Thermodynamics of Fe–Sm, Fe–H, and H–Sm systems and its application to the hydrogen–disproportionation–desorption–recombination (HDDR) process for the system Fe17Sm2–H2

M. Zinkevich, N. Mattern, A. Handstein, O. Gutfleisch

Journal of Alloys and Compounds 339 (1-2) 118-139 (2002) · Elsevier BV

DOI: 10.1016/s0925-8388(01)01990-9

Data: JSON record · id doi:10.1016/s0925-8388(01)01990-9 · metadata: crossref

Roles in ORCHID

• read by ORCHID (values extracted): 30 released values
• assessment behind a TDB file: FeH-02Zin.tdb (Fe–H), FeSm-02Zin.tdb (Fe–Sm), SmH-02Zin.tdb (H–Sm)

Systems

Fe–H, Fe–Sm, H–Sm, Fe–H–Sm

Evidence in ORCHID

30 values read from this paper (28 accepted), from 3 tables and 1 text passages.

ESPEI datasets derived: 6 (derived/invariant-brackets/FE-SM/FeSm-02Zin.zpf-00.json …).

Phase-registry phases citing it: phase:fe-h:bcc-a2, phase:fe-h:fcc-a1, phase:fe-h:gas, phase:fe-h:h2gas, phase:fe-h:hcp-a3, phase:fe-h:liquid, phase:fe-sm:bcc-a2, phase:fe-sm:fcc-a1, phase:fe-sm:fe17sm2, phase:fe-sm:fe2sm-c15, phase:fe-sm:fe3sm, phase:fe-sm:hcp-a3, phase:fe-sm:liquid, phase:fe-sm:rhomb-c19, phase:h-sm:bcc-a2, phase:h-sm:fcc-a1, phase:h-sm:gas, phase:h-sm:h2gas, phase:h-sm:hcp-a3, phase:h-sm:liquid …

Availability

Read by ORCHID: yes (values_extracted). Open-access licence (Crossref license field): none deposited. Crossref is-referenced-by count: 61 (retrieved 2026-10-23).

Relations

Cited by (Crossref reference lists) (21)

• Determination of Hydrogen Solubility in Fe–Mn–C Melts (2011) [crossref_reference_list]
• H-Sm (hydrogen-samarium) (2004) [crossref_reference_list]
• Thermodynamic Assessment of the Mn-H and Mg-Mn-H Systems (2018) [crossref_reference_list]
• Advances in CALPHAD Methodology for Modeling Hydrides: A Comprehensive Review (2024) [crossref_reference_list]
• CALPHAD Modeling of Metal–Hydrogen Systems: A Review (2012) [crossref_reference_list]
• Thermodynamic and ab initio investigation of the Al–H–Mg system (2007) [crossref_reference_list]
• Thermodynamic assessment of the H–La–Ni system (2009) [crossref_reference_list]
• Thermodynamic re-assessment of the Fe-Gd and Fe-Sm binary systems (2017) [crossref_reference_list]
• Experimental study and thermodynamic calculation of the Sm-Co-Fe system (2022) [crossref_reference_list]
• Thermodynamic assessment of the Ce H and CeNi5 H system (2024) [crossref_reference_list]
• Experimental determination and thermodynamic calculation of phase equilibria in the Sm-Fe-B ternary system (2024) [crossref_reference_list]
• The SGTE collection of binary datasets (2025) [crossref_reference_list]
• Thermodynamic assessment of the quaternary Cr–Fe–H–Zr system (2025) [crossref_reference_list]
• Thermodynamic modeling of Cr and Cr–H systems up to high temperatures and high pressures (2022) [crossref_reference_list]
• Study on the thermodynamics of the gadolinium-hydrogen binary system (H/Gd = 0.0–2.0) and implications to metallic gadolinium purification (2016) [crossref_reference_list]
• Experimental study and thermodynamic assessment of the dysprosium-hydrogen binary system (2017) [crossref_reference_list]
• Experimental investigation and thermodynamic assessment of the yttrium-hydrogen binary system (2018) [crossref_reference_list]
• Assessment of phase equilibria and thermodynamic properties in the Fe-RE (RE = rare earth metals) binary systems (2023) [crossref_reference_list]
• Fe-Mo-Sm Ternary Phase Diagram Evaluation (2026) [crossref_reference_list]
• Fe-H-Mn Ternary Phase Diagram Evaluation (2007) [crossref_reference_list]
• Al-Fe-Sm Ternary Phase Diagram Evaluation (2004) [crossref_reference_list]

