Experimental study of ternary Ca–Mg–Si phase equilibria and thermodynamic assessment of Ca–Si and Ca–Mg–Si systems

Joachim Gröbner, Igor Chumak, Rainer Schmid-Fetzer

Intermetallics 11 (10) 1065-1074 (2003) · Elsevier BV

DOI: 10.1016/j.intermet.2003.07.001

Data: JSON record · id doi:10.1016/j.intermet.2003.07.001 · metadata: crossref

Roles in ORCHID

• read by ORCHID (values extracted): 183 released values
• assessment behind a TDB file: CaSi-03Gro.tdb (Ca–Si)
• discovery lead (found by Crossref assessment discovery, not read): rank 1845, score 60; systems named in title: Ca–Mg–Si

Systems

Ca–Si, Ca–Mg–Si

Evidence in ORCHID

183 values read from this paper (123 accepted), from 6 tables and 2 text passages.

ESPEI datasets derived: 22 (derived/invariant-brackets/CA-SI/CaSi-03Gro.zpf-00.json …).

Phase-registry phases citing it: phase:ca-si:a4-diamond, phase:ca-si:bcc-a2, phase:ca-si:ca14si19, phase:ca-si:ca2si-c37, phase:ca-si:ca3si4, phase:ca-si:ca5si3-d8l, phase:ca-si:casi-b33, phase:ca-si:casi2-c12, phase:ca-si:fcc-a1, phase:ca-si:hcp-a3, phase:ca-si:liquid

Availability

Read by ORCHID: yes (values_extracted). Open-access licence (Crossref license field): none deposited. Crossref is-referenced-by count: 71 (retrieved 2026-10-23).

Relations

Cited by (Crossref reference lists) (9)

• Study on Mg–Si–Sr Ternary Alloys for Biomedical Applications (2018) [crossref_reference_list]
• Ca-Si (Calcium-Silicon) (2007) [crossref_reference_list]
• Thermodynamic assessment of the Yb–Si system (2005) [crossref_reference_list]
• The SGTE collection of binary datasets (2025) [crossref_reference_list]
• Identification and description of intermetallic compounds in Mg–Si–Sr cast and heat-treated alloys (2016) [crossref_reference_list]
• First-principle studies of Ca–X (X=Si,Ge,Sn,Pb) intermetallic compounds (2010) [crossref_reference_list]
• Thermodynamics of Liquid Immiscibility in Iron-Silicate Melt Systems: A Study of Nuclear Fallout Glass (2023) [crossref_reference_list]
• Thermodynamic Database for Mg Alloys—Progress in Multicomponent Modeling (2012) [crossref_reference_list]
• Al-Ca-Si Ternary Phase Diagram Evaluation (2004) [crossref_reference_list]

References (Crossref, publisher-deposited) (5)

• Dampfdruck des Calciums über Calcium‐Silicium‐ und Calcium‐Aluminium‐Schmelzen sowie über Calcium‐Aluminium‐Silicium‐Legierungen (1975) [crossref_reference_list]
• Activities in the Ca-Si system (1971) [crossref_reference_list]
• SGTE data for pure elements (1991) [crossref_reference_list]
• Contribution to the experimental and thermodynamic assessment of the AlCaFeSi system—I. AlCaFe, AlCaSi, AlFeSi and CaFeSi systems (1994) [crossref_reference_list]
• The phase diagram of the Ca–Si system (2000) [crossref_reference_list]

Cites (values carry this citation) (4)

• The phase diagram of the Ca–Si system (2000) — 13 values [orchid_extraction]
• Dampfdruck des Calciums über Calcium‐Silicium‐ und Calcium‐Aluminium‐Schmelzen sowie über Calcium‐Aluminium‐Silicium‐Legierungen (1975) — 6 values [orchid_extraction]
• Contribution to the experimental and thermodynamic assessment of the AlCaFeSi system—I. AlCaFe, AlCaSi, AlFeSi and CaFeSi systems (1994) — 3 values [orchid_extraction]
• Activities in the Ca-Si system (1971) — 2 values [orchid_extraction]

TDB files modelling its system (2)

• tdb:CaSi-03Gro.tdb [orchid_literature_model_link]
• tdb:CaSi-03Gro.tdb [sgte_tdb_header]

Reassesses (cites an earlier assessment of the same system) (1)

• Contribution to the experimental and thermodynamic assessment of the AlCaFeSi system—I. AlCaFe, AlCaSi, AlFeSi and CaFeSi systems (1994) [citation+same-system]

Data papers used (4)

• The phase diagram of the Ca–Si system (2000) — 13 values [orchid_extraction]
• Dampfdruck des Calciums über Calcium‐Silicium‐ und Calcium‐Aluminium‐Schmelzen sowie über Calcium‐Aluminium‐Silicium‐Legierungen (1975) — 6 values [orchid_extraction]
• Contribution to the experimental and thermodynamic assessment of the AlCaFeSi system—I. AlCaFe, AlCaSi, AlFeSi and CaFeSi systems (1994) — 3 values [orchid_extraction]
• Activities in the Ca-Si system (1971) — 2 values [orchid_extraction]