In–Li system

22 accepted literature values from 1 paper(s) (experimental 14, model 8); 2 calculated phase diagram(s). 5 further extracted value(s) not accepted by the reader-agreement checks are only in the JSON/CSV.

Data: JSON · CSV · interactive explorer · interactive phase diagram · phases (11) · papers (bibliography) · Markdown

Accepted values by evidence class
Evidence class	Values
experimental	14
model	8

Accepted values by property group
Property group	Values
invariant reaction	20
phase transition	1
phase equilibrium	1

Calculated phase diagrams

Binary phase diagrams calculated with pycalphad 0.11.2 from the SGTE binary collection (Hallstedt 2025, CC BY 4.0). Evidence class: model.

Assessments with a calculated phase diagram
TDB file	Assessment	SHA-256	Links
InLi-20Zho.tdb	X. Zhou, F. Zhang, S. Liu, Y. Du, B. Jin, Calphad, 70, 101779(2020). doi:10.1016/j.calphad.2020.101779	`3296b39d521eca353c878566a377a6d340c00d10ec4729afacdfd9c78c0076bf`	viewer · TDB · JSON
InLi-22Gie.tdb	W. Gierlotka, W. Gasior, A. Debski, M. Zabrocki, J. Mining Metall. B, 58, 75-84(2022). doi:10.2298/JMMB210205041G	`ef7f71f31b5a62afdef9e11439b6ff718b6081df24f830d32b1b220ac27b6f12`	viewer · TDB · JSON

Calculated three-phase invariants (model, mole fraction of the second component)
TDB file	T (K)	Phases at the invariant
InLi-20Zho.tdb	673.13	INLI_B32 (x(Li) 0.75198) + IN3LI13 (x(Li) 0.8125) + LIQUID (x(Li) 0.81393)
InLi-20Zho.tdb	664.28	INLI2 (x(Li) 0.70585) + INLI_B32 (x(Li) 0.74972) + IN3LI13 (x(Li) 0.8125)
InLi-20Zho.tdb	664.28	INLI2 (x(Li) 0.7058) + INLI_B32 (x(Li) 0.74965) + IN3LI13 (x(Li) 0.8125)
InLi-20Zho.tdb	618.95	INLI2 (x(Li) 0.70128) + INLI3_L12 (x(Li) 0.75) + IN3LI13 (x(Li) 0.8125)
InLi-20Zho.tdb	618.95	INLI2 (x(Li) 0.70125) + INLI3_L12 (x(Li) 0.75) + IN3LI13 (x(Li) 0.8125)
InLi-20Zho.tdb	618.95	INLI2 (x(Li) 0.70122) + INLI3_L12 (x(Li) 0.75) + IN3LI13 (x(Li) 0.8125)
InLi-20Zho.tdb	568.85	INLI_B32 (x(Li) 0.56633) + IN2LI3 (x(Li) 0.6) + INLI2 (x(Li) 0.66653)
InLi-20Zho.tdb	451	IN3LI13 (x(Li) 0.8125) + LIQUID (x(Li) 0.99214) + BCC_A2 (x(Li) 1)
InLi-20Zho.tdb	432.71	LIQUID (x(Li) 0.05003) + TETRAGONAL_A6 (x(Li) 0.05008) + INLI_B32 (x(Li) 0.37723)
InLi-22Gie.tdb	663.88	INLI_B32 (x(Li) 0.72013) + LIQUID (x(Li) 0.81141) + IN3LI13 (x(Li) 0.8125)
InLi-22Gie.tdb	656.98	INLI2 (x(Li) 0.66667) + INLI_B32 (x(Li) 0.71622) + IN3LI13 (x(Li) 0.8125)
InLi-22Gie.tdb	583.64	INLI_B32 (x(Li) 0.55294) + IN2LI3 (x(Li) 0.6) + INLI2 (x(Li) 0.66667)
InLi-22Gie.tdb	579.52	IN3LI13 (x(Li) 0.8125) + INLI6 (x(Li) 0.85714) + LIQUID (x(Li) 0.94303)
InLi-22Gie.tdb	451.99	INLI6 (x(Li) 0.85714) + LIQUID (x(Li) 0.99729) + BCC_A2 (x(Li) 1)
InLi-22Gie.tdb	431.97	LIQUID (x(Li) 0.00516) + TETRAGONAL_A6 (x(Li) 0.00876) + INLI_B32 (x(Li) 0.49994)

Convex hulls: Materials Project DFT hull · OQMD DFT hull · CALPHAD hull InLi-20Zho

Invariant reactions (literature)

