Low-temperature molar heat capacities and entropies of MnO2 (pyrolusite), Mn3O4 (hausmanite), and Mn2O3 (bixbyite)
Richard A. Robie, Bruce S. Hemingway
The Journal of Chemical Thermodynamics 17 (2) 165-181 (1985) · Elsevier BV
DOI: 10.1016/0021-9614(85)90069-2
Data: JSON record · id doi:10.1016/0021-9614(85)90069-2 · metadata: crossref
Roles in ORCHID
- cited as the original source of values
Systems
Evidence in ORCHID
8 values in 2 other papers cite this work as their source.
| model | 6 |
| experimental | 2 |
Phase-registry phases citing it: phase:mn-o:mn2o3-d53, phase:mn-o:mno2-c4
Availability
Read by ORCHID: no (full_text_screened_for_origin). Open-access licence (Crossref license field): none deposited. Crossref is-referenced-by count: 58 (retrieved 2026-10-23).
Relations
Cited by (Crossref reference lists) (6)
- Molar heat capacity and thermodynamic functions of the type II antiferromagnet MnO (1999) [crossref_reference_list]
- Thermodynamic data from redox reactions at high temperatures. II. The MnO-0Mn3O4 oxygen buffer, and implications for the thermodynamic properties of MnO and Mn3O4 (1993) [crossref_reference_list]
- Phase relations and gibbs energies in the system Mn-Rh-O (1994) [crossref_reference_list]
- Assessment of the Mn-O system (2003) [crossref_reference_list]
- Thermodynamic Assessment of the Fe-Mn-O System (2010) [crossref_reference_list]
- Heat capacity and thermodynamic behaviour of Mn3O4 and ZnMn2O4 at low temperatures (1986) [crossref_reference_list]
References (Crossref, publisher-deposited) (13)
- Equilibria and hysteresis in the system Mn<sub>2</sub>O<sub>3</sub>Mn<sub>3</sub>O<sub>4</sub>O<sub>2</sub> (1967) [crossref_reference_list]
- Thermodynamic study of the manganese/ manganous-oxide system by the use of solid oxide electrolytes (1967) [crossref_reference_list]
- Specific Heats at Low Temperatures of Manganese Carbide and Manganese Dioxide<sup>1</sup> (1943) [crossref_reference_list]
- Heats of Formation of Manganomanganic Oxide and Manganese Dioxide<sup>1</sup> (1943) [crossref_reference_list]
- High-temperature Heat Content of Mn<sub>3</sub>O<sub>4</sub>, MnSiO<sub>3</sub> and Mn<sub>3</sub>C<sup>1</sup> (1942) [crossref_reference_list]
- Low-temperature Heat Capacities and Entropies at 298.16°K. of Manganese Sesquioxide and Niobium Pentoxide (1954) [crossref_reference_list]
- Magnetic and Crystallographic Transitions in<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msup><mml:mrow><mml:mi mathvariant="normal">Sc</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn><mml:mo>+</mml:mo></mml:mrow></mml:msup></mml:mrow></mml:math>,<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msup><mml:mrow><mml:mi mathvariant="normal">Cr</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn><mml:mo>+</mml:mo></mml:mrow></mml:msup></mml:mrow></mml:math>, and<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msup><mml:mrow><mml:mi mathvariant="normal">Ga</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn><mml:mo>+</mml:mo></mml:mrow></mml:msup></mml:mrow></mml:math>Substituted<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">Mn</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math><mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">O</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math> (1970) [crossref_reference_list]
- Solid‐Solid and Solid‐Vapor Reactions and a New Phase in the System Mn‐O (1960) [crossref_reference_list]
- Thermodynamic Properties of the Oxides of Fe, Ni, Pb, Cu, and Mn, by EMF Measurements (1968) [crossref_reference_list]
- Equilibrium Pressures of Oxygen over MnO[sub 2]-Mn[sub 2]O[sub 3] at Various Temperatures (1965) [crossref_reference_list]
- Thermodynamics of the Mn-S-O System Between 1000° K and 1250° K (1966) [crossref_reference_list]
- Use of Thermal Conductivity Gas Analysis for Thermodynamic Measurements on the Dissociation of CuO, Mn<sub>2</sub>O<sub>3</sub>and MnO<sub>2</sub> (1967) [crossref_reference_list]
- Studies in the system Mn-O--The Mn 2 O 3 -Mn 3 O 4 and Mn 3 O 4 -MnO equilibria (1960) [crossref_reference_list]
Cited for values by (2)
- Assessment of the Mn-O system (2003) — 7 values [orchid_extraction]
- Thermodynamic Assessment of the Fe-Mn-O System (2010) — 1 values [orchid_extraction]
Used in (assessments / papers that took values from it) (2)
- Assessment of the Mn-O system (2003) — 7 values [orchid_extraction]
- Thermodynamic Assessment of the Fe-Mn-O System (2010) — 1 values [orchid_extraction]