Ge–Y system

60 accepted literature values from 1 paper(s) (experimental 26, model 34); 1 calculated phase diagram(s). 2 further extracted value(s) not accepted by the reader-agreement checks are only in the JSON/CSV.

Data: JSON · CSV · interactive explorer · interactive phase diagram · phases (14) · papers (bibliography) · Markdown

Accepted values by evidence class
Evidence class	Values
experimental	26
model	34

Accepted values by property group
Property group	Values
invariant reaction	28
phase transition	9
formation	23

Calculated phase diagrams

Binary phase diagrams calculated with pycalphad 0.11.2 from the SGTE binary collection (Hallstedt 2025, CC BY 4.0). Evidence class: model.

Assessments with a calculated phase diagram
TDB file	Assessment	SHA-256	Links
GeY-13Idb.tdb	M. Idbenali, C. Servant, J. Therm. Anal. Calorim., 111, 911-16(2013). doi:10.1007/s10973-012-2271-0	`06a372a4f32faf120821f330a7702cab696f4e92fb451f414368f8042f13493a`	viewer · TDB · JSON

Calculated three-phase invariants (model, mole fraction of the second component)
TDB file	T (K)	Phases at the invariant
GeY-13Idb.tdb	2215.33	GE4Y5 (x(Y) 0.55556) + LIQUID (x(Y) 0.57356) + GE3Y5_D88 (x(Y) 0.625)
GeY-13Idb.tdb	2215.33	GE4Y5 (x(Y) 0.55556) + LIQUID (x(Y) 0.57339) + GE3Y5_D88 (x(Y) 0.625)
GeY-13Idb.tdb	2215.33	GE4Y5 (x(Y) 0.55556) + LIQUID (x(Y) 0.57394) + GE3Y5_D88 (x(Y) 0.625)
GeY-13Idb.tdb	2157.47	LIQUID (x(Y) 0.47799) + GE10Y11 (x(Y) 0.52381) + GE4Y5 (x(Y) 0.55556)
GeY-13Idb.tdb	2157.46	LIQUID (x(Y) 0.47776) + GE10Y11 (x(Y) 0.52381) + GE4Y5 (x(Y) 0.55556)
GeY-13Idb.tdb	2008.97	LIQUID (x(Y) 0.39879) + GEY_B33 (x(Y) 0.5) + GE10Y11 (x(Y) 0.52381)
GeY-13Idb.tdb	2008.97	LIQUID (x(Y) 0.39871) + GEY_B33 (x(Y) 0.5) + GE10Y11 (x(Y) 0.52381)
