Li21Si5, a Zintl phase as well as a Hume-Rothery phase

Reinhard Nesper, Hans Georg von Schnering

Journal of Solid State Chemistry 70 (1) 48-57 (1987) · Elsevier BV

DOI: 10.1016/0022-4596(87)90176-9

Data: JSON record · id doi:10.1016/0022-4596(87)90176-9 · metadata: crossref

Roles in ORCHID

• cited as the original source of values

Systems

Li–Si

Evidence in ORCHID

1 values in 1 other papers cite this work as their source.

Phase-registry phases citing it: phase:li-si:li21si5

Availability

Read by ORCHID: no (full_text_screened_for_origin). Open-access licence (Crossref license field): none deposited. Crossref is-referenced-by count: 135 (retrieved 2026-10-23).

Relations

Cited by (Crossref reference lists) (9)

• High‐Pressure Synthesis of LiSi: Three‐Dimensional Network of Three‐Bonded Si⁻ Ions (1993) [crossref_reference_list]
• Al69Ta39 - a new variant of a face-centred cubic giant cell structure (1994) [crossref_reference_list]
• Thermodynamics of Li-Si and Li-Si-H phase diagrams applied to hydrogen absorption and Li-ion batteries (2017) [crossref_reference_list]
• Li–Si phase diagram: Enthalpy of mixing, thermodynamic stability, and coherent assessment (2014) [crossref_reference_list]
• Phase formation in the ternary system Li–Si–C (2015) [crossref_reference_list]
• Single Crystal Growth and Thermodynamic Stability of Li₁₇Si₄ (2013) [crossref_reference_list]
• X-ray and Neutron Diffraction Studies on “Li_4.4Sn” (2003) [crossref_reference_list]
• Structural and thermodynamic similarities of phases in the Li–Tt (Tt = Si, Ge) systems: redetermination of the lithium-rich side of the Li–Ge phase diagram and crystal structures of Li ₁₇ Si _4.0−x Ge _x for <i>x</i> = 2.3, 3.1, 3.5, and 4 as well as Li _4.1 Ge (2014) [crossref_reference_list]
• Synthesis of Single-Phase LiSi by Ball-Milling: Electrochemical Behavior and Hydrogenation Properties (2013) [crossref_reference_list]

References (Crossref, publisher-deposited) (3)

• Li₁₂Si₇, eine Verbindung mit trigonal‐planaren Si₄‐Clustern und isometrischen Si₅‐Ringen (1986) [crossref_reference_list]
• Intermetallic Compounds between Lithium and Lead. IV. The Crystal Structure of Li₂₂ Pb₅ (1958) [crossref_reference_list]
• Zur Kenntnis der Phase Li₂₂Si₅ (1966) [crossref_reference_list]

Cited for values by (1)

• Thermodynamics of Li-Si and Li-Si-H phase diagrams applied to hydrogen absorption and Li-ion batteries (2017) — 1 values [orchid_extraction]

Used in (assessments / papers that took values from it) (1)

• Thermodynamics of Li-Si and Li-Si-H phase diagrams applied to hydrogen absorption and Li-ion batteries (2017) — 1 values [orchid_extraction]