Mn–Zn system
97 accepted literature values from 2 paper(s) (experimental 58, model 39); 4 calculated phase diagram(s). 11 further extracted value(s) not accepted by the reader-agreement checks are only in the JSON/CSV.
Data: JSON · CSV · interactive explorer · interactive phase diagram · phases (14) · papers (bibliography) · Markdown
| Evidence class | Values |
|---|---|
| experimental | 58 |
| model | 39 |
| Property group | Values |
|---|---|
| invariant reaction | 60 |
| phase transition | 5 |
| phase equilibrium | 20 |
| crystal structure | 12 |
Calculated phase diagrams
Binary phase diagrams calculated with pycalphad 0.11.2 from the SGTE binary collection (Hallstedt 2025, CC BY 4.0). Evidence class: model.
| TDB file | Assessment | SHA-256 | Links |
|---|---|---|---|
| MnZn-04Mie.tdb | J. Miettinen, Calphad, 28, 313-20(2004). doi:10.1016/j.calphad.2004.09.003 | 67c8e80f90e043adb1136d56df0bf8104cf8fc8adcfab479bbd7172c4dcabc28 | viewer · TDB · JSON |
| MnZn-20Li.tdb | X. Li, S. Liu, K. Xu, Y. Zhang, Y. Du, Calphad, 69, 101770(2020). doi:10.1016/j.calphad.2020.101770 | 3bdc4ce0cf5991cda0878b27815e51bb15d9f5c8e1bd6c3bb7d6db43c70f4c22 | viewer · TDB · JSON |
| MnZn-21Li.tdb | X. Li, S. Liu, J. Huang, D. Huang, Y. Du, J. Alloys Compd., 863, 158484(2021). doi:10.1016/j.jallcom.2020.158484 | e98758ee612e75dd75ea05c6729ff395124968e7cd34877f36db1eabef7a4f97 | viewer · TDB · JSON |
| MnZn-22Li.tdb | X. Li, S. Liu, D. Huang, Y. Du, Calphad, 79, 102479(2022). doi:10.1016/j.calphad.2022.102479 | 3c480a9ea0b5d485aea750443e3f3eae40544a3a8ed1b3edd382fc58253993d3 | viewer · TDB · JSON |
| TDB file | T (K) | Phases at the invariant |
|---|---|---|
| MnZn-04Mie.tdb | 1087.86 | BCC_A2 (x(Zn) 0.46747) + HCP_IM_A3 (x(Zn) 0.54359) + LIQUID (x(Zn) 0.65834) |
| MnZn-04Mie.tdb | 893.33 | FCC_A1 (x(Zn) 0.3447) + BCC_A2 (x(Zn) 0.36926) + HCP_IM_A3 (x(Zn) 0.47786) |
| MnZn-04Mie.tdb | 802.8 | CUB_A13 (x(Zn) 0.25248) + FCC_A1 (x(Zn) 0.3215) + HCP_IM_A3 (x(Zn) 0.4696) |
| MnZn-04Mie.tdb | 735.85 | HCP_IM_A3 (x(Zn) 0.82659) + MNZN9 (x(Zn) 0.9) + LIQUID (x(Zn) 0.96361) |
| MnZn-04Mie.tdb | 735.85 | HCP_IM_A3 (x(Zn) 0.82664) + MNZN9 (x(Zn) 0.9) + LIQUID (x(Zn) 0.96365) |
| MnZn-04Mie.tdb | 686.78 | MNZN9 (x(Zn) 0.9) + LIQUID (x(Zn) 0.98936) + HCP_A3 (x(Zn) 0.99983) |
| MnZn-04Mie.tdb | 686.78 | MNZN9 (x(Zn) 0.9) + LIQUID (x(Zn) 0.98942) + HCP_A3 (x(Zn) 0.99983) |
| MnZn-04Mie.tdb | 454.25 | CBCC_A12 (x(Zn) 0.02482) + CUB_A13 (x(Zn) 0.2169) + HCP_IM_A3 (x(Zn) 0.53141) |
| MnZn-20Li.tdb | 1097.5 | BCC_A2 (x(Zn) 0.44551) + HCP_IM_A3 (x(Zn) 0.51704) + LIQUID (x(Zn) 0.63481) |
| MnZn-20Li.tdb | 889.21 | FCC_A1 (x(Zn) 0.32325) + BCC_A2 (x(Zn) 0.3747) + HCP_IM_A3 (x(Zn) 0.46038) |
| MnZn-20Li.tdb | 800.77 | CUB_A13 (x(Zn) 0.29828) + FCC_A1 (x(Zn) 0.32161) + HCP_IM_A3 (x(Zn) 0.47738) |
| MnZn-20Li.tdb | 754.96 | HCP_IM_A3 (x(Zn) 0.83243) + MNZN9_HT (x(Zn) 0.88836) + LIQUID (x(Zn) 0.95105) |
