Ni–Sb system
118 accepted literature values from 3 paper(s) (experimental 94, model 24); 4 calculated phase diagram(s). 3 further extracted value(s) not accepted by the reader-agreement checks are only in the JSON/CSV.
Data: JSON · CSV · interactive explorer · interactive phase diagram · phases (10) · papers (bibliography) · Markdown
| Evidence class | Values |
|---|---|
| experimental | 94 |
| model | 24 |
| Property group | Values |
|---|---|
| invariant reaction | 114 |
| formation | 4 |
Calculated phase diagrams
Binary phase diagrams calculated with pycalphad 0.11.2 from the SGTE binary collection (Hallstedt 2025, CC BY 4.0). Evidence class: model.
| TDB file | Assessment | SHA-256 | Links |
|---|---|---|---|
| NiSb-08Cao.tdb | Z. Cao, Y. Takaku, I. Ohnuma, R. Kainuma, H. Zhu, K. Ishida, Rare. Met., 27, 384-92(2008). doi:10.1016/S1001-0521(08)60150-3 | c50b9c6a21205dfe003993046d9f6f8fb89c4dae10d9a17fa254d5d30d9c234f | viewer · TDB · JSON |
| NiSb-08Zha.tdb | Y. Zhang, C. Li, Z. Du, C. Guo, Calphad, 32, 378-88(2008). doi:10.1016/j.calphad.2008.02.001 | 1ab705f632704a07ca1d24342fe42a159b30c1cb1d9a36f53a2a635650fcb54d | viewer · TDB · JSON |
| NiSb-13Cao.tdb | Z. Cao, W. Xie, K. Wang, G. Du, Z. Qiao, J. Electron. Mater., 42, 2615-29(2013). doi:10.1007/s11664-013-2599-7 | 57b2cd3fde2a42568c0dc120447c0ef6c036e6012c6926687146837ecfc0881b | viewer · TDB · JSON |
| NiSb-14Kro.tdb | A. Kroupa, R. Mishra, D. Rajamohan, H. Flandorfer, A. Watson, H. Ipser, Calphad, 45, 151-66(2014). doi:10.1016/j.calphad.2013.11.007 | 15754b2a707f1c85565c5582ceabba72e7076f88c69108ed0d113b8e2ee9d407 | viewer · TDB · JSON |
| TDB file | T (K) | Phases at the invariant |
|---|---|---|
| NiSb-08Cao.tdb | 1371.88 | FCC_A1 (x(Sb) 0.10338) + LIQUID (x(Sb) 0.18871) + NI3SB_D03 (x(Sb) 0.25493) |
| NiSb-08Cao.tdb | 1364.23 | NI3SB_D03 (x(Sb) 0.28151) + LIQUID (x(Sb) 0.35709) + NISB_B81 (x(Sb) 0.43752) |
| NiSb-08Cao.tdb | 978.37 | FCC_A1 (x(Sb) 0.08518) + NI3SB_D0A (x(Sb) 0.25) + NI3SB_D03 (x(Sb) 0.2575) |
| NiSb-08Cao.tdb | 978.37 | FCC_A1 (x(Sb) 0.08518) + NI3SB_D0A (x(Sb) 0.25) + NI3SB_D03 (x(Sb) 0.2575) |
| NiSb-08Cao.tdb | 901.22 | NISB_B81 (x(Sb) 0.54003) + NISB2_C18 (x(Sb) 0.66667) + LIQUID (x(Sb) 0.95581) |
| NiSb-08Cao.tdb | 893.5 | NISB2_C18 (x(Sb) 0.66667) + LIQUID (x(Sb) 0.96097) + RHOMBOHEDRAL_A7 (x(Sb) 1) |
| NiSb-08Cao.tdb | 893.5 | NISB2_C18 (x(Sb) 0.66667) + LIQUID (x(Sb) 0.96113) + RHOMBOHEDRAL_A7 (x(Sb) 1) |
| NiSb-08Cao.tdb | 846.28 | NI3SB_D03 (x(Sb) 0.27897) + NI5SB2_LT (x(Sb) 0.283) + NISB_B81 (x(Sb) 0.4405) |
| NiSb-08Cao.tdb | 821.68 | NI3SB_D0A (x(Sb) 0.25) + NI3SB_D03 (x(Sb) 0.2712) + NI5SB2_LT (x(Sb) 0.283) |
| NiSb-08Zha.tdb | 1372.46 | FCC_A1 (x(Sb) 0.08566) + LIQUID (x(Sb) 0.18235) + NI3SB_D03 (x(Sb) 0.25842) |
| NiSb-08Zha.tdb | 1349.08 | NI3SB_D03 (x(Sb) 0.29052) + LIQUID (x(Sb) 0.36791) + NISB_B81 (x(Sb) 0.46682) |
| NiSb-08Zha.tdb | 989.25 | FCC_A1 (x(Sb) 0.08167) + NI3SB_D0A (x(Sb) 0.24568) + NI3SB_D03 (x(Sb) 0.26106) |
| NiSb-08Zha.tdb | 892.34 | NISB_B81 (x(Sb) 0.54254) + NISB2_C18 (x(Sb) 0.66667) + LIQUID (x(Sb) 0.95817) |
| NiSb-08Zha.tdb | 890.32 | NISB2_C18 (x(Sb) 0.66667) + LIQUID (x(Sb) 0.95923) + RHOMBOHEDRAL_A7 (x(Sb) 1) |
| NiSb-08Zha.tdb | 890.32 | NISB2_C18 (x(Sb) 0.66667) + LIQUID (x(Sb) 0.95925) + RHOMBOHEDRAL_A7 (x(Sb) 1) |
| NiSb-08Zha.tdb | 869.35 | NI5SB2_LT (x(Sb) 0.28547) + NI3SB_D03 (x(Sb) 0.29054) + NISB_B81 (x(Sb) 0.46552) |
