NiSb: enthalpy of formation
4 accepted literature formation-enthalpy value(s) (experimental 2, model 2).
Systems: Ni–Sb
Literature values
| Value | Phase as printed | T (K) | Class | Method | System | Source | Location | Quote |
|---|---|---|---|---|---|---|---|---|
| -33.472 kJ/mol (basis unstated) | ζ(NiSb) | 298.15 | experimental | Ni–Sb | [1] Cao 2013 cites Korber 1937 | Table IV, p. 9, row 1 report | ||
| -32.543 kJ/mol (basis unstated) ± 0.494 | ζ(NiSb) | 1060 | experimental | Ni–Sb | [1] Cao 2013 cites Predel 1978 doi | Table IV, p. 9, row 3 report | ||
| -32.659 kJ/mol (basis unstated) | ζ(NiSb) | 1060 | model | Ni–Sb | [1] Cao 2013 | Table IV, p. 9, row 4 report | ||
| -32.171 kJ/mol (basis unstated) | ζ(NiSb) | 298.15 | model | Ni–Sb | [1] Cao 2013 | Table IV, p. 9, row 2 report |
Uncertainty budget
Components kept separate, in the value's unit (literature SCHEMA.md, UNCERTAINTY_CALIBRATION.md): effective = max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter). The method floor is the robust between-study scatter of the method class in ORCHID (calibrated) or a documented prior; printed values and printed uncertainties are unchanged.
| Value | Unit | Printed | Reading | Method (class, basis) | Composition | Scatter | Conversion | Effective |
|---|---|---|---|---|---|---|---|---|
| -33.472 | kJ/mol (basis unstated) | 5.000e-4 | 7 (unknown, calibrated) | 7 | ||||
| -32.543 | kJ/mol (basis unstated) | 0.494 | 5.000e-4 | 7 (unknown, calibrated) | 7 | |||
| -32.659 | kJ/mol (basis unstated) | 5.000e-4 | 7.8 (model_calculated, calibrated) | 7.8 | ||||
| -32.171 | kJ/mol (basis unstated) | 5.000e-4 | 7.8 (model_calculated, calibrated) | 7.8 |
Sources
- Zhanmin Cao, Wei Xie, Kunpeng Wang, Guangwei Du, Zhiyu Qiao, Thermodynamic Assessment of the In-Ni-Sb System and Predictions for Thermally Stable Contacts to InSb, Journal of Elec Materi 42, 2615-2629 (2013). doi:10.1007/s11664-013-2599-7