Co–Si phases

10 phases (tier A 8, liquid 1, needs_review 1); 9 stable in a calculated diagram. Structure types are assigned only when the stored evidence supports an assignment under the stated tier rules (tier A: standard phase name; tier B: unique Materials Project + OQMD on-hull match, DFT-supported; tier C: one structure stated by the assessment's crystallographic table, assessor-stated); other phases list candidates and are marked needs_review. Stability is from phase diagrams calculated with pycalphad from the SGTE binary collection (evidence class: model).

Data: interactive registry · full JSON · Co–Si system page · Markdown · field reference

Phases of the Co–Si system (10)
Phase	Structure	Basis	Stability (calculated)	Literature values	TDB models
DIAMOND_A4 phase:co-si:a4-diamond	C (diamond) · A4 · cF8 · Fd-3m (227)	tier A: standard phase name	stable in 2 of 2 calculated diagram(s): 300–1687 K, x(Si) 1–1	5	2
BCC_A2 phase:co-si:bcc-a2	W · A2 · cI2 · Im-3m (229)	tier A: standard phase name	not stable in 2 calculated diagram(s)	0	2
CO2SI_BETA phase:co-si:co2si-beta		needs_review	stable in 1 of 1 calculated diagram(s): 1512.3–1594.25 K, x(Si) 0.33337–0.34652	13	1
CO2SI_C37 phase:co-si:co2si-c37	Co2Si · C37 · oP12 · Pnma (62)	tier A: standard phase name	stable in 2 of 2 calculated diagram(s): 300–1603.68 K, x(Si) 0.32229–0.33776	26	2
CO3SI_D019 phase:co-si:co3si-d019	Ni3Sn · D0_19 · hP8 · P6_3/mmc (194)	tier A: standard phase name	stable in 2 of 2 calculated diagram(s): 1467.38–1500 K, x(Si) 0.25–0.25	17	2
COSI_B20 phase:co-si:cosi-b20	FeSi · B20 · cP8 · P2_13 (198)	tier A: standard phase name	stable in 2 of 2 calculated diagram(s): 300–1729.38 K, x(Si) 0.49115–0.51491	26	2
COSI2_C1 phase:co-si:cosi2-c1	CaF2 · C1 · cF12 · Fm-3m (225)	tier A: standard phase name	stable in 2 of 2 calculated diagram(s): 300–1596.91 K, x(Si) 0.66667–0.66667	23	2
FCC_A1 phase:co-si:fcc-a1	Cu · A1 · cF4 · Fm-3m (225)	tier A: standard phase name	stable in 2 of 2 calculated diagram(s): 687.99–2500 K, x(Si) 0–0.74075	5	2
HCP_A3 phase:co-si:hcp-a3	Mg · A3 · hP2 · P6_3/mmc (194)	tier A: standard phase name	stable in 2 of 2 calculated diagram(s): 300–1963.38 K, x(Si) 0–0.69033	15	2
LIQUID phase:co-si:liquid	liquid	liquid	stable in 2 of 2 calculated diagram(s): 1475.55–2500 K, x(Si) 0–1	51	2

DIAMOND_A4 (Co–Si)

Id: phase:co-si:a4-diamond; status assigned
Structure: C (diamond) · A4 · cF8 · Fd-3m (227); type st:a4-c-diamond-cf8; tier A: standard phase name; confidence high
Stoichiometry: Si 1.0000
Stability: stable in 2 of 2 calculated diagram(s): 300–1687 K, x(Si) 1–1
Literature: 5 values (5 accepted) from 2 papers
Interactive: phase registry entry

Names (6): corpus: corpus:phase:co-si:a4-diamond, corpus:phase:co-si:diamond-a4
paper: paper:10.1016/0364-5916(92)90003-g:Si, paper:10.1016/j.calphad.2006.06.001:(Si)
tdb: tdb:CoSi-06Zha.tdb:DIAMOND_A4, tdb:CoSi-92Cho-LB.tdb:DIAMOND_A4

TDB models of DIAMOND_A4 (2): PHASE and CONSTITUENT statements as written

CoSi-06Zha.tdb: DIAMOND_A4, type code %, sha256 849716b03f938610…

43: PHASE DIAMOND_A4 % 1 1 !
44: CONST DIAMOND_A4 : SI : !