| NiSb-08Zha.tdb | 802.63 | NI3SB_D0A (x(Sb) 0.24944) + NI3SB_D03 (x(Sb) 0.27216) + NI5SB2_LT (x(Sb) 0.27704) |
| NiSb-13Cao.tdb | 1372.46 | FCC_A1 (x(Sb) 0.08566) + LIQUID (x(Sb) 0.18235) + NI3SB_D03 (x(Sb) 0.25842) |
| NiSb-13Cao.tdb | 1347.72 | NI3SB_D03 (x(Sb) 0.29225) + LIQUID (x(Sb) 0.36911) + NISB_B81 (x(Sb) 0.4626) |
| NiSb-13Cao.tdb | 989.25 | FCC_A1 (x(Sb) 0.08167) + NI3SB_D0A (x(Sb) 0.24568) + NI3SB_D03 (x(Sb) 0.26106) |
| NiSb-13Cao.tdb | 898.01 | NISB_B81 (x(Sb) 0.54484) + NISB2_C18 (x(Sb) 0.66667) + LIQUID (x(Sb) 0.95504) |
| NiSb-13Cao.tdb | 890.32 | NISB2_C18 (x(Sb) 0.66667) + LIQUID (x(Sb) 0.95923) + RHOMBOHEDRAL_A7 (x(Sb) 1) |
| NiSb-13Cao.tdb | 890.32 | NISB2_C18 (x(Sb) 0.66667) + LIQUID (x(Sb) 0.95936) + RHOMBOHEDRAL_A7 (x(Sb) 1) |
| NiSb-13Cao.tdb | 855.45 | NI5SB2_LT (x(Sb) 0.28554) + NI3SB_D03 (x(Sb) 0.29252) + NISB_B81 (x(Sb) 0.46336) |
| NiSb-13Cao.tdb | 802.63 | NI3SB_D0A (x(Sb) 0.24944) + NI3SB_D03 (x(Sb) 0.27216) + NI5SB2_LT (x(Sb) 0.27704) |
| NiSb-14Kro.tdb | 1366.73 | FCC_A1 (x(Sb) 0.08706) + LIQUID (x(Sb) 0.18464) + BCC_A2 (x(Sb) 0.24453) |
| NiSb-14Kro.tdb | 1349.63 | BCC_A2 (x(Sb) 0.28986) + LIQUID (x(Sb) 0.36784) + NISB_B81 (x(Sb) 0.46568) |
| NiSb-14Kro.tdb | 988.84 | FCC_A1 (x(Sb) 0.08166) + NI3SB_D0A (x(Sb) 0.24568) + BCC_A2 (x(Sb) 0.25676) |
| NiSb-14Kro.tdb | 892.34 | NISB_B81 (x(Sb) 0.54254) + NISB2_C18 (x(Sb) 0.66667) + LIQUID (x(Sb) 0.95817) |
| NiSb-14Kro.tdb | 890.32 | NISB2_C18 (x(Sb) 0.66667) + LIQUID (x(Sb) 0.95923) + RHOMBOHEDRAL_A7 (x(Sb) 1) |
| NiSb-14Kro.tdb | 890.32 | NISB2_C18 (x(Sb) 0.66667) + LIQUID (x(Sb) 0.95925) + RHOMBOHEDRAL_A7 (x(Sb) 1) |
| NiSb-14Kro.tdb | 856.98 | NI5SB2_LT (x(Sb) 0.28548) + BCC_A2 (x(Sb) 0.28966) + NISB_B81 (x(Sb) 0.46549) |
| NiSb-14Kro.tdb | 803.04 | NI3SB_D0A (x(Sb) 0.24944) + BCC_A2 (x(Sb) 0.27208) + NI5SB2_LT (x(Sb) 0.27704) |
Convex hulls: Materials Project DFT hull · OQMD DFT hull · CALPHAD hull NiSb-08Cao · CALPHAD hull NiSb-08Zha · CALPHAD hull NiSb-13Cao
Invariant reactions (literature)
| T (K) | Reaction / phases | Compositions (mole fraction) | Class | Source | Location | Quote |
|---|---|---|---|---|---|---|
| 1444 | congruent melting: L <-> Ni3Sb_HT | L: Sb 0.285; Ni3Sb_HT: Ni 0.75, Sb 0.25 | experimental | [1] CAO 2008 cites Panteleimonov 1964 | Table 3, p. 6, row 12 report | |
| 1443 | congruent melting: L ↔ (βNi5Sb2) | L: Sb 0.29; (βNi5Sb2): Sb 0.29 | experimental | [2] Zhang 2008 cites Eremenko 1951 | Table 3, p. 4, row 21 report | |
| 1443 | congruent melting: L ↔ (βNi5Sb2) | L: Sb 0.29; (βNi5Sb2): Sb 0.29 | experimental | [2] Zhang 2008 cites Panteleimonov 1964 | Table 3, p. 4, row 22 report | |
| 1443 | congruent melting: L <-> Ni3Sb_HT | L: Sb 0.283; Ni3Sb_HT: Ni 0.75, Sb 0.25 | experimental | [1] CAO 2008 cites Lossew 1906 | Table 3, p. 6, row 10 report | |
| 1443 | congruent melting: L ↔ (βNi5Sb2) | L: Sb 0.283; (βNi5Sb2): Sb 0.283 | experimental | [2] Zhang 2008 cites Lossew 1906 doi | Table 3, p. 4, row 19 report | |
| 1443 | congruent melting: L <-> Ni3Sb_HT | L: Sb 0.267; Ni3Sb_HT: Ni 0.75, Sb 0.25 | model | [1] CAO 2008 | Table 3, p. 6, row 14 report | |
| 1438 | congruent melting: L <-> NiSb | L: Sb 0.475; NiSb: Ni 0.5, Sb 0.5 | model | [1] CAO 2008 | Table 3, p. 6, row 32 report | |
| 1435 | congruent melting: L ↔ (βNi5Sb2) | L: Sb 0.293; (βNi5Sb2): Sb 0.293 | experimental | [2] Zhang 2008 cites Shibata 1939 | Table 3, p. 4, row 20 report | |
