Equilibrium between MB2 (M=Ti,Zr,Hf) UHTC and Ni: A thermodynamic database for the B–Hf–Ni–Ti–Zr system

G. Cacciamani, P. Riani, F. Valenza

Calphad 35 (4) 601-619 (2011) · Elsevier BV

DOI: 10.1016/j.calphad.2011.10.003

Data: JSON record · id doi:10.1016/j.calphad.2011.10.003 · metadata: crossref

Roles in ORCHID

• read by ORCHID (values extracted): 146 released values
• assessment behind a TDB file: HfB-11Cac.tdb (B–Hf), HfNi-11Cac.tdb (Hf–Ni), NiZr-11Cac.tdb (Ni–Zr), TiB-11Cac.tdb (B–Ti), ZrB-11Cac.tdb (B–Zr)
• discovery lead (found by Crossref assessment discovery, not read): rank 385, score 111; systems named in title: B–Hf–Ni–Ti–Zr

Systems

B–Hf, B–Ni, B–Ti, B–Zr, Hf–Ni, Hf–Ti, Hf–Zr, Ni–Ti, Ni–Zr, Ti–Zr, B–Hf–Ni, B–Ni–Ti, B–Ni–Zr, Hf–Ni–Ti, Hf–Ni–Zr, Hf–Ti–Zr, Ni–Ti–Zr, B–Hf–Ni–Ti–Zr

Evidence in ORCHID

146 values read from this paper (136 accepted), from 15 tables and 7 text passages.

Phase-registry phases citing it: phase:b-hf:b-beta-rhombo, phase:b-hf:b27-mb, phase:b-hf:bcc-a2, phase:b-hf:c32-mb2, phase:b-hf:fcc-a1, phase:b-hf:hcp-a3, phase:b-hf:liquid, phase:b-ni:liquid, phase:b-ti:b-beta-rhombo, phase:b-ti:b27-mb, phase:b-ti:bcc-a2, phase:b-ti:fcc-a1, phase:b-ti:hcp-a3, phase:b-ti:liquid, phase:b-ti:ti3b4-d7b, phase:b-ti:tib2-c32, phase:b-zr:b-beta-rhombo, phase:b-zr:bcc-a2, phase:b-zr:c32-mb2, phase:b-zr:fcc-a1 …

Availability

Read by ORCHID: yes (values_extracted). Open-access licence (Crossref license field): none deposited. Crossref is-referenced-by count: 64 (retrieved 2026-10-23).

Relations

Cited by (Crossref reference lists) (16)

• Phase Equilibria in the Hf2Ni7–Ni–TiNi3 Region of the Hf–Ni–Ti System (2025) [crossref_reference_list]
• Thermodynamic Modeling of the B-Ti-Zr System Over the Whole Composition and Temperature Ranges (2019) [crossref_reference_list]
• Thermodynamic Assessment of the Ternary B-Hf-Zr System with Refined B-Hf Description (2021) [crossref_reference_list]
• Phase Equilibria in the Ti-Zr-Ni System Part 2: Isothermal Sections and Solid-State Transformations in the ZrNi–Ni–TiNi Subsystem (2026) [crossref_reference_list]
• Phase Equilibria in the Ni-Ti-Zr System Part 3: Thermodynamic Description by the CALPHAD Approach (2026) [crossref_reference_list]
• [P88] Calphad-assisted joining of Ultra-High-Temperature Ceramics (UHTCs) (2015) [crossref_reference_list]
• Investigation of the phase equilibria in Ti-Ni-Hf system using diffusion triples and equilibrated alloys (2017) [crossref_reference_list]
• Experimental study and thermodynamic modeling of the Ti–Cu–B system (2022) [crossref_reference_list]
• Thermodynamic assessment of the ternary Ni–Ti-Hf system (2023) [crossref_reference_list]
• Thermodynamic modeling of the Ni–Ti–Hf system (2023) [crossref_reference_list]
• The SGTE collection of binary datasets (2025) [crossref_reference_list]
• Phase diagram and enthalpy of formation of Hf-Ni-Sn (2016) [crossref_reference_list]
• Experimental investigations and thermodynamic modeling in the ZrB2Ni section of the B Ni Zr system (2014) [crossref_reference_list]
• On the constitution and thermodynamic modelling of the system Zr-Ni-Sn (2018) [crossref_reference_list]
• Hf-Ti-Zr Ternary Phase Diagram Evaluation (2017) [crossref_reference_list]
• Mo-Ti-Zr Ternary Phase Diagram Evaluation (2023) [crossref_reference_list]

References (Crossref, publisher-deposited) (23)