| MnZn-20Li.tdb | 722.05 | MNZN9_HT (x(Zn) 0.88872) + MNZN13 (x(Zn) 0.90206) + LIQUID (x(Zn) 0.97729) |
| MnZn-20Li.tdb | 716.94 | MNZN9_HT (x(Zn) 0.88873) + MNZN9_LT (x(Zn) 0.89333) + MNZN13 (x(Zn) 0.90226) |
| MnZn-20Li.tdb | 688.96 | HCP_IM_A3 (x(Zn) 0.80177) + MN5ZN21_D82 (x(Zn) 0.81667) + MNZN9_HT (x(Zn) 0.88818) |
| MnZn-20Li.tdb | 688.42 | MNZN13 (x(Zn) 0.9135) + LIQUID (x(Zn) 0.99135) + HCP_A3 (x(Zn) 0.99878) |
| MnZn-20Li.tdb | 652.46 | MN5ZN21_D82 (x(Zn) 0.81649) + MNZN9_HT (x(Zn) 0.88834) + MNZN9_LT (x(Zn) 0.88849) |
| MnZn-20Li.tdb | 597.54 | HCP_IM_A3 (x(Zn) 0.69967) + MNZN3_L12 (x(Zn) 0.72961) + MN5ZN21_D82 (x(Zn) 0.78917) |
| MnZn-20Li.tdb | 575.06 | CBCC_A12 (x(Zn) 0.01498) + CUB_A13 (x(Zn) 0.27117) + HCP_IM_A3 (x(Zn) 0.57715) |
| MnZn-20Li.tdb | 550.07 | CBCC_A12 (x(Zn) 0.01333) + HCP_IM_A3 (x(Zn) 0.60282) + MNZN3_L12 (x(Zn) 0.70044) |
| MnZn-20Li.tdb | 454.74 | CBCC_A12 (x(Zn) 0.00546) + MNZN_B2 (x(Zn) 0.5) + MNZN3_L12 (x(Zn) 0.71891) |
| MnZn-21Li.tdb | 1083.9 | BCC_A2 (x(Zn) 0.45377) + HCP_IM_A3 (x(Zn) 0.52059) + LIQUID (x(Zn) 0.64607) |
| MnZn-21Li.tdb | 889.41 | FCC_A1 (x(Zn) 0.32316) + BCC_A2 (x(Zn) 0.3746) + HCP_IM_A3 (x(Zn) 0.41852) |
| MnZn-21Li.tdb | 789.79 | CUB_A13 (x(Zn) 0.3013) + FCC_A1 (x(Zn) 0.32491) + HCP_IM_A3 (x(Zn) 0.44795) |
| MnZn-21Li.tdb | 762.52 | HCP_IM_A3 (x(Zn) 0.83552) + MNZN9_HT (x(Zn) 0.89324) + LIQUID (x(Zn) 0.95067) |
| MnZn-21Li.tdb | 722.78 | MNZN9_HT (x(Zn) 0.89875) + MNZN13 (x(Zn) 0.92061) + LIQUID (x(Zn) 0.97311) |
| MnZn-21Li.tdb | 698.11 | HCP_IM_A3 (x(Zn) 0.84662) + MNZN9_HT (x(Zn) 0.89605) + MNZN13 (x(Zn) 0.91943) |
| MnZn-21Li.tdb | 687.46 | MNZN13 (x(Zn) 0.92166) + LIQUID (x(Zn) 0.98947) + HCP_A3 (x(Zn) 0.99849) |
| MnZn-21Li.tdb | 684.16 | HCP_IM_A3 (x(Zn) 0.84479) + MNZN9_LT (x(Zn) 0.89895) + MNZN13 (x(Zn) 0.91919) |
| MnZn-21Li.tdb | 672.17 | MN5ZN21_D82 (x(Zn) 0.81919) + HCP_IM_A3 (x(Zn) 0.84104) + MNZN9_LT (x(Zn) 0.89772) |
| MnZn-21Li.tdb | 594.53 | HCP_IM_A3 (x(Zn) 0.70114) + MNZN3_L12 (x(Zn) 0.74038) + MN5ZN21_D82 (x(Zn) 0.78145) |
| MnZn-21Li.tdb | 568.64 | CBCC_A12 (x(Zn) 0.01492) + CUB_A13 (x(Zn) 0.27832) + HCP_IM_A3 (x(Zn) 0.58517) |
| MnZn-21Li.tdb | 542.65 | CBCC_A12 (x(Zn) 0.01316) + HCP_IM_A3 (x(Zn) 0.61264) + MNZN3_L12 (x(Zn) 0.71921) |
| MnZn-21Li.tdb | 451.92 | CBCC_A12 (x(Zn) 0.00561) + MNZN_B2 (x(Zn) 0.5) + MNZN3_L12 (x(Zn) 0.73332) |
| MnZn-22Li.tdb | 1103 | BCC_A2 (x(Zn) 0.45415) + HCP_IM_A3 (x(Zn) 0.51914) + LIQUID (x(Zn) 0.63048) |
| MnZn-22Li.tdb | 908.2 | FCC_A1 (x(Zn) 0.315) + BCC_A2 (x(Zn) 0.36536) + HCP_IM_A3 (x(Zn) 0.42313) |
| MnZn-22Li.tdb | 806.16 | CUB_A13 (x(Zn) 0.27382) + FCC_A1 (x(Zn) 0.3124) + HCP_IM_A3 (x(Zn) 0.44582) |
| MnZn-22Li.tdb | 749.89 | HCP_IM_A3 (x(Zn) 0.83959) + MNZN9_HT (x(Zn) 0.89311) + LIQUID (x(Zn) 0.95985) |
| MnZn-22Li.tdb | 730.01 | MNZN9_HT (x(Zn) 0.89572) + MNZN13 (x(Zn) 0.92035) + LIQUID (x(Zn) 0.97187) |
