Thermodynamic analysis of the Li–Si phase equilibria from 0 K to liquidus temperatures

Peisheng Wang, Artem Kozlov, Daniel Thomas, Florian Mertens, Rainer Schmid-Fetzer

Intermetallics 42 137-145 (2013) · Elsevier BV

DOI: 10.1016/j.intermet.2013.06.003

Data: JSON record · id doi:10.1016/j.intermet.2013.06.003 · metadata: crossref

Roles in ORCHID

• read by ORCHID (values extracted): 12 released values
• cited as the original source of values
• assessment behind a TDB file: LiSi-13Wan.tdb (Li–Si)

Systems

Li–Si

Evidence in ORCHID

12 values read from this paper (10 accepted), from 1 tables and 4 text passages.

7 values in 1 other papers cite this work as their source.

Phase-registry phases citing it: phase:li-si:a4-diamond, phase:li-si:bcc-a2, phase:li-si:fcc-a1, phase:li-si:hcp-a3, phase:li-si:li12si7, phase:li-si:li13si4, phase:li-si:li22si5, phase:li-si:li7si3, phase:li-si:liquid

Availability

Read by ORCHID: yes (values_extracted). Open-access licence (Crossref license field): none deposited. Crossref is-referenced-by count: 34 (retrieved 2026-10-23).

Relations

Cited by (Crossref reference lists) (15)

• Experimental investigation and thermodynamic description of the Li–Si–Ni ternary system (2015) [crossref_reference_list]
• Inherently consistent temperature function for interaction parameters demonstrated for the Mg–Si assessment (2016) [crossref_reference_list]
• The SGTE collection of binary datasets (2025) [crossref_reference_list]
• Thermodynamics of Li-Si and Li-Si-H phase diagrams applied to hydrogen absorption and Li-ion batteries (2017) [crossref_reference_list]
• Li–Si phase diagram: Enthalpy of mixing, thermodynamic stability, and coherent assessment (2014) [crossref_reference_list]
• Phase formation in the ternary system Li–Si–C (2015) [crossref_reference_list]
• Key experiments and challenging thermodynamic modeling of the Li-Si-C system (2017) [crossref_reference_list]
• Experimental investigation and thermodynamic description of the Li–Si–Mn ternary system (2018) [crossref_reference_list]
• The heat capacity and entropy of the lithium silicides Li17Si4 and Li16.42Si4 in the temperature range from (2 to 873) K (2015) [crossref_reference_list]
• Phase formation in the ternary systems Li-Sn-C and Li-Sn-Si (2018) [crossref_reference_list]
• Structural and thermodynamic similarities of phases in the Li–Tt (Tt = Si, Ge) systems: redetermination of the lithium-rich side of the Li–Ge phase diagram and crystal structures of Li ₁₇ Si _4.0−x Ge _x for <i>x</i> = 2.3, 3.1, 3.5, and 4 as well as Li _4.1 Ge (2014) [crossref_reference_list]
• Simulation of Lithium Adsorption in 4H–SiC, Electron Transfer, and Thermodynamic Functions of Si–C–Li Compounds (2024) [crossref_reference_list]
• Simulation of the Physical-Chemical and Electronic Properties of Lithium-Containing 4H–SiC and Binary Phases of the Si–C–Li System (2024) [crossref_reference_list]
• Phase formation in alloy-type anode materials in the quaternary system Li–Sn–Si–C (2017) [crossref_reference_list]
• Modeling of Physical-Chemical and Electronic Properties of Lithium-Containing 4H—SiC and Binary Phases of the Si—C–Li System (2024) [crossref_reference_list]

References (Crossref, publisher-deposited) (9)

• High‐Pressure Synthesis of LiSi: Three‐Dimensional Network of Three‐Bonded Si⁻ Ions (1993) [crossref_reference_list]
• Li-Si (Lithium-Silicon) (2009) [crossref_reference_list]
• SGTE data for pure elements (1991) [crossref_reference_list]
• A new equation for the temperature dependence of the excess Gibbs energy of solution phases (2004) [crossref_reference_list]
• PANDAT software with PanEngine, PanOptimizer and PanPrecipitation for multi-component phase diagram calculation and materials property simulation (2009) [crossref_reference_list]
• Thermodynamics and Phase Stability in the Ga–N System (2003) [crossref_reference_list]
• Algebraic Representation of Thermodynamic Properties and the Classification of Solutions (1948) [crossref_reference_list]
• Thermodynamic Properties of the Lithium‐Silicon System (1976) [crossref_reference_list]
• The Li–C phase equilibria (2013) [crossref_reference_list]

Cited for values by (1)

• Thermodynamics of Li-Si and Li-Si-H phase diagrams applied to hydrogen absorption and Li-ion batteries (2017) — 7 values [orchid_extraction]

Cites (values carry this citation) (1)

• Li-Si (Lithium-Silicon) (2009) — 1 values [orchid_extraction]

TDB files modelling its system (2)

• tdb:LiSi-13Wan.tdb [sgte_tdb_header]
• tdb:LiSi-13Wan.tdb [orchid_literature_model_link]

Reassessed by (2)

• Thermodynamics of Li-Si and Li-Si-H phase diagrams applied to hydrogen absorption and Li-ion batteries (2017) [citation+same-system]
• Li–Si phase diagram: Enthalpy of mixing, thermodynamic stability, and coherent assessment (2014) [citation+same-system]

Data papers used (1)

• Li-Si (Lithium-Silicon) (2009) — 1 values [orchid_extraction]

Used in (assessments / papers that took values from it) (1)

• Thermodynamics of Li-Si and Li-Si-H phase diagrams applied to hydrogen absorption and Li-ion batteries (2017) — 7 values [orchid_extraction]