Th–U system

8 accepted literature values from 1 paper(s) (experimental 4, model 4); 2 calculated phase diagram(s). 4 further extracted value(s) not accepted by the reader-agreement checks are only in the JSON/CSV.

Data: JSON · CSV · interactive explorer · interactive phase diagram · phases (8) · papers (bibliography) · Markdown

Accepted values by evidence class
Evidence class	Values
experimental	4
model	4

Accepted values by property group
Property group	Values
invariant reaction	8

Calculated phase diagrams

Binary phase diagrams calculated with pycalphad 0.11.2 from the SGTE binary collection (Hallstedt 2025, CC BY 4.0). Evidence class: model.

Assessments with a calculated phase diagram
TDB file	Assessment	SHA-256	Links
ThU-09Li.tdb	Z.S. Li, X.J. Liu, C.P. Wang, J. Alloys Compd., 476, 193-98(2009). doi:10.1016/j.jallcom.2008.09.051	`64caf9670047ca6efc7629beb91124f0cfe7fb71cd0e63703197db8a6c35bcae`	viewer · TDB · JSON
ThU-14Ben.tdb	O. Benes, D. Manara, R.J.M. Konings, J. Nucl. Mater., 449, 15-22(2014). doi:10.1016/j.jnucmat.2014.02.001	`66891b9d678576aa22a2ee00f8fdc82fcd3219a84b67a59006362403d3c3f5c6`	viewer · TDB · JSON

Calculated three-phase invariants (model, mole fraction of the second component)
TDB file	T (K)	Phases at the invariant
ThU-09Li.tdb	1623.82	BCC_A2 (x(U) 0.11822) + LIQUID#2 (x(U) 0.51021) + LIQUID (x(U) 0.92312)
ThU-09Li.tdb	1547.68	FCC_A1 (x(U) 0.06255) + BCC_A2 (x(U) 0.10545) + LIQUID (x(U) 0.94858)
ThU-09Li.tdb	1382.96	FCC_A1 (x(U) 0.03864) + LIQUID (x(U) 0.97538) + BCC_A2 (x(U) 0.99249)
ThU-09Li.tdb	1051.49	FCC_A1 (x(U) 0.00782) + TETRAGONAL_U (x(U) 0.99741) + BCC_A2 (x(U) 0.99868)
ThU-09Li.tdb	944.37	FCC_A1 (x(U) 0.00373) + ORTHORHOMBIC_A20 (x(U) 0.99779) + TETRAGONAL_U (x(U) 0.99867)
ThU-14Ben.tdb	1636.93	BCC_TH (x(U) 0.09137) + LIQUID#2 (x(U) 0.48088) + LIQUID (x(U) 0.92835)
ThU-14Ben.tdb	1527.33	FCC_A1 (x(U) 0.0627) + BCC_TH (x(U) 0.08154) + LIQUID (x(U) 0.95858)
ThU-14Ben.tdb	1381.02	FCC_A1 (x(U) 0.05127) + LIQUID (x(U) 0.97912) + BCC_U (x(U) 0.997)
ThU-14Ben.tdb	1048.19	FCC_A1 (x(U) 0.02) + BCC_U (x(U) 0.99958) + TETRAGONAL_U (x(U) 1)
ThU-14Ben.tdb	1048.19	FCC_A1 (x(U) 0.02) + BCC_U (x(U) 0.99958) + TETRAGONAL_U (x(U) 1)
ThU-14Ben.tdb	942.02	FCC_A1 (x(U) 0.01263) + ORTHORHOMBIC_A20 (x(U) 1) + TETRAGONAL_U (x(U) 1)
ThU-14Ben.tdb	942.02	FCC_A1 (x(U) 0.0126) + TETRAGONAL_U (x(U) 1) + ORTHORHOMBIC_A20 (x(U) 1)

Convex hulls: Materials Project DFT hull · OQMD DFT hull · CALPHAD hull ThU-09Li

Invariant reactions (literature)

Invariant reactions reported in the literature for the Th–U system (8)
T (K)	Reaction / phases	Compositions (mole fraction)	Class	Source	Location
1923.15	critical point: L -> L1 + L2	L: U 0.78	model	[1] Li 2009	Table 3, p. 4, row 8 report
1923.15	critical point: L -> L1 + L2		experimental	[1] Li 2009 cites Peterson 1995	Table 3, p. 4, row 7 report
1648.15	monotectic: L1 -> βTh + L2	L1: U 0.51; βTh: U 0.122; L2: U 0.94	experimental	[1] Li 2009 cites Peterson 1995	Table 3, p. 4, row 1 report
1644.15	monotectic: L1 -> βTh + L2	L1: U 0.507; βTh: U 0.12; L2: U 0.927	model	[1] Li 2009	Table 3, p. 4, row 2 report
1543.15	metatectic/catatectic: βTh -> αTh + L2	βTh: U 0.105; αTh: U 0.088	experimental	[1] Li 2009 cites Peterson 1995	Table 3, p. 4, row 3 report
1543.15	metatectic/catatectic: βTh -> αTh + L2	βTh: U 0.105; αTh: U 0.088; L2: U 0.95	model	[1] Li 2009	Table 3, p. 4, row 4 report
1380.15	eutectic: L2 -> αTh + γU	L2: U 0.97; αTh: U 0.04; γU: U 0.982	model	[1] Li 2009	Table 3, p. 4, row 6 report
1373.15	eutectic: L2 -> αTh + γU	L2: U 0.96	experimental	[1] Li 2009 cites Peterson 1995	Table 3, p. 4, row 5 report

Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

Z.S. Li, X.J. Liu, C.P. Wang, Thermodynamic modeling of the Th–U, Th–Zr and Th–U–Zr systems, Journal of Alloys and Compounds 476, 193-198 (2009). doi:10.1016/j.jallcom.2008.09.051

Please cite

R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23735569
R. Arróyave, J. Saal, D. Shin, ORCHID-Diagrams: calculated binary phase diagrams (version 2026.10), Zenodo (2026). doi:10.5281/zenodo.23735859
R. Arróyave, J. Saal, D. Shin, ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD) (version 2026.10), Zenodo (2026). doi:10.5281/zenodo.23735891
R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0). Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_phase_diagrams_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Diagrams: calculated binary phase diagrams}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735859},
  url       = {https://doi.org/10.5281/zenodo.23735859}
}

@misc{orchid_hulls_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD)}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735891},
  url       = {https://doi.org/10.5281/zenodo.23735891}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}