Sb–Zn phases

24 phases (tier A 5, tier C 5, liquid 1, needs_review 11, unresolved_no_candidates 2); 20 stable in a calculated diagram. Structure types are assigned only when the stored evidence supports an assignment under the stated tier rules (tier A: standard phase name; tier B: unique Materials Project + OQMD on-hull match, DFT-supported; tier C: one structure stated by the assessment's crystallographic table, assessor-stated); other phases list candidates and are marked needs_review. Stability is from phase diagrams calculated with pycalphad from the SGTE binary collection (evidence class: model).

Data: interactive registry · full JSON · Sb–Zn system page · Markdown · field reference

Phases of the Sb–Zn system (24)
Phase	Structure	Basis	Stability (calculated)	Literature values	TDB models
RHOMBOHEDRAL_A7 phase:sb-zn:a7-rhombohedral	alpha-As · A7 · hR2 · R-3m (166)	tier A: standard phase name	stable in 7 of 7 calculated diagram(s): 300–903.78 K, x(Zn) 0–0.01694	10	7
BCC_A2 phase:sb-zn:bcc-a2	W · A2 · cI2 · Im-3m (229)	tier A: standard phase name	not stable in 7 calculated diagram(s)	0	7
FCC_A1 phase:sb-zn:fcc-a1	Cu · A1 · cF4 · Fm-3m (225)	tier A: standard phase name	not stable in 7 calculated diagram(s)	0	7
HCP_A3 phase:sb-zn:hcp-a3	Mg · A3 · hP2 · P6_3/mmc (194)	tier A: standard phase name	stable in 7 of 7 calculated diagram(s): 300–2499.55 K, x(Zn) 0.99423–1	21	7
LIQUID phase:sb-zn:liquid	liquid	liquid	stable in 7 of 7 calculated diagram(s): 682.87–2500 K, x(Zn) 0–1	73	7
SB17ZN23_H phase:sb-zn:sb17zn23-h		needs_review	stable in 1 of 1 calculated diagram(s): 764.91–833.76 K, x(Zn) 0.575–0.575	0	1
SB17ZN23_L phase:sb-zn:sb17zn23-l	Sb17Zn23 · hR22 · R-3c (167)	tier C: assessor-stated (Hallstedt 2025 crystallographic table)	stable in 1 of 1 calculated diagram(s): 489.61–764.91 K, x(Zn) 0.575–0.575	0	1
SB19ZN31 phase:sb-zn:sb19zn31	Sb2Zn3-ht1 · oP30 · Pmmn (59)	tier C: assessor-stated (Hallstedt 2025 crystallographic table)	stable in 1 of 1 calculated diagram(s): 681.25–727.92 K, x(Zn) 0.62–0.62	0	1
SB2ZN3 phase:sb-zn:sb2zn3	Sb2Zn3-ht2 · oP192 · Pccn (56)	tier C: assessor-stated (Hallstedt 2025 crystallographic table)	stable in 1 of 1 calculated diagram(s): 712.64–836.62 K, x(Zn) 0.6–0.6	0	1
SB2ZN3_ETA phase:sb-zn:sb2zn3-eta	Sb2Zn3-ht1 · oP30 · Pmmn (59)	tier C: assessor-stated (Hallstedt 2025 crystallographic table)	stable in 5 of 5 calculated diagram(s): 677.06–757.55 K, x(Zn) 0.6–0.6	15	5
SB2ZN3_HT phase:sb-zn:sb2zn3-ht		needs_review	stable in 1 of 1 calculated diagram(s): 719.86–835.51 K, x(Zn) 0.6–0.6	0	1
SB2ZN3_LT phase:sb-zn:sb2zn3-lt		needs_review	stable in 1 of 1 calculated diagram(s): 676.1–719.86 K, x(Zn) 0.6–0.6	0	1
SB2ZN3_ZETA phase:sb-zn:sb2zn3-zeta		needs_review	stable in 5 of 5 calculated diagram(s): 703.48–852.57 K, x(Zn) 0.59267–0.595	20	5
SB3ZN4_ALPHA phase:sb-zn:sb3zn4-alpha		needs_review	not stable in 3 calculated diagram(s)	9	3
SB3ZN4_ALPHA_P phase:sb-zn:sb3zn4-alpha-p		unresolved_no_candidates	not stable in 2 calculated diagram(s)	1	2
SB3ZN4_BETA phase:sb-zn:sb3zn4-beta		needs_review	stable in 3 of 3 calculated diagram(s): 300–795.32 K, x(Zn) 0.56327–0.57143	0	3
SB3ZN4_DELTA phase:sb-zn:sb3zn4-delta		needs_review	stable in 2 of 2 calculated diagram(s): 766.7–802.76 K, x(Zn) 0.559–0.559	22	2
SB3ZN4_EPS phase:sb-zn:sb3zn4-eps	Sb17Zn23 · hR22 · R-3c (167)	tier C: assessor-stated (Hallstedt 2025 crystallographic table)	stable in 2 of 2 calculated diagram(s): 300–767.62 K, x(Zn) 0.56556–0.57143	26	2
SB3ZN4_GAMMA phase:sb-zn:sb3zn4-gamma		needs_review	stable in 3 of 3 calculated diagram(s): 765.05–810.41 K, x(Zn) 0.55696–0.559	0	3
SB3ZN4_HT phase:sb-zn:sb3zn4-ht		unresolved_no_candidates	stable in 1 of 1 calculated diagram(s): 766–835.75 K, x(Zn) 0.57143–0.57143	0	1
SB3ZN4_LT phase:sb-zn:sb3zn4-lt		needs_review	stable in 1 of 1 calculated diagram(s): 338.81–766 K, x(Zn) 0.57143–0.57143	0	1
SB3ZN4_PRIME phase:sb-zn:sb3zn4-prime		needs_review	stable in 5 of 5 calculated diagram(s): 797.97–852.27 K, x(Zn) 0.55128–0.558	2	5
SB9ZN11 phase:sb-zn:sb9zn11		needs_review	stable in 1 of 1 calculated diagram(s): 764.56–801.01 K, x(Zn) 0.55–0.55	0	1
SBZN_BE phase:sb-zn:sbzn-be	CdSb · B_e · oP16 · Pbca (61)	tier A: standard phase name	stable in 7 of 7 calculated diagram(s): 300–838.84 K, x(Zn) 0.4902–0.5	62	7

RHOMBOHEDRAL_A7 (Sb–Zn)

Id: phase:sb-zn:a7-rhombohedral; status assigned
Structure: alpha-As · A7 · hR2 · R-3m (166); type st:a7-alpha-as-hr2; tier A: standard phase name; confidence high
Stability: stable in 7 of 7 calculated diagram(s): 300–903.78 K, x(Zn) 0–0.01694
Literature: 10 values (10 accepted) from 2 papers
Interactive: phase registry entry

Names (11): corpus: corpus:phase:sb-zn:a7-rhombohedral, corpus:phase:sb-zn:rhombohedral-a7
paper: paper:10.1016/j.jallcom.2006.08.035:Sb, paper:10.1016/j.tca.2022.179327:Rho(Sb)
tdb: tdb:SbZn-00Liu-LB.tdb:RHOMBOHEDRAL_A7, tdb:SbZn-07Li.tdb:RHOMBOHEDRAL_A7, tdb:SbZn-09Liu.tdb:RHOMBOHEDRAL_A7, tdb:SbZn-18Wan.tdb:RHOMBOHEDRAL_A7, tdb:SbZn-22Zha.tdb:RHOMBOHEDRAL_A7, tdb:SbZn-23Zha.tdb:RHOMBOHEDRAL_A7, tdb:SbZn-97Zab.tdb:RHOMBOHEDRAL_A7

TDB models of RHOMBOHEDRAL_A7 (7): PHASE and CONSTITUENT statements as written

SbZn-00Liu-LB.tdb: RHOMBOHEDRAL_A7, type code %, sha256 82e256183b64ede7…

54: PHASE RHOMBOHEDRAL_A7 % 1 1 !
55: CONST RHOMBOHEDRAL_A7 : SB ZN : !

SbZn-07Li.tdb: RHOMBOHEDRAL_A7, type code %, sha256 6e6072cc45a32d33…

40: PHASE RHOMBOHEDRAL_A7 % 1 1 !
41: CONST RHOMBOHEDRAL_A7 : SB : !

SbZn-09Liu.tdb: RHOMBOHEDRAL_A7, type code %, sha256 187d17f544e9280e…

43: PHASE RHOMBOHEDRAL_A7 % 1 1 !
44: CONST RHOMBOHEDRAL_A7 : SB : !

SbZn-18Wan.tdb: RHOMBOHEDRAL_A7, type code %, sha256 8427f99df3872e4e…

46: PHASE RHOMBOHEDRAL_A7 % 1 1 !
47: CONST RHOMBOHEDRAL_A7 : SB : !

SbZn-22Zha.tdb: RHOMBOHEDRAL_A7, type code %, sha256 7c5dd94e653096cd…

47: PHASE RHOMBOHEDRAL_A7 % 1 1 !
48: CONST RHOMBOHEDRAL_A7 : SB% ZN : !

SbZn-23Zha.tdb: RHOMBOHEDRAL_A7, type code %, sha256 be7f7a4bc8316cfd…

46: PHASE RHOMBOHEDRAL_A7 % 1 1 !
47: CONST RHOMBOHEDRAL_A7 : SB% ZN : !

SbZn-97Zab.tdb: RHOMBOHEDRAL_A7, type code %, sha256 dab5acfd3e531488…

40: PHASE RHOMBOHEDRAL_A7 % 1 1 !
41: CONST RHOMBOHEDRAL_A7 : SB : !

