Thermodynamic modeling of the Mg–Si system with the Kaptay equation for the excess Gibbs energy of the liquid phase
Xiaoming Yuan, Weihua Sun, Yong Du, Dongdong Zhao, Huaming Yang
Calphad 33 (4) 673-678 (2009) · Elsevier BV
DOI: 10.1016/j.calphad.2009.08.004
Data: JSON record · id doi:10.1016/j.calphad.2009.08.004 · metadata: crossref
Roles in ORCHID
- read by ORCHID (values extracted): 39 released values
- cited as the original source of values
- assessment behind a TDB file: MgSi-09Yua.tdb (Mg–Si)
Systems
Evidence in ORCHID
39 values read from this paper (39 accepted), from 2 tables and 0 text passages.
| experimental | 32 |
| model | 5 |
| dft | 2 |
| invariant reaction | 21 |
| formation | 18 |
2 values in 1 other papers cite this work as their source.
| model | 2 |
ESPEI datasets derived: 42 (derived/invariant-brackets/MG-SI/MgSi-00Yan-LB.zpf-00.json …).
Phase-registry phases citing it: phase:mg-si:a4-diamond, phase:mg-si:bcc-a2, phase:mg-si:fcc-a1, phase:mg-si:hcp-a3, phase:mg-si:liquid, phase:mg-si:mg2si-c1
Availability
Read by ORCHID: yes (values_extracted). Open-access licence (Crossref license field): none deposited. Crossref is-referenced-by count: 43 (retrieved 2026-10-23).
Relations
Cited by (Crossref reference lists) (16)
- Nano-Calphad: extension of the Calphad method to systems with nano-phases and complexions (2012) [crossref_reference_list]
- Thermodynamic assessment of the Ytterbium–Germanium binary system (2017) [crossref_reference_list]
- Thermodynamic Description of the Al-Fe-Mg-Ni-Si and Al-Cu-Fe-Mg-Ni Quinary Systems and Its Application to Solidification Simulation (2015) [crossref_reference_list]
- A Thermodynamic Assessment of the Li-Ge System (2018) [crossref_reference_list]
- Combined ab initio, experimental, and CALPHAD approach for an improved thermodynamic evaluation of the Mg–Si system (2012) [crossref_reference_list]
- Thermodynamic assessment of the Ga–X (X=B, Ca, Sr, Ba) systems supported by first-principles calculations (2013) [crossref_reference_list]
- Inherently consistent temperature function for interaction parameters demonstrated for the Mg–Si assessment (2016) [crossref_reference_list]
- The SGTE collection of binary datasets (2025) [crossref_reference_list]
- Phase equilibria and thermodynamic modeling of the Mg-Si-Y system (2026) [crossref_reference_list]
- Study of excess free energy of mixing and heat of mixing of liquid ternary Al–Li–Zn alloy by assessing the thermodynamic properties of sub-binary alloys (2021) [crossref_reference_list]
- Thermodynamic description of the Al–Mg–Si system using a new formulation for the temperature dependence of the excess Gibbs energy (2012) [crossref_reference_list]
- Thermodynamic evaluation of the aerial and aqueous oxidation of Al – Mg, Al – Si and Al – Mg – Si system alloys at 298 K (2024) [crossref_reference_list]
- Mixing behaviour of Al–Ga–Mg alloys in liquid state at different temperatures (2025) [crossref_reference_list]
- Thermodynamic modeling of the Fe−Zn system using exponential temperature dependence for the excess Gibbs energy (2011) [crossref_reference_list]
- Reassessment of the Mg–Ge binary system using CALPHAD supported by first-principles calculation (2010) [crossref_reference_list]
- Mg-Si Binary Phase Diagram Evaluation (2017) [crossref_reference_list]
References (Crossref, publisher-deposited) (27)
- Metallographische Mitteilungen aus dem Institut für physikalische Chemie der Universität Göttingen. LXX. Über Magnesium‐Siliciumlegierungen (1909) [crossref_reference_list]
- Die Silicide des Calciums und Magnesiums (1926) [crossref_reference_list]
- Untersuchungen über die Verbindungen des Magnesiums mit den Elementen der IV b‐Gruppe (1941) [crossref_reference_list]
- Experimental Study of Au-Pt-Sn Phase Equilibria and Thermodynamic Assessment of the Au-Pt and Au-Pt-Sn Systems (2007) [crossref_reference_list]
- Phase equilibria and thermodynamics of the Mg-Si-Li system and remodeling of the Mg-Si system (2004) [crossref_reference_list]
- Sublimation in the intermetallic series Mg2Si, Mg2Ge, Mg2Sn and Mg2Pb (1966) [crossref_reference_list]
- The system mg-si optimized 8y a least squares method (1981) [crossref_reference_list]
- The Thermo-Calc databank system (1985) [crossref_reference_list]
- SGTE data for pure elements (1991) [crossref_reference_list]
- Thermodynamic optimization of the Mg-Al-Si phase diagram (1992) [crossref_reference_list]
- A new equation for the temperature dependence of the excess Gibbs energy of solution phases (2004) [crossref_reference_list]
- Thermodynamic modelling of the Zn–Zr system (2006) [crossref_reference_list]