GeY-13Idb.tdb	2008.97	LIQUID (x(Y) 0.39892) + GEY_B33 (x(Y) 0.5) + GE10Y11 (x(Y) 0.52381)
GeY-13Idb.tdb	1735.74	LIQUID (x(Y) 0.97305) + BCC_A2 (x(Y) 0.99709) + HCP_A3 (x(Y) 1)
GeY-13Idb.tdb	1732.57	LIQUID (x(Y) 0.31451) + GE3Y2_HT (x(Y) 0.4) + GEY_B33 (x(Y) 0.5)
GeY-13Idb.tdb	1732.57	LIQUID (x(Y) 0.31445) + GE3Y2_HT (x(Y) 0.4) + GEY_B33 (x(Y) 0.5)
GeY-13Idb.tdb	1732.57	LIQUID (x(Y) 0.31467) + GE3Y2_HT (x(Y) 0.4) + GEY_B33 (x(Y) 0.5)
GeY-13Idb.tdb	1707.4	GE3Y2_HT (x(Y) 0.4) + GE3Y2_C32 (x(Y) 0.4) + GEY_B33 (x(Y) 0.5)
GeY-13Idb.tdb	1707.4	LIQUID (x(Y) 0.30352) + GE3Y2_C32 (x(Y) 0.4) + GE3Y2_HT (x(Y) 0.4)
GeY-13Idb.tdb	1707.4	LIQUID (x(Y) 0.30331) + GE3Y2_HT (x(Y) 0.4) + GE3Y2_C32 (x(Y) 0.4)
GeY-13Idb.tdb	1549.61	GE3Y5_D88 (x(Y) 0.625) + LIQUID (x(Y) 0.90517) + HCP_A3 (x(Y) 1)
GeY-13Idb.tdb	1177.32	LIQUID (x(Y) 0.16179) + GE5Y3_CC (x(Y) 0.375) + GE3Y2_C32 (x(Y) 0.4)
GeY-13Idb.tdb	1177.32	LIQUID (x(Y) 0.16176) + GE5Y3_CC (x(Y) 0.375) + GE3Y2_C32 (x(Y) 0.4)
GeY-13Idb.tdb	1132.58	LIQUID (x(Y) 0.15153) + GE2Y (x(Y) 0.33333) + GE5Y3_CC (x(Y) 0.375)
GeY-13Idb.tdb	1130.45	LIQUID (x(Y) 0.15093) + GE7Y2 (x(Y) 0.22222) + GE2Y (x(Y) 0.33333)
GeY-13Idb.tdb	1112.3	DIAMOND_A4 (x(Y) 0) + LIQUID (x(Y) 0.13854) + GE7Y2 (x(Y) 0.22222)
GeY-13Idb.tdb	1112.3	DIAMOND_A4 (x(Y) 0) + LIQUID (x(Y) 0.13839) + GE7Y2 (x(Y) 0.22222)
GeY-13Idb.tdb	1112.3	DIAMOND_A4 (x(Y) 0) + LIQUID (x(Y) 0.13853) + GE7Y2 (x(Y) 0.22222)
GeY-13Idb.tdb	1031.26	DIAMOND_A4 (x(Y) 0) + GE7Y2 (x(Y) 0.22222) + GE2Y (x(Y) 0.33333)
GeY-13Idb.tdb	1028.66	DIAMOND_A4 (x(Y) 0) + GE2Y (x(Y) 0.33333) + GE5Y3_CC (x(Y) 0.375)
GeY-13Idb.tdb	510.28	GEY_B33 (x(Y) 0.5) + GE10Y11 (x(Y) 0.52381) + GE4Y5 (x(Y) 0.55556)

