Ga–Li phases

12 phases (tier A 5, tier C 5, liquid 1, needs_review 1); 9 stable in a calculated diagram. Structure types are assigned only when the stored evidence supports an assignment under the stated tier rules (tier A: standard phase name; tier B: unique Materials Project + OQMD on-hull match, DFT-supported; tier C: one structure stated by the assessment's crystallographic table, assessor-stated); other phases list candidates and are marked needs_review. Stability is from phase diagrams calculated with pycalphad from the SGTE binary collection (evidence class: model).

Data: interactive registry · full JSON · Ga–Li system page · Markdown · field reference

Phases of the Ga–Li system (12)
Phase	Structure	Basis	Stability (calculated)	Literature values	TDB models
ORTHORHOMBIC_A11 phase:ga-li:a11-orthorhombic	alpha-Ga · A11 · oC8 · Cmce (64)	tier A: standard phase name	stable in 1 of 1 calculated diagram(s): 300–302.91 K, x(Li) 0–0	2	1
BCC_A2 phase:ga-li:bcc-a2	W · A2 · cI2 · Im-3m (229)	tier A: standard phase name	not stable in 1 calculated diagram(s)	2	1
FCC_A1 phase:ga-li:fcc-a1	Cu · A1 · cF4 · Fm-3m (225)	tier A: standard phase name	not stable in 1 calculated diagram(s)	0	1
GA14LI3 phase:ga-li:ga14li3	Ga14Li3 · hR20 · R-3m (166)	tier C: assessor-stated (Hallstedt 2025 crystallographic table)	stable in 1 of 1 calculated diagram(s): 300–354.16 K, x(Li) 0.17647–0.17647	4	1
GA2LI3 phase:ga-li:ga2li3	Al2Li3 · hR5 · R-3m (166)	tier C: assessor-stated (Hallstedt 2025 crystallographic table)	stable in 1 of 1 calculated diagram(s): 300–750 K, x(Li) 0.6–0.6	3	1
GA4LI5 phase:ga-li:ga4li5	Ga4Li5 · hP9 · P-3m1 (164)	tier C: assessor-stated (Hallstedt 2025 crystallographic table)	stable in 1 of 1 calculated diagram(s): 300–447.7 K, x(Li) 0.55556–0.55556	1	1
GA7LI2 phase:ga-li:ga7li2	Ga7Li2 · oC304 · Cmcm (63)	tier C: assessor-stated (Hallstedt 2025 crystallographic table)	stable in 1 of 1 calculated diagram(s): 300–580.04 K, x(Li) 0.22222–0.22222	4	1
GA9LI5 phase:ga-li:ga9li5		needs_review	stable in 1 of 1 calculated diagram(s): 300–652.16 K, x(Li) 0.35714–0.35714	4	1
GALI_B32 phase:ga-li:gali-b32	NaTl · B32 · cF16 · Fd-3m (227)	tier A: standard phase name	stable in 1 of 1 calculated diagram(s): 300–2499.85 K, x(Li) 0.42339–1	7	1
GALI2 phase:ga-li:gali2	GaLi2 · oC12 · Cmcm (63)	tier C: assessor-stated (Hallstedt 2025 crystallographic table)	stable in 1 of 1 calculated diagram(s): 300–783.4 K, x(Li) 0.66667–0.66667	6	1
HCP_A3 phase:ga-li:hcp-a3	Mg · A3 · hP2 · P6_3/mmc (194)	tier A: standard phase name	not stable in 1 calculated diagram(s)	0	1
LIQUID phase:ga-li:liquid	liquid	liquid	stable in 1 of 1 calculated diagram(s): 302.91–2500 K, x(Li) 0–1	13	1

ORTHORHOMBIC_A11 (Ga–Li)

Id: phase:ga-li:a11-orthorhombic; status assigned
Structure: alpha-Ga · A11 · oC8 · Cmce (64); type st:a11-alpha-ga-oc8; tier A: standard phase name; confidence high
Stoichiometry: Ga 1.0000
Stability: stable in 1 of 1 calculated diagram(s): 300–302.91 K, x(Li) 0–0
Literature: 2 values (2 accepted) from 1 papers
Interactive: phase registry entry

