Phosphorus in Al–Si cast alloys: Thermodynamic prediction of the AlP and eutectic (Si) solidification sequence validated by microstructure and nucleation undercooling data

Song-Mao Liang, Rainer Schmid-Fetzer

Acta Materialia 72 41-56 (2014) · Elsevier BV

DOI: 10.1016/j.actamat.2014.02.042

Data: JSON record · id doi:10.1016/j.actamat.2014.02.042 · metadata: crossref

Roles in ORCHID

• read by ORCHID (values extracted): 28 released values
• assessment behind a TDB file: AlSi-14Lia.tdb (Al–Si)

Systems

Al–Si, Al–P–Si, Al–Mg–P–Si

Evidence in ORCHID

28 values read from this paper (16 accepted), from 1 tables and 14 text passages.

Phase-registry phases citing it: phase:al-si:a4-diamond, phase:al-si:bcc-a2, phase:al-si:fcc-a1, phase:al-si:hcp-a3, phase:al-si:liquid

Availability

Read by ORCHID: yes (values_extracted). Open-access licence (Crossref license field): none deposited. Crossref is-referenced-by count: 93 (retrieved 2026-10-23).

Relations

Cited by (Crossref reference lists) (6)

• Phase equilibria and solidification characteristics of the Al–Sc–Si alloys (2015) [crossref_reference_list]
• Analysis of microstructure formation in cast Zn alloys derived from computational thermodynamics of the Zn–Al–Cu–Mg system (2019) [crossref_reference_list]
• Inherently consistent temperature function for interaction parameters demonstrated for the Mg–Si assessment (2016) [crossref_reference_list]
• The SGTE collection of binary datasets (2025) [crossref_reference_list]
• Thermodynamics of Li-Si and Li-Si-H phase diagrams applied to hydrogen absorption and Li-ion batteries (2017) [crossref_reference_list]
• Thermodynamic description of the quaternary Al-Si-Mg-Sc system and its application to the design of novel Sc-additional A356 alloys (2017) [crossref_reference_list]

References (Crossref, publisher-deposited) (13)

• Influence of Phosphorus on the Nucleation of Eutectic Silicon in Al-Si Alloys (2013) [crossref_reference_list]
• Modeling of Thermodynamic Properties and Phase Equilibria of the Si-P System (2013) [crossref_reference_list]
• Preparation and properties of aluminum phosphide (1963) [crossref_reference_list]
• SGTE data for pure elements (1991) [crossref_reference_list]
• Thermodynamic optimization of the Mg-Al-Si phase diagram (1992) [crossref_reference_list]
• Eutectic nucleation in Al–Si alloys (2004) [crossref_reference_list]
• PANDAT software with PanEngine, PanOptimizer and PanPrecipitation for multi-component phase diagram calculation and materials property simulation (2009) [crossref_reference_list]
• Thermodynamic assessment of the Al–P system based on original experimental data (2013) [crossref_reference_list]
• Thermodynamic calculation of the ternary system Al-Si-C (1996) [crossref_reference_list]
• Investigation of the Al-Mg-Si system by experiments and thermodynamic calculations (1997) [crossref_reference_list]
• Algebraic Representation of Thermodynamic Properties and the Classification of Solutions (1948) [crossref_reference_list]
• Effect of phosphorus on modification of eutectic silicon in Al–7Si–0·3Mg alloy (2000) [crossref_reference_list]
• Thermodynamic description of the Al–Fe–Mg–Mn–Si system and investigation of microstructure and microsegregation during directional solidification of an Al–Fe–Mg–Mn–Si alloy (2005) [crossref_reference_list]

Cites (values carry this citation) (3)

• Influence of Phosphorus on the Nucleation of Eutectic Silicon in Al-Si Alloys (2013) — 6 values [orchid_extraction]
• Eutectic nucleation in Al–Si alloys (2004) — 2 values [orchid_extraction]
• Effect of phosphorus on modification of eutectic silicon in Al–7Si–0·3Mg alloy (2000) — 2 values [orchid_extraction]

TDB files modelling its system (1)

• tdb:AlSi-14Lia.tdb [sgte_tdb_header]

Reassesses (cites an earlier assessment of the same system) (1)

• Investigation of the Al-Mg-Si system by experiments and thermodynamic calculations (1997) [citation+same-system]

Data papers used (3)

• Influence of Phosphorus on the Nucleation of Eutectic Silicon in Al-Si Alloys (2013) — 6 values [orchid_extraction]
• Eutectic nucleation in Al–Si alloys (2004) — 2 values [orchid_extraction]
• Effect of phosphorus on modification of eutectic silicon in Al–7Si–0·3Mg alloy (2000) — 2 values [orchid_extraction]