Complete thermodynamic description of the Mg-Ca-O phase diagram including the Ca-O, Mg-O and CaO-MgO subsystems

Song-Mao Liang (ORCID 0000-0002-1099-8017), Rainer Schmid-Fetzer

Journal of the European Ceramic Society 38 (14) 4768-4785 (2018) · Elsevier BV

DOI: 10.1016/j.jeurceramsoc.2018.06.015

Data: JSON record · id doi:10.1016/j.jeurceramsoc.2018.06.015 · metadata: crossref

Roles in ORCHID

• read by ORCHID (values extracted): 51 released values
• cited as the original source of values
• assessment behind a TDB file: CaO-18Lia.tdb (Ca–O), MgO-18Lia.tdb (Mg–O)
• discovery lead (found by Crossref assessment discovery, not read): rank 1580, score 71; systems named in title: Ca–Mg–O

Systems

Ca–Lu, Ca–Mg, Ca–O, Mg–O, Ca–Mg–O

Evidence in ORCHID

51 values read from this paper (44 accepted), from 3 tables and 9 text passages.

10 values in 1 other papers cite this work as their source.

ESPEI datasets derived: 18 (experimental/CA-O/CaO-18Lia.zpf-00.json …).

Phase-registry phases citing it: phase:ca-o:b1-oxide, phase:ca-o:bcc-a2, phase:ca-o:cao2-c11a, phase:ca-o:fcc-a1, phase:ca-o:gas, phase:ca-o:hcp-a3, phase:ca-o:ion, phase:ca-o:liquid, phase:ca-o:o2gas, phase:mg-o:b1-oxide, phase:mg-o:bcc-a2, phase:mg-o:fcc-a1, phase:mg-o:gas, phase:mg-o:hcp-a3, phase:mg-o:ion, phase:mg-o:liquid, phase:mg-o:o2gas

Availability

Read by ORCHID: yes (values_extracted). Open-access licence (Crossref license field): none deposited. Crossref is-referenced-by count: 30 (retrieved 2026-10-23).

Relations

Cited by (Crossref reference lists) (5)

• Thermodynamic modelling of the Ca–O system including 3rd generation description of CaO and CaO2 (2020) [crossref_reference_list]
• The SGTE collection of binary datasets (2025) [crossref_reference_list]
• Thermodynamic evaluation of the aerial and aqueous oxidation of Al – Mg, Al – Si and Al – Mg – Si system alloys at 298 K (2024) [crossref_reference_list]
• Thermodynamic description of the Mg-O and Al-O systems (2023) [crossref_reference_list]
• Ca-Fe-O Ternary Phase Diagram Evaluation (2021) [crossref_reference_list]

References (Crossref, publisher-deposited) (26)

• Thermodynamic data for liquid Ca‐CaF₂ and Ca‐CaCl₂ slags (1985) [crossref_reference_list]
• Arbeiten im Gebiet hoher Temperaturen I. Über das Schmelzen und Verdampfen unserer feuerbeständigsten Oxyde im elektrischen Vakuumofen (1913) [crossref_reference_list]
• An assessment of the Ca-Fe-O system (1990) [crossref_reference_list]
• A thermodynamic analysis of the Cu-O system with an associated solution model (1983) [crossref_reference_list]
• Thermodynamic calculation of some subsystems of the Al-Ca-Mg-Si-O system (1993) [crossref_reference_list]
• The phase diagrams and thermodynamics of the ZrO2-CaO-MgO and MgO-CaO systems (1993) [crossref_reference_list]
• Thermodynamic assessment of the CaO-MgO-SiO2 system (1995) [crossref_reference_list]
• The Mg−O (Magnesium-Oxygen) system (1987) [crossref_reference_list]
• The Ca−O (Calcium-Oxygen) system (1985) [crossref_reference_list]
• Thermodynamics of the Ca-CaO-CaF2 system (2001) [crossref_reference_list]
• Thermodynamic analysis of binary liquid silicates and prediction of ternary solution properties by modified quasichemical equations (1987) [crossref_reference_list]
• Measurement of the solidification points of several refractory oxides by means of a solar furnace (1965) [crossref_reference_list]
• Fundamental research in refractory system with a solar furnace—ZrO2CaO system (1967) [crossref_reference_list]
• Thermal radiative properties of magnesium oxide at high temperatures (1993) [crossref_reference_list]
• Thermodynamic calculation of the CaO-MgO system (1989) [crossref_reference_list]
• SGTE data for pure elements (1991) [crossref_reference_list]
• A reassessment of the CaO-MgO system (1992) [crossref_reference_list]
• Thermodynamic assessment of the Silicon — Oxygen system (1992) [crossref_reference_list]
• The Magnesium — Oxygen system (1993) [crossref_reference_list]
• PANDAT software with PanEngine, PanOptimizer and PanPrecipitation for multi-component phase diagram calculation and materials property simulation (2009) [crossref_reference_list]
• Thermodynamic evaluation and optimization of the (Ca + C + O + S) system (2009) [crossref_reference_list]
• Thermodynamics and phase stability in the Si–O system (2004) [crossref_reference_list]
• MELTING POINTS OF BARIUM, STRONTIUM AND CALCIUM OXIDES¹ (1926) [crossref_reference_list]
• Melting point of MgO (2001) [crossref_reference_list]
• Reinvestigation of the Solidification Point of CaO by Digital Pyrometry (1986) [crossref_reference_list]
• Melting temperatures of refractory oxides: Part I (1982) [crossref_reference_list]