CoSi-92Cho-LB.tdb: DIAMOND_A4, type code %, sha256 9fb5aa520ab17aa5…

49: PHASE DIAMOND_A4 % 1 1 !
50: CONST DIAMOND_A4 : SI : !

Example references (3 of 3; assessments first):

doi:10.1016/j.calphad.2006.06.001 Lijun Zhang, Yong Du, Honghui Xu, Zhu Pan, Experimental investigation and thermodynamic description of the Co–Si system, Calphad 30, 470-481 (2006).
assessment that models this phase; reports values for this phase
doi:10.1016/0364-5916(92)90003-G S.-D. Choi, Calphad, 16, 151-59(1992).
assessment that models this phase; reports values for this phase
doi:10.2320/jinstmet1937.1.3_135 Uichi Haschimoto, The Equilibrium Diagram of the Cobalt-Silicon system, J.Japan Inst.Metals 1, 135-143 (1937).
cited as the source of values for this phase

BCC_A2 (Co–Si)

Id: phase:co-si:bcc-a2; status assigned
Structure: W · A2 · cI2 · Im-3m (229); type st:a2-w-ci2; tier A: standard phase name; confidence high
Stability: not stable in 2 calculated diagram(s)
Literature: 0 values (0 accepted) from 0 papers
Interactive: phase registry entry

Names (3): corpus: corpus:phase:co-si:bcc-a2
tdb: tdb:CoSi-06Zha.tdb:BCC_A2, tdb:CoSi-92Cho-LB.tdb:BCC_A2

TDB models of BCC_A2 (2): PHASE and CONSTITUENT statements as written

CoSi-06Zha.tdb: BCC_A2, type code %B, sha256 849716b03f938610…

33: PHASE BCC_A2 %B 2 1 3 !
34: CONST BCC_A2 : CO SI : VA : !

CoSi-92Cho-LB.tdb: BCC_A2, type code %B, sha256 9fb5aa520ab17aa5…

39: PHASE BCC_A2 %B 2 1 3 !
40: CONST BCC_A2 : CO SI : VA : !

Example references (2 of 2; assessments first):

doi:10.1016/0364-5916(92)90003-G S.-D. Choi, Calphad, 16, 151-59(1992).
assessment that models this phase
doi:10.1016/j.calphad.2006.06.001 Lijun Zhang, Yong Du, Honghui Xu, Zhu Pan, Experimental investigation and thermodynamic description of the Co–Si system, Calphad 30, 470-481 (2006).
assessment that models this phase

CO2SI_BETA (Co–Si)

Id: phase:co-si:co2si-beta; status needs_review
No structure assigned. Why: no_structure_token; off_stoichiometric_model; sgte_mmc2_row_incomplete
Candidate (sgte_mmc2): (Co2Si) — Hallstedt 2025 mmc2 row for CO2SI_BETA: beta-Co2Si
Stability: stable in 1 of 1 calculated diagram(s): 1512.3–1594.25 K, x(Si) 0.33337–0.34652
Literature: 13 values (13 accepted) from 1 papers
Interactive: phase registry entry

Names (3): corpus: corpus:phase:co-si:co2si-beta
paper: paper:10.1016/j.calphad.2006.06.001:βCo2Si
tdb: tdb:CoSi-06Zha.tdb:CO2SI_BETA

TDB models of CO2SI_BETA (1): PHASE and CONSTITUENT statements as written

CoSi-06Zha.tdb: CO2SI_BETA, type code %, sha256 849716b03f938610…

58: PHASE CO2SI_BETA % 2 2 1 !
59: CONST CO2SI_BETA : CO% SI : CO SI% : !

Example references (4 of 4; assessments first):

doi:10.1016/j.calphad.2006.06.001 Lijun Zhang, Yong Du, Honghui Xu, Zhu Pan, Experimental investigation and thermodynamic description of the Co–Si system, Calphad 30, 470-481 (2006).
assessment that models this phase; reports values for this phase
doi:10.1002/srin.193400094 Rudolf Vogel, Kurt Rosenthal, Das Zustandsschaubild Kobalt-Silizium, Archiv für das Eisenhüttenwesen 7, 689-691 (1934).
cited as the source of values for this phase
doi:10.2320/jinstmet1937.1.3_135 Uichi Haschimoto, The Equilibrium Diagram of the Cobalt-Silicon system, J.Japan Inst.Metals 1, 135-143 (1937).
cited as the source of values for this phase
doi:10.1007/bf02645074 K Ishida, T Nishizawa, M. E Schlesinger, The Co-Si (Cobalt-Silicon) system, JPE 12, 578-586 (1991).
cited as the source of values for this phase