| MnZn-22Li.tdb | 692.07 | MNZN13 (x(Zn) 0.92159) + LIQUID (x(Zn) 0.98976) + HCP_A3 (x(Zn) 0.99048) |
| MnZn-22Li.tdb | 682.5 | MNZN9_HT (x(Zn) 0.89475) + MNZN9_LT (x(Zn) 0.89611) + MNZN13 (x(Zn) 0.91929) |
| MnZn-22Li.tdb | 682.14 | HCP_IM_A3 (x(Zn) 0.83704) + MNZN9_HT (x(Zn) 0.89399) + MNZN9_LT (x(Zn) 0.89471) |
| MnZn-22Li.tdb | 676.57 | MN5ZN21_D82 (x(Zn) 0.81883) + HCP_IM_A3 (x(Zn) 0.83526) + MNZN9_LT (x(Zn) 0.89418) |
| MnZn-22Li.tdb | 597.45 | HCP_IM_A3 (x(Zn) 0.7119) + MNZN3_L12 (x(Zn) 0.74698) + MN5ZN21_D82 (x(Zn) 0.78583) |
| MnZn-22Li.tdb | 550.59 | CUB_A13 (x(Zn) 0.33813) + HCP_IM_A3 (x(Zn) 0.64321) + MNZN3_L12 (x(Zn) 0.72866) |
| MnZn-22Li.tdb | 453.01 | CUB_A13 (x(Zn) 0.27798) + MNZN_B2 (x(Zn) 0.5) + MNZN3_L12 (x(Zn) 0.73534) |
| MnZn-22Li.tdb | 421.29 | CBCC_A12 (x(Zn) 0.00346) + CUB_A13 (x(Zn) 0.24433) + MNZN_B2 (x(Zn) 0.5) |
| MnZn-22Li.tdb | 421.29 | CBCC_A12 (x(Zn) 0.00347) + CUB_A13 (x(Zn) 0.24421) + MNZN_B2 (x(Zn) 0.5) |
Convex hulls: Materials Project DFT hull · OQMD DFT hull · CALPHAD hull MnZn-04Mie · CALPHAD hull MnZn-20Li · CALPHAD hull MnZn-21Li
Invariant reactions (literature)
| T (K) | Reaction / phases | Compositions (mole fraction) | Class | Source | Location | Quote |
|---|---|---|---|---|---|---|
| 1118.15 | peritectic: L + (δMn) ↔ ε | L: Zn 0.625; (δMn): Zn 0.46; ε: Zn 0.48 | model | [1] Li 2021 cites Ghosh 2013 doi | Table 5, p. 9, row 5 report | |
| 1108.15 | peritectic: L + (δMn) ↔ ε | L: Zn 0.62; (δMn): Zn 0.47; ε: Zn 0.5 | experimental | [1] Li 2021 cites Schramm 1940 doi | Table 5, p. 9, row 1 report | |
| 1097.15 | peritectic: L + (δMn) ↔ ε | L: Zn 0.635; (δMn): Zn 0.446; ε: Zn 0.517 | model | [1] Li 2021 cites Li 2020 doi | Table 5, p. 9, row 6 report | |
| 1088.15 | peritectic: L + (δMn) ↔ ε | L: Zn 0.658; (δMn): Zn 0.467; ε: Zn 0.544 | model | [1] Li 2021 cites Miettinen 2004 doi | Table 5, p. 9, row 3 report | |
| 1088.15 | peritectic: L + (δMn) ↔ ε | L: Zn 0.655; (δMn): Zn 0.481; ε: Zn 0.511 | model | [1] Li 2021 cites Khan 2009 | Table 5, p. 9, row 4 report | |
| 1088.15 | bcc–hcp–liq | bcc: Zn 0.5; hcp: Zn 0.53; liq: Zn 0.66 | experimental | [2] Miettinen 2004 cites Romer 1971 doi | Table 4, p. 5, row 1 report | |
| 1088.15 | peritectic: L + (δMn) ↔ ε | L: Zn 0.65; (δMn): Zn 0.5; ε: Zn 0.53 | experimental | [1] Li 2021 cites Romer 1971 doi | Table 5, p. 9, row 2 report | |
| 1088.15 | bcc–hcp–liq | bcc: Zn 0.467; hcp: Zn 0.544; liq: Zn 0.658 | model | [2] Miettinen 2004 | Table 4, p. 5, row 2 report | |
| 1084.15 | peritectic: L + (δMn) ↔ ε | L: Zn 0.646; (δMn): Zn 0.454; ε: Zn 0.521 | model | [1] Li 2021 | Table 5, p. 9, row 7 report | |
| 923.15 | eutectoid: (δMn) ↔ (γMn) + ε | (δMn): Zn 0.4; (γMn): Zn 0.35 | experimental | [1] Li 2021 cites Potter 1949 | Table 5, p. 9, row 8 report | |
| 906.15 | eutectoid: (δMn) ↔ (γMn) + ε | (δMn): Zn 0.363; (γMn): Zn 0.347; ε: Zn 0.4 | model | [1] Li 2021 cites Ghosh 2013 doi | Table 5, p. 9, row 12 report | |
