Ce3Sn: enthalpy of formation

5 accepted literature formation-enthalpy value(s) (experimental 1, model 2, DFT 2); experimental median -49.37 kJ/mol-atom (n = 1); Materials Project -39.857 kJ/mol-atom (mp-aaaabern); OQMD -45.291 kJ/mol-atom (oqmd-29193).

Systems: Ce–Sn

Literature values

Enthalpy of formation of Ce3Sn reported in the literature (5)
Value	Phase as printed	T (K)	Class	Method	System	Source	Location
-49.37 kJ/mol-atom ± 2.1	Ce3Sn	300	experimental	calorimetry	Ce–Sn	[1] Dong 2013 cites Borzone 1982 doi	Table 4, p. 4, row 18 report
-53.72 kJ/mol-atom	Ce3Sn	289	model		Ce–Sn	[1] Dong 2013	Table 4, p. 4, row 20 report
-53 kJ/mol-atom	Ce3Sn	300	model		Ce–Sn	[1] Dong 2013 cites Colinet 1984 doi	Table 4, p. 4, row 19 report
-49.526 kJ/mol-atom	Ce3Sn	0	DFT	first-principles calculation	Ce–Sn	[2] Li 2013	Table 1, p. 3, row 2 report
-43.82 kJ/mol-atom	Ce3Sn	0	DFT		Ce–Sn	[1] Dong 2013	Table 4, p. 4, row 17 report

Uncertainty budget

Components kept separate, in the value's unit (literature SCHEMA.md, UNCERTAINTY_CALIBRATION.md): effective = max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter). The method floor is the robust between-study scatter of the method class in ORCHID (calibrated) or a documented prior; printed values and printed uncertainties are unchanged.

Uncertainty budget of the literature values of Ce3Sn
Value	Unit	Printed	Reading	Method (class, basis)	Effective
-49.37	kJ/mol-atom	2.1	0.005	3.2 (solution_reaction_calorimetry, calibrated)	3.2
-53.72	kJ/mol-atom		0.005	3.9 (model_calculated, calibrated)	3.9
-53	kJ/mol-atom		0.5	3.9 (model_calculated, calibrated)	3.9
-49.526	kJ/mol-atom		5.000e-5	8.395 (dft, calibrated)	8.395
-43.82	kJ/mol-atom		0.005	8.395 (dft, calibrated)	8.395

DFT formation energies

Lowest-energy entries at this composition. Materials Project and OQMD use different energy references and are never averaged. 1 eV/atom = 96.485 kJ/mol-atom.

DFT formation energy of Ce3Sn
Source	Entry	kJ/mol-atom	eV/atom	Space group	E above hull (kJ/mol-atom)	E above hull (eV/atom)	Theoretical
Materials Project	mp-aaaabern	-39.857	-0.413094	Pm-3m	0	0	no
OQMD	oqmd-29193	-45.291	-0.469412	Pm-3m	0.2831	0.0029	no

DFT sources: A. Jain et al., Commentary: The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002. doi:10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501-1509; S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010. doi:10.1007/s11837-013-0755-4 (CC BY 4.0);

Sources

H.Q. Dong, X.M. Tao, T. Laurila, V. Vuorinen, M. Paulasto-Kröckel, Thermodynamic modeling of Au–Ce–Sn ternary system, Calphad 42, 38-50 (2013). doi:10.1016/j.calphad.2013.07.013
Juan Li, Xiaoma Tao, Sisi Dong, Feng Yang, Huashan Liu, Zhanpeng Jin et al., Thermodynamic assessment of Sn–Cu–Ce system, Calphad 43, 124-132 (2013). doi:10.1016/j.calphad.2013.04.003

Please cite

R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23735569
R. Arróyave, J. Saal, D. Shin, ORCHID-Parity: DFT-vs-experiment formation-enthalpy benchmark (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23735943
R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0); G. Kim, S. V. Meschel, P. Nash, W. Chen, Experimental formation enthalpies for intermetallic phases and other inorganic compounds, Scientific Data 4 (2017) 170162, https://doi.org/10.1038/sdata.2017.162; B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file. Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_dft_benchmark_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Parity: DFT-vs-experiment formation-enthalpy benchmark}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735943},
  url       = {https://doi.org/10.5281/zenodo.23735943},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}