| 1435 | congruent melting: L <-> Ni3Sb_HT | L: Sb 0.279; Ni3Sb_HT: Ni 0.75, Sb 0.25 | experimental | [1] CAO 2008 cites Shibata 1939 | Table 3, p. 6, row 11 report | |
| 1434 | congruent melting: L ↔ (βNi3Sb) | L: Sb 0.2627; (βNi3Sb): Sb 0.2627 | experimental | [2] Zhang 2008 | Table 3, p. 4, row 25 report | |
| 1434 | congruent melting: L ↔ (βNi5Sb2) | L: Sb 0.279; (βNi5Sb2): Sb 0.279 | model | [2] Zhang 2008 cites Cha 1991 | Table 3, p. 4, row 24 report | |
| 1434 | congruent melting: L ↔ (βNi3Sb) | L: Sb 0.279; (βNi3Sb): Sb 0.279 | experimental | [2] Zhang 2008 cites Feschotte 1989 doi | Table 3, p. 4, row 23 report | |
| 1434 | congruent melting: L <-> Ni3Sb_HT | L: Sb 0.279; Ni3Sb_HT: Ni 0.75, Sb 0.25 | experimental | [1] CAO 2008 cites Feschotte 1989 | Table 3, p. 6, row 13 report | |
| 1432 | congruent melting: L ↔ (γNiSb) | L: Sb 0.47; γNiSb: Sb 0.47 | experimental | [2] Zhang 2008 cites Leubolt 1986 doi | Table 3, p. 5, row 3 report | |
| 1432 | congruent melting: L <-> NiSb | L: Sb 0.47; NiSb: Ni 0.5, Sb 0.5 | experimental | [1] CAO 2008 cites Leubolt 1986 | Table 3, p. 6, row 30 report | |
| 1431 | congruent melting: L ↔ (γNiSb) | L: Sb 0.4965; γNiSb: Sb 0.4965 | experimental | [2] Zhang 2008 cites Lossew 1906 doi | Table 3, p. 5, row 1 report | |
| 1431 | congruent melting: L <-> NiSb | L: Sb 0.497; NiSb: Ni 0.5, Sb 0.5 | experimental | [1] CAO 2008 cites Lossew 1906 | Table 3, p. 6, row 27 report | |
| 1426 | congruent melting: L <-> NiSb | L: Sb 0.494; NiSb: Ni 0.5, Sb 0.5 | experimental | [1] CAO 2008 cites Shibata 1939 | Table 3, p. 6, row 28 report | |
| 1426 | congruent melting: L ↔ (γNiSb) | L: Sb 0.484; γNiSb: Sb 0.484 | experimental | [2] Zhang 2008 cites Shibata 1939 | Table 3, p. 5, row 2 report | |
| 1420 | congruent melting: L ↔ (γNiSb) | L: Sb 0.4838; γNiSb: Sb 0.4838 | model | [2] Zhang 2008 | Table 3, p. 5, row 6 report | |
| 1420 | congruent melting: L ↔ (γNiSb) | L: Sb 0.489; γNiSb: Sb 0.489 | model | [2] Zhang 2008 cites Cha 1991 | Table 3, p. 5, row 5 report | |
| 1420 | congruent melting: L ↔ (γNiSb) | L: Sb 0.489; γNiSb: Sb 0.489 | experimental | [2] Zhang 2008 cites Feschotte 1989 doi | Table 3, p. 5, row 4 report | |
| 1420 | congruent melting: L <-> NiSb | L: Sb 0.489; NiSb: Ni 0.5, Sb 0.5 | experimental | [1] CAO 2008 cites Feschotte 1989 | Table 3, p. 6, row 31 report | |
| 1413 | congruent melting: L <-> NiSb | L: Sb 0.47; NiSb: Ni 0.5, Sb 0.5 | experimental | [1] CAO 2008 cites Chen 1978 | Table 3, p. 6, row 29 report | |
| 1375 | eutectic: L ↔ (αNi) + (βNi5Sb2) | (βNi5Sb2): Ni 0.714286, Sb 0.285714 | experimental | [2] Zhang 2008 cites Panteleimonov 1964 | Table 3, p. 4, row 6 report | |
| 1375 | eutectic: L ↔ (αNi) + (βNi5Sb2) | L: Sb 0.213; (βNi5Sb2): Ni 0.714286, Sb 0.285714 | experimental | [2] Zhang 2008 cites Eremenko 1951 | Table 3, p. 4, row 5 report | |
| 1373 | eutectic: L ↔ (αNi) + (βNi5Sb2) | (αNi): Sb 0.0367; (βNi5Sb2): Ni 0.714286, Sb 0.285714 | experimental | [2] Zhang 2008 cites Lossew 1906 doi | Table 3, p. 4, row 3 report | |
| 1373 | L <-> fcc(Ni)+Ni3Sb_HT | L: Sb 0.205; fcc(Ni): Sb 0.038; Ni3Sb_HT: Sb 0.267 | experimental | [1] CAO 2008 cites Lossew 1906 | Table 3, p. 6, row 1 report | |
| 1372 | eutectic: L ↔ (αNi) + (βNi3Sb) | L: Sb 0.1823; (αNi): Sb 0.085665; (βNi3Sb): Sb 0.2584 | experimental | [2] Zhang 2008 | Table 3, p. 4, row 10 report | |