Invariant reactions reported in the literature for the In–Li system (20)
T (K)	Reaction / phases	Compositions (mole fraction)	Class	Source	Location
907	congruent melting: Liquid ⇄ InLi	Liquid: In 0.5, Li 0.5; InLi: In 0.5, Li 0.5	experimental	[1] Gierlotka 2022 cites Sangster 1991 doi	Table 3, p. 6, row 4 report
903	congruent melting: Liquid ⇄ InLi	Liquid: In 0.5, Li 0.5; InLi: In 0.5, Li 0.5	experimental	[1] Gierlotka 2022 cites Thummel 1970 doi	Table 3, p. 6, row 8 report
903	congruent melting: Liquid ⇄ InLi	Liquid: In 0.5, Li 0.5; InLi: In 0.5, Li 0.5	experimental	[1] Gierlotka 2022 cites Schneider 1956 doi	Table 3, p. 6, row 7 report
902	congruent melting: Liquid ⇄ InLi	Liquid: In 0.5, Li 0.5; InLi: In 0.5, Li 0.5	experimental	[1] Gierlotka 2022 cites Lamprecht 1969	Table 3, p. 6, row 6 report
898	congruent melting: Liquid ⇄ InLi	Liquid: In 0.5, Li 0.5; InLi: In 0.5, Li 0.5	model	[1] Gierlotka 2022	Table 3, p. 6, row 9 report
898	congruent melting: Liquid ⇄ InLi	Liquid: In 0.5, Li 0.5; InLi: In 0.5, Li 0.5	experimental	[1] Gierlotka 2022 cites Grube 1935	Table 3, p. 6, row 5 report
733	polymorphic: InLi ⇄ InLi2	InLi: In 0.5, Li 0.5; InLi2: In 0.333333, Li 0.666667	experimental	[1] Gierlotka 2022 cites Sangster 1991 doi	Table 3, p. 6, row 12 report
732	polymorphic: InLi ⇄ InLi2	InLi: In 0.5, Li 0.5; InLi2: In 0.333333, Li 0.666667	model	[1] Gierlotka 2022	Table 3, p. 6, row 13 report
673	InLi+Liquid ⇄ In3Li13	InLi: In 0.5, Li 0.5; In3Li13: In 0.1875, Li 0.8125	experimental	[1] Gierlotka 2022 cites Sangster 1991 doi	Table 3, p. 6, row 15 report
668	InLi+Liquid ⇄ In3Li13	InLi: In 0.5, Li 0.5; In3Li13: In 0.1875, Li 0.8125	model	[1] Gierlotka 2022	Table 3, p. 6, row 16 report
647	InLi ⇄ InLi2+In3Li13	InLi: In 0.5, Li 0.5; InLi2: In 0.333333, Li 0.666667; In3Li13: In 0.1875, Li 0.8125	model	[1] Gierlotka 2022	Table 3, p. 6, row 14 report
580	In3Li13+Liquid ⇄ InLi6	In3Li13: In 0.1875, Li 0.8125; InLi6: In 0.142857, Li 0.857143	model	[1] Gierlotka 2022	Table 3, p. 6, row 17 report
573	InLi+InLi2 ⇄ In2Li3	InLi: In 0.5, Li 0.5; InLi2: In 0.333333, Li 0.666667; In2Li3: In 0.4, Li 0.6	model	[1] Gierlotka 2022	Table 3, p. 6, row 11 report
568	InLi+InLi2 ⇄ In2Li3	InLi: In 0.5, Li 0.5; InLi2: In 0.333333, Li 0.666667; In2Li3: In 0.4, Li 0.6	experimental	[1] Gierlotka 2022 cites Sangster 1991 doi	Table 3, p. 6, row 10 report
453.5	Liquid ⇄ InLi6+(Li)	InLi6: In 0.142857, Li 0.857143	experimental	[1] Gierlotka 2022 cites Alexander 1976 doi	Table 3, p. 6, row 19 report
453	Liquid ⇄ InLi6+(Li)	InLi6: In 0.142857, Li 0.857143	model	[1] Gierlotka 2022	Table 3, p. 6, row 20 report
452	Liquid ⇄ InLi6+(Li)	InLi6: In 0.142857, Li 0.857143	experimental	[1] Gierlotka 2022 cites Sangster 1991 doi	Table 3, p. 6, row 18 report
432	Liquid ⇄ (In)+InLi	InLi: In 0.5, Li 0.5	model	[1] Gierlotka 2022	Table 3, p. 6, row 3 report
432	Liquid ⇄ (In)+InLi	InLi: In 0.5, Li 0.5	experimental	[1] Gierlotka 2022 cites Sangster 1991 doi	Table 3, p. 6, row 1 report
431	Liquid ⇄ (In)+InLi	InLi: In 0.5, Li 0.5	experimental	[1] Gierlotka 2022 cites Alexander 1976 doi	Table 3, p. 6, row 2 report

Other properties

Phase transition (1)

Phase transition, In–Li system
Property	Value	T (K)	Phases / composition	Class	Source	Location	Quote
Phase transition	898 K	898	congruent transformation	experimental	[1] Gierlotka 2022 cites Grube 1935	p. 1 report	Grube and Wolf [6] measured the congruent melting temperature of the InLi phase at 898 K and determined the liquidus line as well.

Phase equilibrium (1)

Phase equilibrium, In–Li system
Property	Value	T (K)	Phases / composition	Class	Source	Location	Quote
Phase assemblage		850	InLi alloy: Li 0.65	experimental	[1] Gierlotka 2022 cites Gasior 1992	p. 7 report	1), at the temperature of 850 K, two phases exist: Liquid and InLi. The experimental data shown in Figure 4 exhibit the activity of Li in the solid InLi phase. One can see that the calculation fairly reproduces the experiment. A disagreement can be found between the experimental determination for the composition equalling 0.65 mole fraction of Li and the calculation. The experimental point indica…

Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

W. Gierlotka, W. Gąsior, A. Dębski, M. Zabrocki, Thermodynamic modelling of the binary indium-lithium system, a promising li-ion battery material, J min metall B Metall 58, 75-84 (2022). doi:10.2298/jmmb210205041g

Please cite

R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23735569
R. Arróyave, J. Saal, D. Shin, ORCHID-Diagrams: calculated binary phase diagrams (version 2026.10), Zenodo (2026). doi:10.5281/zenodo.23735859
R. Arróyave, J. Saal, D. Shin, ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD) (version 2026.10), Zenodo (2026). doi:10.5281/zenodo.23735891
R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0). Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_phase_diagrams_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Diagrams: calculated binary phase diagrams}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735859},
  url       = {https://doi.org/10.5281/zenodo.23735859}
}

@misc{orchid_hulls_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD)}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735891},
  url       = {https://doi.org/10.5281/zenodo.23735891}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}