Co–Si system

74 accepted literature values from 2 paper(s) (experimental 49, model 13, unspecified 12); 2 calculated phase diagram(s). 21 further extracted value(s) not accepted by the reader-agreement checks are only in the JSON/CSV.

Data: JSON · CSV · interactive explorer · interactive phase diagram · phases (10) · papers (bibliography) · Markdown

Accepted values by evidence class
Evidence class	Values
experimental	49
model	13
unspecified	12

Accepted values by property group
Property group	Values
invariant reaction	54
phase transition	14
formation	5
other property	1

Calculated phase diagrams

Binary phase diagrams calculated with pycalphad 0.11.2 from the SGTE binary collection (Hallstedt 2025, CC BY 4.0). Evidence class: model.

Assessments with a calculated phase diagram
TDB file	Assessment	SHA-256	Links
CoSi-06Zha.tdb	L. Zhang, Y. Du, H. Xu, Z. Pan, Calphad, 30, 470-81(2006). doi:10.1016/j.calphad.2006.06.001	`849716b03f938610d110fb62984db7ff0726ff00bd2e68a5a0e5c47433af5179`	viewer · TDB · JSON
CoSi-92Cho-LB.tdb	S.-D. Choi, Calphad, 16, 151-59(1992). doi:10.1016/0364-5916(92)90003-G	`9fb5aa520ab17aa5cab74dd30e406ecbd7d0ba3318df847e7d1ccdee473950c2`	viewer · TDB · JSON

