Thermodynamic assessment and experimental investigation of the Li–Sn system

D. Li, S. Fürtauer, H. Flandorfer, D.M. Cupid

Calphad 47 181-195 (2014) · Elsevier BV

DOI: 10.1016/j.calphad.2014.09.002

Data: JSON record · id doi:10.1016/j.calphad.2014.09.002 · metadata: crossref

Roles in ORCHID

• read by ORCHID (values extracted): 148 released values
• assessment behind a TDB file: LiSn-14Li.tdb (Li–Sn)

Systems

Li, Sn, Li–Sn

Evidence in ORCHID

148 values read from this paper (117 accepted), from 5 tables and 19 text passages.

ESPEI datasets derived: 5 (derived/invariant-brackets/LI-SN/LiSn-14Li.zpf-00.json …).

Phase-registry phases citing it: phase:li-sn:a4-diamond, phase:li-sn:a5-bct, phase:li-sn:bcc-a2, phase:li-sn:fcc-a1, phase:li-sn:hcp-a3, phase:li-sn:li13sn5, phase:li-sn:li17sn4, phase:li-sn:li2sn5, phase:li-sn:li5sn2, phase:li-sn:li7sn2, phase:li-sn:li7sn3, phase:li-sn:liquid, phase:li-sn:lisn

Availability

Read by ORCHID: yes (values_extracted). Open-access licence (Crossref license field): none deposited. Crossref is-referenced-by count: 54 (retrieved 2026-10-23).

Relations

Cited by (Crossref reference lists) (15)

• Enthalpy of Mixing of Ternary Li-Pb-Sb Alloys (2018) [crossref_reference_list]
• Thermodynamic assessment of the Cu–Li system and prediction of enthalpy of mixing of Cu–Li–Sn liquid alloys (2016) [crossref_reference_list]
• The SGTE collection of binary datasets (2025) [crossref_reference_list]
• Thermodynamic assessment of the Ga-Li-Sn system and its binary subsystems (2026) [crossref_reference_list]
• Enthalpy of formation of Li2Sb and Li3Sb and mixing enthalpy of liquid Li–Sb alloys (2016) [crossref_reference_list]
• The Cu-Li-Sn phase diagram: Isothermal sections (2016) [crossref_reference_list]
• Experimental thermodynamic study of the Cu-Li-Sn system by Knudsen Effusion Mass Spectrometry (2016) [crossref_reference_list]
• The Li-Sb phase diagram part II: Calorimetry and thermodynamic assessment (2017) [crossref_reference_list]
• Sb–Sn alloy anodes for Li-ion batteries: The ternary system Li–Sb–Sn (2021) [crossref_reference_list]
• Enthalpy of mixing of liquid Li-Sb-Sn alloys (2020) [crossref_reference_list]
• Calorimetric study of the enthalpy of mixing in the liquid systems In-Li and In-Li-Sn (2025) [crossref_reference_list]
• Phase formation in the ternary systems Li-Sn-C and Li-Sn-Si (2018) [crossref_reference_list]
• The Cu-Li-Sn Phase Diagram: Isopleths, Liquidus Projection and Reaction Scheme (2016) [crossref_reference_list]
• Phase formation in alloy-type anode materials in the quaternary system Li–Sn–Si–C (2017) [crossref_reference_list]
• Phase diagram, thermodynamic investigations, and modelling of systems relevant to lithium-ion batteries (2017) [crossref_reference_list]

References (Crossref, publisher-deposited) (16)

