High‐Pressure Synthesis of LiSi: Three‐Dimensional Network of Three‐Bonded Si⁻ Ions

Jürgen Evers, Gilbert Oehlinger, Gerhard Sextl

Angewandte Chemie International Edition in English 32 (10) 1442-1444 (1993) · Wiley

DOI: 10.1002/anie.199314421

Data: JSON record · id doi:10.1002/anie.199314421 · metadata: crossref

Roles in ORCHID

• cited as the original source of values

Systems

Li–Si

Evidence in ORCHID

2 values in 1 other papers cite this work as their source.

ESPEI datasets derived: 2 (derived/invariant-brackets/LI-SI/LiSi-17Lia.zpf-00.json …).

Phase-registry phases citing it: phase:li-si:a4-diamond, phase:li-si:li12si7, phase:li-si:liquid, phase:li-si:lisi

Availability

Read by ORCHID: no (full_text_screened_for_origin). Open-access licence (Crossref license field): none deposited. Crossref is-referenced-by count: 46 (retrieved 2026-10-23).

Relations

Cited by (Crossref reference lists) (4)

• Thermodynamic analysis of the Li–Si phase equilibria from 0 K to liquidus temperatures (2013) [crossref_reference_list]
• Thermodynamics of Li-Si and Li-Si-H phase diagrams applied to hydrogen absorption and Li-ion batteries (2017) [crossref_reference_list]
• Structural and thermodynamic similarities of phases in the Li–Tt (Tt = Si, Ge) systems: redetermination of the lithium-rich side of the Li–Ge phase diagram and crystal structures of Li ₁₇ Si _4.0−x Ge _x for <i>x</i> = 2.3, 3.1, 3.5, and 4 as well as Li _4.1 Ge (2014) [crossref_reference_list]
• Synthesis of Single-Phase LiSi by Ball-Milling: Electrochemical Behavior and Hydrogenation Properties (2013) [crossref_reference_list]

References (Crossref, publisher-deposited) (5)

• Li₁₂Si₇, eine Verbindung mit trigonal‐planaren Si₄‐Clustern und isometrischen Si₅‐Ringen (1986) [crossref_reference_list]
• Das Verhalten der Alkalimetalle zu Halbmetallen. X. Die Kristallstrukturen von KSi, RbSi, CsSi, KGe, RbGe und CsGe (1961) [crossref_reference_list]
• Transformation of three-dimensional three-connected silicon nets in SrSi2 (1978) [crossref_reference_list]
• Li21Si5, a Zintl phase as well as a Hume-Rothery phase (1987) [crossref_reference_list]
• Zur Kenntnis der Phase Li₁₃Si₄ / On the Phase Li₁₃Si₄ (1975) [crossref_reference_list]

Cited for values by (1)

• Thermodynamics of Li-Si and Li-Si-H phase diagrams applied to hydrogen absorption and Li-ion batteries (2017) — 2 values [orchid_extraction]

Used in (assessments / papers that took values from it) (1)

• Thermodynamics of Li-Si and Li-Si-H phase diagrams applied to hydrogen absorption and Li-ion batteries (2017) — 2 values [orchid_extraction]