Names (4): corpus: corpus:phase:ga-li:a11-orthorhombic, corpus:phase:ga-li:orthorhombic-a11
paper: paper:10.1016/s1359-6462(02)00634-6:(Ga)
tdb: tdb:GaLi-03Yua.tdb:ORTHORHOMBIC_A11

TDB models of ORTHORHOMBIC_A11 (1): PHASE and CONSTITUENT statements as written

GaLi-03Yua.tdb: ORTHORHOMBIC_A11, type code %, sha256 ce31eaa1dd94d931…

49: PHASE ORTHORHOMBIC_A11 % 1 1 !
50: CONST ORTHORHOMBIC_A11 : GA : !

Example references (1 of 1; assessments first):

doi:10.1016/S1359-6462(02)00634-6 W.X. Yuan, W.J. Wang, Y.T. Song, X.L. Chen, Scripta Mater., 48, 1053-59(2003).
assessment that models this phase; reports values for this phase

BCC_A2 (Ga–Li)

Id: phase:ga-li:bcc-a2; status assigned
Structure: W · A2 · cI2 · Im-3m (229); type st:a2-w-ci2; tier A: standard phase name; confidence high
Stability: not stable in 1 calculated diagram(s)
Literature: 2 values (2 accepted) from 1 papers
Interactive: phase registry entry

Names (3): corpus: corpus:phase:ga-li:bcc-a2
paper: paper:10.1016/s1359-6462(02)00634-6:(Li)
tdb: tdb:GaLi-03Yua.tdb:BCC_A2

TDB models of BCC_A2 (1): PHASE and CONSTITUENT statements as written

GaLi-03Yua.tdb: BCC_A2, type code %B, sha256 ce31eaa1dd94d931…

39: PHASE BCC_A2 %B 2 1 3 !
40: CONST BCC_A2 : GA LI% : VA : !

Example references (1 of 1; assessments first):

doi:10.1016/S1359-6462(02)00634-6 W.X. Yuan, W.J. Wang, Y.T. Song, X.L. Chen, Scripta Mater., 48, 1053-59(2003).
assessment that models this phase; reports values for this phase

FCC_A1 (Ga–Li)

Id: phase:ga-li:fcc-a1; status assigned
Structure: Cu · A1 · cF4 · Fm-3m (225); type st:a1-cu-cf4; tier A: standard phase name; confidence high
Stability: not stable in 1 calculated diagram(s)
Literature: 0 values (0 accepted) from 0 papers
Interactive: phase registry entry

Names (2): corpus: corpus:phase:ga-li:fcc-a1
tdb: tdb:GaLi-03Yua.tdb:FCC_A1

TDB models of FCC_A1 (1): PHASE and CONSTITUENT statements as written

GaLi-03Yua.tdb: FCC_A1, type code %A, sha256 ce31eaa1dd94d931…

34: PHASE FCC_A1 %A 2 1 1 !
35: CONST FCC_A1 : GA LI : VA : !

Example references (1 of 1; assessments first):

doi:10.1016/S1359-6462(02)00634-6 W.X. Yuan, W.J. Wang, Y.T. Song, X.L. Chen, Scripta Mater., 48, 1053-59(2003).
assessment that models this phase

GA14LI3 (Ga–Li)

Id: phase:ga-li:ga14li3; status assigned
Structure: Ga14Li3 · hR20 · R-3m (166); type st:ga14li3-hr20; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated
Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) doi:10.1016/j.calphad.2025.102833
Caveat: not certain from the name or DFT alone (no_on_hull_entry_in_both, no_structure_token); structure as stated in the SGTE crystallographic table for this phase name and system
Stoichiometry: Ga 0.8235, Li 0.1765
Stability: stable in 1 of 1 calculated diagram(s): 300–354.16 K, x(Li) 0.17647–0.17647
Literature: 4 values (4 accepted) from 1 papers
Interactive: phase registry entry

Names (3): corpus: corpus:phase:ga-li:ga14li3
paper: paper:10.1016/s1359-6462(02)00634-6:Ga14Li3
tdb: tdb:GaLi-03Yua.tdb:GA14LI3

TDB models of GA14LI3 (1): PHASE and CONSTITUENT statements as written

GaLi-03Yua.tdb: GA14LI3, type code %, sha256 ce31eaa1dd94d931…

54: PHASE GA14LI3 % 2 14 3 !
55: CONST GA14LI3 : GA : LI : !