• Critical assessment and thermodynamic calculation of the ternary system boron-hafnium-titanium (B-Hf-Ti) (1997) [crossref_reference_list]
• B-Zr (boron-zirconium) (1993) [crossref_reference_list]
• The Hf−Zr (Hafnium−Zirconium) system (1982) [crossref_reference_list]
• Thermodynamic assessment of the Cu-Ti-Zr system. II. Cu-Zr and Ti-Zr systems (2008) [crossref_reference_list]
• The HfNi and ZrNi systems in the region 65 – 80 at.% Ni (1979) [crossref_reference_list]
• Constitution of the Hf-Ni system up to 50 at.% Ni (1993) [crossref_reference_list]
• Thermodynamic assessment of the TiZr system and calculation of the NbTiZr phase diagram (1994) [crossref_reference_list]
• Thermodynamic modeling and optimization of the Fe–Ni–Ti system (2009) [crossref_reference_list]
• Wettability of HfB2 by molten Ni(B) alloys interpreted by CALPHAD methods, Part 1: Definition of the B–Hf–Ni system (2010) [crossref_reference_list]
• Wettability of by molten Ni(B) alloys interpreted by CALPHAD methods, Part 2: Wetting and interfacial reactivity (2010) [crossref_reference_list]
• Thermodynamic assessment of the Ti–B system (2004) [crossref_reference_list]
• The Al–B–Nb–Ti system (2008) [crossref_reference_list]
• Thermodynamic assessment of B–Zr and Si–Zr binary systems (2009) [crossref_reference_list]
• Standard enthalpies of formation of some alloys formed between group IV elements and group VIII elements, determined by high-temperature direct synthesis calorimetry (1998) [crossref_reference_list]
• New modelling of the B2 phase and its associated martensitic transformation in the Ti–Ni system (1999) [crossref_reference_list]
• Thermodynamic assessment of Ni–B phase diagram (1993) [crossref_reference_list]
• Critical assessment and thermodynamic calculation of the ternary system C-Hf-Zr (Carbon-Zirconium-Hafnium) (2002) [crossref_reference_list]
• A thermodynamic assessment of the Ni-Al-B system (1999) [crossref_reference_list]
• Thermodynamics and kinetics of stable and metastable phases in the Ni–Zr system (1994) [crossref_reference_list]
• Thermodynamic Analysis of the Phase Equilibria in the Nb-Ni-Zr System (2006) [crossref_reference_list]
• Thermodynamic Analysis of the Ni-Si-Ti System Using Thermochemical Properties Determined from Ab Initio Calculations (2004) [crossref_reference_list]
• Thermodynamic Calculation of Phase Equilibria in the Nb-Ni-Ti-Zr Quaternary System (2007) [crossref_reference_list]
• Thermodynamic Analysis of the Phase Equilibria in the Fe-Zr-B System (2008) [crossref_reference_list]

Cites (values carry this citation) (1)

• Constitution of the Hf-Ni system up to 50 at.% Ni (1993) — 1 values [orchid_extraction]

TDB files modelling its system (10)

• tdb:HfB-11Cac.tdb [orchid_literature_model_link]
• tdb:HfB-11Cac.tdb [sgte_tdb_header]
• tdb:HfNi-11Cac.tdb [sgte_tdb_header]
• tdb:HfNi-11Cac.tdb [orchid_literature_model_link]
• tdb:NiZr-11Cac.tdb [orchid_literature_model_link]
• tdb:NiZr-11Cac.tdb [sgte_tdb_header]
• tdb:TiB-11Cac.tdb [orchid_literature_model_link]
• tdb:TiB-11Cac.tdb [sgte_tdb_header]
• tdb:ZrB-11Cac.tdb [sgte_tdb_header]
• tdb:ZrB-11Cac.tdb [orchid_literature_model_link]

Reassessed by (2)

• Thermodynamic Modeling of the B-Ti-Zr System Over the Whole Composition and Temperature Ranges (2019) [citation+same-system]
• Thermodynamic Assessment of the Ternary B-Hf-Zr System with Refined B-Hf Description (2021) [citation+same-system]

Reassesses (cites an earlier assessment of the same system) (7)

• Critical assessment and thermodynamic calculation of the ternary system boron-hafnium-titanium (B-Hf-Ti) (1997) [citation+same-system]
• Wettability of HfB2 by molten Ni(B) alloys interpreted by CALPHAD methods, Part 1: Definition of the B–Hf–Ni system (2010) [citation+same-system]
• Thermodynamic assessment of the Ti–B system (2004) [citation+same-system]
• The Al–B–Nb–Ti system (2008) [citation+same-system]
• Thermodynamic assessment of B–Zr and Si–Zr binary systems (2009) [citation+same-system]
• Thermodynamics and kinetics of stable and metastable phases in the Ni–Zr system (1994) [citation+same-system]
• Thermodynamic Analysis of the Phase Equilibria in the Fe-Zr-B System (2008) [citation+same-system]

Data papers used (1)

• Constitution of the Hf-Ni system up to 50 at.% Ni (1993) — 1 values [orchid_extraction]