Thermodynamic assessment of the cesium–oxygen system by coupling density functional theory and CALPHAD approaches

C. Guéneau, J.-L. Flèche

Calphad 49 67-78 (2015) · Elsevier BV

DOI: 10.1016/j.calphad.2015.02.002

Data: JSON record · id doi:10.1016/j.calphad.2015.02.002 · metadata: crossref

Roles in ORCHID

• read by ORCHID (values extracted): 175 released values
• assessment behind a TDB file: CsO-15Gue.tdb (Cs–O)

Systems

Cs–O

Evidence in ORCHID

175 values read from this paper (171 accepted), from 2 tables and 11 text passages.

ESPEI datasets derived: 5 (experimental/CS-O/CsO-15Gue.sm-08.json …).

Phase-registry phases citing it: phase:cs-o:bcc-a2, phase:cs-o:cs2o-c19, phase:cs-o:cs2o2, phase:cs-o:cs3o, phase:cs-o:cs4o, phase:cs-o:cs7o, phase:cs-o:cs7o2, phase:cs-o:cso2-c11a, phase:cs-o:cso3, phase:cs-o:fcc-a1, phase:cs-o:gas, phase:cs-o:hcp-a3, phase:cs-o:ion, phase:cs-o:liquid, phase:cs-o:o2gas

Availability

Read by ORCHID: yes (values_extracted). Open-access licence (Crossref license field): none deposited. Crossref is-referenced-by count: 16 (retrieved 2026-10-23).

Relations

Cited by (Crossref reference lists) (3)

• Thermodynamic modelling assessment of the ternary system Cs-Mo-O (2021) [crossref_reference_list]
• The SGTE collection of binary datasets (2025) [crossref_reference_list]
• Calphad Modeling of LRO and SRO Using ab initio Data (2020) [crossref_reference_list]

References (Crossref, publisher-deposited) (13)

• Untersuchungen über das System Cäsium‐Sauerstoff (1947) [crossref_reference_list]
• Systemes metaux alcalins-oxygene (1976) [crossref_reference_list]
• Cs-O (Cesium-Oxygen) (2009) [crossref_reference_list]
• The enthalpy of formation of dicesium monoxide (Cs2O) (1974) [crossref_reference_list]
• The heat capacity of dicesium monoxide (Cs2O) from 5 to 350 K and the Gibbs energy of formation to 763 K (1974) [crossref_reference_list]
• The Cs-O system;Phase diagram and oxygen potentials (1979) [crossref_reference_list]
• SGTE data for pure elements (1991) [crossref_reference_list]
• Ab initio screening of metal sorbents for elemental mercury capture in syngas streams (2010) [crossref_reference_list]
• Thermodynamic modelling of the plutonium–oxygen system (2008) [crossref_reference_list]
• Thermodynamic study of the U–Si system (2009) [crossref_reference_list]
• Calphad thermodynamic description of some binary systems involving U (2011) [crossref_reference_list]
• Thermodynamic modelling of advanced oxide and carbide nuclear fuels: Description of the U–Pu–O–C systems (2011) [crossref_reference_list]
• High Temperature Vaporization Behavior of Oxides. I. Alkali Metal Binary Oxides (1984) [crossref_reference_list]

Cites (values carry this citation) (8)

• The Cs-O system;Phase diagram and oxygen potentials (1979) — 11 values [orchid_extraction]
• SGTE data for pure elements (1991) — 10 values [orchid_extraction]
• High Temperature Vaporization Behavior of Oxides. I. Alkali Metal Binary Oxides (1984) — 6 values [orchid_extraction]
• Ab initio screening of metal sorbents for elemental mercury capture in syngas streams (2010) — 5 values [orchid_extraction]
• Untersuchungen über das System Cäsium‐Sauerstoff (1947) — 2 values [orchid_extraction]
• The enthalpy of formation of dicesium monoxide (Cs2O) (1974) — 2 values [orchid_extraction]
• The heat capacity of dicesium monoxide (Cs2O) from 5 to 350 K and the Gibbs energy of formation to 763 K (1974) — 2 values [orchid_extraction]
• Systemes metaux alcalins-oxygene (1976) — 1 values [orchid_extraction]

TDB files modelling its system (2)

• tdb:CsO-15Gue.tdb [orchid_literature_model_link]
• tdb:CsO-15Gue.tdb [sgte_tdb_header]

Data papers used (8)

• The Cs-O system;Phase diagram and oxygen potentials (1979) — 11 values [orchid_extraction]
• SGTE data for pure elements (1991) — 10 values [orchid_extraction]
• High Temperature Vaporization Behavior of Oxides. I. Alkali Metal Binary Oxides (1984) — 6 values [orchid_extraction]
• Ab initio screening of metal sorbents for elemental mercury capture in syngas streams (2010) — 5 values [orchid_extraction]
• Untersuchungen über das System Cäsium‐Sauerstoff (1947) — 2 values [orchid_extraction]
• The enthalpy of formation of dicesium monoxide (Cs2O) (1974) — 2 values [orchid_extraction]
• The heat capacity of dicesium monoxide (Cs2O) from 5 to 350 K and the Gibbs energy of formation to 763 K (1974) — 2 values [orchid_extraction]
• Systemes metaux alcalins-oxygene (1976) — 1 values [orchid_extraction]