Convex hulls: Materials Project DFT hull · OQMD DFT hull

Invariant reactions (literature)

Invariant reactions reported in the literature for the Ge–Y system (28)
T (K)	Reaction / phases	Compositions (mole fraction)	Class	Source	Location
2218	Ge4Y5 -> Liq + Ge3Y5	Ge4Y5: Y 0.555556; L: Y 0.552; Ge3Y5: Y 0.625	experimental	[1] Idbenali 2013 cites Schmidt 1972 doi	Table 3, p. 4, row 19 report
2214	Ge4Y5 -> Liq + Ge3Y5	Ge4Y5: Y 0.555556; L: Y 0.572; Ge3Y5: Y 0.625	model	[1] Idbenali 2013	Table 3, p. 4, row 20 report
2173	Ge10Y11 -> Liq + Ge4Y5	Ge10Y11: Y 0.52381; L: Y 0.498; Ge4Y5: Y 0.555556	experimental	[1] Idbenali 2013 cites Schmidt 1972 doi	Table 3, p. 4, row 17 report
2157	Ge10Y11 -> Liq + Ge4Y5	Ge10Y11: Y 0.52381; L: Y 0.477; Ge4Y5: Y 0.555556	model	[1] Idbenali 2013	Table 3, p. 4, row 18 report
2003	GeY -> Liq + Ge10Y11	GeY: Y 0.5; L: Y 0.396; Ge10Y11: Y 0.52381	model	[1] Idbenali 2013	Table 3, p. 4, row 16 report
2003	GeY -> Liq + Ge10Y11	GeY: Y 0.5; L: Y 0.44; Ge10Y11: Y 0.52381	experimental	[1] Idbenali 2013 cites Schmidt 1972 doi	Table 3, p. 4, row 15 report
1736	HCP -> BCC + Liq	L: Y 0.973	model	[1] Idbenali 2013	Table 3, p. 4, row 26 report
1733	Ge1.5Y-HT -> GeY + Liq	Ge1.5Y-HT: Y 0.4; GeY: Y 0.5; L: Y 0.314	model	[1] Idbenali 2013	Table 3, p. 4, row 14 report
1733	HCP -> BCC + Liq	L: Y 0.97	experimental	[1] Idbenali 2013 cites Schmidt 1972 doi	Table 3, p. 4, row 25 report
1732	Ge1.5Y-HT -> GeY + Liq	Ge1.5Y-HT: Y 0.4; GeY: Y 0.5; L: Y 0.384	experimental	[1] Idbenali 2013 cites Schmidt 1972 doi	Table 3, p. 4, row 13 report
1707	Ge1.5Y-HT + Liq -> Ge1.5Y-LT	Ge1.5Y-HT: Y 0.4; L: Y 0.491; Ge1.5Y-LT: Y 0.4	model	[1] Idbenali 2013	Table 3, p. 4, row 28 report
1707	Ge1.5Y-HT + GeY -> Ge1.5Y-LT	Ge1.5Y-HT: Y 0.303; GeY: Y 0.5; Ge1.5Y-LT: Y 0.4	model	[1] Idbenali 2013	Table 3, p. 4, row 30 report
1703	Ge1.5Y-HT + Liq -> Ge1.5Y-LT	Ge1.5Y-HT: Y 0.4; L: Y 0.366; Ge1.5Y-LT: Y 0.4	experimental	[1] Idbenali 2013 cites Schmidt 1972 doi	Table 3, p. 4, row 27 report