| 900.15 | eutectoid: (δMn) ↔ (γMn) + ε | (δMn): Zn 0.372; (γMn): Zn 0.32; ε: Zn 0.428 | model | [1] Li 2021 cites Khan 2009 | Table 5, p. 9, row 11 report | |
| 893.15 | fcc–bcc–hcp | fcc: Zn 0.34; bcc: Zn 0.375; hcp: Zn 0.42 | experimental | [2] Miettinen 2004 cites Romer 1971 doi | Table 4, p. 5, row 3 report | |
| 893.15 | eutectoid: (δMn) ↔ (γMn) + ε | (δMn): Zn 0.38; (γMn): Zn 0.34; ε: Zn 0.42 | experimental | [1] Li 2021 cites Romer 1971 doi | Table 5, p. 9, row 9 report | |
| 892.15 | eutectoid: (δMn) ↔ (γMn) + ε | (δMn): Zn 0.369; (γMn): Zn 0.345; ε: Zn 0.478 | model | [1] Li 2021 cites Miettinen 2004 doi | Table 5, p. 9, row 10 report | |
| 892.15 | fcc–bcc–hcp | fcc: Zn 0.345; bcc: Zn 0.369; hcp: Zn 0.478 | model | [2] Miettinen 2004 | Table 4, p. 5, row 4 report | |
| 889.15 | eutectoid: (δMn) ↔ (γMn) + ε | (δMn): Zn 0.375; (γMn): Zn 0.323; ε: Zn 0.46 | model | [1] Li 2021 cites Li 2020 doi | Table 5, p. 9, row 13 report | |
| 888.15 | eutectoid: (δMn) ↔ (γMn) + ε | (δMn): Zn 0.375; (γMn): Zn 0.323; ε: Zn 0.419 | model | [1] Li 2021 | Table 5, p. 9, row 14 report | |
| 827.15 | eutectoid: (γMn) ↔ (βMn) + ε | (γMn): Zn 0.35; (βMn): Zn 0.18 | experimental | [1] Li 2021 cites Potter 1949 | Table 5, p. 9, row 15 report | |
| 805.15 | eutectoid: (γMn) ↔ (βMn) + ε | (γMn): Zn 0.357; (βMn): Zn 0.212; ε: Zn 0.427 | model | [1] Li 2021 cites Ghosh 2013 doi | Table 5, p. 9, row 19 report | |
| 804.15 | cub–fcc–hcp | cub: Zn 0.253; fcc: Zn 0.322; hcp: Zn 0.47 | model | [2] Miettinen 2004 | Table 4, p. 5, row 6 report | |
| 804.15 | eutectoid: (γMn) ↔ (βMn) + ε | (γMn): Zn 0.322; (βMn): Zn 0.253; ε: Zn 0.47 | model | [1] Li 2021 cites Miettinen 2004 doi | Table 5, p. 9, row 17 report | |
| 803.15 | cub–fcc–hcp | cub: Zn 0.24; fcc: Zn 0.31; hcp: Zn 0.46 | experimental | [2] Miettinen 2004 cites Romer 1971 doi | Table 4, p. 5, row 5 report | |
| 803.15 | eutectoid: (γMn) ↔ (βMn) + ε | (γMn): Zn 0.31; (βMn): Zn 0.25; ε: Zn 0.46 | experimental | [1] Li 2021 cites Romer 1971 doi | Table 5, p. 9, row 16 report | |
| 803.15 | eutectoid: (γMn) ↔ (βMn) + ε | (γMn): Zn 0.338; (βMn): Zn 0.224; ε: Zn 0.477 | model | [1] Li 2021 cites Khan 2009 | Table 5, p. 9, row 18 report | |
| 801.15 | eutectoid: (γMn) ↔ (βMn) + ε | (γMn): Zn 0.322; (βMn): Zn 0.298; ε: Zn 0.477 | model | [1] Li 2021 cites Li 2020 doi | Table 5, p. 9, row 20 report | |
| 790.15 | eutectoid: (γMn) ↔ (βMn) + ε | (γMn): Zn 0.301; (βMn): Zn 0.325; ε: Zn 0.448 | model | [1] Li 2021 | Table 5, p. 9, row 21 report | |
| 755.15 | peritectic: Liquid + ε ↔ δ-MnZn9_HT | Liquid: Zn 0.951; ε: Zn 0.832; δ-MnZn9_HT: Zn 0.889 | model | [1] Li 2021 cites Li 2020 doi | Table 5, p. 9, row 49 report | |
| 753.15 | peritectic: Liquid + ε ↔ δ-MnZn9_HT | Liquid: Zn 0.955; ε: Zn 0.84; δ-MnZn9_HT: Zn 0.894 | model | [1] Li 2021 | Table 5, p. 9, row 50 report | |
