MoNi4: enthalpy of formation

2 accepted literature formation-enthalpy value(s) (DFT 2).

Systems: Mo–Ni

Literature values

Enthalpy of formation of MoNi4 reported in the literature (2)
ValuePhase as printedT (K)ClassMethodSystemSourceLocationQuote
-7.55 kJ/mol (basis unstated)Ni4MoDFTfirst-principlesMo–Ni[1] Zhou 2005
cites Wang 2005 doi		Table 2, p. 4, row 45
report
-7.55 kJ/mol (basis unstated)Ni₄Mo0DFTfirst-principlesMo–Ni[1] Zhou 2005
cites Wang 2005 doi		Table 2, p. 4, row 45
report

Uncertainty budget

Components kept separate, in the value's unit (literature SCHEMA.md, UNCERTAINTY_CALIBRATION.md): effective = max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter). The method floor is the robust between-study scatter of the method class in ORCHID (calibrated) or a documented prior; printed values and printed uncertainties are unchanged.

Uncertainty budget of the literature values of MoNi4
ValueUnitPrintedReadingMethod (class, basis)CompositionScatterConversionEffective
-7.55kJ/mol (basis unstated)0.00519.64 (dft, calibrated)19.64
-7.55kJ/mol (basis unstated)0.00519.64 (dft, calibrated)19.64

Sources

  1. S.H. Zhou, Y. Wang, C. Jiang, J.Z. Zhu, L.-Q. Chen, Z.-K. Liu, First-principles calculations and thermodynamic modeling of the Ni–Mo system, Materials Science and Engineering: A 397, 288-296 (2005). doi:10.1016/j.msea.2005.02.037