1703	Ge1.5Y-HT + GeY -> Ge1.5Y-LT	Ge1.5Y-HT: Y 0.384; GeY: Y 0.5; Ge1.5Y-LT: Y 0.4	experimental	[1] Idbenali 2013 cites Schmidt 1972 doi	Table 3, p. 4, row 29 report
1553	eutectic: Liq -> HCP + Ge3Y5	L: Y 0.88; Ge3Y5: Y 0.625	experimental	[1] Idbenali 2013 cites Schmidt 1972 doi	Table 3, p. 4, row 23 report
1550	eutectic: Liq -> HCP + Ge3Y5	L: Y 0.905; Ge3Y5: Y 0.625	model	[1] Idbenali 2013	Table 3, p. 4, row 24 report
1181	Ge5Y3 -> Liq + Ge1.5Y-LT	Ge5Y3: Y 0.375; L: Y 0.164; Ge1.5Y-LT: Y 0.4	experimental	[1] Idbenali 2013 cites Schmidt 1972 doi	Table 3, p. 4, row 11 report
1177	Ge5Y3 -> Liq + Ge1.5Y-LT	Ge5Y3: Y 0.375; L: Y 0.161; Ge1.5Y-LT: Y 0.4	model	[1] Idbenali 2013	Table 3, p. 4, row 12 report
1163	Ge2Y -> Liq + Ge5Y3	Ge2Y: Y 0.333333; L: Y 0.152; Ge5Y3: Y 0.375	experimental	[1] Idbenali 2013 cites Schmidt 1972 doi	Table 3, p. 4, row 9 report
1150	Ge2Y -> Liq + Ge5Y3	Ge2Y: Y 0.333333; L: Y 0.155; Ge5Y3: Y 0.375	model	[1] Idbenali 2013	Table 3, p. 4, row 10 report
1133	Ge7Y2 -> Ge2Y + Liq	Ge7Y2: Y 0.222222; Ge2Y: Y 0.333333; L: Y 0.142	experimental	[1] Idbenali 2013 cites Schmidt 1972 doi	Table 3, p. 4, row 7 report
1132	Ge7Y2 -> Ge2Y + Liq	Ge7Y2: Y 0.222222; Ge2Y: Y 0.333333; L: Y 0.15	model	[1] Idbenali 2013	Table 3, p. 4, row 8 report
1113	(Ge) + Ge7Y2 -> Liq	(Ge): Y 0; Ge7Y2: Y 0.222222; L: Y 0.137	model	[1] Idbenali 2013	Table 3, p. 4, row 2 report
1093	(Ge) + Ge7Y2 -> Liq	(Ge): Y 0; Ge7Y2: Y 0.222222; L: Y 0.119	experimental	[1] Idbenali 2013 cites Schmidt 1972 doi	Table 3, p. 4, row 1 report
1033	Ge7Y2 -> Ge2Y + (Ge)	Ge7Y2: Y 0.222222; Ge2Y: Y 0.333333; (Ge): Y 0	experimental	[1] Idbenali 2013 cites Schmidt 1972 doi	Table 3, p. 4, row 5 report
1031	Ge7Y2 -> Ge2Y + (Ge)	Ge7Y2: Y 0.222222; Ge2Y: Y 0.333333; (Ge): Y 0	model	[1] Idbenali 2013	Table 3, p. 4, row 6 report
985	(Ge) + Ge5Y3 -> Ge2Y	(Ge): Y 0; Ge5Y3: Y 0.375; Ge2Y: Y 0.333333	experimental	[1] Idbenali 2013 cites Schmidt 1972 doi	Table 3, p. 4, row 3 report
982	(Ge) + Ge5Y3 -> Ge2Y	(Ge): Y 0; Ge5Y3: Y 0.375; Ge2Y: Y 0.333333	model	[1] Idbenali 2013	Table 3, p. 4, row 4 report

