Ga–Li system

16 accepted literature values from 1 paper(s) (experimental 4, model 9, unspecified 3); 1 calculated phase diagram(s). 10 further extracted value(s) not accepted by the reader-agreement checks are only in the JSON/CSV.

Data: JSON · CSV · interactive explorer · interactive phase diagram · phases (12) · papers (bibliography) · Markdown

Accepted values by evidence class
Evidence class	Values
experimental	4
model	9
unspecified	3

Accepted values by property group
Property group	Values
invariant reaction	15
phase transition	1

Calculated phase diagrams

Binary phase diagrams calculated with pycalphad 0.11.2 from the SGTE binary collection (Hallstedt 2025, CC BY 4.0). Evidence class: model.

Assessments with a calculated phase diagram
TDB file	Assessment	SHA-256	Links
GaLi-03Yua.tdb	W.X. Yuan, W.J. Wang, Y.T. Song, X.L. Chen, Scripta Mater., 48, 1053-59(2003). doi:10.1016/S1359-6462(02)00634-6	`ce31eaa1dd94d931ae024ec8a545f410cd8e0f30d56c069c7b9280a0a4317600`	viewer · TDB · JSON

Calculated three-phase invariants (model, mole fraction of the second component)
TDB file	T (K)	Phases at the invariant
GaLi-03Yua.tdb	783.4	GALI_B32 (x(Li) 0.57664) + GALI2 (x(Li) 0.66667) + LIQUID (x(Li) 0.7864)
GaLi-03Yua.tdb	783.4	GALI_B32 (x(Li) 0.57665) + GALI2 (x(Li) 0.66667) + LIQUID (x(Li) 0.78652)
GaLi-03Yua.tdb	747.15	GALI_B32 (x(Li) 0.54998) + GA2LI3 (x(Li) 0.6) + GALI2 (x(Li) 0.66667)
GaLi-03Yua.tdb	652.16	LIQUID (x(Li) 0.11584) + GA9LI5 (x(Li) 0.35714) + GALI_B32 (x(Li) 0.42339)
GaLi-03Yua.tdb	580.04	LIQUID (x(Li) 0.0744) + GA7LI2 (x(Li) 0.22222) + GA9LI5 (x(Li) 0.35714)
GaLi-03Yua.tdb	580.04	LIQUID (x(Li) 0.07436) + GA7LI2 (x(Li) 0.22222) + GA9LI5 (x(Li) 0.35714)
GaLi-03Yua.tdb	580.04	LIQUID (x(Li) 0.07468) + GA7LI2 (x(Li) 0.22222) + GA9LI5 (x(Li) 0.35714)
GaLi-03Yua.tdb	447.7	GALI_B32 (x(Li) 0.50014) + GA4LI5 (x(Li) 0.55556) + GA2LI3 (x(Li) 0.6)
GaLi-03Yua.tdb	438.9	GALI2 (x(Li) 0.66667) + LIQUID (x(Li) 0.97854) + GALI_B32 (x(Li) 0.99909)
GaLi-03Yua.tdb	438.9	GALI2 (x(Li) 0.66667) + LIQUID (x(Li) 0.97855) + GALI_B32 (x(Li) 0.99909)
GaLi-03Yua.tdb	354.16	LIQUID (x(Li) 2.700e-4) + GA14LI3 (x(Li) 0.17647) + GA7LI2 (x(Li) 0.22222)
GaLi-03Yua.tdb	354.16	LIQUID (x(Li) 2.600e-4) + GA14LI3 (x(Li) 0.17647) + GA7LI2 (x(Li) 0.22222)
GaLi-03Yua.tdb	354.16	LIQUID (x(Li) 2.700e-4) + GA14LI3 (x(Li) 0.17647) + GA7LI2 (x(Li) 0.22222)
GaLi-03Yua.tdb	302.91	ORTHORHOMBIC_A11 (x(Li) 0) + LIQUID (x(Li) 1.000e-5) + GA14LI3 (x(Li) 0.17647)
GaLi-03Yua.tdb	302.91	ORTHORHOMBIC_A11 (x(Li) 0) + LIQUID (x(Li) 1.000e-5) + GA14LI3 (x(Li) 0.17647)

Convex hulls: Materials Project DFT hull · OQMD DFT hull

Invariant reactions (literature)

