Hf-Si binary phase diagram determination and thermodynamic modeling

J. -C. Zhao, B. P. Bewlay, M. R. Jackson, Q. Chen

Journal of Phase Equilibria 21 (1) 40-45 (2000) · Springer Science and Business Media LLC

DOI: 10.1361/105497100770340408

Data: JSON record · id doi:10.1361/105497100770340408 · metadata: crossref

Roles in ORCHID

• read by ORCHID (values extracted): 44 released values
• cited as the original source of values
• assessment behind a TDB file: HfSi-00Zha-LB.tdb (Hf–Si)
• original evaluation behind an assessed (handbook) diagram: Hf–Si

Systems

Hf–Si

Evidence in ORCHID

44 values read from this paper (43 accepted), from 3 tables and 3 text passages.

1 values in 1 other papers cite this work as their source.

ESPEI datasets derived: 8 (derived/invariant-brackets/HF-SI/HfSi-00Zha-LB.zpf-00.json …).

Phase-registry phases citing it: phase:hf-si:a4-diamond, phase:hf-si:bcc-a2, phase:hf-si:fcc-a1, phase:hf-si:hcp-a3, phase:hf-si:hf2si-c16, phase:hf-si:hf3si2-d5a, phase:hf-si:hf5si3-d88, phase:hf-si:hf5si4, phase:hf-si:hfsi-b27, phase:hf-si:hfsi2-c49, phase:hf-si:liquid

Assessed phase-assemblage records citing it: 19.

Availability

Read by ORCHID: yes (values_extracted, full_text_screened_for_origin). Open-access licence (Crossref license field): none deposited. Crossref is-referenced-by count: 49 (retrieved 2026-10-23).

Relations

Cited by (Crossref reference lists) (12)

• Bayesian uncertainty quantification and information fusion in CALPHAD-based thermodynamic modeling (2019) [crossref_reference_list]
• Thermodynamic modeling of the Hf–Si–O system (2006) [crossref_reference_list]
• The SGTE collection of binary datasets (2025) [crossref_reference_list]
• Thermodynamic assessment of the Nb–Si–Al system (2004) [crossref_reference_list]
• Solid-state phase equilibria in metal-rich Hf–Ti–Si system at 1350°C (2008) [crossref_reference_list]
• Thermodynamic modeling of the Cr–Hf–Si System (2009) [crossref_reference_list]
• Experimental investigation and thermodynamic modeling of Hf–Si–B system (2010) [crossref_reference_list]
• Phase equilibria and liquidus projection determination of the Hf–Si–V ternary system (2022) [crossref_reference_list]
• Discovering ablation-resistant multicomponent B-C-Si-Zr-Hf ceramics by integrating high-throughput thermodynamic calculations, multi-objective optimization and key experimental validation (2026) [crossref_reference_list]
• Determination of Nb–Hf–Si phase equilibria (2001) [crossref_reference_list]
• Thermodynamic modeling of the Nb–Hf–Si ternary system (2003) [crossref_reference_list]
• C-Hf-Si Ternary Phase Diagram Evaluation (2012) [crossref_reference_list]

References (Crossref, publisher-deposited) (11)

• Handbook of Refractory Compounds (1980) [crossref_reference_list]
• The Si-Zr (Silicon-Zirconium) system (1990) [crossref_reference_list]
• Compounds and pseudo-binary alloys with the CuAl2(C16)-type structure I. Preparation and X-ray results (1972) [crossref_reference_list]
• Standard enthalpies of formation of Me5Si3 (Me  Y, Lu, Zr) and of Hf3Si2 (1990) [crossref_reference_list]
• The Thermo-Calc databank system (1985) [crossref_reference_list]
• SGTE data for pure elements (1991) [crossref_reference_list]
• Thermodynamic assessment of the SiZr system (1994) [crossref_reference_list]
• Standard enthalpies of formation of some 5d transition metal silicides by high temperature direct synthesis calorimetry (1998) [crossref_reference_list]
• Thermodynamic modeling of the Nb–Si–Ti ternary system (1999) [crossref_reference_list]
• Algebraic Representation of Thermodynamic Properties and the Classification of Solutions (1948) [crossref_reference_list]
• The structures of ZrGe2, HfSi2 and HfGe2 (1957) [crossref_reference_list]

Cited for values by (1)

• Thermodynamic modeling of the Nb–Hf–Si ternary system (2003) — 1 values [orchid_extraction]

Cites (values carry this citation) (4)

• Handbook of Refractory Compounds (1980) — 3 values [orchid_extraction]
• Compounds and pseudo-binary alloys with the CuAl2(C16)-type structure I. Preparation and X-ray results (1972) — 2 values [orchid_extraction]
• Standard enthalpies of formation of Me5Si3 (Me  Y, Lu, Zr) and of Hf3Si2 (1990) — 1 values [orchid_extraction]
• Standard enthalpies of formation of some 5d transition metal silicides by high temperature direct synthesis calorimetry (1998) — 1 values [orchid_extraction]

Reproduced by handbook diagrams (1)

• handbook:okamoto-2010:HF-SI [okamoto_handbook_source_line]

TDB files modelling its system (2)

• tdb:HfSi-00Zha-LB.tdb [sgte_tdb_header]
• tdb:HfSi-00Zha-LB.tdb [orchid_literature_model_link]

Reassessed by (2)

• Bayesian uncertainty quantification and information fusion in CALPHAD-based thermodynamic modeling (2019) [citation+same-system]
• Thermodynamic modeling of the Nb–Hf–Si ternary system (2003) [citation+same-system]

Data papers used (4)

• Handbook of Refractory Compounds (1980) — 3 values [orchid_extraction]
• Compounds and pseudo-binary alloys with the CuAl2(C16)-type structure I. Preparation and X-ray results (1972) — 2 values [orchid_extraction]
• Standard enthalpies of formation of Me5Si3 (Me  Y, Lu, Zr) and of Hf3Si2 (1990) — 1 values [orchid_extraction]
• Standard enthalpies of formation of some 5d transition metal silicides by high temperature direct synthesis calorimetry (1998) — 1 values [orchid_extraction]

Used in (assessments / papers that took values from it) (1)

• Thermodynamic modeling of the Nb–Hf–Si ternary system (2003) — 1 values [orchid_extraction]