References (Crossref, publisher-deposited) (12)

• The samarium-iron system (1971) [crossref_reference_list]
• Phase transformations in some rare earth-hydrogen systems (1974) [crossref_reference_list]
• Systematic study of the h.c.p. ⇌ f.c.c. transitions in the heavier LnH2-LnH3 systems (1976) [crossref_reference_list]
• Structural and magnetic properties of SmFeN magnets prepared by hydrogenation and nitrogenation processes (1995) [crossref_reference_list]
• SGTE data for pure elements (1991) [crossref_reference_list]
• Effects of additional elements on hydrogen absorption and desorption characteristics of Sm2Fe17 compounds (1995) [crossref_reference_list]
• Effect of interstitial hydrogen and nitrogen on magnetic and structural properties of R2T17 (R ≡ Y, Ce and Sm; T ≡ Fe, Co and Ni) (1995) [crossref_reference_list]
• Critical assessment and thermodynamic modeling of the Mg–H system (1999) [crossref_reference_list]
• A thermodynamic assessment of the Co–Sm system (1998) [crossref_reference_list]
• Thermodynamics of the Ni–H system (1999) [crossref_reference_list]
• CRYSTAL STRUCTURES OF SOME LANTHANIDE HYDRIDES¹ (1962) [crossref_reference_list]
• The structure of HoD3 (1964) [crossref_reference_list]

Cites (values carry this citation) (5)

• The samarium-iron system (1971) — 4 values [orchid_extraction]
• Phase transformations in some rare earth-hydrogen systems (1974) — 1 values [orchid_extraction]
• Systematic study of the h.c.p. ⇌ f.c.c. transitions in the heavier LnH2-LnH3 systems (1976) — 1 values [orchid_extraction]
• Structural and magnetic properties of SmFeN magnets prepared by hydrogenation and nitrogenation processes (1995) — 1 values [orchid_extraction]
• Effects of additional elements on hydrogen absorption and desorption characteristics of Sm2Fe17 compounds (1995) — 1 values [orchid_extraction]

TDB files modelling its system (5)

• tdb:FeH-02Zin.tdb [sgte_tdb_header]
• tdb:FeSm-02Zin.tdb [sgte_tdb_header]
• tdb:FeSm-02Zin.tdb [orchid_literature_model_link]
• tdb:SmH-02Zin.tdb [orchid_literature_model_link]
• tdb:SmH-02Zin.tdb [sgte_tdb_header]

Reassessed by (1)

• Thermodynamic re-assessment of the Fe-Gd and Fe-Sm binary systems (2017) [citation+same-system]

Data papers used (5)

• The samarium-iron system (1971) — 4 values [orchid_extraction]
• Phase transformations in some rare earth-hydrogen systems (1974) — 1 values [orchid_extraction]
• Systematic study of the h.c.p. ⇌ f.c.c. transitions in the heavier LnH2-LnH3 systems (1976) — 1 values [orchid_extraction]
• Structural and magnetic properties of SmFeN magnets prepared by hydrogenation and nitrogenation processes (1995) — 1 values [orchid_extraction]
• Effects of additional elements on hydrogen absorption and desorption characteristics of Sm2Fe17 compounds (1995) — 1 values [orchid_extraction]