CO2SI_C37 (Co–Si)

Id: phase:co-si:co2si-c37; status assigned
Structure: Co2Si · C37 · oP12 · Pnma (62); type st:c37-co2si-op12; tier A: standard phase name; confidence high
Caveat: partitioned order/disorder model in CoSi-06Zha.tdb also describes the disordered state
Stability: stable in 2 of 2 calculated diagram(s): 300–1603.68 K, x(Si) 0.32229–0.33776
Literature: 26 values (24 accepted) from 2 papers
Interactive: phase registry entry

Names (5): corpus: corpus:phase:co-si:co2si-c37
paper: paper:10.1016/0364-5916(92)90003-g:Co2Si, paper:10.1016/j.calphad.2006.06.001:αCo2Si
tdb: tdb:CoSi-06Zha.tdb:CO2SI_C37, tdb:CoSi-92Cho-LB.tdb:CO2SI_C37

TDB models of CO2SI_C37 (2): PHASE and CONSTITUENT statements as written

CoSi-06Zha.tdb: CO2SI_C37, type code %, sha256 849716b03f938610…

53: PHASE CO2SI_C37 % 2 2 1 !
54: CONST CO2SI_C37 : CO% SI : CO SI% : !

CoSi-92Cho-LB.tdb: CO2SI_C37, type code %, sha256 9fb5aa520ab17aa5…

59: PHASE CO2SI_C37 % 2 2 1 !
60: CONST CO2SI_C37 : CO : SI : !

Example references (6 of 6; assessments first):

doi:10.1016/j.calphad.2006.06.001 Lijun Zhang, Yong Du, Honghui Xu, Zhu Pan, Experimental investigation and thermodynamic description of the Co–Si system, Calphad 30, 470-481 (2006).
assessment that models this phase; reports values for this phase
doi:10.1016/0364-5916(92)90003-G S.-D. Choi, Calphad, 16, 151-59(1992).
assessment that models this phase; reports values for this phase
doi:10.1002/srin.193400094 Rudolf Vogel, Kurt Rosenthal, Das Zustandsschaubild Kobalt-Silizium, Archiv für das Eisenhüttenwesen 7, 689-691 (1934).
cited as the source of values for this phase
doi:10.2320/jinstmet1937.1.3_135 Uichi Haschimoto, The Equilibrium Diagram of the Cobalt-Silicon system, J.Japan Inst.Metals 1, 135-143 (1937).
cited as the source of values for this phase
doi:10.1007/bf02645074 K Ishida, T Nishizawa, M. E Schlesinger, The Co-Si (Cobalt-Silicon) system, JPE 12, 578-586 (1991).
cited as the source of values for this phase
doi:10.1016/0001-6160(72)90001-6 J Van Den Boomgaard, F.M.A Carpay, The eutectoid Co3Si phase in the Co-Si system, Acta Metallurgica 20, 473-476 (1972).
cited as the source of values for this phase

CO3SI_D019 (Co–Si)

Id: phase:co-si:co3si-d019; status assigned
Structure: Ni3Sn · D0_19 · hP8 · P6_3/mmc (194); type st:d0-19-ni3sn-hp8; tier A: standard phase name; confidence high
Stoichiometry: Co 0.7500, Si 0.2500
Stability: stable in 2 of 2 calculated diagram(s): 1467.38–1500 K, x(Si) 0.25–0.25
Literature: 17 values (17 accepted) from 2 papers
Interactive: phase registry entry

Names (5): corpus: corpus:phase:co-si:co3si-d019
paper: paper:10.1016/0364-5916(92)90003-g:Co3Si, paper:10.1016/j.calphad.2006.06.001:αCo3Si
tdb: tdb:CoSi-06Zha.tdb:CO3SI_D019, tdb:CoSi-92Cho-LB.tdb:CO3SI_D019

TDB models of CO3SI_D019 (2): PHASE and CONSTITUENT statements as written

CoSi-06Zha.tdb: CO3SI_D019, type code %, sha256 849716b03f938610…

48: PHASE CO3SI_D019 % 2 3 1 !
49: CONST CO3SI_D019 : CO : SI : !

