Thermodynamic description of the Ge–Na and Ge–K systems using the CALPHAD approach supported by first-principles calculations

Yaru Wang, Peisheng Wang, Dongdong Zhao, Biao Hu, Yong Du, Honghui Xu, Keke Chang

Calphad 37 72-76 (2012) · Elsevier BV

DOI: 10.1016/j.calphad.2012.01.004

Data: JSON record · id doi:10.1016/j.calphad.2012.01.004 · metadata: crossref

Roles in ORCHID

• read by ORCHID (values extracted): 44 released values
• assessment behind a TDB file: GeK-12Wan.tdb (Ge–K), GeNa-12Wan.tdb (Ge–Na)

Systems

K, Na, Ge–K, Ge–Na, Ge–K–Na

Evidence in ORCHID

44 values read from this paper (39 accepted), from 2 tables and 2 text passages.

Phase-registry phases citing it: phase:ge-k:a4-diamond, phase:ge-k:bcc-a2, phase:ge-k:fcc-a1, phase:ge-k:ge4k, phase:ge-k:gek, phase:ge-k:gek3, phase:ge-k:hcp-a3, phase:ge-k:liquid, phase:ge-na:a4-diamond, phase:ge-na:bcc-a2, phase:ge-na:fcc-a1, phase:ge-na:ge4na, phase:ge-na:gena, phase:ge-na:gena3, phase:ge-na:hcp-a3, phase:ge-na:liquid

Availability

Read by ORCHID: yes (values_extracted). Open-access licence (Crossref license field): none deposited. Crossref is-referenced-by count: 13 (retrieved 2026-10-23).

Relations

Cited by (Crossref reference lists) (2)

• Thermodynamic assessment of the Cd–X (X=Sn, Mn, Fe) systems (2014) [crossref_reference_list]
• The SGTE collection of binary datasets (2025) [crossref_reference_list]

References (Crossref, publisher-deposited) (22)

• Das Verhalten der Alkalimetalle zu Halbmetallen. IX. Weitere Beiträge zur Kenntnis der Silicide und Germanide der Alkalimetalle (1961) [crossref_reference_list]
• Das Verhalten der Alkalimetalle zu Halbmetallen. X. Die Kristallstrukturen von KSi, RbSi, CsSi, KGe, RbGe und CsGe (1961) [crossref_reference_list]
• The Ge-K system (Germanium-Potassium) (1997) [crossref_reference_list]
• Crystal structures of the elements at 25°C (1981) [crossref_reference_list]
• A thermodynamic description of the Al-Mn-Si system over the entire composition and temperature ranges (2004) [crossref_reference_list]
• Sur une nouvelle famille de clathrates minéraux isotypes des hydrates de gaz et de liquides. Interprétation des résultats obtenus (1970) [crossref_reference_list]
• The Thermo-Calc databank system (1985) [crossref_reference_list]
• SGTE data for pure elements (1991) [crossref_reference_list]
• Thermodynamic properties of the Al–Fe–Ni system acquired via a hybrid approach combining calorimetry, first-principles and CALPHAD (2009) [crossref_reference_list]
• Experimental investigation and thermodynamic modeling of the Mg–Si–Zn system (2011) [crossref_reference_list]
• A thermodynamic description of the Al–Fe–Si system over the whole composition and temperature ranges via a hybrid approach of CALPHAD and key experiments (2008) [crossref_reference_list]
• Experimental investigation of the Al–Y phase diagram (2006) [crossref_reference_list]
• Structure and thermal conductivity of Na1−xGe3+z (2010) [crossref_reference_list]
• Algebraic Representation of Thermodynamic Properties and the Classification of Solutions (1948) [crossref_reference_list]
• Synthesis and crystal structure of Na _1−x Ge _3+z : a novel zeolite-like framework phase in the Na–Ge system (2007) [crossref_reference_list]
• Solubility of tin and germanium in liquid sodium: the sodium–tin partial phase diagram (1974) [crossref_reference_list]
• Special points for Brillouin-zone integrations (1976) [crossref_reference_list]
• Efficient iterative schemes for <i>ab initio</i> total-energy calculations using a plane-wave basis set (1996) [crossref_reference_list]
• Synthesis and transport properties of type II clathrates (2005) [crossref_reference_list]
• Notizen: Eine Käfigstruktur als gemeinsames Bauprinzip der Verbindungen K₈E₄₆ (E = Si, Ge, Sn) (1969) [crossref_reference_list]
• Thermodynamic modeling of the Al-K system (2009) [crossref_reference_list]
• Construction of the Al–Ni–Si phase diagram over the whole composition and temperature ranges: thermodynamic modeling supported by key experiments and first-principles calculations (2008) [crossref_reference_list]

Cites (values carry this citation) (8)

• Crystal structures of the elements at 25°C (1981) — 3 values [orchid_extraction]
• Sur une nouvelle famille de clathrates minéraux isotypes des hydrates de gaz et de liquides. Interprétation des résultats obtenus (1970) — 2 values [orchid_extraction]
• Structure and thermal conductivity of Na1−xGe3+z (2010) — 2 values [orchid_extraction]
• Synthesis and crystal structure of Na _1−x Ge _3+z : a novel zeolite-like framework phase in the Na–Ge system (2007) — 2 values [orchid_extraction]
• Synthesis and transport properties of type II clathrates (2005) — 2 values [orchid_extraction]
• Das Verhalten der Alkalimetalle zu Halbmetallen. IX. Weitere Beiträge zur Kenntnis der Silicide und Germanide der Alkalimetalle (1961) — 1 values [orchid_extraction]
• Das Verhalten der Alkalimetalle zu Halbmetallen. X. Die Kristallstrukturen von KSi, RbSi, CsSi, KGe, RbGe und CsGe (1961) — 1 values [orchid_extraction]
• Notizen: Eine Käfigstruktur als gemeinsames Bauprinzip der Verbindungen K₈E₄₆ (E = Si, Ge, Sn) (1969) — 1 values [orchid_extraction]

TDB files modelling its system (2)

• tdb:GeK-12Wan.tdb [sgte_tdb_header]
• tdb:GeNa-12Wan.tdb [sgte_tdb_header]

Data papers used (8)

• Crystal structures of the elements at 25°C (1981) — 3 values [orchid_extraction]
• Sur une nouvelle famille de clathrates minéraux isotypes des hydrates de gaz et de liquides. Interprétation des résultats obtenus (1970) — 2 values [orchid_extraction]
• Structure and thermal conductivity of Na1−xGe3+z (2010) — 2 values [orchid_extraction]
• Synthesis and crystal structure of Na _1−x Ge _3+z : a novel zeolite-like framework phase in the Na–Ge system (2007) — 2 values [orchid_extraction]
• Synthesis and transport properties of type II clathrates (2005) — 2 values [orchid_extraction]
• Das Verhalten der Alkalimetalle zu Halbmetallen. IX. Weitere Beiträge zur Kenntnis der Silicide und Germanide der Alkalimetalle (1961) — 1 values [orchid_extraction]
• Das Verhalten der Alkalimetalle zu Halbmetallen. X. Die Kristallstrukturen von KSi, RbSi, CsSi, KGe, RbGe und CsGe (1961) — 1 values [orchid_extraction]
• Notizen: Eine Käfigstruktur als gemeinsames Bauprinzip der Verbindungen K₈E₄₆ (E = Si, Ge, Sn) (1969) — 1 values [orchid_extraction]