| 1371 | L <-> fcc(Ni)+Ni3Sb_HT | L: Sb 0.189; fcc(Ni): Sb 0.104; Ni3Sb_HT: Sb 0.255 | model | [1] CAO 2008 | Table 3, p. 6, row 4 report | |
| 1370 | eutectic: L ↔ (αNi) + (βNi5Sb2) | L: Sb 0.2133; (αNi): Sb 0.084; (βNi5Sb2): Ni 0.714286, Sb 0.285714 | experimental | [2] Zhang 2008 cites Shibata 1939 | Table 3, p. 4, row 4 report | |
| 1370 | eutectic: L ↔ (αNi) + (βNi3Sb) | L: Sb 0.23; (αNi): Sb 0.085; (βNi3Sb): Sb 0.252 | experimental | [2] Zhang 2008 cites Feschotte 1989 doi | Table 3, p. 4, row 8 report | |
| 1370 | eutectic: L ↔ (αNi) + (βNi5Sb2) | L: Sb 0.23; (αNi): Sb 0.09; (βNi5Sb2): Sb 0.252 | model | [2] Zhang 2008 cites Cha 1991 | Table 3, p. 4, row 9 report | |
| 1370 | eutectic: L ↔ (αNi) + (βNi5Sb2) | (αNi): Sb 0.094; (βNi5Sb2): Ni 0.714286, Sb 0.285714 | experimental | [2] Zhang 2008 cites Naud 1972 doi | Table 3, p. 4, row 7 report | |
| 1370 | L <-> fcc(Ni)+Ni3Sb_HT | L: Sb 0.216; fcc(Ni): Sb 0.084; Ni3Sb_HT: Sb 0.236 | experimental | [1] CAO 2008 cites Shibata 1939 | Table 3, p. 6, row 2 report | |
| 1370 | L <-> fcc(Ni)+Ni3Sb_HT | L: Sb 0.23; fcc(Ni): Sb 0.09; Ni3Sb_HT: Sb 0.252 | experimental | [1] CAO 2008 cites Feschotte 1989 | Table 3, p. 6, row 3 report | |
| 1364 | L <-> Ni3Sb_HT+NiSb | L: Sb 0.357; Ni3Sb_HT: Sb 0.281; NiSb: Sb 0.437 | model | [1] CAO 2008 | Table 3, p. 6, row 26 report | |
| 1353 | eutectic: L ↔ (βNi5Sb2) + (γNiSb) | L: Sb 0.35; (βNi5Sb2): Ni 0.714286, Sb 0.285714; (γNiSb): Ni 0.5, Sb 0.5 | experimental | [2] Zhang 2008 cites Panteleimonov 1964 | Table 3, p. 4, row 49 report | |
| 1353 | eutectic: L ↔ (βNi5Sb2) + (γNiSb) | L: Sb 0.35; (βNi5Sb2): Ni 0.714286, Sb 0.285714; (γNiSb): Ni 0.5, Sb 0.5 | experimental | [2] Zhang 2008 cites Eremenko 1951 | Table 3, p. 4, row 48 report | |
| 1349 | eutectic: L ↔ (βNi3Sb) + (γNiSb) | L: Sb 0.3667; (βNi3Sb): Sb 0.2885; (γNiSb): Sb 0.46 | experimental | [2] Zhang 2008 | Table 3, p. 4, row 54 report | |
| 1348 | eutectic: L ↔ (βNi5Sb2) + (γNiSb) | (βNi5Sb2): Ni 0.714286, Sb 0.285714; (γNiSb): Ni 0.5, Sb 0.5 | experimental | [2] Zhang 2008 cites Leubolt 1986 doi | Table 3, p. 4, row 51 report | |
| 1348 | L <-> Ni3Sb_HT+NiSb | Ni3Sb_HT: Ni 0.75, Sb 0.25; NiSb: Ni 0.5, Sb 0.5 | experimental | [1] CAO 2008 cites Leubolt 1986 | Table 3, p. 6, row 24 report | |
| 1345 | eutectic: L ↔ (βNi3Sb) + (γNiSb) | L: Sb 0.35; (βNi3Sb): Sb 0.288; (γNiSb): Sb 0.43 | experimental | [2] Zhang 2008 cites Feschotte 1989 doi | Table 3, p. 4, row 52 report | |
| 1345 | L <-> Ni3Sb_HT+NiSb | L: Sb 0.35; Ni3Sb_HT: Sb 0.288; NiSb: Sb 0.43 | experimental | [1] CAO 2008 cites Feschotte 1989 | Table 3, p. 6, row 25 report | |
| 1345 | eutectic: L ↔ (βNi5Sb2) + (γNiSb) | L: Sb 0.3467; (βNi5Sb2): Sb 0.283; (γNiSb): Sb 0.4965 | experimental | [2] Zhang 2008 cites Lossew 1906 doi | Table 3, p. 4, row 46 report | |
| 1345 | L <-> Ni3Sb_HT+NiSb | L: Sb 0.347; Ni3Sb_HT: Sb 0.283; NiSb: Sb 0.42 | experimental | [1] CAO 2008 cites Lossew 1906 | Table 3, p. 6, row 22 report | |
| 1345 | eutectic: L ↔ (βNi5Sb2) + (γNiSb) | L: Sb 0.37; (βNi5Sb2): Sb 0.288; (γNiSb): Sb 0.43 | model | [2] Zhang 2008 cites Cha 1991 | Table 3, p. 4, row 53 report | |
| 1343 | eutectic: L ↔ (βNi5Sb2) + (γNiSb) | L: Sb 0.37; (βNi5Sb2): Ni 0.714286, Sb 0.285714; (γNiSb): Ni 0.5, Sb 0.5 | experimental | [2] Zhang 2008 cites Shibata 1939 | Table 3, p. 4, row 47 report | |