Formation enthalpies

Literature values in kJ/mol-atom where the per-atom basis is known. DFT columns: the lowest-energy entry at the same composition (Materials Project 2026.04.13, OQMD v1.8; different energy references, never averaged), from dft_parity.json.

Enthalpies of formation, Ge–Y system (23)
Phase	Compound	Value	T (K)	Class	MP DFT (kJ/mol-atom)	OQMD DFT (kJ/mol-atom)	Source	Location
Ge1.5Y-HT	Ge3Y2	-84.1 kJ/mol-atom ± 3.7	870	experimental	-48.013 (mp-aaacreze)		[1] Idbenali 2013 cites Polotskaya 1996 doi	Table 4, p. 5, row 7 report
Ge1.5Y-HT	Ge3Y2	-83.025 kJ/mol-atom	2985	model	-48.013 (mp-aaacreze)		[1] Idbenali 2013	Table 4, p. 5, row 9 report
Ge1.5Y-HT	Ge3Y2	-67.903 kJ/mol-atom	870	model	-48.013 (mp-aaacreze)		[1] Idbenali 2013	Table 4, p. 5, row 8 report
Ge1.5Y-LT	Ge3Y2	-84.785 kJ/mol-atom	298.15	model	-48.013 (mp-aaacreze)		[1] Idbenali 2013	Table 4, p. 5, row 6 report
Ge1.5Y-LT	Ge3Y2	-77.8 kJ/mol-atom ± 3.4	870	experimental	-48.013 (mp-aaacreze)		[1] Idbenali 2013 cites Polotskaya 1996 doi	Table 4, p. 5, row 4 report
Ge1.5Y-LT	Ge3Y2	-69.664 kJ/mol-atom	870	model	-48.013 (mp-aaacreze)		[1] Idbenali 2013	Table 4, p. 5, row 5 report
Ge10Y11	Ge10Y11	-104.82 kJ/mol-atom	298.15	model	-84.382 (mp-aaacqssw)		[1] Idbenali 2013	Table 4, p. 5, row 16 report
Ge10Y11	Ge10Y11	-100.5 kJ/mol-atom ± 5.2	870	experimental	-84.382 (mp-aaacqssw)		[1] Idbenali 2013 cites Polotskaya 1996 doi	Table 4, p. 5, row 14 report
Ge10Y11	Ge10Y11	-89.461 kJ/mol-atom	870	model	-84.382 (mp-aaacqssw)		[1] Idbenali 2013	Table 4, p. 5, row 15 report
Ge2Y	Ge2Y	-69.577 kJ/mol-atom	298.15	model	-51.377 (mp-aaaaapcv)	-59.996 (oqmd-1795069)	[1] Idbenali 2013	Table 4, p. 5, row 2 report
Ge3Y5	Ge3Y5	-109.7 kJ/mol-atom ± 5.7	298.15	experimental	-80.391 (mp-aaaabagt)	-80.471 (oqmd-10313)	[1] Idbenali 2013 cites Jung 1991 doi	Table 4, p. 5, row 20 report
Ge3Y5	Ge3Y5	-107.41 kJ/mol-atom	298.15	model	-80.391 (mp-aaaabagt)	-80.471 (oqmd-10313)	[1] Idbenali 2013	Table 4, p. 5, row 23 report
Ge3Y5	Ge3Y5	-91.861 kJ/mol-atom	870	model	-80.391 (mp-aaaabagt)	-80.471 (oqmd-10313)	[1] Idbenali 2013	Table 4, p. 5, row 22 report
Ge3Y5	Ge3Y5	-89.8 kJ/mol-atom ± 5	298.15	experimental	-80.391 (mp-aaaabagt)	-80.471 (oqmd-10313)	[1] Idbenali 2013 cites Safonov 1985	Table 4, p. 5, row 21 report
Ge4Y5	Ge4Y5	-109.55 kJ/mol-atom	298.15	model	-84.954 (mp-aaaaattw)	-85.431 (oqmd-124138)	[1] Idbenali 2013	Table 4, p. 5, row 19 report
Ge4Y5	Ge4Y5	-102.5 kJ/mol-atom ± 5.5	870	experimental	-84.954 (mp-aaaaattw)	-85.431 (oqmd-124138)	[1] Idbenali 2013 cites Polotskaya 1996 doi	Table 4, p. 5, row 17 report
Ge4Y5	Ge4Y5	-94.131 kJ/mol-atom	870	model	-84.954 (mp-aaaaattw)	-85.431 (oqmd-124138)	[1] Idbenali 2013	Table 4, p. 5, row 18 report
Ge5Y3	Ge5Y3	-79.834 kJ/mol-atom	298.15	model	-69.583 (mp-aaaaazik)	-69.416 (oqmd-1795285)	[1] Idbenali 2013	Table 4, p. 5, row 3 report
Ge7Y2		-42.349 kJ/mol-atom	298.15	model			[1] Idbenali 2013	Table 4, p. 5, row 1 report
GeY	GeY	-108.8 kJ/mol-atom		model	-86.308 (mp-aaaaaotn)	-86.397 (oqmd-7938)	[1] Idbenali 2013 cites Miedema 1976 doi	Table 4, p. 5, row 24 report
GeY	GeY	-101.53 kJ/mol-atom	298.15	model	-86.308 (mp-aaaaaotn)	-86.397 (oqmd-7938)	[1] Idbenali 2013	Table 4, p. 5, row 13 report
GeY	GeY	-98 kJ/mol-atom ± 4.9	870	experimental	-86.308 (mp-aaaaaotn)	-86.397 (oqmd-7938)	[1] Idbenali 2013 cites Polotskaya 1996 doi	Table 4, p. 5, row 10 report
GeY	GeY	-86.218 kJ/mol-atom	870	model	-86.308 (mp-aaaaaotn)	-86.397 (oqmd-7938)	[1] Idbenali 2013	Table 4, p. 5, row 12 report

Other properties

Phase transition (9)