Cited for values by (1)

• Thermodynamic modelling of the Ca–O system including 3rd generation description of CaO and CaO2 (2020) — 10 values [orchid_extraction]

Cites (values carry this citation) (17)

• Melting temperatures of refractory oxides: Part I (1982) — 5 values [orchid_extraction]
• Thermodynamic analysis of binary liquid silicates and prediction of ternary solution properties by modified quasichemical equations (1987) — 3 values [orchid_extraction]
• Thermodynamic calculation of the CaO-MgO system (1989) — 3 values [orchid_extraction]
• Thermodynamic calculation of some subsystems of the Al-Ca-Mg-Si-O system (1993) — 2 values [orchid_extraction]
• The Ca−O (Calcium-Oxygen) system (1985) — 2 values [orchid_extraction]
• Arbeiten im Gebiet hoher Temperaturen I. Über das Schmelzen und Verdampfen unserer feuerbeständigsten Oxyde im elektrischen Vakuumofen (1913) — 1 values [orchid_extraction]
• The phase diagrams and thermodynamics of the ZrO2-CaO-MgO and MgO-CaO systems (1993) — 1 values [orchid_extraction]
• Thermodynamic assessment of the CaO-MgO-SiO2 system (1995) — 1 values [orchid_extraction]
• The Mg−O (Magnesium-Oxygen) system (1987) — 1 values [orchid_extraction]
• Measurement of the solidification points of several refractory oxides by means of a solar furnace (1965) — 1 values [orchid_extraction]
• Fundamental research in refractory system with a solar furnace—ZrO2CaO system (1967) — 1 values [orchid_extraction]
• Thermal radiative properties of magnesium oxide at high temperatures (1993) — 1 values [orchid_extraction]
• A reassessment of the CaO-MgO system (1992) — 1 values [orchid_extraction]
• Thermodynamic evaluation and optimization of the (Ca + C + O + S) system (2009) — 1 values [orchid_extraction]
• MELTING POINTS OF BARIUM, STRONTIUM AND CALCIUM OXIDES¹ (1926) — 1 values [orchid_extraction]
• Melting point of MgO (2001) — 1 values [orchid_extraction]
• Reinvestigation of the Solidification Point of CaO by Digital Pyrometry (1986) — 1 values [orchid_extraction]

TDB files modelling its system (4)

• tdb:CaO-18Lia.tdb [sgte_tdb_header]
• tdb:CaO-18Lia.tdb [orchid_literature_model_link]
• tdb:MgO-18Lia.tdb [orchid_literature_model_link]
• tdb:MgO-18Lia.tdb [sgte_tdb_header]

Reassessed by (2)

• Thermodynamic modelling of the Ca–O system including 3rd generation description of CaO and CaO2 (2020) [citation+same-system]
• Thermodynamic description of the Mg-O and Al-O systems (2023) [citation+same-system]

Reassesses (cites an earlier assessment of the same system) (1)

• The Magnesium — Oxygen system (1993) [citation+same-system]

Data papers used (17)

• Melting temperatures of refractory oxides: Part I (1982) — 5 values [orchid_extraction]
• Thermodynamic analysis of binary liquid silicates and prediction of ternary solution properties by modified quasichemical equations (1987) — 3 values [orchid_extraction]
• Thermodynamic calculation of the CaO-MgO system (1989) — 3 values [orchid_extraction]
• Thermodynamic calculation of some subsystems of the Al-Ca-Mg-Si-O system (1993) — 2 values [orchid_extraction]
• The Ca−O (Calcium-Oxygen) system (1985) — 2 values [orchid_extraction]
• Arbeiten im Gebiet hoher Temperaturen I. Über das Schmelzen und Verdampfen unserer feuerbeständigsten Oxyde im elektrischen Vakuumofen (1913) — 1 values [orchid_extraction]
• The phase diagrams and thermodynamics of the ZrO2-CaO-MgO and MgO-CaO systems (1993) — 1 values [orchid_extraction]
• Thermodynamic assessment of the CaO-MgO-SiO2 system (1995) — 1 values [orchid_extraction]
• The Mg−O (Magnesium-Oxygen) system (1987) — 1 values [orchid_extraction]
• Measurement of the solidification points of several refractory oxides by means of a solar furnace (1965) — 1 values [orchid_extraction]
• Fundamental research in refractory system with a solar furnace—ZrO2CaO system (1967) — 1 values [orchid_extraction]
• Thermal radiative properties of magnesium oxide at high temperatures (1993) — 1 values [orchid_extraction]
• A reassessment of the CaO-MgO system (1992) — 1 values [orchid_extraction]
• Thermodynamic evaluation and optimization of the (Ca + C + O + S) system (2009) — 1 values [orchid_extraction]
• MELTING POINTS OF BARIUM, STRONTIUM AND CALCIUM OXIDES¹ (1926) — 1 values [orchid_extraction]
• Melting point of MgO (2001) — 1 values [orchid_extraction]
• Reinvestigation of the Solidification Point of CaO by Digital Pyrometry (1986) — 1 values [orchid_extraction]

Used in (assessments / papers that took values from it) (1)

• Thermodynamic modelling of the Ca–O system including 3rd generation description of CaO and CaO2 (2020) — 10 values [orchid_extraction]