| 1343 | L <-> Ni3Sb_HT+NiSb | L: Sb 0.37; Ni3Sb_HT: Sb 0.299; NiSb: Sb 0.432 | experimental | [1] CAO 2008 cites Shibata 1939 | Table 3, p. 6, row 23 report | |
| 1343 | eutectic: L ↔ (βNi5Sb2) + (γNiSb) | (βNi5Sb2): Ni 0.714286, Sb 0.285714; (γNiSb): Ni 0.5, Sb 0.5 | experimental | [2] Zhang 2008 cites Naud 1972 doi | Table 3, p. 4, row 50 report | |
| 1163 | polymorphic: (βNi5Sb2) ↔ (β'Ni5Sb2) | (βNi5Sb2): Ni 0.714286, Sb 0.285714 | experimental | [2] Zhang 2008 cites Panteleimonov 1964 | Table 3, p. 4, row 27 report | |
| 989 | peritectoid: (αNi) + (βNi3Sb) ↔ (δNi3Sb) | (αNi): Sb 0.08167; (βNi3Sb): Sb 0.261; (δNi3Sb): Sb 0.2456 | experimental | [2] Zhang 2008 | Table 3, p. 4, row 18 report | |
| 988 | fcc(Ni)+Ni3Sb_HT <-> Ni3Sb | fcc(Ni): Sb 0.09; Ni3Sb_HT: Sb 0.25; Ni3Sb: Sb 0.237 | experimental | [1] CAO 2008 cites Feschotte 1989 | Table 3, p. 6, row 6 report | |
| 988 | peritectoid: (αNi) + (βNi3Sb) ↔ (δNi3Sb) | (βNi3Sb): Sb 0.257; (δNi3Sb): Sb 0.237 | experimental | [2] Zhang 2008 cites Feschotte 1989 doi | Table 3, p. 4, row 16 report | |
| 988 | fcc(Ni)+Ni3Sb_HT <-> Ni3Sb | fcc(Ni): Sb 0.09; Ni3Sb_HT: Sb 0.257; Ni3Sb: Sb 0.237 | experimental | [1] CAO 2008 cites Nash 1991 | Table 3, p. 6, row 8 report | |
| 988 | peritectoid: (αNi) + (βNi5Sb2) ↔ (δNi3Sb) | (αNi): Sb 0.09; (βNi5Sb2): Sb 0.257; (δNi3Sb): Sb 0.237 | model | [2] Zhang 2008 cites Cha 1991 | Table 3, p. 4, row 17 report | |
| 987 | fcc(Ni)+Ni3Sb_HT <-> Ni3Sb | fcc(Ni): Sb 0.086; Ni3Sb_HT: Sb 0.258; Ni3Sb: Sb 0.25 | model | [1] CAO 2008 | Table 3, p. 6, row 9 report | |
| 982 | peritectoid: (αNi) + (βNi5Sb2) ↔ δNi3Sb | (αNi): Sb 0.094; (βNi5Sb2): Ni 0.714286, Sb 0.285714; δNi3Sb: Ni 0.75, Sb 0.25 | experimental | [2] Zhang 2008 cites Naud 1972 doi | Table 3, p. 4, row 15 report | |
| 973 | peritectoid: (αNi) + (βNi5Sb2) ↔ (δNi13Sb4) | (βNi5Sb2): Ni 0.714286, Sb 0.285714 | experimental | [2] Zhang 2008 cites Panteleimonov 1964 | Table 3, p. 4, row 14 report | |
| 971 | fcc(Ni)+Ni3Sb_HT <-> Ni3Sb | fcc(Ni): Sb 0.081; Ni3Sb_HT: Sb 0.25; Ni3Sb: Sb 0.25 | experimental | [1] CAO 2008 cites Shibata 1939 | Table 3, p. 6, row 5 report | |
| 971 | peritectoid: (αNi) + (βNi5Sb2) ↔ (δNi3Sb) | (αNi): Sb 0.084; (βNi5Sb2): Sb 0.25; (δNi3Sb): Ni 0.75, Sb 0.25 | experimental | [2] Zhang 2008 cites Shibata 1939 | Table 3, p. 4, row 12 report | |
| 958 | fcc(Ni)+Ni3Sb_HT <-> Ni3Sb | Ni3Sb_HT: Ni 0.75, Sb 0.25; Ni3Sb: Ni 0.75, Sb 0.25 | experimental | [1] CAO 2008 cites Elbakkouri 1986 | Table 3, p. 6, row 7 report | |
| 950 | peritectoid: (αNi) + (βNi5Sb2) ↔ δNi4Sb | (αNi): Sb 0.0376; (βNi5Sb2): Ni 0.714286, Sb 0.285714; δNi4Sb: Sb 0.2 | experimental | [2] Zhang 2008 cites Lossew 1906 doi | Table 3, p. 4, row 11 report | |
| 932 | peritectoid: (αNi) + (βNi5Sb2) ↔ (δNi3Sb) | (βNi5Sb2): Ni 0.714286, Sb 0.285714; (δNi3Sb): Ni 0.75, Sb 0.25 | experimental | [2] Zhang 2008 cites Eremenko 1951 | Table 3, p. 4, row 13 report | |
| 901 | L+NiSb <-> NiSb2 | L: Sb 0.956; NiSb: Sb 0.54; NiSb2: Sb 0.667 | model | [1] CAO 2008 | Table 3, p. 6, row 37 report | |
| 899 | peritectic: L + (γNiSb) ↔ ζNiSb2 | γNiSb: Ni 0.5, Sb 0.5; ζNiSb2: Ni 0.333333, Sb 0.666667 | experimental | [2] Zhang 2008 cites Naud 1972 doi | Table 3, p. 5, row 9 report | |
| 899 | peritectic: L + (γNiSb) ↔ ζNiSb2 | L: Sb 0.95; γNiSb: Ni 0.5, Sb 0.5; ζNiSb2: Ni 0.333333, Sb 0.666667 | experimental | [2] Zhang 2008 cites Shibata 1939 | Table 3, p. 5, row 8 report | |