| 740.15 | peritectic: Liquid + ε ↔ δ-MnZn9_HT | Liquid: Zn 0.97; ε: Zn 0.863; δ-MnZn9_HT: Zn 0.883 | model | [1] Li 2021 cites Ghosh 2013 doi | Table 5, p. 9, row 48 report | |
| 736.15 | hcp–liq–MnZn9 | hcp: Zn 0.827; liq: Zn 0.964; MnZn9: Zn 0.9 | model | [2] Miettinen 2004 | Table 4, p. 5, row 8 report | |
| 736.15 | peritectic: Liquid + ε ↔ δ-MnZn9_HT | Liquid: Zn 0.964; ε: Zn 0.827; δ-MnZn9_HT: Zn 0.9 | model | [1] Li 2021 cites Miettinen 2004 doi | Table 5, p. 9, row 46 report | |
| 735.15 | peritectic: Liquid + ε ↔ δ-MnZn9_HT | Liquid: Zn 0.974; ε: Zn 0.87; δ-MnZn9_HT: Zn 0.9 | model | [1] Li 2021 cites Khan 2009 | Table 5, p. 9, row 47 report | |
| 735.15 | peritectic: Liquid + ε ↔ δ-MnZn9_HT | Liquid: Zn 0.963; ε: Zn 0.886; δ-MnZn9_HT: Zn 0.9 | experimental | [1] Li 2021 cites Schramm 1940 doi | Table 5, p. 9, row 44 report | |
| 735.15 | hcp–liq–MnZn9 | hcp: Zn 0.88; liq: Zn 0.96; MnZn9: Zn 0.9 | experimental | [2] Miettinen 2004 cites Romer 1971 doi | Table 4, p. 5, row 7 report | |
| 735.15 | peritectic: Liquid + ε ↔ δ-MnZn9_HT | ε: Zn 0.885; δ-MnZn9_HT: Zn 0.9 | experimental | [1] Li 2021 cites Wachtel 1967 doi | Table 5, p. 9, row 45 report | |
| 722.15 | peritectic: Liquid + δ-MnZn9_HT ↔ ζ-MnZn13 | Liquid: Zn 0.974; δ-MnZn9_HT: Zn 0.899; ζ-MnZn13: Zn 0.921 | model | [1] Li 2021 | Table 5, p. 9, row 55 report | |
| 713.15 | peritectoid: δ-MnZn9_HT + ζ-MnZn13 ↔ δ1-MnZn9 | δ-MnZn9_HT: Zn 0.889; ζ-MnZn13: Zn 0.907; δ1-MnZn9: Zn 0.893 | model | [1] Li 2021 cites Li 2020 doi | Table 5, p. 9, row 58 report | |
| 706.15 | peritectic: Liquid + δ-MnZn9_HT ↔ ζ-MnZn13 | Liquid: Zn 0.987; δ-MnZn9_HT: Zn 0.896; ζ-MnZn13: Zn 0.93 | model | [1] Li 2021 cites Ghosh 2013 doi | Table 5, p. 9, row 54 report | |
| 703.15 | peritectic: Liquid + δ-MnZn9_HT ↔ ζ-MnZn13 | δ-MnZn9_HT: Zn 0.905; ζ-MnZn13: Zn 0.92 | experimental | [1] Li 2021 cites Wachtel 1967 doi | Table 5, p. 9, row 52 report | |
| 701.15 | peritectic: Liquid + δ-MnZn9_HT ↔ ζ-MnZn13 | Liquid: Zn 0.987; δ-MnZn9_HT: Zn 0.9; ζ-MnZn13: Zn 0.929 | model | [1] Li 2021 cites Khan 2009 | Table 5, p. 9, row 53 report | |
| 701.15 | peritectic: Liquid + δ-MnZn9_HT ↔ ζ-MnZn13 | Liquid: Zn 0.981; δ-MnZn9_HT: Zn 0.906; ζ-MnZn13: Zn 0.927 | experimental | [1] Li 2021 cites Schramm 1940 doi | Table 5, p. 9, row 51 report | |
| 698.15 | peritectoid: δ-MnZn9_HT + ζ-MnZn13 ↔ δ1-MnZn9 | δ-MnZn9_HT: Zn 0.895; ζ-MnZn13: Zn 0.93; δ1-MnZn9: Zn 0.9 | model | [1] Li 2021 cites Ghosh 2013 doi | Table 5, p. 9, row 57 report | |
| 697.15 | peritectoid: δ-MnZn9_HT + ζ-MnZn13 ↔ δ1-MnZn9 | δ-MnZn9_HT: Zn 0.906; ζ-MnZn13: Zn 0.926; δ1-MnZn9: Zn 0.908 | experimental | [1] Li 2021 cites Schramm 1940 doi | Table 5, p. 9, row 56 report | |
| 691.15 | eutectic: Liquid ↔ ζ-MnZn13 + (Zn) | Liquid: Zn 0.993; ζ-MnZn13: Zn 0.875; (Zn): Zn 1 | experimental | [1] Li 2021 cites Parravano 1915 | Table 5, p. 9, row 60 report | |