Calculated three-phase invariants (model, mole fraction of the second component)
TDB file	T (K)	Phases at the invariant
CoSi-06Zha.tdb	1594.25	LIQUID (x(Si) 0.31643) + CO2SI_C37 (x(Si) 0.33297) + CO2SI_BETA (x(Si) 0.33337)
CoSi-06Zha.tdb	1585.96	COSI_B20 (x(Si) 0.51489) + LIQUID (x(Si) 0.63509) + COSI2_C1 (x(Si) 0.66667)
CoSi-06Zha.tdb	1585.96	COSI_B20 (x(Si) 0.51491) + LIQUID (x(Si) 0.63517) + COSI2_C1 (x(Si) 0.66667)
CoSi-06Zha.tdb	1576.88	CO2SI_BETA (x(Si) 0.34652) + LIQUID (x(Si) 0.37804) + COSI_B20 (x(Si) 0.49115)
CoSi-06Zha.tdb	1532.45	COSI2_C1 (x(Si) 0.66667) + LIQUID (x(Si) 0.77847) + DIAMOND_A4 (x(Si) 1)
CoSi-06Zha.tdb	1532.45	COSI2_C1 (x(Si) 0.66667) + LIQUID (x(Si) 0.77863) + DIAMOND_A4 (x(Si) 1)
CoSi-06Zha.tdb	1512.3	CO2SI_C37 (x(Si) 0.33776) + CO2SI_BETA (x(Si) 0.34317) + COSI_B20 (x(Si) 0.4914)
CoSi-06Zha.tdb	1509.61	FCC_A1 (x(Si) 0.13082) + HCP_A3 (x(Si) 0.15924) + LIQUID (x(Si) 0.20946)
CoSi-06Zha.tdb	1487.93	LIQUID (x(Si) 0.24267) + CO3SI_D019 (x(Si) 0.25) + CO2SI_C37 (x(Si) 0.32401)
CoSi-06Zha.tdb	1475.55	HCP_A3 (x(Si) 0.18563) + LIQUID (x(Si) 0.23231) + CO3SI_D019 (x(Si) 0.25)
CoSi-06Zha.tdb	1467.38	HCP_A3 (x(Si) 0.18891) + CO3SI_D019 (x(Si) 0.25) + CO2SI_C37 (x(Si) 0.32229)
CoSi-92Cho-LB.tdb	1963.38	LIQUID (x(Si) 0.51481) + HCP_A3 (x(Si) 0.55527) + FCC_A1 (x(Si) 0.55791)
CoSi-92Cho-LB.tdb	1758.89	HCP_A3 (x(Si) 0.69033) + FCC_A1 (x(Si) 0.69201) + LIQUID (x(Si) 0.72173)
CoSi-92Cho-LB.tdb	1588.89	COSI_B20 (x(Si) 0.5) + LIQUID (x(Si) 0.63052) + COSI2_C1 (x(Si) 0.66667)
CoSi-92Cho-LB.tdb	1588.89	COSI_B20 (x(Si) 0.5) + LIQUID (x(Si) 0.63023) + COSI2_C1 (x(Si) 0.66667)
CoSi-92Cho-LB.tdb	1588.89	COSI_B20 (x(Si) 0.5) + LIQUID (x(Si) 0.63063) + COSI2_C1 (x(Si) 0.66667)
CoSi-92Cho-LB.tdb	1564.79	CO2SI_C37 (x(Si) 0.33333) + LIQUID (x(Si) 0.3815) + COSI_B20 (x(Si) 0.5)
CoSi-92Cho-LB.tdb	1564.79	CO2SI_C37 (x(Si) 0.33333) + LIQUID (x(Si) 0.38166) + COSI_B20 (x(Si) 0.5)
CoSi-92Cho-LB.tdb	1530.79	COSI2_C1 (x(Si) 0.66667) + LIQUID (x(Si) 0.78879) + DIAMOND_A4 (x(Si) 1)
CoSi-92Cho-LB.tdb	1530.79	COSI2_C1 (x(Si) 0.66667) + LIQUID (x(Si) 0.78904) + DIAMOND_A4 (x(Si) 1)
CoSi-92Cho-LB.tdb	1526.23	FCC_A1 (x(Si) 0.16288) + HCP_A3 (x(Si) 0.16901) + LIQUID (x(Si) 0.2213)
CoSi-92Cho-LB.tdb	1482.7	LIQUID (x(Si) 0.24778) + CO3SI_D019 (x(Si) 0.25) + CO2SI_C37 (x(Si) 0.33333)
CoSi-92Cho-LB.tdb	1482.7	LIQUID (x(Si) 0.2479) + CO3SI_D019 (x(Si) 0.25) + CO2SI_C37 (x(Si) 0.33333)
CoSi-92Cho-LB.tdb	1482.22	HCP_A3 (x(Si) 0.19075) + LIQUID (x(Si) 0.24535) + CO3SI_D019 (x(Si) 0.25)
CoSi-92Cho-LB.tdb	1482.22	HCP_A3 (x(Si) 0.19073) + LIQUID (x(Si) 0.24533) + CO3SI_D019 (x(Si) 0.25)
CoSi-92Cho-LB.tdb	1474.88	HCP_A3 (x(Si) 0.19101) + CO3SI_D019 (x(Si) 0.25) + CO2SI_C37 (x(Si) 0.33333)
CoSi-92Cho-LB.tdb	1474.88	HCP_A3 (x(Si) 0.19102) + CO3SI_D019 (x(Si) 0.25) + CO2SI_C37 (x(Si) 0.33333)

Convex hulls: Materials Project DFT hull · OQMD DFT hull · CALPHAD hull CoSi-92Cho-LB

Invariant reactions (literature)