CoSi-92Cho-LB.tdb: CO3SI_D019, type code %, sha256 9fb5aa520ab17aa5…

54: PHASE CO3SI_D019 % 2 3 1 !
55: CONST CO3SI_D019 : CO : SI : !

Example references (5 of 5; assessments first):

doi:10.1016/j.calphad.2006.06.001 Lijun Zhang, Yong Du, Honghui Xu, Zhu Pan, Experimental investigation and thermodynamic description of the Co–Si system, Calphad 30, 470-481 (2006).
assessment that models this phase; reports values for this phase
doi:10.1016/0364-5916(92)90003-G S.-D. Choi, Calphad, 16, 151-59(1992).
assessment that models this phase; reports values for this phase
doi:10.1002/srin.193400094 Rudolf Vogel, Kurt Rosenthal, Das Zustandsschaubild Kobalt-Silizium, Archiv für das Eisenhüttenwesen 7, 689-691 (1934).
cited as the source of values for this phase
doi:10.1016/0001-6160(72)90001-6 J Van Den Boomgaard, F.M.A Carpay, The eutectoid Co3Si phase in the Co-Si system, Acta Metallurgica 20, 473-476 (1972).
cited as the source of values for this phase
doi:10.2320/jinstmet1937.1.3_135 Uichi Haschimoto, The Equilibrium Diagram of the Cobalt-Silicon system, J.Japan Inst.Metals 1, 135-143 (1937).
cited as the source of values for this phase

COSI_B20 (Co–Si)

Id: phase:co-si:cosi-b20; status assigned
Structure: FeSi · B20 · cP8 · P2_13 (198); type st:b20-fesi-cp8; tier A: standard phase name; confidence high
Caveat: partitioned order/disorder model in CoSi-06Zha.tdb also describes the disordered state
Stability: stable in 2 of 2 calculated diagram(s): 300–1729.38 K, x(Si) 0.49115–0.51491
Literature: 26 values (24 accepted) from 2 papers
Interactive: phase registry entry

Names (5): corpus: corpus:phase:co-si:cosi-b20
paper: paper:10.1016/0364-5916(92)90003-g:CoSi, paper:10.1016/j.calphad.2006.06.001:CoSi
tdb: tdb:CoSi-06Zha.tdb:COSI_B20, tdb:CoSi-92Cho-LB.tdb:COSI_B20

TDB models of COSI_B20 (2): PHASE and CONSTITUENT statements as written

CoSi-06Zha.tdb: COSI_B20, type code %, sha256 849716b03f938610…

63: PHASE COSI_B20 % 2 1 1 !
64: CONST COSI_B20 : CO% SI : CO SI% : !

CoSi-92Cho-LB.tdb: COSI_B20, type code %, sha256 9fb5aa520ab17aa5…

64: PHASE COSI_B20 % 2 1 1 !
65: CONST COSI_B20 : CO : SI : !

Example references (4 of 4; assessments first):

doi:10.1016/j.calphad.2006.06.001 Lijun Zhang, Yong Du, Honghui Xu, Zhu Pan, Experimental investigation and thermodynamic description of the Co–Si system, Calphad 30, 470-481 (2006).
assessment that models this phase; reports values for this phase
doi:10.1016/0364-5916(92)90003-G S.-D. Choi, Calphad, 16, 151-59(1992).
assessment that models this phase; reports values for this phase
doi:10.2320/jinstmet1937.1.3_135 Uichi Haschimoto, The Equilibrium Diagram of the Cobalt-Silicon system, J.Japan Inst.Metals 1, 135-143 (1937).
cited as the source of values for this phase
doi:10.1002/srin.193400094 Rudolf Vogel, Kurt Rosenthal, Das Zustandsschaubild Kobalt-Silizium, Archiv für das Eisenhüttenwesen 7, 689-691 (1934).
cited as the source of values for this phase

COSI2_C1 (Co–Si)