Example references (10 of 10; assessments first):

doi:10.1016/j.jallcom.2006.08.035 Jing-Bo Li, Marie-Christine Record, Jean-Claude Tedenac, A thermodynamic assessment of the Sb–Zn system, Journal of Alloys and Compounds 438, 171-177 (2007).
assessment that models this phase; reports values for this phase
doi:10.1016/j.tca.2022.179327 Jiyuan Zhang, Yuan Yuan, A coupled experimental and thermodynamic assessment of the Mg-Bi-Sb and Zn-Bi-Sb ternary system and extrapolate to the Mg-Bi-Zn-Sb system, Thermochimica Acta 716, 179327 (2022).
assessment that models this phase; reports values for this phase
doi:10.1361/105497100770339608 X. J. Liu, C. P. Wang, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the phase diagrams of the Cu-Sb and Sb-Zn systems, JPE 21, 432-442 (2000).
assessment that models this phase; cited as the source of values for this phase
doi:10.1007/s11664-017-5757-5 W. Wang, L. Yang, N. Wang, H. Zhang, Y. Jia, J. Electron. Mater., 47, 261-71(2018).
assessment that models this phase
doi:10.1016/j.calphad.2009.08.006 Ya Liu, Jean-Claude Tedenac, Thermodynamic modeling of the Cd–Sb–Zn ternary system, Calphad 33, 684-694 (2009).
assessment that models this phase
doi:10.1016/j.calphad.2022.102525 J. Zhang, Y. Yuan, Calphad, 80, 102525(2023).
assessment that models this phase
doi:10.1016/S0364-5916(97)00036-9 L.A. Zabdyr, Calphad, 21, 349-58(1997).
assessment that models this phase
doi:10.1016/s0364-5916(02)00008-1 V. Izard, M.C. Record, J.C. Tedenac, S.G. Fries, Discussion on the stability of the antimony-zinc binary phases, Calphad 25 (2001) 567–581.
cited as the source of values for this phase
doi:10.1016/0364-5916(93)90005-v L.A. Zabdyr, CALPHAD 17 (3) (1993) 269.
cited as the source of values for this phase
doi:10.1016/j.jallcom.2006.04.051 Fouzia Adjadj, El-djemai Belbacha, Malek Bouharkat, Differential calorimetric analysis of the binary system Sb–Zn, Journal of Alloys and Compounds 430, 85-91 (2007).
cited as the source of values for this phase

BCC_A2 (Sb–Zn)

Id: phase:sb-zn:bcc-a2; status assigned
Structure: W · A2 · cI2 · Im-3m (229); type st:a2-w-ci2; tier A: standard phase name; confidence high
Stability: not stable in 7 calculated diagram(s)
Literature: 0 values (0 accepted) from 0 papers
Interactive: phase registry entry

Names (8): corpus: corpus:phase:sb-zn:bcc-a2
tdb: tdb:SbZn-00Liu-LB.tdb:BCC_A2, tdb:SbZn-07Li.tdb:BCC_A2, tdb:SbZn-09Liu.tdb:BCC_A2, tdb:SbZn-18Wan.tdb:BCC_A2, tdb:SbZn-22Zha.tdb:BCC_A2, tdb:SbZn-23Zha.tdb:BCC_A2, tdb:SbZn-97Zab.tdb:BCC_A2

TDB models of BCC_A2 (7): PHASE and CONSTITUENT statements as written

SbZn-00Liu-LB.tdb: BCC_A2, type code %B, sha256 82e256183b64ede7…

44: PHASE BCC_A2 %B 2 1 3 !
45: CONST BCC_A2 : SB ZN : VA : !

SbZn-07Li.tdb: BCC_A2, type code %B, sha256 6e6072cc45a32d33…

30: PHASE BCC_A2 %B 2 1 3 !
31: CONST BCC_A2 : SB ZN : VA : !

SbZn-09Liu.tdb: BCC_A2, type code %B, sha256 187d17f544e9280e…

33: PHASE BCC_A2 %B 2 1 3 !
34: CONST BCC_A2 : SB ZN : VA : !

SbZn-18Wan.tdb: BCC_A2, type code %B, sha256 8427f99df3872e4e…

36: PHASE BCC_A2 %B 2 1 3 !
37: CONST BCC_A2 : SB ZN : VA : !

SbZn-22Zha.tdb: BCC_A2, type code %B, sha256 7c5dd94e653096cd…

37: PHASE BCC_A2 %B 2 1 3 !
38: CONST BCC_A2 : SB ZN : VA : !

SbZn-23Zha.tdb: BCC_A2, type code %B, sha256 be7f7a4bc8316cfd…

36: PHASE BCC_A2 %B 2 1 3 !
37: CONST BCC_A2 : SB ZN : VA : !

SbZn-97Zab.tdb: BCC_A2, type code %B, sha256 dab5acfd3e531488…

30: PHASE BCC_A2 %B 2 1 3 !
31: CONST BCC_A2 : SB ZN : VA : !

Example references (7 of 7; assessments first):

doi:10.1007/s11664-017-5757-5 W. Wang, L. Yang, N. Wang, H. Zhang, Y. Jia, J. Electron. Mater., 47, 261-71(2018).
assessment that models this phase
doi:10.1016/j.calphad.2009.08.006 Ya Liu, Jean-Claude Tedenac, Thermodynamic modeling of the Cd–Sb–Zn ternary system, Calphad 33, 684-694 (2009).
assessment that models this phase
doi:10.1016/j.calphad.2022.102525 J. Zhang, Y. Yuan, Calphad, 80, 102525(2023).
assessment that models this phase
doi:10.1016/j.jallcom.2006.08.035 Jing-Bo Li, Marie-Christine Record, Jean-Claude Tedenac, A thermodynamic assessment of the Sb–Zn system, Journal of Alloys and Compounds 438, 171-177 (2007).
assessment that models this phase
doi:10.1016/j.tca.2022.179327 Jiyuan Zhang, Yuan Yuan, A coupled experimental and thermodynamic assessment of the Mg-Bi-Sb and Zn-Bi-Sb ternary system and extrapolate to the Mg-Bi-Zn-Sb system, Thermochimica Acta 716, 179327 (2022).
assessment that models this phase
doi:10.1016/S0364-5916(97)00036-9 L.A. Zabdyr, Calphad, 21, 349-58(1997).
assessment that models this phase
doi:10.1361/105497100770339608 X. J. Liu, C. P. Wang, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the phase diagrams of the Cu-Sb and Sb-Zn systems, JPE 21, 432-442 (2000).
assessment that models this phase

FCC_A1 (Sb–Zn)

Id: phase:sb-zn:fcc-a1; status assigned
Structure: Cu · A1 · cF4 · Fm-3m (225); type st:a1-cu-cf4; tier A: standard phase name; confidence high
Stability: not stable in 7 calculated diagram(s)
Literature: 0 values (0 accepted) from 0 papers
Interactive: phase registry entry

Names (8): corpus: corpus:phase:sb-zn:fcc-a1
tdb: tdb:SbZn-00Liu-LB.tdb:FCC_A1, tdb:SbZn-07Li.tdb:FCC_A1, tdb:SbZn-09Liu.tdb:FCC_A1, tdb:SbZn-18Wan.tdb:FCC_A1, tdb:SbZn-22Zha.tdb:FCC_A1, tdb:SbZn-23Zha.tdb:FCC_A1, tdb:SbZn-97Zab.tdb:FCC_A1

TDB models of FCC_A1 (7): PHASE and CONSTITUENT statements as written

SbZn-00Liu-LB.tdb: FCC_A1, type code %A, sha256 82e256183b64ede7…

39: PHASE FCC_A1 %A 2 1 1 !
40: CONST FCC_A1 : SB ZN : VA : !

SbZn-07Li.tdb: FCC_A1, type code %A, sha256 6e6072cc45a32d33…

25: PHASE FCC_A1 %A 2 1 1 !
26: CONST FCC_A1 : SB ZN : VA : !

SbZn-09Liu.tdb: FCC_A1, type code %A, sha256 187d17f544e9280e…

28: PHASE FCC_A1 %A 2 1 1 !
29: CONST FCC_A1 : SB ZN : VA : !

SbZn-18Wan.tdb: FCC_A1, type code %A, sha256 8427f99df3872e4e…

31: PHASE FCC_A1 %A 2 1 1 !
32: CONST FCC_A1 : SB ZN : VA : !

SbZn-22Zha.tdb: FCC_A1, type code %A, sha256 7c5dd94e653096cd…

32: PHASE FCC_A1 %A 2 1 1 !
33: CONST FCC_A1 : SB ZN : VA : !

SbZn-23Zha.tdb: FCC_A1, type code %A, sha256 be7f7a4bc8316cfd…

31: PHASE FCC_A1 %A 2 1 1 !
32: CONST FCC_A1 : SB ZN : VA : !

SbZn-97Zab.tdb: FCC_A1, type code %A, sha256 dab5acfd3e531488…

25: PHASE FCC_A1 %A 2 1 1 !
26: CONST FCC_A1 : SB ZN : VA : !

Example references (7 of 7; assessments first):

doi:10.1007/s11664-017-5757-5 W. Wang, L. Yang, N. Wang, H. Zhang, Y. Jia, J. Electron. Mater., 47, 261-71(2018).
assessment that models this phase
doi:10.1016/j.calphad.2009.08.006 Ya Liu, Jean-Claude Tedenac, Thermodynamic modeling of the Cd–Sb–Zn ternary system, Calphad 33, 684-694 (2009).
assessment that models this phase
doi:10.1016/j.calphad.2022.102525 J. Zhang, Y. Yuan, Calphad, 80, 102525(2023).
assessment that models this phase
doi:10.1016/j.jallcom.2006.08.035 Jing-Bo Li, Marie-Christine Record, Jean-Claude Tedenac, A thermodynamic assessment of the Sb–Zn system, Journal of Alloys and Compounds 438, 171-177 (2007).
assessment that models this phase
doi:10.1016/j.tca.2022.179327 Jiyuan Zhang, Yuan Yuan, A coupled experimental and thermodynamic assessment of the Mg-Bi-Sb and Zn-Bi-Sb ternary system and extrapolate to the Mg-Bi-Zn-Sb system, Thermochimica Acta 716, 179327 (2022).
assessment that models this phase
doi:10.1016/S0364-5916(97)00036-9 L.A. Zabdyr, Calphad, 21, 349-58(1997).
assessment that models this phase
doi:10.1361/105497100770339608 X. J. Liu, C. P. Wang, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the phase diagrams of the Cu-Sb and Sb-Zn systems, JPE 21, 432-442 (2000).
assessment that models this phase

HCP_A3 (Sb–Zn)

Id: phase:sb-zn:hcp-a3; status assigned
Structure: Mg · A3 · hP2 · P6_3/mmc (194); type st:a3-mg-hp2; tier A: standard phase name; confidence high
Stability: stable in 7 of 7 calculated diagram(s): 300–2499.55 K, x(Zn) 0.99423–1
Literature: 21 values (21 accepted) from 2 papers
Interactive: phase registry entry

Names (10): corpus: corpus:phase:sb-zn:hcp-a3
paper: paper:10.1016/j.jallcom.2006.08.035:Zn, paper:10.1016/j.tca.2022.179327:Hcp(Zn)
tdb: tdb:SbZn-00Liu-LB.tdb:HCP_A3, tdb:SbZn-07Li.tdb:HCP_A3, tdb:SbZn-09Liu.tdb:HCP_A3, tdb:SbZn-18Wan.tdb:HCP_A3, tdb:SbZn-22Zha.tdb:HCP_A3, tdb:SbZn-23Zha.tdb:HCP_A3, tdb:SbZn-97Zab.tdb:HCP_A3

TDB models of HCP_A3 (7): PHASE and CONSTITUENT statements as written

SbZn-00Liu-LB.tdb: HCP_A3, type code %A, sha256 82e256183b64ede7…

49: PHASE HCP_A3 %A 2 1 0.5 !
50: CONST HCP_A3 : SB ZN : VA : !