Invariant reactions reported in the literature for the Co–Si system (54)
T (K)	Reaction / phases	Compositions (mole fraction)	Class	Source	Location
1738	congruent melting: L -> CoSi	L: Si 0.5; CoSi: Si 0.5	experimental	[1] Zhang 2006 cites Kalishevich 1964	Table 5, p. 9, row 35 report
1733	congruent melting: L -> CoSi	L: Si 0.5; CoSi: Si 0.5	experimental	[1] Zhang 2006 cites Haschimoto 1937 doi	Table 5, p. 9, row 34 report
1730	congruent melting: L -> CoSi	L: Si 0.5; CoSi: Si 0.5	unspecified	[1] Zhang 2006	Table 5, p. 9, row 36 report
1605.15	congruent melting: L -> βCo2Si	L: Si 0.333; βCo2Si: Si 0.333	experimental	[1] Zhang 2006 cites Haschimoto 1937 doi	Table 5, p. 9, row 32 report
1605.15	congruent melting: L -> βCo2Si	L: Si 0.333; βCo2Si: Si 0.333	experimental	[1] Zhang 2006 cites Vogel 1934 doi	Table 5, p. 9, row 31 report
1600	congruent melting: L -> βCo2Si	L: Si 0.333; βCo2Si: Si 0.333	unspecified	[1] Zhang 2006	Table 5, p. 9, row 33 report
1599	congruent melting: L -> CoSi2	L: Si 0.667; CoSi2: Si 0.667	experimental	[1] Zhang 2006 cites Haschimoto 1937 doi	Table 5, p. 9, row 37 report
1595	congruent melting: L -> CoSi2	L: Si 0.667; CoSi2: Si 0.667	experimental	[1] Zhang 2006 cites Kalishevich 1968	Table 5, p. 9, row 38 report
1593	peritectic: L + βCo2Si -> αCo2Si	L: Si 0.31; βCo2Si: Si 0.326; αCo2Si: Si 0.33	experimental	[1] Zhang 2006 cites Ishida 1991 doi	Table 5, p. 9, row 15 report
1593	congruent melting: L -> CoSi2	L: Si 0.667; CoSi2: Si 0.667	unspecified	[1] Zhang 2006	Table 5, p. 9, row 40 report
1592	peritectic: L + βCo2Si -> αCo2Si	L: Si 0.312; βCo2Si: Si 0.333; αCo2Si: Si 0.333	unspecified	[1] Zhang 2006	Table 5, p. 9, row 16 report
1591	congruent melting: L -> CoSi2	L: Si 0.667; CoSi2: Si 0.667	experimental	[1] Zhang 2006	Table 5, p. 9, row 39 report
1588.95	L=CoSi+CoSi2	L: Si 0.631; CoSi: Si 0.5; CoSi2: Si 0.667	model	[2] Soon-Don 1992	Table 3, p. 7, row 4 report
1587	eutectic: L -> CoSi + CoSi2	L: Si 0.635; CoSi: Si 0.515; CoSi2: Si 0.667	unspecified	[1] Zhang 2006	Table 5, p. 9, row 27 report
1584	eutectic: L -> CoSi + CoSi2	CoSi: Co 0.5, Si 0.5; CoSi2: Co 0.333333, Si 0.666667	experimental	[1] Zhang 2006	Table 5, p. 9, row 26 report
1583.15	L=CoSi+CoSi2	L: Si 0.618; CoSi: Si 0.5; CoSi2: Si 0.667	experimental	[2] Soon-Don 1992	Table 3, p. 7, row 3 report
1583.15	eutectic: L -> CoSi + CoSi2	L: Si 0.618; CoSi: Si 0.521; CoSi2: Si 0.667	experimental	[1] Zhang 2006 cites Haschimoto 1937 doi	Table 5, p. 9, row 25 report
1577	eutectic: L -> βCo2Si + CoSi	L: Si 0.378; βCo2Si: Si 0.346; CoSi: Si 0.491	unspecified	[1] Zhang 2006	Table 5, p. 9, row 20 report