Example references (1 of 1; assessments first):

doi:10.1016/S1359-6462(02)00634-6 W.X. Yuan, W.J. Wang, Y.T. Song, X.L. Chen, Scripta Mater., 48, 1053-59(2003).
assessment that models this phase; reports values for this phase

GA2LI3 (Ga–Li)

Id: phase:ga-li:ga2li3; status assigned
Structure: Al2Li3 · hR5 · R-3m (166); type st:al2li3-hr5; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated
Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) doi:10.1016/j.calphad.2025.102833
Caveat: not certain from the name or DFT alone (dft_space_group_166_matches_3_structure_types, no_structure_token); structure as stated in the SGTE crystallographic table for this phase name and system
Stoichiometry: Ga 0.4000, Li 0.6000
Stability: stable in 1 of 1 calculated diagram(s): 300–750 K, x(Li) 0.6–0.6
Literature: 3 values (3 accepted) from 1 papers
Interactive: phase registry entry

Names (3): corpus: corpus:phase:ga-li:ga2li3
paper: paper:10.1016/s1359-6462(02)00634-6:Ga2Li3
tdb: tdb:GaLi-03Yua.tdb:GA2LI3

TDB models of GA2LI3 (1): PHASE and CONSTITUENT statements as written

GaLi-03Yua.tdb: GA2LI3, type code %, sha256 ce31eaa1dd94d931…

79: PHASE GA2LI3 % 2 2 3 !
80: CONST GA2LI3 : GA : LI : !

Example references (1 of 1; assessments first):

doi:10.1016/S1359-6462(02)00634-6 W.X. Yuan, W.J. Wang, Y.T. Song, X.L. Chen, Scripta Mater., 48, 1053-59(2003).
assessment that models this phase; reports values for this phase

GA4LI5 (Ga–Li)

Id: phase:ga-li:ga4li5; status assigned
Structure: Ga4Li5 · hP9 · P-3m1 (164); type st:ga4li5-hp9; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated
Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) doi:10.1016/j.calphad.2025.102833
Caveat: not certain from the name or DFT alone (no_on_hull_entry_in_oqmd, no_structure_token); structure as stated in the SGTE crystallographic table for this phase name and system
Stoichiometry: Ga 0.4444, Li 0.5556
Stability: stable in 1 of 1 calculated diagram(s): 300–447.7 K, x(Li) 0.55556–0.55556
Literature: 1 values (1 accepted) from 1 papers
Interactive: phase registry entry

Names (3): corpus: corpus:phase:ga-li:ga4li5
paper: paper:10.1016/s1359-6462(02)00634-6:Ga4Li5
tdb: tdb:GaLi-03Yua.tdb:GA4LI5

TDB models of GA4LI5 (1): PHASE and CONSTITUENT statements as written

GaLi-03Yua.tdb: GA4LI5, type code %, sha256 ce31eaa1dd94d931…

74: PHASE GA4LI5 % 2 4 5 !
75: CONST GA4LI5 : GA : LI : !