| 897 | L+NiSb <-> NiSb2 | NiSb: Ni 0.5, Sb 0.5; NiSb2: Ni 0.333333, Sb 0.666667 | experimental | [1] CAO 2008 cites Leubolt 1986 | Table 3, p. 6, row 36 report | |
| 897 | peritectic: L + (γNiSb) ↔ ζNiSb2 | γNiSb: Ni 0.5, Sb 0.5; ζNiSb2: Ni 0.333333, Sb 0.666667 | experimental | [2] Zhang 2008 cites Leubolt 1986 doi | Table 3, p. 5, row 11 report | |
| 894 | peritectic: L + (γNiSb) ↔ (ζNiSb2) | L: Sb 0.97; γNiSb: Sb 0.52; ζNiSb2: Sb 0.665 | model | [2] Zhang 2008 cites Cha 1991 | Table 3, p. 5, row 13 report | |
| 894 | peritectic: L + (γNiSb) ↔ ζNiSb2 | L: Sb 0.96; γNiSb: Sb 0.5354; ζNiSb2: Sb 0.6667 | model | [2] Zhang 2008 | Table 3, p. 5, row 14 report | |
| 894 | peritectic: L + (γNiSb) ↔ ζNiSb2 | L: Sb 0.97; γNiSb: Sb 0.52; ζNiSb2: Sb 0.662 | experimental | [2] Zhang 2008 cites Feschotte 1989 doi | Table 3, p. 5, row 10 report | |
| 894 | L <-> NiSb2+rhomb (Sb) | L: Sb 0.961; NiSb2: Sb 0.667; rhomb (Sb): Sb 1 | model | [1] CAO 2008 | Table 3, p. 6, row 41 report | |
| 894 | L+NiSb <-> NiSb2 | L: Sb 0.96; NiSb: Sb 0.52; NiSb2: Sb 0.662 | experimental | [1] CAO 2008 cites Feschotte 1989 | Table 3, p. 6, row 35 report | |
| 890 | eutectic: L ↔ ζNiSb2 + εSb | L: Sb 0.96; ζNiSb2: Sb 0.6667; εSb: Sb 1 | model | [2] Zhang 2008 | Table 3, p. 5, row 20 report | |
| 889 | L+NiSb <-> NiSb2 | L: Sb 0.95; NiSb: Sb 0.535; NiSb2: Sb 0.713 | experimental | [1] CAO 2008 cites Shibata 1939 | Table 3, p. 6, row 34 report | |
| 889 | eutectic: L ↔ ζNiSb2 + (εSb) | L: Sb 0.96; ζNiSb2: Sb 0.714 | experimental | [2] Zhang 2008 cites Shibata 1939 | Table 3, p. 5, row 16 report | |
| 889 | eutectic: L ↔ ζNiSb2 + (εSb) | ζNiSb2: Ni 0.333333, Sb 0.666667 | experimental | [2] Zhang 2008 cites Naud 1972 doi | Table 3, p. 5, row 17 report | |
| 889 | L <-> NiSb2+rhomb (Sb) | L: Sb 0.97; NiSb2: Sb 0.722; rhomb (Sb): Sb 0.995 | experimental | [1] CAO 2008 cites Shibata 1939 | Table 3, p. 6, row 39 report | |
| 885 | congruent transformation: (βNi3Sb) ↔ (θNi5Sb2) | (βNi3Sb): Ni 0.75, Sb 0.25; (θNi5Sb2): Sb 0.285 | experimental | [2] Zhang 2008 | Table 3, p. 4, row 30 report | |
| 885 | L+NiSb <-> NiSb2 | L: Sb 0.941; NiSb: Sb 0.42; NiSb2: Sb 0.552 | experimental | [1] CAO 2008 cites Lossew 1906 | Table 3, p. 6, row 33 report | |
| 885 | peritectic: L + (γNiSb) ↔ (ζNi4Sb5) | L: Sb 0.9456; γNiSb: Sb 0.4965; ζNi4Sb5: Sb 0.5522; (ζNi4Sb5): Sb 0.5522 | experimental | [2] Zhang 2008 cites Lossew 1906 doi | Table 3, p. 5, row 7 report | |
| 884 | eutectic: L ↔ ζNi4Sb5 + (εSb) | L: Sb 0.9456; ζNi4Sb5: Sb 0.5522 | experimental | [2] Zhang 2008 cites Lossew 1906 doi | Table 3, p. 5, row 15 report | |
| 884 | L <-> NiSb2+rhomb (Sb) | L: Sb 0.946; NiSb2: Sb 0.552; rhomb (Sb): Sb 1 | experimental | [1] CAO 2008 cites Lossew 1906 | Table 3, p. 6, row 38 report | |
| 883 | peritectic: L + (γNiSb) ↔ ζNiSb2 | γNiSb: Ni 0.5, Sb 0.5; ζNiSb2: Ni 0.333333, Sb 0.666667 | experimental | [2] Zhang 2008 cites Kjekshus 1977 doi | Table 3, p. 5, row 12 report | |
| 882 | L <-> NiSb2+rhomb (Sb) | L: Sb 0.97; NiSb2: Sb 0.665; rhomb (Sb): Sb 0.998 | experimental | [1] CAO 2008 cites Feschotte 1989 | Table 3, p. 6, row 40 report | |
| 882 | eutectic: L ↔ ζNiSb2 + (εSb) | L: Sb 0.98; ζNiSb2: Sb 0.666; εSb: Sb 0.999; (εSb): Sb 0.999 | experimental | [2] Zhang 2008 cites Feschotte 1989 doi | Table 3, p. 5, row 18 report | |
