Synthesis and Characterization of A₃Bi₂ (A = K, Rb, Cs) with Isolated Diatomic Dianion of Bismuth, [Bi₂]²^-, and an Extra Delocalized Electron

Franck Gascoin, Slavi C. Sevov

Journal of the American Chemical Society 122 (41) 10251-10252 (2000) · American Chemical Society (ACS)

DOI: 10.1021/ja002606t

Data: JSON record · id doi:10.1021/ja002606t · metadata: crossref

Roles in ORCHID

• cited as the original source of values

Systems

Bi–Cs, Bi–Rb

Evidence in ORCHID

9 values in 2 other papers cite this work as their source.

Phase-registry phases citing it: phase:bi-cs:bi2cs3, phase:bi-rb:bi2rb3

Availability

Read by ORCHID: no. Open-access licence (Crossref license field): none deposited. Crossref is-referenced-by count: 68 (retrieved 2026-10-23).

Relations

Cited by (Crossref reference lists) (5)

• Alkalimetallbismutide ABi und ABi₂ (A = K, Rb, Cs) — Synthesen, Kristallstrukturen, Eigenschaften (2004) [crossref_reference_list]
• Synthesis and Crystal Structure of M11X10 Compounds, M=Sr, Ba and X=Bi, Sb. Electronic Requirements and Chemical Bonding (2002) [crossref_reference_list]
• Thermodynamic Reassessment of the Bi-Rb System Supported by Ab-Initio Calculations (2022) [crossref_reference_list]
• Thermodynamic description of the Bi–Cs and Bi–Tm system supported by first-principles calculations (2015) [crossref_reference_list]
• Synthesis and Characterization of the “Metallic Salts” A₅Pn₄ (A = K, Rb, Cs and Pn = As, Sb, Bi) with Isolated Zigzag Tetramers of Pn₄^4- and an Extra Delocalized Electron (2001) [crossref_reference_list]

References (Crossref, publisher-deposited) (2)

• Das Verhalten der Alkalimetalle zu Halbmetallen. IV. Die Systeme des Kaliums, Rubidiums und Caesiums mit Wismut (1961) [crossref_reference_list]
• Zur Kenntnis von Ca₁₁Sb₁₀ und Ca₁₁Bi₁₀ (1976) [crossref_reference_list]

Cited for values by (2)

• Thermodynamic Reassessment of the Bi-Rb System Supported by Ab-Initio Calculations (2022) — 6 values [orchid_extraction]
• Thermodynamic description of the Bi–Cs and Bi–Tm system supported by first-principles calculations (2015) — 3 values [orchid_extraction]

Used in (assessments / papers that took values from it) (2)

• Thermodynamic Reassessment of the Bi-Rb System Supported by Ab-Initio Calculations (2022) — 6 values [orchid_extraction]
• Thermodynamic description of the Bi–Cs and Bi–Tm system supported by first-principles calculations (2015) — 3 values [orchid_extraction]