SbZn-07Li.tdb: HCP_A3, type code %A, sha256 6e6072cc45a32d33…

35: PHASE HCP_A3 %A 2 1 0.5 !
36: CONST HCP_A3 : ZN : VA : !

SbZn-09Liu.tdb: HCP_A3, type code %A, sha256 187d17f544e9280e…

38: PHASE HCP_A3 %A 2 1 0.5 !
39: CONST HCP_A3 : SB ZN : VA : !

SbZn-18Wan.tdb: HCP_A3, type code %A, sha256 8427f99df3872e4e…

41: PHASE HCP_A3 %A 2 1 0.5 !
42: CONST HCP_A3 : SB ZN% : VA : !

SbZn-22Zha.tdb: HCP_A3, type code %A, sha256 7c5dd94e653096cd…

42: PHASE HCP_A3 %A 2 1 0.5 !
43: CONST HCP_A3 : SB ZN% : VA : !

SbZn-23Zha.tdb: HCP_A3, type code %A, sha256 be7f7a4bc8316cfd…

41: PHASE HCP_A3 %A 2 1 0.5 !
42: CONST HCP_A3 : SB ZN% : VA : !

SbZn-97Zab.tdb: HCP_A3, type code %A, sha256 dab5acfd3e531488…

35: PHASE HCP_A3 %A 2 1 0.5 !
36: CONST HCP_A3 : ZN : VA : !

Example references (10 of 11; assessments first):

doi:10.1016/j.tca.2022.179327 Jiyuan Zhang, Yuan Yuan, A coupled experimental and thermodynamic assessment of the Mg-Bi-Sb and Zn-Bi-Sb ternary system and extrapolate to the Mg-Bi-Zn-Sb system, Thermochimica Acta 716, 179327 (2022).
assessment that models this phase; reports values for this phase
doi:10.1016/j.jallcom.2006.08.035 Jing-Bo Li, Marie-Christine Record, Jean-Claude Tedenac, A thermodynamic assessment of the Sb–Zn system, Journal of Alloys and Compounds 438, 171-177 (2007).
assessment that models this phase; reports values for this phase
doi:10.1361/105497100770339608 X. J. Liu, C. P. Wang, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the phase diagrams of the Cu-Sb and Sb-Zn systems, JPE 21, 432-442 (2000).
assessment that models this phase; cited as the source of values for this phase
doi:10.1016/j.calphad.2009.08.006 Ya Liu, Jean-Claude Tedenac, Thermodynamic modeling of the Cd–Sb–Zn ternary system, Calphad 33, 684-694 (2009).
assessment that models this phase; cited as the source of values for this phase
doi:10.1007/s11664-017-5757-5 W. Wang, L. Yang, N. Wang, H. Zhang, Y. Jia, J. Electron. Mater., 47, 261-71(2018).
assessment that models this phase
doi:10.1016/j.calphad.2022.102525 J. Zhang, Y. Yuan, Calphad, 80, 102525(2023).
assessment that models this phase
doi:10.1016/S0364-5916(97)00036-9 L.A. Zabdyr, Calphad, 21, 349-58(1997).
assessment that models this phase
doi:10.1016/s0364-5916(02)00008-1 V. Izard, M.C. Record, J.C. Tedenac, S.G. Fries, Discussion on the stability of the antimony-zinc binary phases, Calphad 25 (2001) 567–581.
cited as the source of values for this phase
doi:10.1016/0364-5916(93)90005-v L.A. Zabdyr, CALPHAD 17 (3) (1993) 269.
cited as the source of values for this phase
doi:10.1016/j.jallcom.2006.04.051 Fouzia Adjadj, El-djemai Belbacha, Malek Bouharkat, Differential calorimetric analysis of the binary system Sb–Zn, Journal of Alloys and Compounds 430, 85-91 (2007).
cited as the source of values for this phase

LIQUID (Sb–Zn)

Id: phase:sb-zn:liquid; status assigned
Structure: liquid; type st:liquid; liquid; confidence high
Stability: stable in 7 of 7 calculated diagram(s): 682.87–2500 K, x(Zn) 0–1
Literature: 73 values (72 accepted) from 4 papers
Interactive: phase registry entry

Names (14): corpus: corpus:phase:sb-zn:liquid
paper: paper:10.1016/j.calphad.2009.08.006:L, paper:10.1016/j.jallcom.2006.08.035:L, paper:10.1016/j.jallcom.2006.08.035:L1, paper:10.1016/j.tca.2022.179327:L, paper:10.1016/j.tca.2022.179327:liquid, paper:10.1361/105497100770339608:liquid
tdb: tdb:SbZn-00Liu-LB.tdb:LIQUID, tdb:SbZn-07Li.tdb:LIQUID, tdb:SbZn-09Liu.tdb:LIQUID, tdb:SbZn-18Wan.tdb:LIQUID, tdb:SbZn-22Zha.tdb:LIQUID, tdb:SbZn-23Zha.tdb:LIQUID, tdb:SbZn-97Zab.tdb:LIQUID

TDB models of LIQUID (7): PHASE and CONSTITUENT statements as written

SbZn-00Liu-LB.tdb: LIQUID, type code %, sha256 82e256183b64ede7…

34: PHASE LIQUID:L % 1 1 !
35: CONST LIQUID:L : SB ZN : !

SbZn-07Li.tdb: LIQUID, type code %, sha256 6e6072cc45a32d33…

20: PHASE LIQUID:L % 1 1 !
21: CONST LIQUID:L : SB ZN : !

SbZn-09Liu.tdb: LIQUID, type code %, sha256 187d17f544e9280e…

23: PHASE LIQUID:L % 1 1 !
24: CONST LIQUID:L : SB ZN : !

SbZn-18Wan.tdb: LIQUID, type code %, sha256 8427f99df3872e4e…

26: PHASE LIQUID:L % 1 1 !
27: CONST LIQUID:L : SB ZN : !

SbZn-22Zha.tdb: LIQUID, type code %, sha256 7c5dd94e653096cd…

27: PHASE LIQUID:L % 1 1 !
28: CONST LIQUID:L : SB ZN : !

SbZn-23Zha.tdb: LIQUID, type code %, sha256 be7f7a4bc8316cfd…

26: PHASE LIQUID:L % 1 1 !
27: CONST LIQUID:L : SB SB3ZN4 ZN : !

SbZn-97Zab.tdb: LIQUID, type code %, sha256 dab5acfd3e531488…

20: PHASE LIQUID:L % 1 1 !
21: CONST LIQUID:L : SB ZN : !

Example references (10 of 13; assessments first):

doi:10.1016/j.tca.2022.179327 Jiyuan Zhang, Yuan Yuan, A coupled experimental and thermodynamic assessment of the Mg-Bi-Sb and Zn-Bi-Sb ternary system and extrapolate to the Mg-Bi-Zn-Sb system, Thermochimica Acta 716, 179327 (2022).
assessment that models this phase; reports values for this phase
doi:10.1016/j.jallcom.2006.08.035 Jing-Bo Li, Marie-Christine Record, Jean-Claude Tedenac, A thermodynamic assessment of the Sb–Zn system, Journal of Alloys and Compounds 438, 171-177 (2007).
assessment that models this phase; reports values for this phase
doi:10.1361/105497100770339608 X. J. Liu, C. P. Wang, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the phase diagrams of the Cu-Sb and Sb-Zn systems, JPE 21, 432-442 (2000).
assessment that models this phase; cited as the source of values for this phase; reports values for this phase
doi:10.1016/j.calphad.2009.08.006 Ya Liu, Jean-Claude Tedenac, Thermodynamic modeling of the Cd–Sb–Zn ternary system, Calphad 33, 684-694 (2009).
assessment that models this phase; cited as the source of values for this phase; reports values for this phase
doi:10.1007/s11664-017-5757-5 W. Wang, L. Yang, N. Wang, H. Zhang, Y. Jia, J. Electron. Mater., 47, 261-71(2018).
assessment that models this phase
doi:10.1016/j.calphad.2022.102525 J. Zhang, Y. Yuan, Calphad, 80, 102525(2023).
assessment that models this phase
doi:10.1016/S0364-5916(97)00036-9 L.A. Zabdyr, Calphad, 21, 349-58(1997).
assessment that models this phase
doi:10.1016/s0364-5916(02)00008-1 V. Izard, M.C. Record, J.C. Tedenac, S.G. Fries, Discussion on the stability of the antimony-zinc binary phases, Calphad 25 (2001) 567–581.
cited as the source of values for this phase
doi:10.1016/0364-5916(93)90005-v L.A. Zabdyr, CALPHAD 17 (3) (1993) 269.
cited as the source of values for this phase
doi:10.1016/j.jallcom.2006.04.051 Fouzia Adjadj, El-djemai Belbacha, Malek Bouharkat, Differential calorimetric analysis of the binary system Sb–Zn, Journal of Alloys and Compounds 430, 85-91 (2007).
cited as the source of values for this phase

SB17ZN23_H (Sb–Zn)

Id: phase:sb-zn:sb17zn23-h; status needs_review
No structure assigned. Why: name_has_descriptive_tokens:H; no_structure_token; sgte_mmc2_row_incomplete
Candidate (sgte_mmc2): (Sb17Zn23) — Hallstedt 2025 mmc2 row for SB17ZN23_H: Sb17Zn23 (delta)
Stoichiometry: Sb 0.4250, Zn 0.5750
Stability: stable in 1 of 1 calculated diagram(s): 764.91–833.76 K, x(Zn) 0.575–0.575
Literature: 0 values (0 accepted) from 0 papers
Interactive: phase registry entry

Names (2): corpus: corpus:phase:sb-zn:sb17zn23-h
tdb: tdb:SbZn-00Liu-LB.tdb:SB17ZN23_H

TDB models of SB17ZN23_H (1): PHASE and CONSTITUENT statements as written

SbZn-00Liu-LB.tdb: SB17ZN23_H, type code %, sha256 82e256183b64ede7…

74: PHASE SB17ZN23_H % 2 0.425 0.575 !
75: CONST SB17ZN23_H : SB : ZN : !