| 873 | congruent transformation: (βNi3Sb) ↔ (θNi5Sb2) | (βNi3Sb): Ni 0.75, Sb 0.25; (θNi5Sb2): Sb 0.283 | experimental | [2] Zhang 2008 cites Feschotte 1989 doi | Table 3, p. 4, row 28 report | |
| 873 | congruent transformation: (βNi5Sb2) ↔ (θNi7Sb3) | (βNi5Sb2): Ni 0.714286, Sb 0.285714; (θNi7Sb3): Sb 0.283 | model | [2] Zhang 2008 cites Cha 1991 | Table 3, p. 4, row 29 report | |
| 865 | polymorphic: (βNi5Sb2) ↔ (β'Ni5Sb2) + (γNiSb) | (βNi5Sb2): Ni 0.714286, Sb 0.285714; (γNiSb): Ni 0.5, Sb 0.5 | experimental | [2] Zhang 2008 cites Leubolt 1986 doi | Table 3, p. 4, row 35 report | |
| 865 | Ni3Sb_HT+NiSb <-> Ni7Sb3 | Ni3Sb_HT: Ni 0.75, Sb 0.25; NiSb: Ni 0.5, Sb 0.5; Ni7Sb3: Ni 0.717, Sb 0.283 | experimental | [1] CAO 2008 cites Leubolt 1986 | Table 3, p. 6, row 16 report | |
| 861 | peritectoid: (β'Ni5Sb2) + (γNiSb) ↔ (θNi7Sb3) | (β'Ni5Sb2): Ni 0.714286, Sb 0.285714; (γNiSb): Ni 0.5, Sb 0.5; (θNi7Sb3): Sb 0.3 | experimental | [2] Zhang 2008 cites Shibata 1939 | Table 3, p. 4, row 31 report | |
| 861 | peritectoid: (β'Ni5Sb2) + (γNiSb) ↔ (θNi7Sb3) | (β'Ni5Sb2): Ni 0.714286, Sb 0.285714; (γNiSb): Ni 0.5, Sb 0.5 | experimental | [2] Zhang 2008 cites Naud 1972 doi | Table 3, p. 4, row 34 report | |
| 857 | eutectoid: (βNi3Sb) ↔ θNi5Sb2 + (γNiSb) | (βNi3Sb): Sb 0.292; θNi5Sb2: Sb 0.285; (γNiSb): Sb 0.462 | experimental | [2] Zhang 2008 | Table 3, p. 4, row 38 report | |
| 855 | eutectoid: (βNi3Sb) ↔ θNi5Sb2 + (γNiSb) | (βNi3Sb): Sb 0.288; θNi5Sb2: Sb 0.284; (γNiSb): Sb 0.465 | experimental | [2] Zhang 2008 cites Feschotte 1989 doi | Table 3, p. 4, row 36 report | |
| 855 | eutectoid: (βNi5Sb2) ↔ θNi7Sb3 + (γNiSb) | (βNi5Sb2): Sb 0.288; θNi7Sb3: Sb 0.284; (γNiSb): Sb 0.465 | model | [2] Zhang 2008 cites Cha 1991 | Table 3, p. 4, row 37 report | |
| 855 | Ni3Sb_HT+NiSb <-> Ni7Sb3 | Ni3Sb_HT: Sb 0.288; NiSb: Sb 0.284; Ni7Sb3: Sb 0.465 | experimental | [1] CAO 2008 cites Feschotte 1989 | Table 3, p. 6, row 15 report | |
| 853 | polymorphic: (βNi5Sb2) ↔ (β'Ni5Sb2) | (βNi5Sb2): Ni 0.714286, Sb 0.285714 | experimental | [2] Zhang 2008 cites Lossew 1906 doi | Table 3, p. 4, row 26 report | |
| 853 | Ni3Sb_HT+NiSb <-> Ni7Sb3 | Ni3Sb_HT: Sb 0.279; NiSb: Sb 0.283; Ni7Sb3: Sb 0.44 | model | [1] CAO 2008 | Table 3, p. 6, row 17 report | |
| 833 | eutectoid: (βNi5Sb2) ↔ θNi5Sb2 + (γNiSb) | (βNi5Sb2): Sb 0.32; θNi5Sb2: Ni 0.714286, Sb 0.285714; (γNiSb): Ni 0.5, Sb 0.5 | experimental | [2] Zhang 2008 cites Panteleimonov 1964 | Table 3, p. 4, row 33 report | |
| 829 | Ni3Sb_HT <-> Ni3Sb+Ni7Sb3 | Ni3Sb_HT: Sb 0.271; Ni3Sb: Sb 0.25; Ni7Sb3: Sb 0.283 | model | [1] CAO 2008 | Table 3, p. 6, row 21 report | |
| 820 | eutectoid: (βNi5Sb2) ↔ (θNi5Sb2) + (γNiSb) | (βNi5Sb2): Ni 0.714286, Sb 0.285714; (θNi5Sb2): Ni 0.714286, Sb 0.285714; (γNiSb): Ni 0.5, Sb 0.5 | experimental | [2] Zhang 2008 cites Eremenko 1951 | Table 3, p. 4, row 32 report | |
| 808 | eutectoid: (β'Ni5Sb2) ↔ δNi3Sb + (θNi7Sb3) | (β'Ni5Sb2): Ni 0.714286, Sb 0.285714; δNi3Sb: Ni 0.75, Sb 0.25 | experimental | [2] Zhang 2008 cites Naud 1972 doi | Table 3, p. 4, row 42 report | |
| 806 | Ni3Sb_HT <-> Ni3Sb+Ni7Sb3 | Ni3Sb_HT: Sb 0.288; Ni3Sb: Sb 0.254; Ni7Sb3: Sb 0.293 | experimental | [1] CAO 2008 cites Shibata 1939 | Table 3, p. 6, row 18 report | |
| 806 | eutectoid: (β'Ni5Sb2) ↔ (δNi3Sb) + (θNi7Sb3) | (β'Ni5Sb2): Sb 0.283; (δNi3Sb): Ni 0.75, Sb 0.25 | experimental | [2] Zhang 2008 cites Shibata 1939 | Table 3, p. 4, row 39 report | |