| 691.15 | eutectic: Liquid ↔ ζ-MnZn13 + (Zn) | Liquid: Zn 0.989; ζ-MnZn13: Zn 0.922; (Zn): Zn 0.999 | model | [1] Li 2021 | Table 5, p. 9, row 66 report | |
| 689.15 | eutectic: Liquid ↔ ζ-MnZn13 + (Zn) | Liquid: Zn 0.986; ζ-MnZn13: Zn 0.929; (Zn): Zn 0.994 | experimental | [1] Li 2021 cites Schramm 1940 doi | Table 5, p. 9, row 63 report | |
| 689.15 | eutectic: Liquid ↔ ζ-MnZn13 + (Zn) | ζ-MnZn13: Zn 0.928571 | experimental | [1] Li 2021 cites Wachtel 1967 doi | Table 5, p. 9, row 64 report | |
| 689.15 | eutectic: Liquid ↔ ζ-MnZn13 + (Zn) | Liquid: Zn 0.99; ζ-MnZn13: Zn 0.872; (Zn): Zn 1 | experimental | [1] Li 2021 cites Siebe 1919 doi | Table 5, p. 9, row 61 report | |
| 688.15 | eutectic: Liquid ↔ ζ-MnZn13 + (Zn) | Liquid: Zn 0.991; ζ-MnZn13: Zn 0.919; (Zn): Zn 0.999 | model | [1] Li 2021 cites Li 2020 doi | Table 5, p. 9, row 65 report | |
| 688.15 | eutectoid: δ-MnZn9_HT ↔ ε + δ1-MnZn9 | δ-MnZn9_HT: Zn 0.886; ε: Zn 0.87; δ1-MnZn9: Zn 0.889 | experimental | [1] Li 2021 cites Schramm 1940 doi | Table 5, p. 9, row 38 report | |
| 687.15 | eutectic: Liquid ↔ ζ-MnZn13 + (Zn) | Liquid: Zn 0.995; ζ-MnZn13: Zn 0.9; (Zn): Zn 1 | experimental | [1] Li 2021 cites Ackermann 1927 doi | Table 5, p. 9, row 62 report | |
| 679.15 | eutectoid: δ-MnZn9_HT ↔ ε + δ1-MnZn9 | δ-MnZn9_HT: Zn 0.896; ε: Zn 0.844; δ1-MnZn9: Zn 0.898 | model | [1] Li 2021 | Table 5, p. 9, row 40 report | |
| 679.15 | peritectoid: δ-MnZn9_HT + ζ-MnZn13 ↔ δ1-MnZn9 | δ-MnZn9_HT: Zn 0.896; ζ-MnZn13: Zn 0.919; δ1-MnZn9: Zn 0.899 | model | [1] Li 2021 | Table 5, p. 9, row 59 report | |
| 672.15 | eutectoid: ε ↔ γ-Mn5Zn8 + δ1-MnZn9 | ε: Zn 0.8402; γ-Mn5Zn8: Zn 0.819; δ1-MnZn9: Zn 0.898 | model | [1] Li 2021 | Table 5, p. 9, row 43 report | |
| 653.15 | eutectoid: δ-MnZn9_HT ↔ ε + δ1-MnZn9 | δ-MnZn9_HT: Zn 0.865; ε: Zn 0.855; δ1-MnZn9: Zn 0.88 | experimental | [1] Li 2021 cites Wachtel 1967 doi | Table 5, p. 9, row 39 report | |
| 623.15 | eutectoid: ε ↔ γ-Mn5Zn8 + δ1-MnZn9 | ε: Zn 0.85; γ-Mn5Zn8: Zn 0.84; δ1-MnZn9: Zn 0.88 | experimental | [1] Li 2021 cites Wachtel 1967 doi | Table 5, p. 9, row 42 report | |
| 623.15 | eutectoid: ε ↔ γ-Mn5Zn8 + δ1-MnZn9 | ε: Zn 0.856; γ-Mn5Zn8: Zn 0.844; δ1-MnZn9: Zn 0.889 | experimental | [1] Li 2021 cites Schramm 1940 doi | Table 5, p. 9, row 41 report | |
| 575.15 | eutectoid: (βMn) ↔ ε + (αMn) | (βMn): Zn 0.271; ε: Zn 0.577; (αMn): Zn 0.0145 | model | [1] Li 2021 cites Li 2020 doi | Table 5, p. 9, row 22 report | |
| 568.15 | eutectoid: (βMn) ↔ ε + (αMn) | (βMn): Zn 0.585; ε: Zn 0.278; (αMn): Zn 0.0145 | model | [1] Li 2021 | Table 5, p. 9, row 23 report |
Other properties
Phase transition (5)
| Property | Value | T (K) | Phases / composition | Class | Source | Location | Quote |
|---|---|---|---|---|---|---|---|
| Phase transition | 673.15 K | 673.15 | congruent transformation: ε ↔ γ-Mn5Zn8 ε: Zn 0.808; γ-Mn5Zn8: Zn 0.808 | experimental | [1] Li 2021 cites Schramm 1940 doi | Table 5, p. 9, row 33 report | |
