A new equation for the temperature dependence of the excess Gibbs energy of solution phases

George Kaptay

Calphad 28 (2) 115-124 (2004) · Elsevier BV

DOI: 10.1016/j.calphad.2004.08.005

Reference as printed in ORCHID's sources: G. Kaptay, Calphad 28 (2004) 115.

Data: JSON record · id doi:10.1016/j.calphad.2004.08.005 · metadata: crossref

Roles in ORCHID

cited as the original source of values

Systems

Ge, Tl, Yb, Cr–Ge, Er–Ge, Gd–Tl, Ge–Yb, Ru–Ti

Evidence in ORCHID

63 values in 5 other papers cite this work as their source.

Cited values by evidence class
model	63

Phase-registry phases citing it: phase:cr-ge:a4-diamond, phase:cr-ge:bcc-a2, phase:cr-ge:cr11ge19, phase:cr-ge:cr11ge8, phase:cr-ge:cr3ge-a15, phase:cr-ge:cr5ge3, phase:cr-ge:cr5ge3-d8m, phase:cr-ge:crge-b20, phase:cr-ge:liquid, phase:er-ge:a4-diamond, phase:er-ge:er11ge10, phase:er-ge:er2ge3, phase:er-ge:er2ge3-c32, phase:er-ge:er2ge5, phase:er-ge:er3ge4, phase:er-ge:er5ge3-d88, phase:er-ge:er5ge4, phase:er-ge:erge-b33, phase:er-ge:erge2-ht, phase:er-ge:erge2-lt …

Availability

Read by ORCHID: no (full_text_screened_for_origin). Open-access licence (Crossref license field): none deposited. Crossref is-referenced-by count: 120 (retrieved 2026-10-23).

Relations

Cited by (Crossref reference lists) (52)