Example references (1 of 1; assessments first):

doi:10.1361/105497100770339608 X. J. Liu, C. P. Wang, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the phase diagrams of the Cu-Sb and Sb-Zn systems, JPE 21, 432-442 (2000).
assessment that models this phase

SB17ZN23_L (Sb–Zn)

Id: phase:sb-zn:sb17zn23-l; status assigned
Structure: Sb17Zn23 · hR22 · R-3c (167); type st:sb17zn23-hr22; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated
Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) doi:10.1016/j.calphad.2025.102833
Caveat: not certain from the name or DFT alone (name_has_descriptive_tokens:L, no_structure_token); structure as stated in the SGTE crystallographic table for this phase name and system
Stoichiometry: Sb 0.4250, Zn 0.5750
Stability: stable in 1 of 1 calculated diagram(s): 489.61–764.91 K, x(Zn) 0.575–0.575
Literature: 0 values (0 accepted) from 0 papers
Interactive: phase registry entry

Names (2): corpus: corpus:phase:sb-zn:sb17zn23-l
tdb: tdb:SbZn-00Liu-LB.tdb:SB17ZN23_L

TDB models of SB17ZN23_L (1): PHASE and CONSTITUENT statements as written

SbZn-00Liu-LB.tdb: SB17ZN23_L, type code %, sha256 82e256183b64ede7…

69: PHASE SB17ZN23_L % 2 0.425 0.575 !
70: CONST SB17ZN23_L : SB : ZN : !

Example references (1 of 1; assessments first):

doi:10.1361/105497100770339608 X. J. Liu, C. P. Wang, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the phase diagrams of the Cu-Sb and Sb-Zn systems, JPE 21, 432-442 (2000).
assessment that models this phase

SB19ZN31 (Sb–Zn)

Id: phase:sb-zn:sb19zn31; status assigned
Structure: Sb2Zn3-ht1 · oP30 · Pmmn (59); type st:sb2zn3-ht1-op30; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated
Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) doi:10.1016/j.calphad.2025.102833
Caveat: not certain from the name or DFT alone (no_on_hull_entry_in_both, no_structure_token); structure as stated in the SGTE crystallographic table for this phase name and system
Stoichiometry: Sb 0.3800, Zn 0.6200
Stability: stable in 1 of 1 calculated diagram(s): 681.25–727.92 K, x(Zn) 0.62–0.62
Literature: 0 values (0 accepted) from 0 papers
Interactive: phase registry entry

Names (2): corpus: corpus:phase:sb-zn:sb19zn31
tdb: tdb:SbZn-00Liu-LB.tdb:SB19ZN31

TDB models of SB19ZN31 (1): PHASE and CONSTITUENT statements as written

SbZn-00Liu-LB.tdb: SB19ZN31, type code %, sha256 82e256183b64ede7…

79: PHASE SB19ZN31 % 2 0.38 0.62 !
80: CONST SB19ZN31 : SB : ZN : !

Example references (1 of 1; assessments first):

doi:10.1361/105497100770339608 X. J. Liu, C. P. Wang, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the phase diagrams of the Cu-Sb and Sb-Zn systems, JPE 21, 432-442 (2000).
assessment that models this phase

SB2ZN3 (Sb–Zn)

Id: phase:sb-zn:sb2zn3; status assigned
Structure: Sb2Zn3-ht2 · oP192 · Pccn (56); type st:sb2zn3-ht2-op192; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated
Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) doi:10.1016/j.calphad.2025.102833
Caveat: not certain from the name or DFT alone (no_structure_token, polymorph_family:other phases of this system have the same composition); structure as stated in the SGTE crystallographic table for this phase name and system
Stoichiometry: Sb 0.4000, Zn 0.6000
Stability: stable in 1 of 1 calculated diagram(s): 712.64–836.62 K, x(Zn) 0.6–0.6
Literature: 0 values (0 accepted) from 0 papers
Interactive: phase registry entry

Names (2): corpus: corpus:phase:sb-zn:sb2zn3
tdb: tdb:SbZn-00Liu-LB.tdb:SB2ZN3

TDB models of SB2ZN3 (1): PHASE and CONSTITUENT statements as written

SbZn-00Liu-LB.tdb: SB2ZN3, type code %, sha256 82e256183b64ede7…

84: PHASE SB2ZN3 % 2 0.4 0.6 !
85: CONST SB2ZN3 : SB : ZN : !

Example references (1 of 1; assessments first):

doi:10.1361/105497100770339608 X. J. Liu, C. P. Wang, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the phase diagrams of the Cu-Sb and Sb-Zn systems, JPE 21, 432-442 (2000).
assessment that models this phase

SB2ZN3_ETA (Sb–Zn)

Id: phase:sb-zn:sb2zn3-eta; status assigned
Structure: Sb2Zn3-ht1 · oP30 · Pmmn (59); type st:sb2zn3-ht1-op30; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated
Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) doi:10.1016/j.calphad.2025.102833
Caveat: not certain from the name or DFT alone (no_structure_token, polymorph_family:other phases of this system have the same composition); structure as stated in the SGTE crystallographic table for this phase name and system
Stoichiometry: Sb 0.4000, Zn 0.6000
Stability: stable in 5 of 5 calculated diagram(s): 677.06–757.55 K, x(Zn) 0.6–0.6
Literature: 15 values (15 accepted) from 1 papers
Interactive: phase registry entry

Names (7): corpus: corpus:phase:sb-zn:sb2zn3-eta
paper: paper:10.1016/j.jallcom.2006.08.035:ηSb2Zn3
tdb: tdb:SbZn-07Li.tdb:SB2ZN3_ETA, tdb:SbZn-09Liu.tdb:SB2ZN3_ETA, tdb:SbZn-18Wan.tdb:SB2ZN3_ETA, tdb:SbZn-22Zha.tdb:SB2ZN3_ETA, tdb:SbZn-23Zha.tdb:SB2ZN3_ETA

TDB models of SB2ZN3_ETA (5): PHASE and CONSTITUENT statements as written

SbZn-07Li.tdb: SB2ZN3_ETA, type code %, sha256 6e6072cc45a32d33…

65: PHASE SB2ZN3_ETA % 2 2 3 !
66: CONST SB2ZN3_ETA : SB : ZN : !

SbZn-09Liu.tdb: SB2ZN3_ETA, type code %, sha256 187d17f544e9280e…

68: PHASE SB2ZN3_ETA % 2 2 3 !
69: CONST SB2ZN3_ETA : SB : ZN : !

SbZn-18Wan.tdb: SB2ZN3_ETA, type code %, sha256 8427f99df3872e4e…

76: PHASE SB2ZN3_ETA % 2 2 3 !
77: CONST SB2ZN3_ETA : SB : ZN : !

SbZn-22Zha.tdb: SB2ZN3_ETA, type code %, sha256 7c5dd94e653096cd…

82: PHASE SB2ZN3_ETA % 2 2 3 !
83: CONST SB2ZN3_ETA : SB : ZN : !

SbZn-23Zha.tdb: SB2ZN3_ETA, type code %, sha256 be7f7a4bc8316cfd…

81: PHASE SB2ZN3_ETA % 2 2 3 !
82: CONST SB2ZN3_ETA : SB : ZN : !

Example references (8 of 8; assessments first):

doi:10.1016/j.jallcom.2006.08.035 Jing-Bo Li, Marie-Christine Record, Jean-Claude Tedenac, A thermodynamic assessment of the Sb–Zn system, Journal of Alloys and Compounds 438, 171-177 (2007).
assessment that models this phase; reports values for this phase
doi:10.1007/s11664-017-5757-5 W. Wang, L. Yang, N. Wang, H. Zhang, Y. Jia, J. Electron. Mater., 47, 261-71(2018).
assessment that models this phase
doi:10.1016/j.calphad.2009.08.006 Ya Liu, Jean-Claude Tedenac, Thermodynamic modeling of the Cd–Sb–Zn ternary system, Calphad 33, 684-694 (2009).
assessment that models this phase
doi:10.1016/j.calphad.2022.102525 J. Zhang, Y. Yuan, Calphad, 80, 102525(2023).
assessment that models this phase
doi:10.1016/j.tca.2022.179327 Jiyuan Zhang, Yuan Yuan, A coupled experimental and thermodynamic assessment of the Mg-Bi-Sb and Zn-Bi-Sb ternary system and extrapolate to the Mg-Bi-Zn-Sb system, Thermochimica Acta 716, 179327 (2022).
assessment that models this phase
doi:10.1016/s0364-5916(02)00008-1 V. Izard, M.C. Record, J.C. Tedenac, S.G. Fries, Discussion on the stability of the antimony-zinc binary phases, Calphad 25 (2001) 567–581.
cited as the source of values for this phase
doi:10.1361/105497100770339608 X. J. Liu, C. P. Wang, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the phase diagrams of the Cu-Sb and Sb-Zn systems, JPE 21, 432-442 (2000).
cited as the source of values for this phase
doi:10.1016/0364-5916(93)90005-v L.A. Zabdyr, CALPHAD 17 (3) (1993) 269.
cited as the source of values for this phase

SB2ZN3_HT (Sb–Zn)

Id: phase:sb-zn:sb2zn3-ht; status needs_review
No structure assigned. Why: no_structure_token; polymorph_family:other phases of this system have the same composition
Candidate (tdb_comment): Sb2Zn3-ht2 · oP192 · Pccn — SbZn-97Zab.tdb: 'Prototype Sb2Zn3-ht2 (oP192, Pccn), zeta, ht2'
Stoichiometry: Sb 0.4000, Zn 0.6000
Stability: stable in 1 of 1 calculated diagram(s): 719.86–835.51 K, x(Zn) 0.6–0.6
Literature: 0 values (0 accepted) from 0 papers
Interactive: phase registry entry

Names (2): corpus: corpus:phase:sb-zn:sb2zn3-ht
tdb: tdb:SbZn-97Zab.tdb:SB2ZN3_HT

TDB models of SB2ZN3_HT (1): PHASE and CONSTITUENT statements as written

SbZn-97Zab.tdb: SB2ZN3_HT, type code %, sha256 dab5acfd3e531488…

65: PHASE SB2ZN3_HT % 2 2 3 !
66: CONST SB2ZN3_HT : SB : ZN : !

