Thermodynamic Modeling of the Ge-X (X = As, Se, S, P) Systems

Shanxiong Chen, Jiong Wang, Shangzhao Yu, Biao Hu, Qing Wu, Yong Du

Journal of Electronic Materials 51 (5) 2114-2130 (2022) · Springer Science and Business Media LLC

DOI: 10.1007/s11664-022-09474-1

Data: JSON record · id doi:10.1007/s11664-022-09474-1 · metadata: crossref

Roles in ORCHID

• read by ORCHID (values extracted): 132 released values
• assessment behind a TDB file: GeAs-22Che.tdb (As–Ge), GeP-22Che.tdb (Ge–P), GeS-22Che.tdb (Ge–S), GeSe-22Che.tdb (Ge–Se)
• discovery lead (found by Crossref assessment discovery, not read): rank 944, score 96; systems named in title: none

Systems

Ge, P, S, Se, As–Ge, Ge–P, Ge–S, Ge–Se, As–Ge–P–S–Se

Evidence in ORCHID

132 values read from this paper (126 accepted), from 3 tables and 10 text passages.

Phase-registry phases citing it: phase:as-ge:a4-diamond, phase:as-ge:a7-rhombohedral, phase:as-ge:bcc-a2, phase:as-ge:fcc-a1, phase:as-ge:geas, phase:as-ge:geas2, phase:as-ge:hcp-a3, phase:as-ge:liquid, phase:ge-p:a4-diamond, phase:ge-p:bcc-a2, phase:ge-p:fcc-a1, phase:ge-p:gep, phase:ge-p:hcp-a3, phase:ge-p:liquid, phase:ge-p:p-red, phase:ge-p:p-white, phase:ge-s:a16-orthorhombic, phase:ge-s:a4-diamond, phase:ge-s:bcc-a2, phase:ge-s:fcc-a1 …

Availability

Read by ORCHID: yes (values_extracted). Open-access licence (Crossref license field): none deposited. Crossref is-referenced-by count: 10 (retrieved 2026-10-23).

Relations

Cited by (Crossref reference lists) (9)

• Phase Equilibria and Thermodynamic Properties of Functional Chalcogenides in the Ag–Pd–Ge–S System (2026) [crossref_reference_list]
• Thermodynamic Modeling of the Te-X (X = Gd, Dy, Ho) Binary Systems Combined with the First-Principles Method (2023) [crossref_reference_list]
• Thermodynamic Modeling of the Cu-Sb-Se System (2023) [crossref_reference_list]
• Thermodynamic Modeling of the Bi-Se and Bi-Te Binary Systems (2024) [crossref_reference_list]
• The SGTE collection of binary datasets (2025) [crossref_reference_list]
• Thermodynamic and kinetic studies of the performance effect of Al doping in the Ge-Sb-Te phase change materials (2025) [crossref_reference_list]
• Phase equilibria and thermodynamic modeling of the Ge-Te-Bi ternary system (2026) [crossref_reference_list]
• Thermodynamic investigation of the Ag–Ge–Te system: measurement, modeling, and application (2026) [crossref_reference_list]
• Thermodynamic description of the Ge-Sb-Te phase change materials and its applications in predictions of crystallization and solidification (2025) [crossref_reference_list]

References (Crossref, publisher-deposited) (33)

• Germanium and Silicon Liquidus Curves (1960) [crossref_reference_list]
• Über Zweistoffsysteme mit Germanium. II. Germanium/Arsen, Germanium/Antimon, Germanium/Wismut (1940) [crossref_reference_list]
• The thermal expansion and high temperature transformation of GeSe (1975) [crossref_reference_list]
• The Thermal Expansion of GeS and GeTe (1977) [crossref_reference_list]
• Structural Transformations in Three-Dimensional Crystalline GeSe2 at High Pressures and High Temperatures (2000) [crossref_reference_list]
• The Ge−P (Germanium-Phosphorus) system (1985) [crossref_reference_list]
• Thermodynamic Assessment of the Ag-Se System Aided by First-Principles Calculations (2018) [crossref_reference_list]
• Thermodynamic Description of the Al–X (X = S, Se, Te) Systems (2019) [crossref_reference_list]
• Materials Design and Discovery with High-Throughput Density Functional Theory: The Open Quantum Materials Database (OQMD) (2013) [crossref_reference_list]
• Enthalpies of formation for Group IV selenides (GeSe2, GeSe2(am), SnSe, SnSe2, PbSe) by direct-combination drop calorimetry (1992) [crossref_reference_list]
• Thermodynamic study of the Al-Ga-As-Ge system (1984) [crossref_reference_list]
• The Thermo-Calc databank system (1985) [crossref_reference_list]
• SGTE data for pure elements (1991) [crossref_reference_list]
• Direct synthesis calorimetry of some binary alloys in the systems SiAs, GeAs and SnAs (1996) [crossref_reference_list]
• Computational thermodynamics and its applications (2020) [crossref_reference_list]
• First-principles calculations of binary Al compounds: Enthalpies of formation and elastic properties (2011) [crossref_reference_list]
• Thermodynamic assessment of the Te-X (X = As, Si, Co) systems (2020) [crossref_reference_list]
• Thermodynamic reassessment of the Mo–Hf and Mo–Zr systems supported by first-principles calculations (2020) [crossref_reference_list]
• Thermodynamic modeling of the Te-X (X = Zr, Ce, Eu) systems (2021) [crossref_reference_list]
• Thermodynamic assessment of the As-X (X=Si, Ge, Sn) binary systems (2021) [crossref_reference_list]
• High-temperature enthalpies of As2Te3, Sb2Se3, Bi2Se3, GeAs, GeAs2, and SnAs (1971) [crossref_reference_list]
• On the Structure of Germanium Selenide and Related Binary IV/VI Compounds (1965) [crossref_reference_list]
• Algebraic Representation of Thermodynamic Properties and the Classification of Solutions (1948) [crossref_reference_list]
• Bond distances and chain angle of hexagonal selenium at high pressure (1972) [crossref_reference_list]
• Commentary: The Materials Project: A materials genome approach to accelerating materials innovation (2013) [crossref_reference_list]
• Special points for Brillouin-zone integrations (1976) [crossref_reference_list]
• Efficient iterative schemes for <i>ab initio</i> total-energy calculations using a plane-wave basis set (1996) [crossref_reference_list]
• From ultrasoft pseudopotentials to the projector augmented-wave method (1999) [crossref_reference_list]
• Generalized Gradient Approximation Made Simple (1996) [crossref_reference_list]
• The crystal structures of the germanium–arsenic compounds: I. Germanium diarsenide, GeAs₂ (1962) [crossref_reference_list]
• Über Struktur und Eigenschaften der Halbmetalle. XXII. Die Kristallstruktur des Hittorfschen Phosphors (1969) [crossref_reference_list]
• Die Kristallstruktur von H.T.-GeS₂ (1975) [crossref_reference_list]
• The Crystal Structures of SiP2, SiAs2, and GeP. (1967) [crossref_reference_list]