Nano-Calphad: extension of the Calphad method to systems with nano-phases and complexions (2012) [crossref_reference_list]
Thermodynamic evaluation of the Ga–Y system (2013) [crossref_reference_list]
Thermodynamic assessment of the Ytterbium–Germanium binary system (2017) [crossref_reference_list]
Thermodynamic reassessment of the Al–Zr binary system (2017) [crossref_reference_list]
Thermodynamic assessment of the Ho–Ga system (2019) [crossref_reference_list]
Experimental Study of Au-Pt-Sn Phase Equilibria and Thermodynamic Assessment of the Au-Pt and Au-Pt-Sn Systems (2007) [crossref_reference_list]
Thermodynamic and Surface Properties of Liquid Al-Cu-Ni Alloys (2023) [crossref_reference_list]
New Thermodynamic Assessment of the Fe-Y System (2017) [crossref_reference_list]
A Thermodynamic Assessment of the Li-Ge System (2018) [crossref_reference_list]
Excess Thermodynamic Properties of Solutions in Ln-Ru (Ln = Nd, Gd, Dy) Binary Systems Based on Quadratic, Exponential and Combined Models Supported by Ab-Initio Calculations (2023) [crossref_reference_list]
Thermodynamic Modeling of the (Ce and Sm)-Ru Binary Systems Based on Linear, Exponential, and Combined Models Aided by Ab-Initio Calculations (2023) [crossref_reference_list]
Thermodynamic Description of the Gadolinium-Cadmium Phase Diagram (2024) [crossref_reference_list]
Thermodynamic modelling of the Zn–Zr system (2006) [crossref_reference_list]
A thermodynamic modelling of the Ba–Pb system (2007) [crossref_reference_list]
A thermodynamic description of the Mg–Pr–Y system (2008) [crossref_reference_list]
A Calphad-compatible method to calculate liquid/liquid interfacial energies in immiscible metallic systems (2008) [crossref_reference_list]
A thermodynamic reassessment of the Ca–Pb system (2008) [crossref_reference_list]
Thermodynamic modeling of the Mg–Si system with the Kaptay equation for the excess Gibbs energy of the liquid phase (2009) [crossref_reference_list]
Thermodynamic description on the miscibility gap of the Mg-based solid solution in the Mg–Zn, Mg–Nd and Mg–Zn–Nd systems (2010) [crossref_reference_list]
Combined ab initio, experimental, and CALPHAD approach for an improved thermodynamic evaluation of the Mg–Si system (2012) [crossref_reference_list]
Thermodynamic assessment of the Sc–Sn system (2013) [crossref_reference_list]
Thermodynamic description of the Ni–Sc system (2013) [crossref_reference_list]
Thermodynamic assessment of the Ga–X (X=B, Ca, Sr, Ba) systems supported by first-principles calculations (2013) [crossref_reference_list]
Inherently consistent temperature function for interaction parameters demonstrated for the Mg–Si assessment (2016) [crossref_reference_list]
Thermodynamic description of the Ti-Mo-Nb-Ta-Zr system and its implications for phase stability of Ti bio-implant materials (2018) [crossref_reference_list]
Thermodynamic evaluation of the germanium-lutetium and dysprosium-germanium binary systems (2018) [crossref_reference_list]
Thermodynamic assessment of the Ce-Co-Sb ternary system (2018) [crossref_reference_list]
Thermodynamic assessment of the Ce-Fe-Sb system (2019) [crossref_reference_list]
Thermodynamic assessment of the Ti–Al–Zr system and atomic mobility of its bcc phase (2020) [crossref_reference_list]
Thermodynamic assessment of the Ga–Lu system by the combination of ab-initio calculations and the CALPHAD approach (2022) [crossref_reference_list]
Thermodynamic analysis of the Li–Si phase equilibria from 0 K to liquidus temperatures (2013) [crossref_reference_list]
Thermodynamic assessment of the Fe–Hf binary system (2008) [crossref_reference_list]
Thermodynamic modeling of the Ru–Ti system (2009) [crossref_reference_list]
A thermodynamic description of the Cr–Ge system (2009) [crossref_reference_list]
A thermodynamic modeling of the Gd–Tl system (2010) [crossref_reference_list]
Thermodynamic optimization of the Cu–Nd system (2011) [crossref_reference_list]
Thermodynamic assessment of the Si–Ta system (2013) [crossref_reference_list]
A thermodynamic assessment of the iron–yttrium system (2014) [crossref_reference_list]
Thermodynamic optimization of the Erbium-Germanium binary system (2017) [crossref_reference_list]
The U–Ti system: Strengths and weaknesses of the CALPHAD method (2011) [crossref_reference_list]
Thermodynamic modeling of the Ga-Gd binary system (2020) [crossref_reference_list]
Calphad-type assessment of the Pd-Yb binary system supported by first-principles calculations – Part II: Results (2020) [crossref_reference_list]
Thermodynamic re-assessment of the Zn–P binary system (2019) [crossref_reference_list]
Study of excess free energy of mixing and heat of mixing of liquid ternary Al–Li–Zn alloy by assessing the thermodynamic properties of sub-binary alloys (2021) [crossref_reference_list]
Assessment of thermophysical properties of Al–Mg–Si liquid alloys (2024) [crossref_reference_list]
Experimental investigation and thermodynamic assessment of the Zn–Si–P system (2016) [crossref_reference_list]
Thermodynamic description of the Al–Mg–Si system using a new formulation for the temperature dependence of the excess Gibbs energy (2012) [crossref_reference_list]
Thermodynamic assessment of Hafnium Iridium binary system (2018) [crossref_reference_list]
Mixing behaviour of Al–Ga–Mg alloys in liquid state at different temperatures (2025) [crossref_reference_list]
Thermodynamic description of the aluminum-barium phase diagram (2017) [crossref_reference_list]
… 2 more in the JSON record

References (Crossref, publisher-deposited) (3)

Algebraic Representation of Thermodynamic Properties and the Classification of Solutions (1948) [crossref_reference_list]
Thermodynamic assessment of systems of actinide or rare earth with Cd (2001) [crossref_reference_list]
Thermodynamic constraints to describe gibbs energies for binary alloys (1999) [crossref_reference_list]

Cited for values by (5)

Thermodynamic assessment of the Ytterbium–Germanium binary system (2017) — 23 values [orchid_extraction]
Thermodynamic optimization of the Erbium-Germanium binary system (2017) — 17 values [orchid_extraction]
A thermodynamic modeling of the Gd–Tl system (2010) — 11 values [orchid_extraction]
A thermodynamic description of the Cr–Ge system (2009) — 8 values [orchid_extraction]
Thermodynamic modeling of the Ru–Ti system (2009) — 4 values [orchid_extraction]

Used in (assessments / papers that took values from it) (5)

Thermodynamic assessment of the Ytterbium–Germanium binary system (2017) — 23 values [orchid_extraction]
Thermodynamic optimization of the Erbium-Germanium binary system (2017) — 17 values [orchid_extraction]
A thermodynamic modeling of the Gd–Tl system (2010) — 11 values [orchid_extraction]
A thermodynamic description of the Cr–Ge system (2009) — 8 values [orchid_extraction]
Thermodynamic modeling of the Ru–Ti system (2009) — 4 values [orchid_extraction]