Example references (1 of 1; assessments first):

doi:10.1016/S0364-5916(97)00036-9 L.A. Zabdyr, Calphad, 21, 349-58(1997).
assessment that models this phase

SB2ZN3_LT (Sb–Zn)

Id: phase:sb-zn:sb2zn3-lt; status needs_review
No structure assigned. Why: no_structure_token; polymorph_family:other phases of this system have the same composition
Candidate (tdb_comment): Sb2Zn3-ht1 · oP30 · Pmmn — SbZn-97Zab.tdb: 'Prototype Sb2Zn3-ht1 (oP30, Pmmn), eta, ht1'
Stoichiometry: Sb 0.4000, Zn 0.6000
Stability: stable in 1 of 1 calculated diagram(s): 676.1–719.86 K, x(Zn) 0.6–0.6
Literature: 0 values (0 accepted) from 0 papers
Interactive: phase registry entry

Names (2): corpus: corpus:phase:sb-zn:sb2zn3-lt
tdb: tdb:SbZn-97Zab.tdb:SB2ZN3_LT

TDB models of SB2ZN3_LT (1): PHASE and CONSTITUENT statements as written

SbZn-97Zab.tdb: SB2ZN3_LT, type code %, sha256 dab5acfd3e531488…

60: PHASE SB2ZN3_LT % 2 2 3 !
61: CONST SB2ZN3_LT : SB : ZN : !

Example references (1 of 1; assessments first):

doi:10.1016/S0364-5916(97)00036-9 L.A. Zabdyr, Calphad, 21, 349-58(1997).
assessment that models this phase

SB2ZN3_ZETA (Sb–Zn)

Id: phase:sb-zn:sb2zn3-zeta; status needs_review
No structure assigned. Why: assessment_declared_blocked_by:models_disagree_on_composition; models_disagree_on_composition; no_structure_token
Candidate (literature_printed): Sb2Zn3-ht2 · oP192 — printed with a label mapped to this phase
Candidate (sgte_mmc2): Sb2Zn3-ht2 · oP192 · Pccn (56) — Hallstedt 2025 mmc2 row for SB2ZN3_ZETA: Sb2Zn3 (zeta, ht2)
Candidate (tdb_comment): Sb2Zn3-ht2 · oP192 · Pccn — SbZn-07Li.tdb: 'Prototype Sb2Zn3-ht2 (oP192, Pccn), zeta, ht2'
Candidate (tdb_comment): Sb2Zn3-ht2 · oP192 · Pccn — SbZn-09Liu.tdb: 'Prototype Sb2Zn3-ht2 (oP192, Pccn), zeta, ht2'
Candidate (tdb_comment): Sb2Zn3-ht2 · oP192 · Pccn — SbZn-18Wan.tdb: 'Prototype Sb2Zn3-ht2 (oP192, Pccn), zeta, ht2'
Candidate (tdb_comment): Sb2Zn3-ht2 · oP192 · Pccn — SbZn-22Zha.tdb: 'Prototype Sb2Zn3-ht2 (oP192, Pccn), zeta, ht2'
Candidate (tdb_comment): Sb2Zn3-ht2 · oP192 · Pccn — SbZn-23Zha.tdb: 'Prototype Sb2Zn3-ht2 (oP192, Pccn), zeta, ht2'
Stability: stable in 5 of 5 calculated diagram(s): 703.48–852.57 K, x(Zn) 0.59267–0.595
Literature: 20 values (20 accepted) from 1 papers
Interactive: phase registry entry

Names (7): corpus: corpus:phase:sb-zn:sb2zn3-zeta
paper: paper:10.1016/j.jallcom.2006.08.035:ξSb2Zn3
tdb: tdb:SbZn-07Li.tdb:SB2ZN3_ZETA, tdb:SbZn-09Liu.tdb:SB2ZN3_ZETA, tdb:SbZn-18Wan.tdb:SB2ZN3_ZETA, tdb:SbZn-22Zha.tdb:SB2ZN3_ZETA, tdb:SbZn-23Zha.tdb:SB2ZN3_ZETA

TDB models of SB2ZN3_ZETA (5): PHASE and CONSTITUENT statements as written

SbZn-07Li.tdb: SB2ZN3_ZETA, type code %, sha256 6e6072cc45a32d33…

70: PHASE SB2ZN3_ZETA % 2 2.025 2.975 !
71: CONST SB2ZN3_ZETA : SB : ZN : !

SbZn-09Liu.tdb: SB2ZN3_ZETA, type code %, sha256 187d17f544e9280e…

73: PHASE SB2ZN3_ZETA % 2 2.025 2.975 !
74: CONST SB2ZN3_ZETA : SB : ZN : !

SbZn-18Wan.tdb: SB2ZN3_ZETA, type code %, sha256 8427f99df3872e4e…

81: PHASE SB2ZN3_ZETA % 2 2.025 2.975 !
82: CONST SB2ZN3_ZETA : SB : ZN : !

SbZn-22Zha.tdb: SB2ZN3_ZETA, type code %, sha256 7c5dd94e653096cd…

87: PHASE SB2ZN3_ZETA % 2 2 2.91 !
88: CONST SB2ZN3_ZETA : SB : ZN : !

SbZn-23Zha.tdb: SB2ZN3_ZETA, type code %, sha256 be7f7a4bc8316cfd…

86: PHASE SB2ZN3_ZETA % 2 2 2.91 !
87: CONST SB2ZN3_ZETA : SB : ZN : !

Example references (8 of 8; assessments first):

doi:10.1016/j.jallcom.2006.08.035 Jing-Bo Li, Marie-Christine Record, Jean-Claude Tedenac, A thermodynamic assessment of the Sb–Zn system, Journal of Alloys and Compounds 438, 171-177 (2007).
assessment that models this phase; reports values for this phase
doi:10.1007/s11664-017-5757-5 W. Wang, L. Yang, N. Wang, H. Zhang, Y. Jia, J. Electron. Mater., 47, 261-71(2018).
assessment that models this phase
doi:10.1016/j.calphad.2009.08.006 Ya Liu, Jean-Claude Tedenac, Thermodynamic modeling of the Cd–Sb–Zn ternary system, Calphad 33, 684-694 (2009).
assessment that models this phase
doi:10.1016/j.calphad.2022.102525 J. Zhang, Y. Yuan, Calphad, 80, 102525(2023).
assessment that models this phase
doi:10.1016/j.tca.2022.179327 Jiyuan Zhang, Yuan Yuan, A coupled experimental and thermodynamic assessment of the Mg-Bi-Sb and Zn-Bi-Sb ternary system and extrapolate to the Mg-Bi-Zn-Sb system, Thermochimica Acta 716, 179327 (2022).
assessment that models this phase
doi:10.1016/s0364-5916(02)00008-1 V. Izard, M.C. Record, J.C. Tedenac, S.G. Fries, Discussion on the stability of the antimony-zinc binary phases, Calphad 25 (2001) 567–581.
cited as the source of values for this phase
doi:10.1361/105497100770339608 X. J. Liu, C. P. Wang, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the phase diagrams of the Cu-Sb and Sb-Zn systems, JPE 21, 432-442 (2000).
cited as the source of values for this phase
doi:10.1016/0364-5916(93)90005-v L.A. Zabdyr, CALPHAD 17 (3) (1993) 269.
cited as the source of values for this phase

SB3ZN4_ALPHA (Sb–Zn)

Id: phase:sb-zn:sb3zn4-alpha; status needs_review
No structure assigned. Why: assessment_declared_blocked_by:models_disagree_on_composition; models_disagree_on_composition; no_structure_token
Candidate (literature_printed): Sb10Zn13 · aP92 — printed with a label mapped to this phase
Candidate (sgte_mmc2): Sb10Zn13 · aP92 · P-1 (2) — Hallstedt 2025 mmc2 row for SB3ZN4_ALPHA: Sb3Zn4 (alpha, stable below RT)
Candidate (tdb_comment): Sb10Zn13 · aP92 · P-1 — SbZn-18Wan.tdb: 'Prototype Sb10Zn13 (aP92, P-1)'
Candidate (tdb_comment): Sb10Zn13 · aP92 · P-1 — SbZn-22Zha.tdb: 'Prototype Sb10Zn13 (aP92, P-1)'
Candidate (tdb_comment): Sb10Zn13 · aP92 · P-1 — SbZn-23Zha.tdb: 'Prototype Sb10Zn13 (aP92, P-1)'
Stability: not stable in 3 calculated diagram(s)
Literature: 9 values (9 accepted) from 1 papers
Interactive: phase registry entry

Names (5): corpus: corpus:phase:sb-zn:sb3zn4-alpha
paper: paper:10.1016/j.tca.2022.179327:α-Zn13Sb10
tdb: tdb:SbZn-18Wan.tdb:SB3ZN4_ALPHA, tdb:SbZn-22Zha.tdb:SB3ZN4_ALPHA, tdb:SbZn-23Zha.tdb:SB3ZN4_ALPHA

TDB models of SB3ZN4_ALPHA (3): PHASE and CONSTITUENT statements as written

SbZn-18Wan.tdb: SB3ZN4_ALPHA, type code %, sha256 8427f99df3872e4e…

56: PHASE SB3ZN4_ALPHA % 2 3 4 !
57: CONST SB3ZN4_ALPHA : SB : ZN : !