Id: phase:co-si:cosi2-c1; status assigned
Structure: CaF2 · C1 · cF12 · Fm-3m (225); type st:c1-caf2-cf12; tier A: standard phase name; confidence high
Caveat: DFT agrees: on-hull mp-aaaaadnn and oqmd-5256, space group 225
Stoichiometry: Co 0.3333, Si 0.6667
Stability: stable in 2 of 2 calculated diagram(s): 300–1596.91 K, x(Si) 0.66667–0.66667
Literature: 23 values (21 accepted) from 2 papers
Interactive: phase registry entry

Names (7): corpus: corpus:phase:co-si:cosi2-c1
mp: mp:mp-aaaaadnn
oqmd: oqmd:oqmd-5256
paper: paper:10.1016/0364-5916(92)90003-g:CoSi2, paper:10.1016/j.calphad.2006.06.001:CoSi2
tdb: tdb:CoSi-06Zha.tdb:COSI2_C1, tdb:CoSi-92Cho-LB.tdb:COSI2_C1

TDB models of COSI2_C1 (2): PHASE and CONSTITUENT statements as written

CoSi-06Zha.tdb: COSI2_C1, type code %, sha256 849716b03f938610…

68: PHASE COSI2_C1 % 2 1 2 !
69: CONST COSI2_C1 : CO : SI : !

CoSi-92Cho-LB.tdb: COSI2_C1, type code %, sha256 9fb5aa520ab17aa5…

69: PHASE COSI2_C1 % 2 1 2 !
70: CONST COSI2_C1 : CO : SI : !

Example references (3 of 3; assessments first):

doi:10.1016/j.calphad.2006.06.001 Lijun Zhang, Yong Du, Honghui Xu, Zhu Pan, Experimental investigation and thermodynamic description of the Co–Si system, Calphad 30, 470-481 (2006).
assessment that models this phase; reports values for this phase
doi:10.1016/0364-5916(92)90003-G S.-D. Choi, Calphad, 16, 151-59(1992).
assessment that models this phase; reports values for this phase
doi:10.2320/jinstmet1937.1.3_135 Uichi Haschimoto, The Equilibrium Diagram of the Cobalt-Silicon system, J.Japan Inst.Metals 1, 135-143 (1937).
cited as the source of values for this phase

FCC_A1 (Co–Si)

Id: phase:co-si:fcc-a1; status assigned
Structure: Cu · A1 · cF4 · Fm-3m (225); type st:a1-cu-cf4; tier A: standard phase name; confidence high
Stability: stable in 2 of 2 calculated diagram(s): 687.99–2500 K, x(Si) 0–0.74075
Literature: 5 values (5 accepted) from 2 papers
Interactive: phase registry entry

Names (5): corpus: corpus:phase:co-si:fcc-a1
paper: paper:10.1016/0364-5916(92)90003-g:α-Co, paper:10.1016/j.calphad.2006.06.001:(αCo)
tdb: tdb:CoSi-06Zha.tdb:FCC_A1, tdb:CoSi-92Cho-LB.tdb:FCC_A1

TDB models of FCC_A1 (2): PHASE and CONSTITUENT statements as written

CoSi-06Zha.tdb: FCC_A1, type code %A, sha256 849716b03f938610…

28: PHASE FCC_A1 %A 2 1 1 !
29: CONST FCC_A1 : CO SI : VA : !

CoSi-92Cho-LB.tdb: FCC_A1, type code %A, sha256 9fb5aa520ab17aa5…

34: PHASE FCC_A1 %A 2 1 1 !
35: CONST FCC_A1 : CO SI : VA : !

Example references (2 of 2; assessments first):

doi:10.1016/j.calphad.2006.06.001 Lijun Zhang, Yong Du, Honghui Xu, Zhu Pan, Experimental investigation and thermodynamic description of the Co–Si system, Calphad 30, 470-481 (2006).
assessment that models this phase; reports values for this phase
doi:10.1016/0364-5916(92)90003-G S.-D. Choi, Calphad, 16, 151-59(1992).
assessment that models this phase; reports values for this phase

HCP_A3 (Co–Si)

Id: phase:co-si:hcp-a3; status assigned
Structure: Mg · A3 · hP2 · P6_3/mmc (194); type st:a3-mg-hp2; tier A: standard phase name; confidence high
Stability: stable in 2 of 2 calculated diagram(s): 300–1963.38 K, x(Si) 0–0.69033
Literature: 15 values (15 accepted) from 2 papers
Interactive: phase registry entry