1572	eutectic: L -> βCo2Si + CoSi	βCo2Si: Co 0.666667, Si 0.333333; CoSi: Co 0.5, Si 0.5	experimental	[1] Zhang 2006	Table 5, p. 9, row 19 report
1564.95	L=Co2Si+CoSi	L: Si 0.382; Co2Si: Si 0.333; CoSi: Si 0.5	model	[2] Soon-Don 1992	Table 3, p. 7, row 6 report
1559.15	eutectic: L -> βCo2Si + CoSi	L: Si 0.397; βCo2Si: Si 0.358; CoSi: Si 0.491	experimental	[1] Zhang 2006 cites Haschimoto 1937 doi	Table 5, p. 9, row 18 report
1559.15	L=Co2Si+CoSi	L: Si 0.397; Co2Si: Si 0.333; CoSi: Si 0.5	experimental	[2] Soon-Don 1992	Table 3, p. 7, row 5 report
1543.15	eutectic: L -> βCo2Si + CoSi	L: Si 0.396; βCo2Si: Si 0.36; CoSi: Si 0.5	experimental	[1] Zhang 2006 cites Vogel 1934 doi	Table 5, p. 9, row 17 report
1533	eutectic: L -> CoSi2 + (Si)	L: Si 0.779; CoSi2: Si 0.667; (Si): Si 1	unspecified	[1] Zhang 2006	Table 5, p. 9, row 30 report
1533	eutectic: L -> CoSi2 + (Si)	CoSi2: Co 0.333333, Si 0.666667	experimental	[1] Zhang 2006	Table 5, p. 9, row 29 report
1532.15	eutectic: L -> CoSi2 + (Si)	L: Si 0.775; CoSi2: Si 0.667; (Si): Si 0.979	experimental	[1] Zhang 2006 cites Haschimoto 1937 doi	Table 5, p. 9, row 28 report
1532.15	L=CoSi2+Si	L: Si 0.775; CoSi2: Si 0.667; Si: Si 1	experimental	[2] Soon-Don 1992	Table 3, p. 7, row 1 report
1530.85	L=CoSi2+Si	L: Si 0.789; CoSi2: Si 0.667; Si: Si 1	model	[2] Soon-Don 1992	Table 3, p. 7, row 2 report
1523.15	peritectic: L + (αCo) -> (εCo)	L: Si 0.214; (αCo): Si 0.165; (εCo): Si 0.175	experimental	[1] Zhang 2006 cites Koster 1973	Table 5, p. 9, row 1 report
1523.15	α-Co+L=ε-Co	α-Co: Si 0.165; L: Si 0.214; ε-Co: Si 0.175	experimental	[2] Soon-Don 1992	Table 3, p. 7, row 13 report
1520.55	α-Co+L=ε-Co	α-Co: Si 0.162; L: Si 0.22; ε-Co: Si 0.168	model	[2] Soon-Don 1992	Table 3, p. 7, row 14 report
1517	eutectoid: βCo2Si -> αCo2Si + CoSi	βCo2Si: Co 0.666667, Si 0.333333; αCo2Si: Co 0.666667, Si 0.333333; CoSi: Co 0.5, Si 0.5	experimental	[1] Zhang 2006	Table 5, p. 9, row 23 report
1514	peritectic: L + (αCo) -> (εCo)		experimental	[1] Zhang 2006	Table 5, p. 9, row 2 report
1511.15	eutectoid: βCo2Si -> αCo2Si + CoSi	βCo2Si: Si 0.351; αCo2Si: Si 0.341; CoSi: Si 0.491	experimental	[1] Zhang 2006 cites Haschimoto 1937 doi	Table 5, p. 9, row 22 report
1511	eutectoid: βCo2Si -> αCo2Si + CoSi	βCo2Si: Si 0.343; αCo2Si: Si 0.338; CoSi: Si 0.491	unspecified	[1] Zhang 2006	Table 5, p. 9, row 24 report
1510	peritectic: L + (αCo) -> (εCo)	L: Si 0.209; (αCo): Si 0.131; (εCo): Si 0.159	unspecified	[1] Zhang 2006	Table 5, p. 9, row 3 report