SbZn-22Zha.tdb: SB3ZN4_ALPHA, type code %, sha256 7c5dd94e653096cd…

57: PHASE SB3ZN4_ALPHA % 2 10 13 !
58: CONST SB3ZN4_ALPHA : SB : ZN : !

SbZn-23Zha.tdb: SB3ZN4_ALPHA, type code %, sha256 be7f7a4bc8316cfd…

56: PHASE SB3ZN4_ALPHA % 2 10 13 !
57: CONST SB3ZN4_ALPHA : SB : ZN : !

Example references (4 of 4; assessments first):

doi:10.1016/j.tca.2022.179327 Jiyuan Zhang, Yuan Yuan, A coupled experimental and thermodynamic assessment of the Mg-Bi-Sb and Zn-Bi-Sb ternary system and extrapolate to the Mg-Bi-Zn-Sb system, Thermochimica Acta 716, 179327 (2022).
assessment that models this phase; reports values for this phase
doi:10.1007/s11664-017-5757-5 W. Wang, L. Yang, N. Wang, H. Zhang, Y. Jia, J. Electron. Mater., 47, 261-71(2018).
assessment that models this phase
doi:10.1016/j.calphad.2022.102525 J. Zhang, Y. Yuan, Calphad, 80, 102525(2023).
assessment that models this phase
doi:10.1021/cm035274a Yurij Mozharivskyj, Alexandra O. Pecharsky, Sergey Bud'ko, Gordon J. Miller, A Promising Thermoelectric Material: Zn4Sb3 or Zn6-δSb5. Its Composition, Structure, Stability, and Polymorphs. Structure and Stability of Zn1-δSb, Chem. Mater. 16, 1580-1589 (2004).
cited as the source of values for this phase

SB3ZN4_ALPHA_P (Sb–Zn)

Id: phase:sb-zn:sb3zn4-alpha-p; status unresolved_no_candidates
No structure assigned. Why: name_has_descriptive_tokens:P; no_structure_token
Stoichiometry: Sb 0.4348, Zn 0.5652
Stability: not stable in 2 calculated diagram(s)
Literature: 1 values (1 accepted) from 1 papers
Interactive: phase registry entry

Names (4): corpus: corpus:phase:sb-zn:sb3zn4-alpha-p
paper: paper:10.1016/j.tca.2022.179327:α'-Zn13Sb10
tdb: tdb:SbZn-22Zha.tdb:SB3ZN4_ALPHA_P, tdb:SbZn-23Zha.tdb:SB3ZN4_ALPHA_P

TDB models of SB3ZN4_ALPHA_P (2): PHASE and CONSTITUENT statements as written

SbZn-22Zha.tdb: SB3ZN4_ALPHA_P, type code %, sha256 7c5dd94e653096cd…

62: PHASE SB3ZN4_ALPHA_P % 2 10 13 !
63: CONST SB3ZN4_ALPHA_P : SB : ZN : !

SbZn-23Zha.tdb: SB3ZN4_ALPHA_P, type code %, sha256 be7f7a4bc8316cfd…

61: PHASE SB3ZN4_ALPHA_P % 2 10 13 !
62: CONST SB3ZN4_ALPHA_P : SB : ZN : !

Example references (3 of 3; assessments first):

doi:10.1016/j.tca.2022.179327 Jiyuan Zhang, Yuan Yuan, A coupled experimental and thermodynamic assessment of the Mg-Bi-Sb and Zn-Bi-Sb ternary system and extrapolate to the Mg-Bi-Zn-Sb system, Thermochimica Acta 716, 179327 (2022).
assessment that models this phase; reports values for this phase
doi:10.1016/j.calphad.2022.102525 J. Zhang, Y. Yuan, Calphad, 80, 102525(2023).
assessment that models this phase
doi:10.1021/cm035274a Yurij Mozharivskyj, Alexandra O. Pecharsky, Sergey Bud'ko, Gordon J. Miller, A Promising Thermoelectric Material: Zn4Sb3 or Zn6-δSb5. Its Composition, Structure, Stability, and Polymorphs. Structure and Stability of Zn1-δSb, Chem. Mater. 16, 1580-1589 (2004).
cited as the source of values for this phase

SB3ZN4_BETA (Sb–Zn)

Id: phase:sb-zn:sb3zn4-beta; status needs_review
No structure assigned. Why: assessment_declared_compound_differs_from_site_ratios; no_structure_token; off_stoichiometric_model
Candidate (sgte_mmc2): Sb17Zn23 · hR22 · R-3c (167) — Hallstedt 2025 mmc2 row for SB3ZN4_BETA: Sb3Zn4 (beta, same as epsilon)
Candidate (tdb_comment): Sb17Zn23 · hR22 · R-3c — SbZn-18Wan.tdb: 'Prototype Sb17Zn23 (hR22, R-3c), previously epsilon'
Candidate (tdb_comment): Sb17Zn23 · hR22 · R-3c — SbZn-22Zha.tdb: 'Prototype Sb17Zn23 (hR22, R-3c), previously epsilon'
Candidate (tdb_comment): Sb17Zn23 · hR22 · R-3c — SbZn-23Zha.tdb: 'Prototype Sb17Zn23 (hR22, R-3c), previously epsilon'
Stability: stable in 3 of 3 calculated diagram(s): 300–795.32 K, x(Zn) 0.56327–0.57143
Literature: 0 values (0 accepted) from 0 papers
Interactive: phase registry entry

Names (4): corpus: corpus:phase:sb-zn:sb3zn4-beta
tdb: tdb:SbZn-18Wan.tdb:SB3ZN4_BETA, tdb:SbZn-22Zha.tdb:SB3ZN4_BETA, tdb:SbZn-23Zha.tdb:SB3ZN4_BETA

TDB models of SB3ZN4_BETA (3): PHASE and CONSTITUENT statements as written

SbZn-18Wan.tdb: SB3ZN4_BETA, type code %, sha256 8427f99df3872e4e…

61: PHASE SB3ZN4_BETA % 2 3 4 !
62: CONST SB3ZN4_BETA : SB : ZN : !

SbZn-22Zha.tdb: SB3ZN4_BETA, type code %, sha256 7c5dd94e653096cd…

67: PHASE SB3ZN4_BETA % 2 10 13 !
68: CONST SB3ZN4_BETA : SB : VA ZN% : !

SbZn-23Zha.tdb: SB3ZN4_BETA, type code %, sha256 be7f7a4bc8316cfd…

66: PHASE SB3ZN4_BETA % 2 10 13 !
67: CONST SB3ZN4_BETA : SB : VA ZN% : !

Example references (3 of 3; assessments first):

doi:10.1007/s11664-017-5757-5 W. Wang, L. Yang, N. Wang, H. Zhang, Y. Jia, J. Electron. Mater., 47, 261-71(2018).
assessment that models this phase
doi:10.1016/j.calphad.2022.102525 J. Zhang, Y. Yuan, Calphad, 80, 102525(2023).
assessment that models this phase
doi:10.1016/j.tca.2022.179327 Jiyuan Zhang, Yuan Yuan, A coupled experimental and thermodynamic assessment of the Mg-Bi-Sb and Zn-Bi-Sb ternary system and extrapolate to the Mg-Bi-Zn-Sb system, Thermochimica Acta 716, 179327 (2022).
assessment that models this phase

SB3ZN4_DELTA (Sb–Zn)

Id: phase:sb-zn:sb3zn4-delta; status needs_review
No structure assigned. Why: no_structure_token; polymorph_family:other phases of this system have the same composition; sgte_mmc2_row_incomplete
Candidate (literature_printed): (Sb17Zn23) · ? — printed with a label mapped to this phase
Candidate (sgte_mmc2): (Sb17Zn23) — Hallstedt 2025 mmc2 row for SB3ZN4_DELTA: Sb3Zn4 (delta)
Stoichiometry: Sb 0.4410, Zn 0.5590
Stability: stable in 2 of 2 calculated diagram(s): 766.7–802.76 K, x(Zn) 0.559–0.559
Literature: 22 values (22 accepted) from 1 papers
Interactive: phase registry entry

Names (5): corpus: corpus:phase:sb-zn:sb3zn4-delta
paper: paper:10.1016/j.jallcom.2006.08.035:δ'Sb3Zn4, paper:10.1016/j.jallcom.2006.08.035:δSb3Zn4
tdb: tdb:SbZn-07Li.tdb:SB3ZN4_DELTA, tdb:SbZn-09Liu.tdb:SB3ZN4_DELTA

TDB models of SB3ZN4_DELTA (2): PHASE and CONSTITUENT statements as written

SbZn-07Li.tdb: SB3ZN4_DELTA, type code %, sha256 6e6072cc45a32d33…

55: PHASE SB3ZN4_DELTA % 2 3.087 3.913 !
56: CONST SB3ZN4_DELTA : SB : ZN : !

SbZn-09Liu.tdb: SB3ZN4_DELTA, type code %, sha256 187d17f544e9280e…

58: PHASE SB3ZN4_DELTA % 2 3.087 3.913 !
59: CONST SB3ZN4_DELTA : SB : ZN : !