Phase transition, Ge–Y system
Property	Value	T (K)	Phases / composition	Class	Source	Location	Quote
Phase transition	1093 K	1093	(Ge) ? Ge7Y2 , Liq	experimental	[1] Idbenali 2013 cites Schmidt 1972 doi	p. 4 report	The temperature of invariant reactions fits well the experiments [1] except both the temperature of the invariant reaction: (Ge) ? Ge7Y2 , Liq (calculated 1113 K, measured 1093 K) and Ge10Y11 , Liq ? Ge4Y5 (calculated 2157 K, measured 2173 K).
Phase transition	1113 K	1113	(Ge) ? Ge7Y2 , Liq	model	[1] Idbenali 2013	p. 4 report	The temperature of invariant reactions fits well the experiments [1] except both the temperature of the invariant reaction: (Ge) ? Ge7Y2 , Liq (calculated 1113 K, measured 1093 K) and Ge10Y11 , Liq ? Ge4Y5 (calculated 2157 K, measured 2173 K).
Phase transition	1703 K	1703	polymorphic	experimental	[1] Idbenali 2013 cites Schmidt 1972 doi	p. 1 report	A polymorphic transition (Ge1.5Y_LT , Ge1.5Y_HT) was determined at 1703 K for Ge1.5Y in [1].
Phase transition	1710 K	1710	polymorphic	model	[1] Idbenali 2013	p. 4 report	It is necessary to use all the digits of the optimized parameters listed in Table 3 for the calculation of the polymorphic transition temperature between the polytypes at T = 1710 K.
Phase transition	2157 K	2157	Ge10Y11 , Liq ? Ge4Y5	model	[1] Idbenali 2013	p. 4 report	The temperature of invariant reactions fits well the experiments [1] except both the temperature of the invariant reaction: (Ge) ? Ge7Y2 , Liq (calculated 1113 K, measured 1093 K) and Ge10Y11 , Liq ? Ge4Y5 (calculated 2157 K, measured 2173 K).
Phase transition	2173 K	2173	Ge10Y11 , Liq ? Ge4Y5	experimental	[1] Idbenali 2013 cites Schmidt 1972 doi	p. 4 report	The temperature of invariant reactions fits well the experiments [1] except both the temperature of the invariant reaction: (Ge) ? Ge7Y2 , Liq (calculated 1113 K, measured 1093 K) and Ge10Y11 , Liq ? Ge4Y5 (calculated 2157 K, measured 2173 K).
Phase transition	2238 K	2238	Ge3Y5 -> Liq Ge3Y5: Y 0.625; L: Y 0.625	experimental	[1] Idbenali 2013 cites Schmidt 1972 doi	Table 3, p. 4, row 21 report
Phase transition	2238 K	2238	congruent melting	experimental	[1] Idbenali 2013	p. 1 report	For the Ge3Y5 compound, a congruent melting was determined at 2238 K; for the Ge4Y5, Ge10Y11, GeY, Ge1.5Y-LT, Ge1.5Y-HT, Ge5Y3, Ge2Y and Ge7Y2 compounds, a peritectic formation was reported, respectively, at 2218, 2173, 2003, 1733, 1183, 1153, and 1133 K see Fig. 1.
Phase transition	2241 K	2241	Ge3Y5 -> Liq Ge3Y5: Y 0.625; L: Y 0.625	model	[1] Idbenali 2013	Table 3, p. 4, row 22 report

Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

Mohamed Idbenali, Colette Servant, Thermodynamic optimization of the germanium–yttrium system, J Therm Anal Calorim 111, 911-916 (2013). doi:10.1007/s10973-012-2271-0

Please cite

R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23735569
R. Arróyave, J. Saal, D. Shin, ORCHID-Diagrams: calculated binary phase diagrams (version 2026.10), Zenodo (2026). doi:10.5281/zenodo.23735859
R. Arróyave, J. Saal, D. Shin, ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD) (version 2026.10), Zenodo (2026). doi:10.5281/zenodo.23735891
R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0). Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_phase_diagrams_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Diagrams: calculated binary phase diagrams}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735859},
  url       = {https://doi.org/10.5281/zenodo.23735859}
}

@misc{orchid_hulls_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD)}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735891},
  url       = {https://doi.org/10.5281/zenodo.23735891}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}