1488	peritectic: L + αCo2Si -> αCo3Si	L: Si 0.243; αCo2Si: Si 0.324; αCo3Si: Si 0.25	unspecified	[1] Zhang 2006	Table 5, p. 9, row 14 report
1487.15	L+Co2Si=Co3Si	L: Si 0.244; Co2Si: Si 0.333; Co3Si: Si 0.25	experimental	[2] Soon-Don 1992	Table 3, p. 7, row 7 report
1487	peritectic: L + αCo2Si -> αCo3Si	L: Si 0.244; αCo2Si: Co 0.666667, Si 0.333333; αCo3Si: Si 0.25	experimental	[1] Zhang 2006 cites Koster 1973	Table 5, p. 9, row 13 report
1485.15	peritectic: L + αCo2Si -> αCo3Si	L: Si 0.239; αCo2Si: Si 0.323; αCo3Si: Si 0.25	experimental	[1] Zhang 2006 cites Haschimoto 1937 doi	Table 5, p. 9, row 11 report
1483.15	peritectic: L + αCo2Si -> αCo3Si	L: Si 0.248; αCo2Si: Si 0.333; αCo3Si: Si 0.25	experimental	[1] Zhang 2006 cites Vogel 1934 doi	Table 5, p. 9, row 10 report
1483.15	peritectic: L + αCo2Si -> αCo3Si	αCo2Si: Si 0.333; αCo3Si: Si 0.25	experimental	[1] Zhang 2006 cites Boomgaard 1972 doi	Table 5, p. 9, row 12 report
1483.15	L+Co2Si=Co3Si	L: Si 0.248; Co2Si: Si 0.333; Co3Si: Si 0.25	model	[2] Soon-Don 1992	Table 3, p. 7, row 8 report
1481.35	L=ε-Co+Co3Si	L: Si 0.242; ε-Co: Si 0.188; Co3Si: Si 0.25	model	[2] Soon-Don 1992	Table 3, p. 7, row 10 report
1481.15	eutectoid: βCo2Si -> αCo2Si + CoSi	βCo2Si: Si 0.357; αCo2Si: Si 0.34; CoSi: Si 0.5	experimental	[1] Zhang 2006 cites Vogel 1934 doi	Table 5, p. 9, row 21 report
1478	eutectic: L -> αCo3Si + (εCo)	αCo3Si: Co 0.75, Si 0.25	experimental	[1] Zhang 2006	Table 5, p. 9, row 5 report
1477.15	eutectic: L -> αCo3Si + (εCo)	L: Si 0.231; αCo3Si: Si 0.25; (εCo): Si 0.184	experimental	[1] Zhang 2006 cites Koster 1973	Table 5, p. 9, row 4 report
1477.15	L=ε-Co+Co3Si	L: Si 0.231; ε-Co: Si 0.184; Co3Si: Si 0.25	experimental	[2] Soon-Don 1992	Table 3, p. 7, row 9 report
1475	eutectic: L -> αCo3Si + (εCo)	L: Si 0.232; αCo3Si: Si 0.25; (εCo): Si 0.186	unspecified	[1] Zhang 2006	Table 5, p. 9, row 6 report
1467	eutectic: αCo3Si -> (εCo) + αCo2Si	αCo3Si: Si 0.25; (εCo): Si 0.189; αCo2Si: Si 0.322	unspecified	[1] Zhang 2006	Table 5, p. 9, row 9 report
1466.15	eutectic: αCo3Si -> (εCo) + αCo2Si	αCo3Si: Si 0.25; (εCo): Si 0.181; αCo2Si: Co 0.666667, Si 0.333333	experimental	[1] Zhang 2006 cites Koster 1973	Table 5, p. 9, row 7 report
1466.15	Co3Si=ε-Co+Co2Si	Co3Si: Si 0.25; ε-Co: Si 0.181; Co2Si: Si 0.333	experimental	[2] Soon-Don 1992	Table 3, p. 7, row 11 report
1464	eutectic: αCo3Si -> (εCo) + αCo2Si	αCo3Si: Co 0.75, Si 0.25; αCo2Si: Co 0.666667, Si 0.333333	experimental	[1] Zhang 2006	Table 5, p. 9, row 8 report
1463.05	Co3Si=ε-Co+Co2Si	Co3Si: Si 0.25; ε-Co: Si 0.188; Co2Si: Si 0.333	model	[2] Soon-Don 1992	Table 3, p. 7, row 12 report