| 803 | Ni3Sb_HT <-> Ni3Sb+Ni7Sb3 | Ni3Sb_HT: Sb 0.277; Ni3Sb: Sb 0.248; Ni7Sb3: Sb 0.28 | experimental | [1] CAO 2008 cites Feschotte 1989 | Table 3, p. 6, row 20 report | |
| 803 | eutectoid: (βNi5Sb2) ↔ (δNi3Sb) + (θNi7Sb3) | (βNi5Sb2): Sb 0.277; (δNi3Sb): Sb 0.25; (θNi7Sb3): Sb 0.28 | model | [2] Zhang 2008 cites Cha 1991 | Table 3, p. 4, row 44 report | |
| 803 | eutectoid: (βNi3Sb) ↔ (δNi3Sb) + (θNi5Sb2) | (βNi3Sb): Sb 0.272; (δNi3Sb): Sb 0.2494; (θNi5Sb2): Sb 0.277 | experimental | [2] Zhang 2008 | Table 3, p. 4, row 45 report | |
| 803 | eutectoid: (βNi3Sb) ↔ (δNi3Sb) + (θNi5Sb2) | (βNi3Sb): Sb 0.277; (δNi3Sb): Sb 0.248; (θNi5Sb2): Sb 0.28 | experimental | [2] Zhang 2008 cites Feschotte 1989 doi | Table 3, p. 4, row 43 report | |
| 798 | eutectoid: (βNi5Sb2) ↔ (δNi13Sb4) + (θNi5Sb2) | (βNi5Sb2): Sb 0.2725; (θNi5Sb2): Ni 0.714286, Sb 0.285714 | experimental | [2] Zhang 2008 cites Panteleimonov 1964 | Table 3, p. 4, row 41 report | |
| 798 | Ni3Sb_HT <-> Ni3Sb+Ni7Sb3 | Ni3Sb_HT: Sb 0.267; Ni3Sb: Sb 0.241; Ni7Sb3: Sb 0.283 | experimental | [1] CAO 2008 cites Panteleimonov 1964 | Table 3, p. 6, row 19 report | |
| 768 | eutectoid: (βNi5Sb2) ↔ δNi3Sb + (θNi5Sb2) | (βNi5Sb2): Ni 0.714286, Sb 0.285714; δNi3Sb: Ni 0.75, Sb 0.25; (θNi5Sb2): Ni 0.714286, Sb 0.285714 | experimental | [2] Zhang 2008 cites Eremenko 1951 | Table 3, p. 4, row 40 report | |
| 733 | congruent transformation: (αNi) ↔ (α'Ni15Sb) | (αNi): Sb 0.063; (α'Ni15Sb): Sb 0.063 | model | [2] Zhang 2008 cites Cha 1991 | Table 3, p. 4, row 2 report | |
| 733 | congruent transformation: (αNi) ↔ (α'Ni15Sb) | (αNi): Sb 0.0625; (α'Ni15Sb): Sb 0.0625 | experimental | [2] Zhang 2008 cites Osawa 1940 | Table 3, p. 4, row 1 report |
Formation enthalpies
Literature values in kJ/mol-atom where the per-atom basis is known. DFT columns: the lowest-energy entry at the same composition (Materials Project 2026.04.13, OQMD v1.8; different energy references, never averaged), from dft_parity.json.
| Phase | Compound | Value | T (K) | Class | MP DFT (kJ/mol-atom) | OQMD DFT (kJ/mol-atom) | Source | Location | Quote |
|---|---|---|---|---|---|---|---|---|---|
| ζ(NiSb) | -33.472 kJ/mol (basis unstated) | 298.15 | experimental | [3] Cao 2013 cites Korber 1937 | Table IV, p. 9, row 1 report | ||||
| ζ(NiSb) | -32.659 kJ/mol (basis unstated) | 1060 | model | [3] Cao 2013 | Table IV, p. 9, row 4 report | ||||
| ζ(NiSb) | -32.543 kJ/mol (basis unstated) ± 0.494 | 1060 | experimental | [3] Cao 2013 cites Predel 1978 doi | Table IV, p. 9, row 3 report | ||||
| ζ(NiSb) | -32.171 kJ/mol (basis unstated) | 298.15 | model | [3] Cao 2013 | Table IV, p. 9, row 2 report |
Sources
Reporting papers the values were read from (a value cited from another work names that work in its row).
- Z CAO, Y TAKAKU, I OHNUMA, R KAINUMA, H ZHU, K ISHIDA, Thermodynamic assessment of the Ni-Sb binary system, Rare Metals 27, 384-392 (2008). doi:10.1016/s1001-0521(08)60150-3
- Yubi Zhang, Changrong Li, Zhenmin Du, Cuiping Guo, A thermodynamic assessment of Ni–Sb system, Calphad 32, 378-388 (2008). doi:10.1016/j.calphad.2008.02.001
- Zhanmin Cao, Wei Xie, Kunpeng Wang, Guangwei Du, Zhiyu Qiao, Thermodynamic Assessment of the In-Ni-Sb System and Predictions for Thermally Stable Contacts to InSb, Journal of Elec Materi 42, 2615-2629 (2013). doi:10.1007/s11664-013-2599-7