Invariant reactions reported in the literature for the Ga–Li system (15)
T (K)	Reaction / phases	Compositions (mole fraction)	Class	Source	Location
788	Liquid + GaLi -> GaLi2	Liquid: Li 0.715; GaLi: Li 0.58; GaLi2: Li 0.667	experimental	[1] Yuan 2003 cites Yatsenko 1973	Table 3, p. 6, row 12 report
788	Liquid + GaLi -> GaLi2	Liquid: Li 0.78; GaLi: Li 0.58; GaLi2: Li 0.667	model	[1] Yuan 2003	Table 3, p. 6, row 11 report
750	GaLi + GaLi2 -> Ga2Li3	GaLi: Li 0.56; GaLi2: Li 0.667; Ga2Li3: Li 0.6	experimental	[1] Yuan 2003 cites Yatsenko 1973	Table 3, p. 6, row 14 report
750	GaLi + GaLi2 -> Ga2Li3	GaLi: Li 0.57; GaLi2: Li 0.667; Ga2Li3: Li 0.6	model	[1] Yuan 2003	Table 3, p. 6, row 13 report
654	Liquid + GaLi -> Ga9Li5	Liquid: Li 0.11; GaLi: Li 0.5; Ga9Li5: Li 0.357	unspecified	[1] Yuan 2003 cites Tillard-Charbonnel 1998	Table 3, p. 6, row 10 report
654	Liquid + GaLi -> Ga9Li5	Liquid: Li 0.12; GaLi: Li 0.44; Ga9Li5: Li 0.357	model	[1] Yuan 2003	Table 3, p. 6, row 9 report
575	Liquid + Ga9Li5 -> Ga7Li2	Liquid: Li 0.08; Ga9Li5: Li 0.357; Ga7Li2: Li 0.222	model	[1] Yuan 2003	Table 3, p. 6, row 7 report
575	Liquid + Ga9Li5 -> Ga7Li2	Liquid: Li 0.06; Ga9Li5: Li 0.357; Ga7Li2: Li 0.222	unspecified	[1] Yuan 2003 cites Tillard-Charbonnel 1998	Table 3, p. 6, row 8 report
475	GaLi + Ga2Li3 -> Ga4Li5	GaLi: Li 0.5; Ga2Li3: Li 0.6; Ga4Li5: Li 0.556	model	[1] Yuan 2003	Table 3, p. 6, row 15 report
440	eutectic: Liquid -> GaLi2 + (Li)	Liquid: Li 0.975; GaLi2: Li 0.667; (Li): Li 1	experimental	[1] Yuan 2003 cites Th 1970	Table 3, p. 6, row 4 report
439	eutectic: Liquid -> GaLi2 + (Li)	Liquid: Li 0.979; GaLi2: Li 0.667; (Li): Li 1	model	[1] Yuan 2003	Table 3, p. 6, row 3 report
347	Liquid + Ga7Li2 -> Ga14Li3	Liquid: Li 0.005; Ga7Li2: Li 0.222; Ga14Li3: Li 0.176	unspecified	[1] Yuan 2003 cites Tillard-Charbonnel 1998	Table 3, p. 6, row 6 report
347	Liquid + Ga7Li2 -> Ga14Li3	Liquid: Li 0.001; Ga7Li2: Li 0.222; Ga14Li3: Li 0.176	model	[1] Yuan 2003	Table 3, p. 6, row 5 report
302	eutectic: Liquid -> (Ga) + Ga14Li3	Liquid: Li 8.000e-5; (Ga): Li 0; Ga14Li3: Li 0.176	model	[1] Yuan 2003	Table 3, p. 6, row 1 report
300.5	eutectic: Liquid -> (Ga) + Ga14Li3	Liquid: Li 0.017; (Ga): Li 0; Ga14Li3: Li 0.176	experimental	[1] Yuan 2003 cites Yatsenko 1973	Table 3, p. 6, row 2 report

Other properties

Phase transition (1)

Phase transition, Ga–Li system
Property	Value	T (K)	Phases / composition	Class	Source	Location	Quote
Phase transition	1003.15 K	1003.15	congruent transformation	model	[1] Yuan 2003	p. 4 report	The calculated congruent-melting point of GaLi phase is 730 °C at 0.50 mol fraction of Li, which is in good agreement with the work of [13,14].

Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

W.X. Yuan, W.J. Wang, Y.T. Song, X.L. Chen, Thermodynamic descriptions of the Ga–Li system, Scripta Materialia 48, 1053-1059 (2003). doi:10.1016/s1359-6462(02)00634-6

Please cite

R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23735569
R. Arróyave, J. Saal, D. Shin, ORCHID-Diagrams: calculated binary phase diagrams (version 2026.10), Zenodo (2026). doi:10.5281/zenodo.23735859
R. Arróyave, J. Saal, D. Shin, ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD) (version 2026.10), Zenodo (2026). doi:10.5281/zenodo.23735891
R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0). Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_phase_diagrams_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Diagrams: calculated binary phase diagrams}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735859},
  url       = {https://doi.org/10.5281/zenodo.23735859}
}

@misc{orchid_hulls_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD)}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735891},
  url       = {https://doi.org/10.5281/zenodo.23735891}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}