Other properties

Phase transition (14)

Phase transition, Co–Si system
Property	Value	T (K)	Phases / composition	Class	Source	Location
Phase transition	1373.15 K	1373.15	1 alloy: Co 0.88, Si 0.12	experimental	[1] Zhang 2006	Table 2, p. 4, row 1 report
Phase transition	1373.15 K	1373.15	2 alloy: Co 0.8, Si 0.2	experimental	[1] Zhang 2006	Table 2, p. 4, row 2 report
Phase transition	1373.15 K	1373.15	3 alloy: Co 0.704, Si 0.296	experimental	[1] Zhang 2006	Table 2, p. 4, row 3 report
Phase transition	1373.15 K	1373.15	4 alloy: Co 0.6, Si 0.4	experimental	[1] Zhang 2006	Table 2, p. 4, row 4 report
Phase transition	1373.15 K	1373.15	5 alloy: Co 0.4, Si 0.6	experimental	[1] Zhang 2006	Table 2, p. 4, row 5 report
Phase transition	1373.15 K	1373.15	6 alloy: Co 0.3333, Si 0.6667	experimental	[1] Zhang 2006	Table 2, p. 4, row 6 report
Phase transition	1373.15 K	1373.15	7 alloy: Co 0.28, Si 0.72	experimental	[1] Zhang 2006	Table 2, p. 4, row 7 report
Phase transition	1373.15 K	1373.15	8 alloy: Co 0.14, Si 0.86	experimental	[1] Zhang 2006	Table 2, p. 4, row 8 report
Phase transition	1597.15 K	1597.15	L=CoSi2. CoSi2: Si 0.667	model	[2] Soon-Don 1992	Table 3, p. 7, row 16 report
Phase transition	1599.15 K	1599.15	L=CoSi2. CoSi2: Si 0.667	experimental	[2] Soon-Don 1992	Table 3, p. 7, row 15 report
Phase transition	1603.85 K	1603.85	L=Co2Si Co2Si: Si 0.333	model	[2] Soon-Don 1992	Table 3, p. 7, row 20 report
Phase transition	1607.15 K	1607.15	L=Co2Si Co2Si: Si 0.333	experimental	[2] Soon-Don 1992	Table 3, p. 7, row 19 report
Phase transition	1728.25 K	1728.25	L=CoSi CoSi: Si 0.5	model	[2] Soon-Don 1992	Table 3, p. 7, row 18 report
Phase transition	1733.15 K	1733.15	L=CoSi CoSi: Si 0.5	experimental	[2] Soon-Don 1992	Table 3, p. 7, row 17 report

Formation (5)

Formation, Co–Si system
Property	Value	T (K)	Phases / composition	Class	Source	Location
Entropy of formation printed: ΔSf(298K)	-0.32 unknown	298.15	Co2Si alloy: Si 0.333333	model	[2] Soon-Don 1992	Table 4, p. 8, row 2 report
Entropy of formation printed: ΔSf(298K)	-1.2 unknown	298.15	Co2Si alloy: Si 0.333333	experimental	[2] Soon-Don 1992	Table 4, p. 8, row 1 report
Entropy of formation printed: ΔSf(298K)	-2.4 unknown	298.15	CoSi alloy: Si 0.5	model	[2] Soon-Don 1992	Table 4, p. 8, row 4 report
Entropy of formation printed: ΔSf(298K)	-3.1 unknown	298.15	CoSi alloy: Si 0.5	experimental	[2] Soon-Don 1992	Table 4, p. 8, row 3 report
Entropy of formation printed: ΔSf(298K)	0.63 unknown	298.15	CoSi2 alloy: Si 0.666667	model	[2] Soon-Don 1992	Table 4, p. 8, row 6 report

Other property (1)

Other property, Co–Si system
Property	Value	T (K)	Phases / composition	Class	Source	Location	Quote
Other printed: βCo	1.35 μB	1396		experimental	[1] Zhang 2006 cites Fernandez 1987	p. 8 report	According to Guillermet [48], TCo 0 (1396 K) and βCo (1.35 μB) of (εCo) phase are equal to those Co,Si of (αCo) phase.

Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

Lijun Zhang, Yong Du, Honghui Xu, Zhu Pan, Experimental investigation and thermodynamic description of the Co–Si system, Calphad 30, 470-481 (2006). doi:10.1016/j.calphad.2006.06.001
Choi Soon-Don, Thermodynamic analysis of the Co-Si system, Calphad 16, 151-159 (1992). doi:10.1016/0364-5916(92)90003-g

Please cite

R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23735569
R. Arróyave, J. Saal, D. Shin, ORCHID-Diagrams: calculated binary phase diagrams (version 2026.10), Zenodo (2026). doi:10.5281/zenodo.23735859
R. Arróyave, J. Saal, D. Shin, ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD) (version 2026.10), Zenodo (2026). doi:10.5281/zenodo.23735891
R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0). Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_phase_diagrams_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Diagrams: calculated binary phase diagrams}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735859},
  url       = {https://doi.org/10.5281/zenodo.23735859}
}

@misc{orchid_hulls_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD)}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735891},
  url       = {https://doi.org/10.5281/zenodo.23735891}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}