- Thermodynamic modeling of the Mg–Si–Sn system (2007) [crossref_reference_list]
- A thermodynamic modelling of the Ba–Pb system (2007) [crossref_reference_list]
- A thermodynamic description of the Mg–Pr–Y system (2008) [crossref_reference_list]
- A thermodynamic reassessment of the Ca–Pb system (2008) [crossref_reference_list]
- Enthalpies of formation of magnesium compounds from first-principles calculations (2009) [crossref_reference_list]
- Thermodynamic assessment of the Fe–Hf binary system (2008) [crossref_reference_list]
- Thermodynamic modeling of the Ru–Ti system (2009) [crossref_reference_list]
- A thermodynamic description of the Cr–Ge system (2009) [crossref_reference_list]
- Investigation of the Al-Mg-Si system by experiments and thermodynamic calculations (1997) [crossref_reference_list]
- Thermal Study of Groups II—IV Semiconductors. Lattice Heat Capacities and Free Energies of Formation. Heat Capacity of Mg2Si from 15°—300°K (1967) [crossref_reference_list]
- Special points for Brillouin-zone integrations (1976) [crossref_reference_list]
- Efficient iterative schemes for <i>ab initio</i> total-energy calculations using a plane-wave basis set (1996) [crossref_reference_list]
- From ultrasoft pseudopotentials to the projector augmented-wave method (1999) [crossref_reference_list]
- A thermodynamic analysis of the Mg-Si system (2000) [crossref_reference_list]
- Notizen: Die Molwärme des Mg<sub>2</sub>Si von 12° bis 300°K (1965) [crossref_reference_list]
Cited for values by (1)
- Thermodynamic description of the Al–Mg–Si system using a new formulation for the temperature dependence of the excess Gibbs energy (2012) — 2 values [orchid_extraction]
Cites (values carry this citation) (8)
- Metallographische Mitteilungen aus dem Institut für physikalische Chemie der Universität Göttingen. LXX. Über Magnesium‐Siliciumlegierungen (1909) — 3 values [orchid_extraction]
- Die Silicide des Calciums und Magnesiums (1926) — 2 values [orchid_extraction]
- Thermal Study of Groups II—IV Semiconductors. Lattice Heat Capacities and Free Energies of Formation. Heat Capacity of Mg2Si from 15°—300°K (1967) — 2 values [orchid_extraction]
- Untersuchungen über die Verbindungen des Magnesiums mit den Elementen der IV b‐Gruppe (1941) — 1 values [orchid_extraction]
- Sublimation in the intermetallic series Mg2Si, Mg2Ge, Mg2Sn and Mg2Pb (1966) — 1 values [orchid_extraction]
- Enthalpies of formation of magnesium compounds from first-principles calculations (2009) — 1 values [orchid_extraction]
- Investigation of the Al-Mg-Si system by experiments and thermodynamic calculations (1997) — 1 values [orchid_extraction]
- Notizen: Die Molwärme des Mg<sub>2</sub>Si von 12° bis 300°K (1965) — 1 values [orchid_extraction]
TDB files modelling its system (2)
tdb:MgSi-09Yua.tdb[orchid_literature_model_link]tdb:MgSi-09Yua.tdb[sgte_tdb_header]
Reassessed by (2)
- Combined ab initio, experimental, and CALPHAD approach for an improved thermodynamic evaluation of the Mg–Si system (2012) [citation+same-system]
- Inherently consistent temperature function for interaction parameters demonstrated for the Mg–Si assessment (2016) [citation+same-system]
Reassesses (cites an earlier assessment of the same system) (2)
- Investigation of the Al-Mg-Si system by experiments and thermodynamic calculations (1997) [citation+same-system]
- A thermodynamic analysis of the Mg-Si system (2000) [citation+same-system]
Data papers used (8)
- Metallographische Mitteilungen aus dem Institut für physikalische Chemie der Universität Göttingen. LXX. Über Magnesium‐Siliciumlegierungen (1909) — 3 values [orchid_extraction]
- Die Silicide des Calciums und Magnesiums (1926) — 2 values [orchid_extraction]
- Thermal Study of Groups II—IV Semiconductors. Lattice Heat Capacities and Free Energies of Formation. Heat Capacity of Mg2Si from 15°—300°K (1967) — 2 values [orchid_extraction]
- Untersuchungen über die Verbindungen des Magnesiums mit den Elementen der IV b‐Gruppe (1941) — 1 values [orchid_extraction]
- Sublimation in the intermetallic series Mg2Si, Mg2Ge, Mg2Sn and Mg2Pb (1966) — 1 values [orchid_extraction]
- Enthalpies of formation of magnesium compounds from first-principles calculations (2009) — 1 values [orchid_extraction]
- Investigation of the Al-Mg-Si system by experiments and thermodynamic calculations (1997) — 1 values [orchid_extraction]
- Notizen: Die Molwärme des Mg<sub>2</sub>Si von 12° bis 300°K (1965) — 1 values [orchid_extraction]
Used in (assessments / papers that took values from it) (1)
- Thermodynamic description of the Al–Mg–Si system using a new formulation for the temperature dependence of the excess Gibbs energy (2012) — 2 values [orchid_extraction]