Example references (1 of 1; assessments first):

doi:10.1016/S1359-6462(02)00634-6 W.X. Yuan, W.J. Wang, Y.T. Song, X.L. Chen, Scripta Mater., 48, 1053-59(2003).
assessment that models this phase; reports values for this phase

GA7LI2 (Ga–Li)

Id: phase:ga-li:ga7li2; status assigned
Structure: Ga7Li2 · oC304 · Cmcm (63); type st:ga7li2-oc304; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated
Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) doi:10.1016/j.calphad.2025.102833
Caveat: not certain from the name or DFT alone (no_on_hull_entry_in_oqmd, no_structure_token); structure as stated in the SGTE crystallographic table for this phase name and system
Stoichiometry: Ga 0.7778, Li 0.2222
Stability: stable in 1 of 1 calculated diagram(s): 300–580.04 K, x(Li) 0.22222–0.22222
Literature: 4 values (4 accepted) from 1 papers
Interactive: phase registry entry

Names (3): corpus: corpus:phase:ga-li:ga7li2
paper: paper:10.1016/s1359-6462(02)00634-6:Ga7Li2
tdb: tdb:GaLi-03Yua.tdb:GA7LI2

TDB models of GA7LI2 (1): PHASE and CONSTITUENT statements as written

GaLi-03Yua.tdb: GA7LI2, type code %, sha256 ce31eaa1dd94d931…

59: PHASE GA7LI2 % 2 7 2 !
60: CONST GA7LI2 : GA : LI : !

Example references (1 of 1; assessments first):

doi:10.1016/S1359-6462(02)00634-6 W.X. Yuan, W.J. Wang, Y.T. Song, X.L. Chen, Scripta Mater., 48, 1053-59(2003).
assessment that models this phase; reports values for this phase

GA9LI5 (Ga–Li)

Id: phase:ga-li:ga9li5; status needs_review
No structure assigned. Why: no_on_hull_entry_in_both; no_structure_token; sgte_mmc2_row_incomplete
Candidate (literature_printed): (Ga9Li5) · ? — printed with a label mapped to this phase
Candidate (sgte_mmc2): (Ga9Li5) — Hallstedt 2025 mmc2 row for GA9LI5: Ga9Li5
Stoichiometry: Ga 0.6429, Li 0.3571
Stability: stable in 1 of 1 calculated diagram(s): 300–652.16 K, x(Li) 0.35714–0.35714
Literature: 4 values (4 accepted) from 1 papers
Interactive: phase registry entry

Names (3): corpus: corpus:phase:ga-li:ga9li5
paper: paper:10.1016/s1359-6462(02)00634-6:Ga9Li5
tdb: tdb:GaLi-03Yua.tdb:GA9LI5

TDB models of GA9LI5 (1): PHASE and CONSTITUENT statements as written

GaLi-03Yua.tdb: GA9LI5, type code %, sha256 ce31eaa1dd94d931…

64: PHASE GA9LI5 % 2 9 5 !
65: CONST GA9LI5 : GA : LI : !

Example references (1 of 1; assessments first):

doi:10.1016/S1359-6462(02)00634-6 W.X. Yuan, W.J. Wang, Y.T. Song, X.L. Chen, Scripta Mater., 48, 1053-59(2003).
assessment that models this phase; reports values for this phase

GALI_B32 (Ga–Li)

Id: phase:ga-li:gali-b32; status assigned
Structure: NaTl · B32 · cF16 · Fd-3m (227); type st:b32-natl-cf16; tier A: standard phase name; confidence high
Stability: stable in 1 of 1 calculated diagram(s): 300–2499.85 K, x(Li) 0.42339–1
Literature: 7 values (7 accepted) from 1 papers
Interactive: phase registry entry

Names (3): corpus: corpus:phase:ga-li:gali-b32
paper: paper:10.1016/s1359-6462(02)00634-6:GaLi
tdb: tdb:GaLi-03Yua.tdb:GALI_B32

TDB models of GALI_B32 (1): PHASE and CONSTITUENT statements as written

GaLi-03Yua.tdb: GALI_B32, type code %, sha256 ce31eaa1dd94d931…

69: PHASE GALI_B32 % 2 1 1 !
70: CONST GALI_B32 : GA% LI : LI% VA : !

