0). Evidence class: model.

Assessments with a calculated phase diagram
TDB file	Assessment	SHA-256	Links
SnZn-93Sri.tdb	M. Srivastava, R.C. Sharma, J. Phase Equilib., 14, 700-709(1993). doi:10.1007/BF02667882	`a477685a7eeb967ec28603af368ec70bf659bd7a5dfa917a7010ac1286dc2a1b`	viewer · TDB · JSON
SnZn-96Lee.tdb	B.-J. Lee, Calphad, 20, 471-80(1996). doi:10.1016/S0364-5916(97)00009-6	`242f5b5ef74d7149d9ea48fe2dbb3eae8fc06425b3da8acb981c5fd52f25823a`	viewer · TDB · JSON
SnZn-98Fri-LB.tdb	S.G. Fries, H.L. Lukas, I. Ansara, COST 507, Final report round 2, 1998.	`c592cd8539bbd4681855f490aaf6dac51bd6f90ccb6d10e80c27c3ccba289656`	viewer · TDB · JSON
SnZn-99Oht.tdb	H. Ohtani, M. Miyashita, K. Ishida, J. Jpn. Inst. Met., 63, 685-94(1999). doi:10.2320/jinstmet1952.63.6_685	`b9bc638c140accc3777d03f02590e52f24f4de31b13a6d4a541642c27d2c16c9`	viewer · TDB · JSON

Calculated three-phase invariants (model, mole fraction of the second component)
TDB file	T (K)	Phases at the invariant
SnZn-93Sri.tdb	471.38	BCT_A5 (x(Zn) 0.00535) + LIQUID (x(Zn) 0.15073) + HCP_A3 (x(Zn) 0.99961)
SnZn-96Lee.tdb	472.45	BCT_A5 (x(Zn) 0.01231) + LIQUID (x(Zn) 0.1498) + HCP_A3 (x(Zn) 0.9996)
SnZn-98Fri-LB.tdb	471.7	BCT_A5 (x(Zn) 0.0059) + LIQUID (x(Zn) 0.13475) + HCP_A3 (x(Zn) 0.99929)
SnZn-99Oht.tdb	465.53	BCT_A5 (x(Zn) 0.00714) + LIQUID (x(Zn) 0.14726) + HCP_A3 (x(Zn) 0.99997)
SnZn-99Oht.tdb	465.53	BCT_A5 (x(Zn) 0.00714) + LIQUID (x(Zn) 0.14725) + HCP_A3 (x(Zn) 0.99997)

Convex hulls: Materials Project DFT hull · OQMD DFT hull · CALPHAD hull SnZn-93Sri · CALPHAD hull SnZn-96Lee · CALPHAD hull SnZn-98Fri-LB

Invariant reactions (literature)

Invariant reactions reported in the literature for the Sn–Zn system (8)
T (K)	Reaction / phases	Compositions (mole fraction)	Class	Source	Location
472	eutectic: L <-> (Zn) + (Sn)	L: Zn 0.139	experimental	[1] Srivastava 1993 cites ref. 7	Table 4, p. 7, row 3 report
472	eutectic: L <-> (Zn) + (Sn)	L: Zn 0.135	experimental	[1] Srivastava 1993 cites ref. 5	Table 4, p. 7, row 2 report
472	eutectic: L <-> (Zn) + (Sn)	L: Zn 0.146	experimental	[1] Srivastava 1993 cites ref. 15	Table 4, p. 7, row 5 report
471.7	eutectic: Liquid -> bct-A5 + hcp-Zn	L: Zn 0.135; bct-A5: Zn 0.006; hcp-Zn: Zn 1	model	[2] (ed.) 1998	Table I, p. 305, row 1 report
471.46	eutectic: L <-> (Zn) + (Sn)	L: Zn 0.149	model	[1] Srivastava 1993	Table 4, p. 7, row 7 report
471	eutectic: L <-> (Zn) + (Sn)	L: Zn 0.146	experimental	[1] Srivastava 1993 cites ref. 9	Table 4, p. 7, row 6 report
471	eutectic: L <-> (Zn) + (Sn)	L: Zn 0.158	experimental	[1] Srivastava 1993 cites ref. 3	Table 4, p. 7, row 1 report
471	eutectic: L <-> (Zn) + (Sn)	L: Zn 0.152	experimental	[1] Srivastava 1993 cites ref. 8	Table 4, p. 7, row 4 report

Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

M. Srivastava, R. C. Sharma, Thermodynamic analysis and phase equilibria calculations of pb-zn, sn-zn, and pb-sn-zn systems, JPE 14, 700-709 (1993). doi:10.1007/bf02667882
I. Ansara, A. T. Dinsdale, M. H. Rand (eds.), COST 507: Thermochemical database for light metal alloys, Volume 2, EUR 18499 EN, Office for Official Publications of the European Communities, Luxembourg (1998), ISBN 92-828-3902-8.

Please cite

R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23735569
R. Arróyave, J. Saal, D. Shin, ORCHID-Diagrams: calculated binary phase diagrams (version 2026.10), Zenodo (2026). doi:10.5281/zenodo.23735859
R. Arróyave, J. Saal, D. Shin, ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD) (version 2026.10), Zenodo (2026). doi:10.5281/zenodo.23735891
R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0). Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_phase_diagrams_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Diagrams: calculated binary phase diagrams}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735859},
  url       = {https://doi.org/10.5281/zenodo.23735859}
}

@misc{orchid_hulls_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD)}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735891},
  url       = {https://doi.org/10.5281/zenodo.23735891}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}