Ca–Li–Na system

8 accepted literature values from 1 paper(s) (unspecified 8); 0 calculated phase diagram(s).

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Accepted values by evidence class
Evidence class	Values
unspecified	8

Accepted values by property group
Property group	Values
invariant reaction	8

Invariant reactions (literature)

Invariant reactions reported in the literature for the Ca–Li–Na system (8)
T (K)	Reaction / phases	Compositions (mole fraction)	Class	Source	Location
648.4	peritectic: Liquid1 + liquid2 + bcc(Ca) -> fcc(Ca)	Liquid1: Ca 0.55467, Li 0.40843; liquid2: Ca 0.02915, Li 0.03553; bcc(Ca): Ca 0.00919, Li 0.07767; fcc(Ca): Ca 0.00938, Li 0.0596	unspecified	[1] Zhang 2003	Table 6, p. 6, row 1 report
648.4	quasi-peritectic: Liquid2 + bcc(Ca) -> fcc(Ca) + liquid1	Liquid2: Ca 0.02915, Li 0.03553; bcc(Ca): Ca 0.00919, Li 0.07767; fcc(Ca): Ca 0.00938, Li 0.0596; liquid1: Ca 0.55467, Li 0.40843	unspecified	[1] Zhang 2003	Table 6, p. 6, row 2 report
503.3	eutectic: Liquid1 -> fcc(Ca) + CaLi2 + liquid2	Liquid1: Ca 0.4187, Li 0.56827; fcc(Ca): Ca 0.90507, Li 0.09418; CaLi2: Ca 0.33333, Li 0.66667; liquid2: Ca 3.460e-4, Li 0.03853	unspecified	[1] Zhang 2003	Table 6, p. 6, row 3 report
503.3	quasi-peritectic: Liquid2 + liquid1 -> fcc(Ca) + CaLi2	Liquid2: Ca 3.460e-4, Li 0.03853; liquid1: Ca 0.4187, Li 0.56827; fcc(Ca): Ca 0.90507, Li 0.09418; CaLi2: Ca 0.33333, Li 0.66667	unspecified	[1] Zhang 2003	Table 6, p. 6, row 4 report
415	quasi-peritectic: Liquid2 + liquid1 -> bcc(Li) + CaLi2	Liquid2: Li 0.0709; liquid1: Ca 0.06343, Li 0.92035; bcc(Li): Ca 0.01401, Li 0.98335; CaLi2: Ca 0.33333, Li 0.66667	unspecified	[1] Zhang 2003	Table 6, p. 6, row 6 report
415	eutectic: Liquid1 -> bcc(Li) + CaLi2 + liquid2	Liquid1: Ca 0.06343, Li 0.92035; bcc(Li): Ca 0.01401, Li 0.98335; CaLi2: Ca 0.33333, Li 0.66667; liquid2: Li 0.0709	unspecified	[1] Zhang 2003	Table 6, p. 6, row 5 report
368.5	quasi-peritectic: Liquid2 + fcc(Ca) -> bcc(Na) + CaLi2	Liquid2: Li 0.00689; fcc(Ca): Ca 0.97337, Li 0.02658; bcc(Na): Li 0.00121; CaLi2: Ca 0.33333, Li 0.66667	unspecified	[1] Zhang 2003	Table 6, p. 6, row 7 report
359.7	quasi-peritectic: Liquid2 + CaLi2 -> bcc(Na) + bcc(Li)	Liquid2: Li 0.03525; CaLi2: Ca 0.33333, Li 0.66667; bcc(Na): Li 0.00496; bcc(Li): Li 0.50054	unspecified	[1] Zhang 2003	Table 6, p. 6, row 8 report

Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

Shengjun Zhang, Dongwon Shin, Zi-Kui Liu, Thermodynamic modeling of the Ca–Li–Na system, Calphad 27, 235-241 (2003). doi:10.1016/j.calphad.2003.09.001

Please cite

R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23735569
R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0). Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}