Names (5): corpus: corpus:phase:co-si:hcp-a3
paper: paper:10.1016/0364-5916(92)90003-g:ε-Co, paper:10.1016/j.calphad.2006.06.001:(εCo)
tdb: tdb:CoSi-06Zha.tdb:HCP_A3, tdb:CoSi-92Cho-LB.tdb:HCP_A3

TDB models of HCP_A3 (2): PHASE and CONSTITUENT statements as written

CoSi-06Zha.tdb: HCP_A3, type code %A, sha256 849716b03f938610…

38: PHASE HCP_A3 %A 2 1 0.5 !
39: CONST HCP_A3 : CO SI : VA : !

CoSi-92Cho-LB.tdb: HCP_A3, type code %A, sha256 9fb5aa520ab17aa5…

44: PHASE HCP_A3 %A 2 1 0.5 !
45: CONST HCP_A3 : CO SI : VA : !

Example references (2 of 2; assessments first):

doi:10.1016/j.calphad.2006.06.001 Lijun Zhang, Yong Du, Honghui Xu, Zhu Pan, Experimental investigation and thermodynamic description of the Co–Si system, Calphad 30, 470-481 (2006).
assessment that models this phase; reports values for this phase
doi:10.1016/0364-5916(92)90003-G S.-D. Choi, Calphad, 16, 151-59(1992).
assessment that models this phase; reports values for this phase

LIQUID (Co–Si)

Id: phase:co-si:liquid; status assigned
Structure: liquid; type st:liquid; liquid; confidence high
Stability: stable in 2 of 2 calculated diagram(s): 1475.55–2500 K, x(Si) 0–1
Literature: 51 values (51 accepted) from 2 papers
Interactive: phase registry entry

Names (5): corpus: corpus:phase:co-si:liquid
paper: paper:10.1016/0364-5916(92)90003-g:L, paper:10.1016/j.calphad.2006.06.001:L
tdb: tdb:CoSi-06Zha.tdb:LIQUID, tdb:CoSi-92Cho-LB.tdb:LIQUID

TDB models of LIQUID (2): PHASE and CONSTITUENT statements as written

CoSi-06Zha.tdb: LIQUID, type code %, sha256 849716b03f938610…

23: PHASE LIQUID:L % 1 1 !
24: CONST LIQUID:L : CO SI : !

CoSi-92Cho-LB.tdb: LIQUID, type code %, sha256 9fb5aa520ab17aa5…

29: PHASE LIQUID:L % 1 1 !
30: CONST LIQUID:L : CO SI : !

Example references (6 of 6; assessments first):

doi:10.1016/j.calphad.2006.06.001 Lijun Zhang, Yong Du, Honghui Xu, Zhu Pan, Experimental investigation and thermodynamic description of the Co–Si system, Calphad 30, 470-481 (2006).
assessment that models this phase; reports values for this phase
doi:10.1016/0364-5916(92)90003-G S.-D. Choi, Calphad, 16, 151-59(1992).
assessment that models this phase; reports values for this phase
doi:10.2320/jinstmet1937.1.3_135 Uichi Haschimoto, The Equilibrium Diagram of the Cobalt-Silicon system, J.Japan Inst.Metals 1, 135-143 (1937).
cited as the source of values for this phase
doi:10.1002/srin.193400094 Rudolf Vogel, Kurt Rosenthal, Das Zustandsschaubild Kobalt-Silizium, Archiv für das Eisenhüttenwesen 7, 689-691 (1934).
cited as the source of values for this phase
doi:10.1007/bf02645074 K Ishida, T Nishizawa, M. E Schlesinger, The Co-Si (Cobalt-Silicon) system, JPE 12, 578-586 (1991).
cited as the source of values for this phase
doi:10.1016/0001-6160(72)90001-6 J Van Den Boomgaard, F.M.A Carpay, The eutectoid Co3Si phase in the Co-Si system, Acta Metallurgica 20, 473-476 (1972).
cited as the source of values for this phase

Please cite

R. Arróyave, J. Saal, D. Shin, ORCHID-Registry: phase registry of binary systems (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23735970
R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23736065

Also cite B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0); the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work). Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

@misc{orchid_phase_registry_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Registry: phase registry of binary systems}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735970},
  url       = {https://doi.org/10.5281/zenodo.23735970},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}