Thermodynamic assessment and first principle calculations of the Na Sb Sn system

Liya Dreval (ORCID 0000-0002-8992-5303), Matthias Zschornak, Wolfram Münchgesang, Olga Fabrichnaya, David Rafaja, Miléna L. Martine, Lars Giebeler, Mykhailo Motylenko

Journal of Alloys and Compounds 695 1725-1742 (2017) · Elsevier BV

DOI: 10.1016/j.jallcom.2016.11.003

Data: JSON record · id doi:10.1016/j.jallcom.2016.11.003 · metadata: crossref

Roles in ORCHID

• read by ORCHID (values extracted): 110 released values
• assessment behind a TDB file: NaSb-17Dre.tdb (Na–Sb), NaSn-17Dre.tdb (Na–Sn)
• discovery lead (found by Crossref assessment discovery, not read): rank 1061, score 93; systems named in title: none

Systems

Na–Sb, Na–Sn, Sb–Sn, Na–Sb–Sn

Evidence in ORCHID

110 values read from this paper (95 accepted), from 5 tables and 13 text passages.

ESPEI datasets derived: 14 (derived/invariant-brackets/NA-SN/NaSn-17Dre.zpf-00.json …).

Phase-registry phases citing it: phase:na-sb:a7-rhombohedral, phase:na-sb:bcc-a2, phase:na-sb:fcc-a1, phase:na-sb:hcp-a3, phase:na-sb:liquid, phase:na-sb:na3sb-d018, phase:na-sb:nasb, phase:na-sn:a5-bct, phase:na-sn:bcc-a2, phase:na-sn:fcc-a1, phase:na-sn:hcp-a3, phase:na-sn:liquid, phase:na-sn:na15sn4-d86, phase:na-sn:na3sn, phase:na-sn:na4sn3, phase:na-sn:na5sn13, phase:na-sn:na7sn12, phase:na-sn:na9sn4, phase:na-sn:nasn-ht, phase:na-sn:nasn-lt …

Availability

Read by ORCHID: yes (values_extracted). Open-access licence (Crossref license field): none deposited. Crossref is-referenced-by count: 9 (retrieved 2026-10-23).

Relations

Cited by (Crossref reference lists) (3)

• Experimental investigation and thermodynamic modeling of the Mo–Co–B ternary system (2021) [crossref_reference_list]
• The SGTE collection of binary datasets (2025) [crossref_reference_list]
• Thermodynamic reassessment of the Sb-Sn and In-Sb-Sn systems (2019) [crossref_reference_list]

References (Crossref, publisher-deposited) (25)

• Über Bismutide und intermetallische Verbindungen (1911) [crossref_reference_list]
• XV. Über die Verbindungen von Natrium mit Zinn (1905) [crossref_reference_list]
• Metallographische Mitteilung aus dem Institut für anorganische Chemie der Universität Göttingen. XXXIV. Natrium‐Blei‐, Natrium‐Kadmium‐, Natrium‐Wismut‐ und Natrium‐Antimonlegierungen (1906) [crossref_reference_list]
• Zintl‐Phasen mit Schichtanionen: Darstellung und Kristallstrukturen der isotypen Verbindungen SrSn₂As₂ und Sr_0,87Ba_0,13Sn₂As₂ sowie eine Einkristallstrukturbestimmung von KSnSb (1991) [crossref_reference_list]
• K₃[SnSb₃], eine Zintl‐Phase mit [SnSb₃]³⁻‐Bändern (1997) [crossref_reference_list]
• Thermodynamic study of phase equilibria in the Pb-Sn-Sb system (1995) [crossref_reference_list]
• Phase Equilibria of the Sn-Sb Binary System (2008) [crossref_reference_list]
• Phase Equilibria in the Sn-Rich Corner of the Ni-Sb-Sn System (2013) [crossref_reference_list]
• Application of Na+-ion-conducting β-Al2O3 to thermodynamic studies of liquid sodium-based alloys: {xNa+(1−x)Cd}, {xNa+(1−x)In}, and {xNa+(1−x)Sn} (1985) [crossref_reference_list]
• The Thermo-Calc databank system (1985) [crossref_reference_list]
• SGTE data for pure elements (1991) [crossref_reference_list]
• A thermodynamic study on the AgSbSn system (1996) [crossref_reference_list]
• Constitution of the tin-antimony system (1990) [crossref_reference_list]
• Phase equilibria in the ternary Ni–Sb–Sn system: Experiments and calculations (2014) [crossref_reference_list]
• The 260°C phase equilibria of the Sn–Sb–Cu ternary system and interfacial reactions at the Sn–Sb/Cu joints (2007) [crossref_reference_list]
• Phase equilibria of the Sn–Sb–Ag ternary system and interfacial reactions at the Sn–Sb/Ag joints at 400°C and 150°C (2008) [crossref_reference_list]
• The 260°C phase equilibria of the Sn–Sb–Ag ternary system and interfacial reactions at the Sn–Sb/Ag joints (2008) [crossref_reference_list]
• Thermodynamic evaluation and optimization of the (Na + X) binary systems (X = Ag, Ca, In, Sn, Zn) using combined Calphad and first-principles methods of calculation (2013) [crossref_reference_list]
• Thermodynamic descriptions and phase diagrams for Sb–Na and Sb–K binary systems (2013) [crossref_reference_list]
• Solubility of metals in liquid sodium. I. Sodium-tin (1967) [crossref_reference_list]
• Solubility of tin and germanium in liquid sodium: the sodium–tin partial phase diagram (1974) [crossref_reference_list]
• CXXV.—The system sodium–tin (1928) [crossref_reference_list]
• From ultrasoft pseudopotentials to the projector augmented-wave method (1999) [crossref_reference_list]
• Generalized Gradient Approximation Made Simple (1996) [crossref_reference_list]
• Thermodynamic assessment of Sb–Sn system (1986) [crossref_reference_list]

