Thermodynamic Assessment of the Mo–Si System

Andreas Klaus Czerny (ORCID 0000-0003-3580-719X), Wenhao Ma, Clemens Simon Hausner, Peter Franke, Magnus Rohde, Hans Jürgen Seifert

Advanced Engineering Materials 26 (17) 2302085 (2024) · Wiley

DOI: 10.1002/adem.202302085

Data: JSON record · id doi:10.1002/adem.202302085 · metadata: crossref

Roles in ORCHID

• read by ORCHID (values extracted): 73 released values
• assessment behind a TDB file: MoSi-24Cze.tdb (Mo–Si)

Systems

Mo–Si

Evidence in ORCHID

73 values read from this paper (66 accepted), from 4 tables and 4 text passages.

ESPEI datasets derived: 20 (derived/invariant-brackets/MO-SI/MoSi-00Liu.zpf-00.json …).

Phase-registry phases citing it: phase:mo-si:a4-diamond, phase:mo-si:bcc-a2, phase:mo-si:fcc-a1, phase:mo-si:hcp-a3, phase:mo-si:liquid, phase:mo-si:mo3si-a15, phase:mo-si:mo5si3-d8m, phase:mo-si:mosi2-c11b

Availability

Read by ORCHID: yes (values_extracted). Open-access licence (Crossref license field): http://creativecommons.org/licenses/by-nc/4.0/ (vor). Crossref is-referenced-by count: 12 (retrieved 2026-10-23).

Relations

Cited by (Crossref reference lists) (3)

• The SGTE collection of binary datasets (2025) [crossref_reference_list]
• Liquidus projection of the Mo-Ni-Si ternary system (2027) [crossref_reference_list]
• Experimental investigation of phase equilibria in the Cr-Mo-Si ternary system at 1500 °C (2026) [crossref_reference_list]

References (Crossref, publisher-deposited) (17)

• The Mo-Si (Molybdenum-Silicon) system (1991) [crossref_reference_list]
• The heats of formation of some transition metal silicides (1955) [crossref_reference_list]
• The enthalpy of formation of solid borides, carbides, nitrides, silicides and phosphides of transition and noble metals (1981) [crossref_reference_list]
• Coupled phase diagrams and thermochemical data for transition metal binary systems-VI (1979) [crossref_reference_list]
• Correction terms to pair potential model values of the energy of formation for transition element-polyvalent element phases (1981) [crossref_reference_list]
• The Thermo-Calc databank system (1985) [crossref_reference_list]
• A thermodynamic evaluation of four Si-M (M = Mo, Ta, Ti, W) binary systems (1989) [crossref_reference_list]
• SGTE data for pure elements (1991) [crossref_reference_list]
• Cohesion in alloys — fundamentals of a semi-empirical model (1980) [crossref_reference_list]
• Thermodynamic assessment of the Nb–Si–Mo system (2010) [crossref_reference_list]
• A thermodynamic description of the Al–Mo–Si system (2012) [crossref_reference_list]
• Enthalpies of formation of TM–X compounds (X=Al, Ga, Si, Ge, Sn). Comparison of ab-initio values and experimental data (2016) [crossref_reference_list]
• Standard enthalpies of formation of some 4d transition metal silicides by high temperature direct synthesis calorimetry (1998) [crossref_reference_list]
• Thermodynamic reassessment of the Mo–Si and Al–Mo–Si systems (2000) [crossref_reference_list]
• Thermodynamic modeling of the Nb–Si system (2002) [crossref_reference_list]
• High‐Temperature Behavior of MoSi ₂ and Mo ₅ Si ₃ (1964) [crossref_reference_list]
• Thermodynamic Properties of the System Molybdenum–Silicon (1974) [crossref_reference_list]

TDB files modelling its system (2)

• tdb:MoSi-24Cze.tdb [orchid_literature_model_link]
• tdb:MoSi-24Cze.tdb [sgte_tdb_header]

Reassesses (cites an earlier assessment of the same system) (4)

• A thermodynamic evaluation of four Si-M (M = Mo, Ta, Ti, W) binary systems (1989) [citation+same-system]
• Thermodynamic assessment of the Nb–Si–Mo system (2010) [citation+same-system]
• A thermodynamic description of the Al–Mo–Si system (2012) [citation+same-system]
• Thermodynamic reassessment of the Mo–Si and Al–Mo–Si systems (2000) [citation+same-system]