Example references (5 of 5; assessments first):

doi:10.1016/j.jallcom.2006.08.035 Jing-Bo Li, Marie-Christine Record, Jean-Claude Tedenac, A thermodynamic assessment of the Sb–Zn system, Journal of Alloys and Compounds 438, 171-177 (2007).
assessment that models this phase; reports values for this phase
doi:10.1016/j.calphad.2009.08.006 Ya Liu, Jean-Claude Tedenac, Thermodynamic modeling of the Cd–Sb–Zn ternary system, Calphad 33, 684-694 (2009).
assessment that models this phase
doi:10.1016/s0364-5916(02)00008-1 V. Izard, M.C. Record, J.C. Tedenac, S.G. Fries, Discussion on the stability of the antimony-zinc binary phases, Calphad 25 (2001) 567–581.
cited as the source of values for this phase
doi:10.1016/0364-5916(93)90005-v L.A. Zabdyr, CALPHAD 17 (3) (1993) 269.
cited as the source of values for this phase
doi:10.1361/105497100770339608 X. J. Liu, C. P. Wang, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the phase diagrams of the Cu-Sb and Sb-Zn systems, JPE 21, 432-442 (2000).
cited as the source of values for this phase

SB3ZN4_EPS (Sb–Zn)

Id: phase:sb-zn:sb3zn4-eps; status assigned
Structure: Sb17Zn23 · hR22 · R-3c (167); type st:sb17zn23-hr22; tier C: assessor-stated (Hallstedt 2025 crystallographic table); confidence assessor-stated
Structure source: B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, supplementary crystallographic table (mmc2) doi:10.1016/j.calphad.2025.102833
Caveat: not certain from the name or DFT alone (name_has_descriptive_tokens:EPS, no_structure_token); structure as stated in the SGTE crystallographic table for this phase name and system
Stability: stable in 2 of 2 calculated diagram(s): 300–767.62 K, x(Zn) 0.56556–0.57143
Literature: 26 values (26 accepted) from 1 papers
Interactive: phase registry entry

Names (5): corpus: corpus:phase:sb-zn:sb3zn4-eps
paper: paper:10.1016/j.jallcom.2006.08.035:ε-Sb3Zn4, paper:10.1016/j.jallcom.2006.08.035:εSb3Zn4
tdb: tdb:SbZn-07Li.tdb:SB3ZN4_EPS, tdb:SbZn-09Liu.tdb:SB3ZN4_EPS

TDB models of SB3ZN4_EPS (2): PHASE and CONSTITUENT statements as written

SbZn-07Li.tdb: SB3ZN4_EPS, type code %, sha256 6e6072cc45a32d33…

50: PHASE SB3ZN4_EPS % 2 3 4 !
51: CONST SB3ZN4_EPS : SB : ZN : !

SbZn-09Liu.tdb: SB3ZN4_EPS, type code %, sha256 187d17f544e9280e…

53: PHASE SB3ZN4_EPS % 2 3 4 !
54: CONST SB3ZN4_EPS : SB : VA ZN% : !

Example references (5 of 5; assessments first):

doi:10.1016/j.jallcom.2006.08.035 Jing-Bo Li, Marie-Christine Record, Jean-Claude Tedenac, A thermodynamic assessment of the Sb–Zn system, Journal of Alloys and Compounds 438, 171-177 (2007).
assessment that models this phase; reports values for this phase
doi:10.1016/j.calphad.2009.08.006 Ya Liu, Jean-Claude Tedenac, Thermodynamic modeling of the Cd–Sb–Zn ternary system, Calphad 33, 684-694 (2009).
assessment that models this phase
doi:10.1016/s0364-5916(02)00008-1 V. Izard, M.C. Record, J.C. Tedenac, S.G. Fries, Discussion on the stability of the antimony-zinc binary phases, Calphad 25 (2001) 567–581.
cited as the source of values for this phase
doi:10.1361/105497100770339608 X. J. Liu, C. P. Wang, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the phase diagrams of the Cu-Sb and Sb-Zn systems, JPE 21, 432-442 (2000).
cited as the source of values for this phase
doi:10.1016/0364-5916(93)90005-v L.A. Zabdyr, CALPHAD 17 (3) (1993) 269.
cited as the source of values for this phase

SB3ZN4_GAMMA (Sb–Zn)

Id: phase:sb-zn:sb3zn4-gamma; status needs_review
No structure assigned. Why: models_disagree_on_composition; no_structure_token; sgte_mmc2_row_incomplete
Candidate (sgte_mmc2): (Sb17Zn23) — Hallstedt 2025 mmc2 row for SB3ZN4_GAMMA: Sb3Zn4 (gamma, same as delta)
Stability: stable in 3 of 3 calculated diagram(s): 765.05–810.41 K, x(Zn) 0.55696–0.559
Literature: 0 values (0 accepted) from 0 papers
Interactive: phase registry entry

Names (4): corpus: corpus:phase:sb-zn:sb3zn4-gamma
tdb: tdb:SbZn-18Wan.tdb:SB3ZN4_GAMMA, tdb:SbZn-22Zha.tdb:SB3ZN4_GAMMA, tdb:SbZn-23Zha.tdb:SB3ZN4_GAMMA

TDB models of SB3ZN4_GAMMA (3): PHASE and CONSTITUENT statements as written

SbZn-18Wan.tdb: SB3ZN4_GAMMA, type code %, sha256 8427f99df3872e4e…

66: PHASE SB3ZN4_GAMMA % 2 3.087 3.913 !
67: CONST SB3ZN4_GAMMA : SB : ZN : !

SbZn-22Zha.tdb: SB3ZN4_GAMMA, type code %, sha256 7c5dd94e653096cd…

72: PHASE SB3ZN4_GAMMA % 2 7 8.8 !
73: CONST SB3ZN4_GAMMA : SB : ZN : !

SbZn-23Zha.tdb: SB3ZN4_GAMMA, type code %, sha256 be7f7a4bc8316cfd…

71: PHASE SB3ZN4_GAMMA % 2 7 8.8 !
72: CONST SB3ZN4_GAMMA : SB : ZN : !

Example references (3 of 3; assessments first):

doi:10.1007/s11664-017-5757-5 W. Wang, L. Yang, N. Wang, H. Zhang, Y. Jia, J. Electron. Mater., 47, 261-71(2018).
assessment that models this phase
doi:10.1016/j.calphad.2022.102525 J. Zhang, Y. Yuan, Calphad, 80, 102525(2023).
assessment that models this phase
doi:10.1016/j.tca.2022.179327 Jiyuan Zhang, Yuan Yuan, A coupled experimental and thermodynamic assessment of the Mg-Bi-Sb and Zn-Bi-Sb ternary system and extrapolate to the Mg-Bi-Zn-Sb system, Thermochimica Acta 716, 179327 (2022).
assessment that models this phase

SB3ZN4_HT (Sb–Zn)

Id: phase:sb-zn:sb3zn4-ht; status unresolved_no_candidates
No structure assigned. Why: no_structure_token; polymorph_family:other phases of this system have the same composition
Stoichiometry: Sb 0.4286, Zn 0.5714
Stability: stable in 1 of 1 calculated diagram(s): 766–835.75 K, x(Zn) 0.57143–0.57143
Literature: 0 values (0 accepted) from 0 papers
Interactive: phase registry entry

Names (2): corpus: corpus:phase:sb-zn:sb3zn4-ht
tdb: tdb:SbZn-97Zab.tdb:SB3ZN4_HT

TDB models of SB3ZN4_HT (1): PHASE and CONSTITUENT statements as written

SbZn-97Zab.tdb: SB3ZN4_HT, type code %, sha256 dab5acfd3e531488…

55: PHASE SB3ZN4_HT % 2 3 4 !
56: CONST SB3ZN4_HT : SB : ZN : !

Example references (1 of 1; assessments first):

doi:10.1016/S0364-5916(97)00036-9 L.A. Zabdyr, Calphad, 21, 349-58(1997).
assessment that models this phase

SB3ZN4_LT (Sb–Zn)

Id: phase:sb-zn:sb3zn4-lt; status needs_review
No structure assigned. Why: no_structure_token; polymorph_family:other phases of this system have the same composition
Candidate (tdb_comment): Sb17Zn23 · hR22 · R-3c — SbZn-97Zab.tdb: 'Prototype Sb17Zn23 (hR22, R-3c)'
Stoichiometry: Sb 0.4286, Zn 0.5714
Stability: stable in 1 of 1 calculated diagram(s): 338.81–766 K, x(Zn) 0.57143–0.57143
Literature: 0 values (0 accepted) from 0 papers
Interactive: phase registry entry

Names (2): corpus: corpus:phase:sb-zn:sb3zn4-lt
tdb: tdb:SbZn-97Zab.tdb:SB3ZN4_LT

TDB models of SB3ZN4_LT (1): PHASE and CONSTITUENT statements as written

SbZn-97Zab.tdb: SB3ZN4_LT, type code %, sha256 dab5acfd3e531488…

50: PHASE SB3ZN4_LT % 2 3 4 !
51: CONST SB3ZN4_LT : SB : ZN : !

Example references (1 of 1; assessments first):

doi:10.1016/S0364-5916(97)00036-9 L.A. Zabdyr, Calphad, 21, 349-58(1997).
assessment that models this phase

SB3ZN4_PRIME (Sb–Zn)

Id: phase:sb-zn:sb3zn4-prime; status needs_review
No structure assigned. Why: models_disagree_on_composition; name_has_descriptive_tokens:PRIME; no_structure_token; sgte_mmc2_row_incomplete
Candidate (literature_printed): (Sb17Zn23) · ? — printed with a label mapped to this phase
Candidate (sgte_mmc2): (Sb17Zn23) — Hallstedt 2025 mmc2 row for SB3ZN4_PRIME: Sb3Zn4 (delta-prime/gamma-prime)
Stability: stable in 5 of 5 calculated diagram(s): 797.97–852.27 K, x(Zn) 0.55128–0.558
Literature: 2 values (2 accepted) from 1 papers
Interactive: phase registry entry

Names (7): corpus: corpus:phase:sb-zn:sb3zn4-prime
paper: paper:10.1016/j.jallcom.2006.08.035:γSb5Zn6
tdb: tdb:SbZn-07Li.tdb:SB3ZN4_PRIME, tdb:SbZn-09Liu.tdb:SB3ZN4_PRIME, tdb:SbZn-18Wan.tdb:SB3ZN4_PRIME, tdb:SbZn-22Zha.tdb:SB3ZN4_PRIME, tdb:SbZn-23Zha.tdb:SB3ZN4_PRIME

TDB models of SB3ZN4_PRIME (5): PHASE and CONSTITUENT statements as written

SbZn-07Li.tdb: SB3ZN4_PRIME, type code %, sha256 6e6072cc45a32d33…

60: PHASE SB3ZN4_PRIME % 2 3.094 3.906 !
61: CONST SB3ZN4_PRIME : SB : ZN : !

