The ternary bismuth–iron–antimony system: Experimental phase diagram study and thermodynamic evaluation

D. Boa, S. Hassam, G. Kra, K.P. Kotchi, J. Rogez

Calphad 32 (2) 227-239 (2008) · Elsevier BV

DOI: 10.1016/j.calphad.2008.01.001

Data: JSON record · id doi:10.1016/j.calphad.2008.01.001 · metadata: crossref

Roles in ORCHID

• read by ORCHID (values extracted): 103 released values
• assessment behind a TDB file: BiFe-08Boa.tdb (Bi–Fe), FeSb-08Boa.tdb (Fe–Sb)

Systems

Bi–Fe, Bi–Sb, Fe–Sb, Bi–Fe–Sb

Evidence in ORCHID

103 values read from this paper (49 accepted), from 8 tables and 10 text passages.

ESPEI datasets derived: 6 (derived/invariant-brackets/FE-SB/FeSb-08Boa.zpf-00.json …).

Phase-registry phases citing it: phase:bi-fe:a7-rhombohedral, phase:bi-fe:bcc-a2, phase:bi-fe:fcc-a1, phase:bi-fe:hcp-a3, phase:bi-fe:liquid, phase:fe-sb:a7-rhombohedral, phase:fe-sb:bcc-a2, phase:fe-sb:fcc-a1, phase:fe-sb:fesb-b81, phase:fe-sb:fesb2-c18, phase:fe-sb:hcp-a3, phase:fe-sb:liquid

Availability

Read by ORCHID: yes (values_extracted). Open-access licence (Crossref license field): none deposited. Crossref is-referenced-by count: 33 (retrieved 2026-10-23).

Relations

Cited by (Crossref reference lists) (15)

• Thermodynamics on the Bi-Fe-Ti System and the Gibbs Energy of Bi9Ti8 (2018) [crossref_reference_list]
• Bi-Fe-Sb (Bismuth-Iron-Antimony) (2008) [crossref_reference_list]
• Bi-Ce-Fe (Bismuth-Cerium-Iron) (2012) [crossref_reference_list]
• Thermodynamic description of the Er–Fe–Sb system (2011) [crossref_reference_list]
• Thermodynamic modeling of Fe–Ce–Bi system and explanation of interfacial reaction in Fe-45at%–Ce/Bi couple (2012) [crossref_reference_list]
• Thermodynamic modeling of Fe–Ti–Bi system assisted with key experiments (2014) [crossref_reference_list]
• Thermodynamic assessment of the Co–Fe–Sb system (2014) [crossref_reference_list]
• Thermodynamic assessment of the Ce-Fe-Sb system (2019) [crossref_reference_list]
• Experimental investigation and thermodynamic calculation of the Fe–Si–Bi system (2020) [crossref_reference_list]
• The SGTE collection of binary datasets (2025) [crossref_reference_list]
• DSC investigation of phase equilibria in the Bi-Pb-Sb system (2016) [crossref_reference_list]
• Thermodynamic assessment of solubility and activity of iron, chromium, and nickel in lead bismuth eutectic (2014) [crossref_reference_list]
• Review of phase equilibria in the Pb-Bi-Fe-Cr-Ni-U-N system – Basis for a “heavy liquid metal coolant – Fuel cladding steel – Nitride fuel” interactions (2024) [crossref_reference_list]
• Rationally designed mineral phase reconstruction for selective extraction and full-component recovery of Nd-Fe-B magnet scraps (2025) [crossref_reference_list]
• A Thermodynamic Modeling of the Fe–Nd–Sb System (2016) [crossref_reference_list]

References (Crossref, publisher-deposited) (13)

• XLIX. Über das Verhalten von Eisen zu Blei, Wismut, Thallium und Cadmium (1907) [crossref_reference_list]
• Te-Zr (Tellurium-Zirconium) (1999) [crossref_reference_list]
• Les systemes binaires Fe-Sb, Co-Sb et Ni-Sb (1989) [crossref_reference_list]
• Kalorimetrische untersuchungen an festen legierungen der systeme eisen—antimon, kobalt—antimon und nickel-antimon (1978) [crossref_reference_list]
• The Thermo-Calc databank system (1985) [crossref_reference_list]
• SGTE data for pure elements (1991) [crossref_reference_list]
• Thermodynamic evaluation of the system bismuth-antimony (1992) [crossref_reference_list]
• A thermodynamic assessment of the iron — Antimony system (1995) [crossref_reference_list]
• Thermodynamic investigation of the moderately dilute liquid Bi–Fe–Sb alloys (2006) [crossref_reference_list]
• The iron–antimony system: enthalpies of formation of the FeSb2 and ε-FeSb phases (2004) [crossref_reference_list]
• Reinvestigation of the binary Fe-Sb phase diagram (1997) [crossref_reference_list]
• Algebraic Representation of Thermodynamic Properties and the Classification of Solutions (1948) [crossref_reference_list]
• Effect of Magnetic Transition on the Solubility of Alloying Elements in <I>BCC</I> Iron and <I>FCC</I> Cobalt (1981) [crossref_reference_list]

Cites (values carry this citation) (5)

• Reinvestigation of the binary Fe-Sb phase diagram (1997) — 11 values [orchid_extraction]
• Thermodynamic investigation of the moderately dilute liquid Bi–Fe–Sb alloys (2006) — 2 values [orchid_extraction]
• The iron–antimony system: enthalpies of formation of the FeSb2 and ε-FeSb phases (2004) — 2 values [orchid_extraction]
• Kalorimetrische untersuchungen an festen legierungen der systeme eisen—antimon, kobalt—antimon und nickel-antimon (1978) — 1 values [orchid_extraction]
• Thermodynamic evaluation of the system bismuth-antimony (1992) — 1 values [orchid_extraction]

TDB files modelling its system (4)

• tdb:BiFe-08Boa.tdb [sgte_tdb_header]
• tdb:BiFe-08Boa.tdb [orchid_literature_model_link]
• tdb:FeSb-08Boa.tdb [orchid_literature_model_link]
• tdb:FeSb-08Boa.tdb [sgte_tdb_header]

Reassessed by (1)

• Thermodynamic assessment of the Co–Fe–Sb system (2014) [citation+same-system]

Reassesses (cites an earlier assessment of the same system) (1)

• A thermodynamic assessment of the iron — Antimony system (1995) [citation+same-system]

Data papers used (5)

• Reinvestigation of the binary Fe-Sb phase diagram (1997) — 11 values [orchid_extraction]
• Thermodynamic investigation of the moderately dilute liquid Bi–Fe–Sb alloys (2006) — 2 values [orchid_extraction]
• The iron–antimony system: enthalpies of formation of the FeSb2 and ε-FeSb phases (2004) — 2 values [orchid_extraction]
• Kalorimetrische untersuchungen an festen legierungen der systeme eisen—antimon, kobalt—antimon und nickel-antimon (1978) — 1 values [orchid_extraction]
• Thermodynamic evaluation of the system bismuth-antimony (1992) — 1 values [orchid_extraction]