Zn–P system

0 accepted literature values from 0 paper(s); 3 calculated phase diagram(s).

Data: interactive phase diagram · Markdown

Calculated phase diagrams

Binary phase diagrams calculated with pycalphad 0.11.2 from the SGTE binary collection (Hallstedt 2025, CC BY 4.0). Evidence class: model.

Assessments with a calculated phase diagram
TDB file	Assessment	SHA-256	Links
ZnP-09Tu.tdb	H. Tu, F. Yin, X. Su, Y. Liu, X. Wang, Calphad, 33, 755-60(2009). doi:10.1016/j.calphad.2009.10.003	`5a43eb27a53acc7bc1dd637623438477b72af5bfec2357bdab24015d66e8d4c0`	viewer · TDB · JSON
ZnP-16Liu.tdb	Y. Liu, B. Zhou, W. Lv, C. Wu, X. Su, J. Wang, Surf. Coat. Technol., 306, 370-77(2016). doi:10.1016/j.surfcoat.2016.01.016	`9f1fa0c8b5e7cc7839fc35721c768f734f6adbda382d87db4a01468b1a502f95`	viewer · TDB · JSON
ZnP-19Gha.tdb	M. Ghasemi, E. Stutz, S. Escobar Steinvall, M. Zamani, A. Fontcuberta i Morral, Materialia, 6, 100301(2019). doi:10.1016/j.mtla.2019.100301	`42b7557b5f07288001aee201566e4afc7756dfdd3574ac944437ef7a71b68fec`	viewer · TDB · JSON

Calculated three-phase invariants (model, mole fraction of the second component)
TDB file	T (K)	Phases at the invariant
ZnP-09Tu.tdb	1268.87	ZN3P2 (x(P) 0.4) + LIQUID (x(P) 0.58694) + ZNP2 (x(P) 0.66667)
ZnP-09Tu.tdb	1268.87	ZN3P2 (x(P) 0.4) + LIQUID (x(P) 0.587) + ZNP2 (x(P) 0.66667)
ZnP-09Tu.tdb	1268.87	ZN3P2 (x(P) 0.4) + LIQUID (x(P) 0.58661) + ZNP2 (x(P) 0.66667)
ZnP-09Tu.tdb	1046.98	ZNP2 (x(P) 0.66667) + LIQUID (x(P) 0.87814) + GAS (x(P) 1)
ZnP-09Tu.tdb	1046.98	ZNP2 (x(P) 0.66667) + LIQUID (x(P) 0.87814) + GAS (x(P) 1)
ZnP-09Tu.tdb	704.7	ZNP2 (x(P) 0.66667) + GAS (x(P) 1) + RED_P (x(P) 1)
ZnP-09Tu.tdb	687.4	HCP_A3 (x(P) 0) + LIQUID (x(P) 0.00642) + ZN3P2 (x(P) 0.4)
ZnP-09Tu.tdb	687.4	HCP_A3 (x(P) 0) + LIQUID (x(P) 0.00637) + ZN3P2 (x(P) 0.4)
ZnP-16Liu.tdb	1258.57	ZN3P2 (x(P) 0.4) + LIQUID (x(P) 0.59472) + ZNP2 (x(P) 0.66667)
ZnP-16Liu.tdb	1258.57	ZN3P2 (x(P) 0.4) + LIQUID (x(P) 0.59489) + ZNP2 (x(P) 0.66667)
ZnP-16Liu.tdb	1258.57	ZN3P2 (x(P) 0.4) + LIQUID (x(P) 0.59467) + ZNP2 (x(P) 0.66667)
ZnP-16Liu.tdb	1056.27	ZNP2 (x(P) 0.66667) + LIQUID (x(P) 0.83182) + GAS (x(P) 1)
ZnP-16Liu.tdb	1056.27	ZNP2 (x(P) 0.66667) + LIQUID (x(P) 0.83182) + GAS (x(P) 1)
ZnP-16Liu.tdb	704.7	ZNP2 (x(P) 0.66667) + GAS (x(P) 1) + RED_P (x(P) 1)
ZnP-16Liu.tdb	682.98	HCP_A3 (x(P) 0) + LIQUID (x(P) 0.01126) + ZN3P2 (x(P) 0.4)
ZnP-16Liu.tdb	682.98	HCP_A3 (x(P) 0) + LIQUID (x(P) 0.01113) + ZN3P2 (x(P) 0.4)
ZnP-19Gha.tdb	1301.83	LIQUID (x(P) 0.62749) + ZNP2_HT (x(P) 0.66667) + GAS (x(P) 1)
ZnP-19Gha.tdb	1301.83	LIQUID (x(P) 0.62739) + ZNP2_HT (x(P) 0.66667) + GAS (x(P) 1)
ZnP-19Gha.tdb	1262.62	ZNP2_HT (x(P) 0.66667) + ZNP2_LT (x(P) 0.66667) + GAS (x(P) 1)
ZnP-19Gha.tdb	1262.62	ZNP2_HT (x(P) 0.66667) + ZNP2_LT (x(P) 0.66667) + GAS (x(P) 1)
ZnP-19Gha.tdb	1262.62	LIQUID (x(P) 0.57734) + ZNP2_HT (x(P) 0.66667) + ZNP2_LT (x(P) 0.66667)
ZnP-19Gha.tdb	1262.62	LIQUID (x(P) 0.57792) + ZNP2_LT (x(P) 0.66667) + ZNP2_HT (x(P) 0.66667)
ZnP-19Gha.tdb	1256.22	ZN3P2_HT (x(P) 0.4) + LIQUID (x(P) 0.56027) + ZNP2_LT (x(P) 0.66667)
ZnP-19Gha.tdb	1256.22	ZN3P2_HT (x(P) 0.4) + LIQUID (x(P) 0.5603) + ZNP2_LT (x(P) 0.66667)
ZnP-19Gha.tdb	1256.22	ZN3P2_HT (x(P) 0.4) + LIQUID (x(P) 0.55987) + ZNP2_LT (x(P) 0.66667)
ZnP-19Gha.tdb	1123.02	ZN3P2_LT (x(P) 0.4) + ZN3P2_HT (x(P) 0.4) + ZNP2_LT (x(P) 0.66667)
ZnP-19Gha.tdb	1123.02	LIQUID (x(P) 0.03957) + ZN3P2_LT (x(P) 0.4) + ZN3P2_HT (x(P) 0.4)
ZnP-19Gha.tdb	704.7	ZNP2_LT (x(P) 0.66667) + GAS (x(P) 1) + RED_P (x(P) 1)
ZnP-19Gha.tdb	704.7	ZNP2_LT (x(P) 0.66667) + GAS (x(P) 1) + RED_P (x(P) 1)
ZnP-19Gha.tdb	692.64	HCP_A3 (x(P) 0) + LIQUID (x(P) 6.000e-5) + ZN3P2_LT (x(P) 0.4)

Please cite

R. Arróyave, J. Saal, D. Shin, ORCHID-Diagrams: calculated binary phase diagrams (version 2026.10), Zenodo (2026). doi:10.5281/zenodo.23735859
R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23736065

Also cite B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0). Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

@misc{orchid_phase_diagrams_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Diagrams: calculated binary phase diagrams}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735859},
  url       = {https://doi.org/10.5281/zenodo.23735859}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}