SbZn-09Liu.tdb: SB3ZN4_PRIME, type code %, sha256 187d17f544e9280e…

63: PHASE SB3ZN4_PRIME % 2 3.094 3.906 !
64: CONST SB3ZN4_PRIME : SB : ZN : !

SbZn-18Wan.tdb: SB3ZN4_PRIME, type code %, sha256 8427f99df3872e4e…

71: PHASE SB3ZN4_PRIME % 2 3.094 3.906 !
72: CONST SB3ZN4_PRIME : SB : ZN : !

SbZn-22Zha.tdb: SB3ZN4_PRIME, type code %, sha256 7c5dd94e653096cd…

77: PHASE SB3ZN4_PRIME % 2 7 8.6 !
78: CONST SB3ZN4_PRIME : SB : ZN : !

SbZn-23Zha.tdb: SB3ZN4_PRIME, type code %, sha256 be7f7a4bc8316cfd…

76: PHASE SB3ZN4_PRIME % 2 7 8.6 !
77: CONST SB3ZN4_PRIME : SB : ZN : !

Example references (6 of 6; assessments first):

doi:10.1016/j.jallcom.2006.08.035 Jing-Bo Li, Marie-Christine Record, Jean-Claude Tedenac, A thermodynamic assessment of the Sb–Zn system, Journal of Alloys and Compounds 438, 171-177 (2007).
assessment that models this phase; reports values for this phase
doi:10.1007/s11664-017-5757-5 W. Wang, L. Yang, N. Wang, H. Zhang, Y. Jia, J. Electron. Mater., 47, 261-71(2018).
assessment that models this phase
doi:10.1016/j.calphad.2009.08.006 Ya Liu, Jean-Claude Tedenac, Thermodynamic modeling of the Cd–Sb–Zn ternary system, Calphad 33, 684-694 (2009).
assessment that models this phase
doi:10.1016/j.calphad.2022.102525 J. Zhang, Y. Yuan, Calphad, 80, 102525(2023).
assessment that models this phase
doi:10.1016/j.tca.2022.179327 Jiyuan Zhang, Yuan Yuan, A coupled experimental and thermodynamic assessment of the Mg-Bi-Sb and Zn-Bi-Sb ternary system and extrapolate to the Mg-Bi-Zn-Sb system, Thermochimica Acta 716, 179327 (2022).
assessment that models this phase
doi:10.1361/105497100770339608 X. J. Liu, C. P. Wang, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the phase diagrams of the Cu-Sb and Sb-Zn systems, JPE 21, 432-442 (2000).
cited as the source of values for this phase

SB9ZN11 (Sb–Zn)

Id: phase:sb-zn:sb9zn11; status needs_review
No structure assigned. Why: no_on_hull_entry_in_both; no_structure_token; sgte_mmc2_row_incomplete
Candidate (sgte_mmc2): (Sb9Zn11) — Hallstedt 2025 mmc2 row for SB9ZN11: Sb9Zn11 (gamma)
Stoichiometry: Sb 0.4500, Zn 0.5500
Stability: stable in 1 of 1 calculated diagram(s): 764.56–801.01 K, x(Zn) 0.55–0.55
Literature: 0 values (0 accepted) from 0 papers
Interactive: phase registry entry

Names (2): corpus: corpus:phase:sb-zn:sb9zn11
tdb: tdb:SbZn-00Liu-LB.tdb:SB9ZN11

TDB models of SB9ZN11 (1): PHASE and CONSTITUENT statements as written

SbZn-00Liu-LB.tdb: SB9ZN11, type code %, sha256 82e256183b64ede7…

64: PHASE SB9ZN11 % 2 0.45 0.55 !
65: CONST SB9ZN11 : SB : ZN : !

Example references (1 of 1; assessments first):

doi:10.1361/105497100770339608 X. J. Liu, C. P. Wang, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the phase diagrams of the Cu-Sb and Sb-Zn systems, JPE 21, 432-442 (2000).
assessment that models this phase

SBZN_BE (Sb–Zn)

Id: phase:sb-zn:sbzn-be; status assigned
Structure: CdSb · B_e · oP16 · Pbca (61); type st:b-e-cdsb-op16; tier A: standard phase name; confidence high
Stability: stable in 7 of 7 calculated diagram(s): 300–838.84 K, x(Zn) 0.4902–0.5
Literature: 62 values (61 accepted) from 2 papers
Interactive: phase registry entry

Names (11): corpus: corpus:phase:sb-zn:sbzn-be
paper: paper:10.1016/j.jallcom.2006.08.035:SbZn, paper:10.1016/j.jallcom.2006.08.035:βSbZn, paper:10.1016/j.tca.2022.179327:SbZn
tdb: tdb:SbZn-00Liu-LB.tdb:SBZN_BE, tdb:SbZn-07Li.tdb:SBZN_BE, tdb:SbZn-09Liu.tdb:SBZN_BE, tdb:SbZn-18Wan.tdb:SBZN_BE, tdb:SbZn-22Zha.tdb:SBZN_BE, tdb:SbZn-23Zha.tdb:SBZN_BE, tdb:SbZn-97Zab.tdb:SBZN_BE

TDB models of SBZN_BE (7): PHASE and CONSTITUENT statements as written

SbZn-00Liu-LB.tdb: SBZN_BE, type code %, sha256 82e256183b64ede7…

59: PHASE SBZN_BE % 2 1 1 !
60: CONST SBZN_BE : SB : ZN : !

SbZn-07Li.tdb: SBZN_BE, type code %, sha256 6e6072cc45a32d33…

45: PHASE SBZN_BE % 2 1 1 !
46: CONST SBZN_BE : SB : ZN : !

SbZn-09Liu.tdb: SBZN_BE, type code %, sha256 187d17f544e9280e…

48: PHASE SBZN_BE % 2 1 1 !
49: CONST SBZN_BE : SB : VA ZN% : !

SbZn-18Wan.tdb: SBZN_BE, type code %, sha256 8427f99df3872e4e…

51: PHASE SBZN_BE % 2 1 1 !
52: CONST SBZN_BE : SB : ZN : !

SbZn-22Zha.tdb: SBZN_BE, type code %, sha256 7c5dd94e653096cd…

52: PHASE SBZN_BE % 2 1 1 !
53: CONST SBZN_BE : SB : VA ZN% : !

SbZn-23Zha.tdb: SBZN_BE, type code %, sha256 be7f7a4bc8316cfd…

51: PHASE SBZN_BE % 2 1 1 !
52: CONST SBZN_BE : SB : VA ZN% : !

SbZn-97Zab.tdb: SBZN_BE, type code %, sha256 dab5acfd3e531488…

45: PHASE SBZN_BE % 2 1 1 !
46: CONST SBZN_BE : SB : ZN : !

Example references (10 of 13; assessments first):

doi:10.1016/j.jallcom.2006.08.035 Jing-Bo Li, Marie-Christine Record, Jean-Claude Tedenac, A thermodynamic assessment of the Sb–Zn system, Journal of Alloys and Compounds 438, 171-177 (2007).
assessment that models this phase; reports values for this phase
doi:10.1016/j.tca.2022.179327 Jiyuan Zhang, Yuan Yuan, A coupled experimental and thermodynamic assessment of the Mg-Bi-Sb and Zn-Bi-Sb ternary system and extrapolate to the Mg-Bi-Zn-Sb system, Thermochimica Acta 716, 179327 (2022).
assessment that models this phase; reports values for this phase
doi:10.1361/105497100770339608 X. J. Liu, C. P. Wang, I. Ohnuma, R. Kainuma, K. Ishida, Thermodynamic assessment of the phase diagrams of the Cu-Sb and Sb-Zn systems, JPE 21, 432-442 (2000).
assessment that models this phase; cited as the source of values for this phase
doi:10.1007/s11664-017-5757-5 W. Wang, L. Yang, N. Wang, H. Zhang, Y. Jia, J. Electron. Mater., 47, 261-71(2018).
assessment that models this phase
doi:10.1016/j.calphad.2009.08.006 Ya Liu, Jean-Claude Tedenac, Thermodynamic modeling of the Cd–Sb–Zn ternary system, Calphad 33, 684-694 (2009).
assessment that models this phase
doi:10.1016/j.calphad.2022.102525 J. Zhang, Y. Yuan, Calphad, 80, 102525(2023).
assessment that models this phase
doi:10.1016/S0364-5916(97)00036-9 L.A. Zabdyr, Calphad, 21, 349-58(1997).
assessment that models this phase
doi:10.1016/s0364-5916(02)00008-1 V. Izard, M.C. Record, J.C. Tedenac, S.G. Fries, Discussion on the stability of the antimony-zinc binary phases, Calphad 25 (2001) 567–581.
cited as the source of values for this phase
doi:10.1021/ja01266a055 Bernard. DeWitt, Harry. Seltz, A Thermodynamic Study of the Zinc-Antimony System. The Thermodynamic Properties of the Intermetallic Compounds: ZnSb, Zn3Sb2 and Zn4Sb3, J. Am. Chem. Soc. 61, 3170-3173 (1939).
cited as the source of values for this phase
doi:10.1039/c8dt02521e Chun-Wan Timothy Lo, Volodymyr Svitlyk, Dmitry Chernyshov, Yurij Mozharivskyj, The updated Zn–Sb phase diagram. How to make pure Zn 13 Sb 10 (“Zn 4 Sb 3 ”)., Dalton Trans. 47, 11512-11520 (2018).
cited as the source of values for this phase

Please cite

R. Arróyave, J. Saal, D. Shin, ORCHID-Registry: phase registry of binary systems (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23735970
R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23736065

Also cite B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0); the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work). Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

@misc{orchid_phase_registry_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Registry: phase registry of binary systems}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735970},
  url       = {https://doi.org/10.5281/zenodo.23735970},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}