• Metallographische Mitteilungen aus dem Institut für physikalische Chemie der Universität Göttingen. LXXV. Über das Verhalten von Lithium zu Natrium, Kalium, Zinn, Cadmium und Magnesium (1910) [crossref_reference_list]
• The Li-Sn (Lithium-Tin) System (1998) [crossref_reference_list]
• Densities and lattice parameters of tin (indium) solid solutions (1964) [crossref_reference_list]
• Lithium-tin phase relationships between Li7Sn2 and LiSn (1979) [crossref_reference_list]
• The Thermo-Calc databank system (1985) [crossref_reference_list]
• Thermodynamic assessment of the Li–Sn (Lithium–Tin) system (2005) [crossref_reference_list]
• Calorimetric studies of Cu–Li, Li–Sn, and Cu–Li–Sn (2013) [crossref_reference_list]
• Interfaces in lead-free solder alloys: Enthalpy of formation of binary Ag–Sn, Cu–Sn and Ni–Sn intermetallic compounds (2007) [crossref_reference_list]
• Thermodynamic studies and the phase diagram of the Li-Sn system (1996) [crossref_reference_list]
• X-ray and Neutron Diffraction Studies on “Li_4.4Sn” (2003) [crossref_reference_list]
• Algebraic Representation of Thermodynamic Properties and the Classification of Solutions (1948) [crossref_reference_list]
• Neutron powder-diffraction studies of lithium, sodium, and potassium metal (1989) [crossref_reference_list]
• Crystal structure of Li₂Sn₅ (1969) [crossref_reference_list]
• Thermodynamic Study of the Lithium‐Tin System (1981) [crossref_reference_list]
• Darstellung und Struktur der Phase Li₇Sn₃ / Preparation und Crystal Structure of Li₇Sn₃ (1974) [crossref_reference_list]
• Die Kristallstruktur der Phase Li₇Sn₂ / The Crystal Structure of Li₇Sn₂ (1975) [crossref_reference_list]

Cites (values carry this citation) (10)

• The Li-Sn (Lithium-Tin) System (1998) — 18 values [orchid_extraction]
• Die Kristallstruktur der Phase Li₇Sn₂ / The Crystal Structure of Li₇Sn₂ (1975) — 10 values [orchid_extraction]
• Darstellung und Struktur der Phase Li₇Sn₃ / Preparation und Crystal Structure of Li₇Sn₃ (1974) — 4 values [orchid_extraction]
• Densities and lattice parameters of tin (indium) solid solutions (1964) — 3 values [orchid_extraction]
• Crystal structure of Li₂Sn₅ (1969) — 3 values [orchid_extraction]
• Lithium-tin phase relationships between Li7Sn2 and LiSn (1979) — 2 values [orchid_extraction]
• Thermodynamic studies and the phase diagram of the Li-Sn system (1996) — 2 values [orchid_extraction]
• X-ray and Neutron Diffraction Studies on “Li_4.4Sn” (2003) — 2 values [orchid_extraction]
• Neutron powder-diffraction studies of lithium, sodium, and potassium metal (1989) — 2 values [orchid_extraction]
• Thermodynamic Study of the Lithium‐Tin System (1981) — 2 values [orchid_extraction]

TDB files modelling its system (2)

• tdb:LiSn-14Li.tdb [orchid_literature_model_link]
• tdb:LiSn-14Li.tdb [sgte_tdb_header]

Reassesses (cites an earlier assessment of the same system) (1)

• Thermodynamic assessment of the Li–Sn (Lithium–Tin) system (2005) [citation+same-system]

Data papers used (10)

• The Li-Sn (Lithium-Tin) System (1998) — 18 values [orchid_extraction]
• Die Kristallstruktur der Phase Li₇Sn₂ / The Crystal Structure of Li₇Sn₂ (1975) — 10 values [orchid_extraction]
• Darstellung und Struktur der Phase Li₇Sn₃ / Preparation und Crystal Structure of Li₇Sn₃ (1974) — 4 values [orchid_extraction]
• Densities and lattice parameters of tin (indium) solid solutions (1964) — 3 values [orchid_extraction]
• Crystal structure of Li₂Sn₅ (1969) — 3 values [orchid_extraction]
• Lithium-tin phase relationships between Li7Sn2 and LiSn (1979) — 2 values [orchid_extraction]
• Thermodynamic studies and the phase diagram of the Li-Sn system (1996) — 2 values [orchid_extraction]
• X-ray and Neutron Diffraction Studies on “Li_4.4Sn” (2003) — 2 values [orchid_extraction]
• Neutron powder-diffraction studies of lithium, sodium, and potassium metal (1989) — 2 values [orchid_extraction]
• Thermodynamic Study of the Lithium‐Tin System (1981) — 2 values [orchid_extraction]