Example references (1 of 1; assessments first):

doi:10.1016/S1359-6462(02)00634-6 W.X. Yuan, W.J. Wang, Y.T. Song, X.L. Chen, Scripta Mater., 48, 1053-59(2003).
assessment that models this phase; reports values for this phase

GALI2 (Ga–Li)

Id: phase:ga-li:gali2; status assigned
Structure: GaLi2 · oC12 · Cmcm (63); type st:gali2-oc12; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated
Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) doi:10.1016/j.calphad.2025.102833
Caveat: not certain from the name or DFT alone (dft_space_group_63_matches_3_structure_types, no_structure_token); structure as stated in the SGTE crystallographic table for this phase name and system
Stoichiometry: Ga 0.3333, Li 0.6667
Stability: stable in 1 of 1 calculated diagram(s): 300–783.4 K, x(Li) 0.66667–0.66667
Literature: 6 values (6 accepted) from 1 papers
Interactive: phase registry entry

Names (3): corpus: corpus:phase:ga-li:gali2
paper: paper:10.1016/s1359-6462(02)00634-6:GaLi2
tdb: tdb:GaLi-03Yua.tdb:GALI2

TDB models of GALI2 (1): PHASE and CONSTITUENT statements as written

GaLi-03Yua.tdb: GALI2, type code %, sha256 ce31eaa1dd94d931…

84: PHASE GALI2 % 2 1 2 !
85: CONST GALI2 : GA : LI : !

Example references (1 of 1; assessments first):

doi:10.1016/S1359-6462(02)00634-6 W.X. Yuan, W.J. Wang, Y.T. Song, X.L. Chen, Scripta Mater., 48, 1053-59(2003).
assessment that models this phase; reports values for this phase

HCP_A3 (Ga–Li)

Id: phase:ga-li:hcp-a3; status assigned
Structure: Mg · A3 · hP2 · P6_3/mmc (194); type st:a3-mg-hp2; tier A: standard phase name; confidence high
Stability: not stable in 1 calculated diagram(s)
Literature: 0 values (0 accepted) from 0 papers
Interactive: phase registry entry

Names (2): corpus: corpus:phase:ga-li:hcp-a3
tdb: tdb:GaLi-03Yua.tdb:HCP_A3

TDB models of HCP_A3 (1): PHASE and CONSTITUENT statements as written

GaLi-03Yua.tdb: HCP_A3, type code %A, sha256 ce31eaa1dd94d931…

44: PHASE HCP_A3 %A 2 1 0.5 !
45: CONST HCP_A3 : GA LI : VA : !

Example references (1 of 1; assessments first):

doi:10.1016/S1359-6462(02)00634-6 W.X. Yuan, W.J. Wang, Y.T. Song, X.L. Chen, Scripta Mater., 48, 1053-59(2003).
assessment that models this phase

LIQUID (Ga–Li)

Id: phase:ga-li:liquid; status assigned
Structure: liquid; type st:liquid; liquid; confidence high
Stability: stable in 1 of 1 calculated diagram(s): 302.91–2500 K, x(Li) 0–1
Literature: 13 values (13 accepted) from 1 papers
Interactive: phase registry entry

Names (4): corpus: corpus:phase:ga-li:liquid
paper: paper:10.1016/s1359-6462(02)00634-6:Liquid, paper:10.1016/s1359-6462(02)00634-6:liquid
tdb: tdb:GaLi-03Yua.tdb:LIQUID

TDB models of LIQUID (1): PHASE and CONSTITUENT statements as written

GaLi-03Yua.tdb: LIQUID, type code %, sha256 ce31eaa1dd94d931…

29: PHASE LIQUID:L % 1 1 !
30: CONST LIQUID:L : GA LI : !

Example references (1 of 1; assessments first):

doi:10.1016/S1359-6462(02)00634-6 W.X. Yuan, W.J. Wang, Y.T. Song, X.L. Chen, Scripta Mater., 48, 1053-59(2003).
assessment that models this phase; reports values for this phase

Please cite

R. Arróyave, J. Saal, D. Shin, ORCHID-Registry: phase registry of binary systems (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23735970
R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23736065

Also cite B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0); the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work). Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

@misc{orchid_phase_registry_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Registry: phase registry of binary systems}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735970},
  url       = {https://doi.org/10.5281/zenodo.23735970},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}