Thermodynamic modelling assessment of the ternary system Cs-Mo-O

A.L. Smith (ORCID 0000-0002-0355-5859), T.N. Pham Thi, C. Guéneau, J.-C. Dumas, E. Epifano, W. van Burik, N. Dupin

Calphad 75 102350 (2021) · Elsevier BV

DOI: 10.1016/j.calphad.2021.102350

Data: JSON record · id doi:10.1016/j.calphad.2021.102350 · metadata: crossref

Roles in ORCHID

• read by ORCHID (values extracted): 123 released values
• assessment behind a TDB file: CsMo-21Smi.tdb (Cs–Mo)
• discovery lead (found by Crossref assessment discovery, not read): rank 1910, score 57; systems named in title: Cs–Mo–O

Systems

Cs–Mo, Cs–Mo–O

Evidence in ORCHID

123 values read from this paper (102 accepted), from 5 tables and 11 text passages.

Phase-registry phases citing it: phase:cs-mo:bcc-a2, phase:cs-mo:fcc-a1, phase:cs-mo:hcp-a3, phase:cs-mo:liquid

Availability

Read by ORCHID: yes (values_extracted). Open-access licence (Crossref license field): http://creativecommons.org/licenses/by/4.0/ (vor). Crossref is-referenced-by count: 12 (retrieved 2026-10-23).

Relations

Cited by (Crossref reference lists) (2)

• The SGTE collection of binary datasets (2025) [crossref_reference_list]
• Experimental investigations and thermodynamic modelling of the ternary system Pb-Mo-O (2024) [crossref_reference_list]

References (Crossref, publisher-deposited) (14)

• The Cs2MoO4MoO3 system (1973) [crossref_reference_list]
• Cesium molybdate, Cs2MoO4: Heat capacity and thermodynamic properties from 5 to 350 K (1974) [crossref_reference_list]
• The Thermo-Calc databank system (1985) [crossref_reference_list]
• SGTE data for pure elements (1991) [crossref_reference_list]
• Thermodynamic assessment of the cesium–oxygen system by coupling density functional theory and CALPHAD approaches (2015) [crossref_reference_list]
• Thermodynamic investigations of the uranium-molybdenum-oxygen system by a coupling of density functional theory and CALPHAD methodologies (2018) [crossref_reference_list]
• Thermodynamic study of Cs3Na(MoO4)2: Determination of the standard enthalpy of formation and standard entropy at 298.15 K (2018) [crossref_reference_list]
• Experimental studies and thermodynamic assessment of the Ba-Mo-O system by the CALPHAD method (2021) [crossref_reference_list]
• High-temperature behavior of dicesium molybdate Cs2MoO4: Implications for fast neutron reactors (2014) [crossref_reference_list]
• Structural and thermodynamic study of dicesium molybdate Cs2Mo2O7: Implications for fast neutron reactors (2017) [crossref_reference_list]
• New insights into the Cs-Mo-O system: Experimental studies of the Cs2MoO4-MoO3 pseudo-binary system (2021) [crossref_reference_list]
• Calorimetric Determination of the Formation Enthalpies of Cs Polymolybdates at 298.15 K and 0.1 MPa (2020) [crossref_reference_list]
• Two Original Infinite Chains in the New Caesium Tetramolybdate Compound Cs2Mo4O13 (1995) [crossref_reference_list]
• Crystal structure of β-Cs2Mo4O13 (2011) [crossref_reference_list]

Cites (values carry this citation) (9)

• New insights into the Cs-Mo-O system: Experimental studies of the Cs2MoO4-MoO3 pseudo-binary system (2021) — 26 values [orchid_extraction]
• Structural and thermodynamic study of dicesium molybdate Cs2Mo2O7: Implications for fast neutron reactors (2017) — 13 values [orchid_extraction]
• Calorimetric Determination of the Formation Enthalpies of Cs Polymolybdates at 298.15 K and 0.1 MPa (2020) — 10 values [orchid_extraction]
• The Cs2MoO4MoO3 system (1973) — 9 values [orchid_extraction]
• Crystal structure of β-Cs2Mo4O13 (2011) — 6 values [orchid_extraction]
• High-temperature behavior of dicesium molybdate Cs2MoO4: Implications for fast neutron reactors (2014) — 4 values [orchid_extraction]
• Two Original Infinite Chains in the New Caesium Tetramolybdate Compound Cs2Mo4O13 (1995) — 4 values [orchid_extraction]
• Cesium molybdate, Cs2MoO4: Heat capacity and thermodynamic properties from 5 to 350 K (1974) — 3 values [orchid_extraction]
• Thermodynamic study of Cs3Na(MoO4)2: Determination of the standard enthalpy of formation and standard entropy at 298.15 K (2018) — 1 values [orchid_extraction]

TDB files modelling its system (1)

• tdb:CsMo-21Smi.tdb [sgte_tdb_header]

Data papers used (9)

• New insights into the Cs-Mo-O system: Experimental studies of the Cs2MoO4-MoO3 pseudo-binary system (2021) — 26 values [orchid_extraction]
• Structural and thermodynamic study of dicesium molybdate Cs2Mo2O7: Implications for fast neutron reactors (2017) — 13 values [orchid_extraction]
• Calorimetric Determination of the Formation Enthalpies of Cs Polymolybdates at 298.15 K and 0.1 MPa (2020) — 10 values [orchid_extraction]
• The Cs2MoO4MoO3 system (1973) — 9 values [orchid_extraction]
• Crystal structure of β-Cs2Mo4O13 (2011) — 6 values [orchid_extraction]
• High-temperature behavior of dicesium molybdate Cs2MoO4: Implications for fast neutron reactors (2014) — 4 values [orchid_extraction]
• Two Original Infinite Chains in the New Caesium Tetramolybdate Compound Cs2Mo4O13 (1995) — 4 values [orchid_extraction]
• Cesium molybdate, Cs2MoO4: Heat capacity and thermodynamic properties from 5 to 350 K (1974) — 3 values [orchid_extraction]
• Thermodynamic study of Cs3Na(MoO4)2: Determination of the standard enthalpy of formation and standard entropy at 298.15 K (2018) — 1 values [orchid_extraction]