Cites (values carry this citation) (11)

• CXXV.—The system sodium–tin (1928) — 10 values [orchid_extraction]
• XV. Über die Verbindungen von Natrium mit Zinn (1905) — 9 values [orchid_extraction]
• Thermodynamic evaluation and optimization of the (Na + X) binary systems (X = Ag, Ca, In, Sn, Zn) using combined Calphad and first-principles methods of calculation (2013) — 8 values [orchid_extraction]
• Über Bismutide und intermetallische Verbindungen (1911) — 6 values [orchid_extraction]
• Phase Equilibria of the Sn-Sb Binary System (2008) — 6 values [orchid_extraction]
• Zintl‐Phasen mit Schichtanionen: Darstellung und Kristallstrukturen der isotypen Verbindungen SrSn₂As₂ und Sr_0,87Ba_0,13Sn₂As₂ sowie eine Einkristallstrukturbestimmung von KSnSb (1991) — 2 values [orchid_extraction]
• K₃[SnSb₃], eine Zintl‐Phase mit [SnSb₃]³⁻‐Bändern (1997) — 2 values [orchid_extraction]
• Constitution of the tin-antimony system (1990) — 2 values [orchid_extraction]
• Application of Na+-ion-conducting β-Al2O3 to thermodynamic studies of liquid sodium-based alloys: {xNa+(1−x)Cd}, {xNa+(1−x)In}, and {xNa+(1−x)Sn} (1985) — 1 values [orchid_extraction]
• Solubility of metals in liquid sodium. I. Sodium-tin (1967) — 1 values [orchid_extraction]
• Solubility of tin and germanium in liquid sodium: the sodium–tin partial phase diagram (1974) — 1 values [orchid_extraction]

TDB files modelling its system (3)

• tdb:NaSb-17Dre.tdb [sgte_tdb_header]
• tdb:NaSn-17Dre.tdb [orchid_literature_model_link]
• tdb:NaSn-17Dre.tdb [sgte_tdb_header]

Reassesses (cites an earlier assessment of the same system) (1)

• Thermodynamic descriptions and phase diagrams for Sb–Na and Sb–K binary systems (2013) [citation+same-system]

Data papers used (11)

• CXXV.—The system sodium–tin (1928) — 10 values [orchid_extraction]
• XV. Über die Verbindungen von Natrium mit Zinn (1905) — 9 values [orchid_extraction]
• Thermodynamic evaluation and optimization of the (Na + X) binary systems (X = Ag, Ca, In, Sn, Zn) using combined Calphad and first-principles methods of calculation (2013) — 8 values [orchid_extraction]
• Über Bismutide und intermetallische Verbindungen (1911) — 6 values [orchid_extraction]
• Phase Equilibria of the Sn-Sb Binary System (2008) — 6 values [orchid_extraction]
• Zintl‐Phasen mit Schichtanionen: Darstellung und Kristallstrukturen der isotypen Verbindungen SrSn₂As₂ und Sr_0,87Ba_0,13Sn₂As₂ sowie eine Einkristallstrukturbestimmung von KSnSb (1991) — 2 values [orchid_extraction]
• K₃[SnSb₃], eine Zintl‐Phase mit [SnSb₃]³⁻‐Bändern (1997) — 2 values [orchid_extraction]
• Constitution of the tin-antimony system (1990) — 2 values [orchid_extraction]
• Application of Na+-ion-conducting β-Al2O3 to thermodynamic studies of liquid sodium-based alloys: {xNa+(1−x)Cd}, {xNa+(1−x)In}, and {xNa+(1−x)Sn} (1985) — 1 values [orchid_extraction]
• Solubility of metals in liquid sodium. I. Sodium-tin (1967) — 1 values [orchid_extraction]
• Solubility of tin and germanium in liquid sodium: the sodium–tin partial phase diagram (1974) — 1 values [orchid_extraction]