Li–Si phase diagram: Enthalpy of mixing, thermodynamic stability, and coherent assessment

M. Helena Braga, Adam Dębski, Władysław Gąsior

Journal of Alloys and Compounds 616 581-593 (2014) · Elsevier BV

DOI: 10.1016/j.jallcom.2014.06.212

Data: JSON record · id doi:10.1016/j.jallcom.2014.06.212 · metadata: crossref

Roles in ORCHID

• read by ORCHID (values extracted): 26 released values
• cited as the original source of values
• assessment behind a TDB file: LiSi-14Bra.tdb (Li–Si)

Systems

Li–Si

Evidence in ORCHID

26 values read from this paper (24 accepted), from 1 tables and 1 text passages.

21 values in 1 other papers cite this work as their source.

ESPEI datasets derived: 7 (derived/invariant-brackets/LI-SI/LiSi-17Lia.zpf-01.json …).

Phase-registry phases citing it: phase:li-si:a4-diamond, phase:li-si:bcc-a2, phase:li-si:fcc-a1, phase:li-si:hcp-a3, phase:li-si:li12si7, phase:li-si:li13si4, phase:li-si:li17si4, phase:li-si:li21si5, phase:li-si:li33si8, phase:li-si:li7si3, phase:li-si:liquid, phase:li-si:lisi

Availability

Read by ORCHID: yes (values_extracted). Open-access licence (Crossref license field): none deposited. Crossref is-referenced-by count: 52 (retrieved 2026-10-23).

Relations

Cited by (Crossref reference lists) (11)

• Experimental investigation and thermodynamic description of the Li–Si–Ni ternary system (2015) [crossref_reference_list]
• The SGTE collection of binary datasets (2025) [crossref_reference_list]
• Thermodynamics of Li-Si and Li-Si-H phase diagrams applied to hydrogen absorption and Li-ion batteries (2017) [crossref_reference_list]
• Phase formation in the ternary system Li–Si–C (2015) [crossref_reference_list]
• Key experiments and challenging thermodynamic modeling of the Li-Si-C system (2017) [crossref_reference_list]
• Experimental investigation and thermodynamic description of the Li–Si–Mn ternary system (2018) [crossref_reference_list]
• The heat capacity and entropy of the lithium silicides Li17Si4 and Li16.42Si4 in the temperature range from (2 to 873) K (2015) [crossref_reference_list]
• Simulation of Lithium Adsorption in 4H–SiC, Electron Transfer, and Thermodynamic Functions of Si–C–Li Compounds (2024) [crossref_reference_list]
• Simulation of the Physical-Chemical and Electronic Properties of Lithium-Containing 4H–SiC and Binary Phases of the Si–C–Li System (2024) [crossref_reference_list]
• Phase formation in alloy-type anode materials in the quaternary system Li–Sn–Si–C (2017) [crossref_reference_list]
• Modeling of Physical-Chemical and Electronic Properties of Lithium-Containing 4H—SiC and Binary Phases of the Si—C–Li System (2024) [crossref_reference_list]

References (Crossref, publisher-deposited) (16)

• Die Kristallstruktur von Lithiumsilicid Li₂Si (1965) [crossref_reference_list]
• Li₁₂Si₇, eine Verbindung mit trigonal‐planaren Si₄‐Clustern und isometrischen Si₅‐Ringen (1986) [crossref_reference_list]
• The Li-Si (Lithium-Silicon) system (1990) [crossref_reference_list]
• Li-Si (Lithium-Silicon) (2009) [crossref_reference_list]
• Li21Si5, a Zintl phase as well as a Hume-Rothery phase (1987) [crossref_reference_list]
• SGTE data for pure elements (1991) [crossref_reference_list]
• Thermodynamic analysis of the Li–Si phase equilibria from 0 K to liquidus temperatures (2013) [crossref_reference_list]
• Single Crystal Growth and Thermodynamic Stability of Li₁₇Si₄ (2013) [crossref_reference_list]
• Algebraic Representation of Thermodynamic Properties and the Classification of Solutions (1948) [crossref_reference_list]
• Efficient iterative schemes for <i>ab initio</i> total-energy calculations using a plane-wave basis set (1996) [crossref_reference_list]
• Generalized Gradient Approximation Made Simple (1996) [crossref_reference_list]
• Structural Changes in Silicon Anodes during Lithium Insertion/Extraction (2004) [crossref_reference_list]
• Thermodynamic Properties of the Lithium‐Silicon System (1976) [crossref_reference_list]
• Synthesis of Single-Phase LiSi by Ball-Milling: Electrochemical Behavior and Hydrogenation Properties (2013) [crossref_reference_list]
• Zur Kenntnis der Phase Li₂₂Si₅ (1966) [crossref_reference_list]
• Zur Kenntnis der Phase Li₁₃Si₄ / On the Phase Li₁₃Si₄ (1975) [crossref_reference_list]

Cited for values by (1)

• Thermodynamics of Li-Si and Li-Si-H phase diagrams applied to hydrogen absorption and Li-ion batteries (2017) — 21 values [orchid_extraction]

Cites (values carry this citation) (1)

• Single Crystal Growth and Thermodynamic Stability of Li₁₇Si₄ (2013) — 2 values [orchid_extraction]

TDB files modelling its system (1)

• tdb:LiSi-14Bra.tdb [sgte_tdb_header]

Reassessed by (1)

• Thermodynamics of Li-Si and Li-Si-H phase diagrams applied to hydrogen absorption and Li-ion batteries (2017) [citation+same-system]

Reassesses (cites an earlier assessment of the same system) (1)

• Thermodynamic analysis of the Li–Si phase equilibria from 0 K to liquidus temperatures (2013) [citation+same-system]

Data papers used (1)

• Single Crystal Growth and Thermodynamic Stability of Li₁₇Si₄ (2013) — 2 values [orchid_extraction]

Used in (assessments / papers that took values from it) (1)

• Thermodynamics of Li-Si and Li-Si-H phase diagrams applied to hydrogen absorption and Li-ion batteries (2017) — 21 values [orchid_extraction]