| Phase transition | 684.15 K | 684.15 | congruent transformation: ε ↔ γ-Mn5Zn8 ε: Zn 0.81; γ-Mn5Zn8: Zn 0.81 | model | [1] Li 2021 | Table 5, p. 9, row 37 report | |
| Phase transition | 686.15 K | 686.15 | congruent transformation: ε ↔ γ-Mn5Zn8 ε: Zn 0.816; γ-Mn5Zn8: Zn 0.816 | model | [1] Li 2021 cites Khan 2009 | Table 5, p. 9, row 35 report | |
| Phase transition | 693.15 K | 693.15 | congruent transformation: ε ↔ γ-Mn5Zn8 ε: Zn 0.615385; γ-Mn5Zn8: Zn 0.615385 | experimental | [1] Li 2021 cites Wachtel 1967 doi | Table 5, p. 9, row 34 report | |
| Phase transition | 694.15 K | 694.15 | congruent transformation: ε ↔ γ-Mn5Zn8 ε: Zn 0.807; γ-Mn5Zn8: Zn 0.807 | model | [1] Li 2021 cites Ghosh 2013 doi | Table 5, p. 9, row 36 report |
Phase equilibrium (20)
| Property | Value | T (K) | Phases / composition | Class | Source | Location | Quote |
|---|---|---|---|---|---|---|---|
| Phase assemblage | (Zn) alloy: Mn 0.08, Zn 0.92 | experimental | [1] Li 2021 | Table 6, p. 11, row 7 report | |||
| Phase assemblage | (Zn) alloy: Mn 0.045, Zn 0.955 | experimental | [1] Li 2021 | Table 6, p. 11, row 10 report | |||
| Phase assemblage | (Zn) alloy: Mn 0.045, Zn 0.955 | experimental | [1] Li 2021 | Table 6, p. 11, row 9 report | |||
| Phase assemblage | (Zn) alloy: Mn 0.08, Zn 0.92 | experimental | [1] Li 2021 | Table 6, p. 11, row 8 report | |||
| Phase assemblage | δ-MnZn9_HT alloy: Mn 0.08, Zn 0.92 | experimental | [1] Li 2021 | Table 6, p. 11, row 11 report | |||
| Phase assemblage | δ-MnZn9_HT alloy: Mn 0.045, Zn 0.955 | experimental | [1] Li 2021 | Table 6, p. 11, row 12 report | |||
| Phase assemblage | ε alloy: Mn 0.08, Zn 0.92 | experimental | [1] Li 2021 | Table 6, p. 11, row 2 report | |||
| Phase assemblage | ε alloy: Mn 0.08, Zn 0.92 | experimental | [1] Li 2021 | Table 6, p. 11, row 1 report | |||
| Phase assemblage | ζ-MnZn13 alloy: Mn 0.08, Zn 0.92 | experimental | [1] Li 2021 | Table 6, p. 11, row 4 report | |||
| Phase assemblage | ζ-MnZn13 alloy: Mn 0.045, Zn 0.955 | experimental | [1] Li 2021 | Table 6, p. 11, row 5 report | |||
| Phase assemblage | ζ-MnZn13 alloy: Mn 0.045, Zn 0.955 | experimental | [1] Li 2021 | Table 6, p. 11, row 6 report | |||
| Phase assemblage | ζ-MnZn13 alloy: Mn 0.08, Zn 0.92 | experimental | [1] Li 2021 | Table 6, p. 11, row 3 report | |||
| Phase composition | 673.15 | δ1-MnZn9 δ1-MnZn9: Mn 0.0997, Zn 0.9003 | experimental | [1] Li 2021 | Table 1, p. 2, row 3 report | ||
| Phase composition | 673.15 | δ1-MnZn9 + ζ-MnZn13 δ1-MnZn9: Mn 0.0982, Zn 0.9018; ζ-MnZn13: Mn 0.0846, Zn 0.9154 | experimental | [1] Li 2021 | Table 1, p. 2, row 4 report | ||
| Phase composition | 673.15 | ε + δ1-MnZn9 ε: Mn 0.1164, Zn 0.8836; δ1-MnZn9: Mn 0.1029, Zn 0.8971 | experimental | [1] Li 2021 | Table 1, p. 2, row 2 report | ||