Cites (values carry this citation) (11)

• The Crystal Structures of SiP2, SiAs2, and GeP. (1967) — 6 values [orchid_extraction]
• The Thermal Expansion of GeS and GeTe (1977) — 3 values [orchid_extraction]
• Structural Transformations in Three-Dimensional Crystalline GeSe2 at High Pressures and High Temperatures (2000) — 3 values [orchid_extraction]
• On the Structure of Germanium Selenide and Related Binary IV/VI Compounds (1965) — 3 values [orchid_extraction]
• Bond distances and chain angle of hexagonal selenium at high pressure (1972) — 3 values [orchid_extraction]
• The crystal structures of the germanium–arsenic compounds: I. Germanium diarsenide, GeAs₂ (1962) — 3 values [orchid_extraction]
• Über Struktur und Eigenschaften der Halbmetalle. XXII. Die Kristallstruktur des Hittorfschen Phosphors (1969) — 3 values [orchid_extraction]
• Die Kristallstruktur von H.T.-GeS₂ (1975) — 3 values [orchid_extraction]
• Direct synthesis calorimetry of some binary alloys in the systems SiAs, GeAs and SnAs (1996) — 2 values [orchid_extraction]
• High-temperature enthalpies of As2Te3, Sb2Se3, Bi2Se3, GeAs, GeAs2, and SnAs (1971) — 2 values [orchid_extraction]
• The thermal expansion and high temperature transformation of GeSe (1975) — 1 values [orchid_extraction]

TDB files modelling its system (4)

• tdb:GeAs-22Che.tdb [sgte_tdb_header]
• tdb:GeP-22Che.tdb [sgte_tdb_header]
• tdb:GeS-22Che.tdb [sgte_tdb_header]
• tdb:GeSe-22Che.tdb [sgte_tdb_header]

Reassesses (cites an earlier assessment of the same system) (2)

• Thermodynamic study of the Al-Ga-As-Ge system (1984) [citation+same-system]
• Thermodynamic assessment of the As-X (X=Si, Ge, Sn) binary systems (2021) [citation+same-system]

Data papers used (11)

• The Crystal Structures of SiP2, SiAs2, and GeP. (1967) — 6 values [orchid_extraction]
• The Thermal Expansion of GeS and GeTe (1977) — 3 values [orchid_extraction]
• Structural Transformations in Three-Dimensional Crystalline GeSe2 at High Pressures and High Temperatures (2000) — 3 values [orchid_extraction]
• On the Structure of Germanium Selenide and Related Binary IV/VI Compounds (1965) — 3 values [orchid_extraction]
• Bond distances and chain angle of hexagonal selenium at high pressure (1972) — 3 values [orchid_extraction]
• The crystal structures of the germanium–arsenic compounds: I. Germanium diarsenide, GeAs₂ (1962) — 3 values [orchid_extraction]
• Über Struktur und Eigenschaften der Halbmetalle. XXII. Die Kristallstruktur des Hittorfschen Phosphors (1969) — 3 values [orchid_extraction]
• Die Kristallstruktur von H.T.-GeS₂ (1975) — 3 values [orchid_extraction]
• Direct synthesis calorimetry of some binary alloys in the systems SiAs, GeAs and SnAs (1996) — 2 values [orchid_extraction]
• High-temperature enthalpies of As2Te3, Sb2Se3, Bi2Se3, GeAs, GeAs2, and SnAs (1971) — 2 values [orchid_extraction]
• The thermal expansion and high temperature transformation of GeSe (1975) — 1 values [orchid_extraction]