| Phase composition | 673.15 | ε + δ1-MnZn9 ε: Mn 0.1263, Zn 0.8737; δ1-MnZn9: Mn 0.099, Zn 0.901 | experimental | [1] Li 2021 | Table 1, p. 2, row 1 report | ||
| Phase composition | 673.15 | ζ-MnZn13 ζ-MnZn13: Mn 0.0795, Zn 0.9205 | experimental | [1] Li 2021 | Table 1, p. 2, row 5 report | ||
| Phase composition | 673.15 | ζ-MnZn13 + (Zn) ζ-MnZn13: Mn 0.0752, Zn 0.9248; (Zn): Mn 0.0069, Zn 0.9931 | experimental | [1] Li 2021 | Table 1, p. 2, row 8 report | ||
| Phase composition | 673.15 | ζ-MnZn13 + (Zn) ζ-MnZn13: Mn 0.0776, Zn 0.9224; (Zn): Mn 0.0091, Zn 0.9909 | experimental | [1] Li 2021 | Table 1, p. 2, row 6 report | ||
| Phase composition | 673.15 | ζ-MnZn13 + (Zn) ζ-MnZn13: Mn 0.0732, Zn 0.9268; (Zn): Mn 0.0085, Zn 0.9915 | experimental | [1] Li 2021 | Table 1, p. 2, row 7 report |
Crystal structure (12)
| Property | Value | T (K) | Phases / composition | Class | Source | Location | Quote |
|---|---|---|---|---|---|---|---|
| Lattice a | 12.772 Å | 298.15 | δ1-MnZn9 alloy: Zn 0.9 | experimental | [1] Li 2021 | Table 2, p. 3, row 1 report | |
| Lattice a | 12.772 Å | 298.15 | δ1-MnZn9 alloy: Zn 0.9 | experimental | [1] Li 2021 | Table 2, p. 3, row 2 report | |
| Lattice b | 12.772 Å | 298.15 | δ1-MnZn9 alloy: Zn 0.9 | experimental | [1] Li 2021 | Table 2, p. 3, row 1 report | |
| Lattice b | 12.772 Å | 298.15 | δ1-MnZn9 alloy: Zn 0.9 | experimental | [1] Li 2021 | Table 2, p. 3, row 2 report | |
| Lattice c | 57.069 Å | 298.15 | δ1-MnZn9 alloy: Zn 0.9 | experimental | [1] Li 2021 | Table 2, p. 3, row 1 report | |
| Lattice c | 57.069 Å | 298.15 | δ1-MnZn9 alloy: Zn 0.9 | experimental | [1] Li 2021 | Table 2, p. 3, row 2 report | |
| lattice alpha | 90 not_printed | 298.15 | δ1-MnZn9 alloy: Zn 0.9 | experimental | [1] Li 2021 | Table 2, p. 3, row 1 report | |
| lattice alpha | 90 not_printed | 298.15 | δ1-MnZn9 alloy: Zn 0.9 | experimental | [1] Li 2021 | Table 2, p. 3, row 2 report | |
| lattice beta | 90 not_printed | 298.15 | δ1-MnZn9 alloy: Zn 0.9 | experimental | [1] Li 2021 | Table 2, p. 3, row 1 report | |
| lattice beta | 90 not_printed | 298.15 | δ1-MnZn9 alloy: Zn 0.9 | experimental | [1] Li 2021 | Table 2, p. 3, row 2 report | |
| lattice gamma | 120 not_printed | 298.15 | δ1-MnZn9 alloy: Zn 0.9 | experimental | [1] Li 2021 | Table 2, p. 3, row 1 report | |
| lattice gamma | 120 not_printed | 298.15 | δ1-MnZn9 alloy: Zn 0.9 | experimental | [1] Li 2021 | Table 2, p. 3, row 2 report |
Sources
Reporting papers the values were read from (a value cited from another work names that work in its row).
- Xiaojing Li, Shuhong Liu, Jinhui Huang, Dandan Huang, Yong Du, Phase equilibria, crystal structure of δ1-MnZn9 and thermodynamic re-assessment of the Zn-Mn system, Journal of Alloys and Compounds 863, 158484 (2021). doi:10.1016/j.jallcom.2020.158484
- Jyrki Miettinen, Thermodynamic description of the Cu–Mn–Zn system in the copper-rich corner, Calphad 28, 313-320 (2004). doi:10.1016/j.calphad.2004.09.003