Thermodynamic Reassessment of the Bi-Rb System Supported by Ab-Initio Calculations

F. Dziri, Y. Djaballah, E. Belbacha, A. Belgacem Bouzida

Journal of Phase Equilibria and Diffusion 43 (3) 382-392 (2022) · Springer Science and Business Media LLC

DOI: 10.1007/s11669-022-00968-3

Data: JSON record · id doi:10.1007/s11669-022-00968-3 · metadata: crossref

Roles in ORCHID

• read by ORCHID (values extracted): 175 released values
• assessment behind a TDB file: BiRb-22Dzi.tdb (Bi–Rb)

Systems

Bi, Rb, Bi–Rb

Evidence in ORCHID

175 values read from this paper (175 accepted), from 3 tables and 0 text passages.

ESPEI datasets derived: 28 (derived/invariant-brackets/BI-RB/BiRb-13Liu.zpf-00.json …).

Phase-registry phases citing it: phase:bi-rb:a7-rhombohedral, phase:bi-rb:bcc-a2, phase:bi-rb:bi2rb-c15, phase:bi-rb:bi2rb3, phase:bi-rb:bi4rb5, phase:bi-rb:birb, phase:bi-rb:birb3-d018, phase:bi-rb:birb3-d03, phase:bi-rb:fcc-a1, phase:bi-rb:hcp-a3, phase:bi-rb:liquid

Availability

Read by ORCHID: yes (values_extracted). Open-access licence (Crossref license field): none deposited. Crossref is-referenced-by count: 2 (retrieved 2026-10-23).

Relations

Cited by (Crossref reference lists) (1)

• The SGTE collection of binary datasets (2025) [crossref_reference_list]

References (Crossref, publisher-deposited) (26)

• Das Verhalten der Alkalimetalle zu Halbmetallen. IV. Die Systeme des Kaliums, Rubidiums und Caesiums mit Wismut (1961) [crossref_reference_list]
• Alkalimetallbismutide ABi und ABi₂ (A = K, Rb, Cs) — Synthesen, Kristallstrukturen, Eigenschaften (2004) [crossref_reference_list]
• Contribution to the evaluation of rare earth alloy systems (1993) [crossref_reference_list]
• The Bi-Rb (bismuth-rubidium) system (1993) [crossref_reference_list]
• First-Principles Calculations and CALPHAD Modeling of Thermodynamics (2009) [crossref_reference_list]
• SGTE data for pure elements (1991) [crossref_reference_list]
• Thermodynamic assessments of the Bi–Lu and Lu–Sb systems (2011) [crossref_reference_list]
• Thermodynamic assessment of the Gd–Bi and the Ho–Bi systems (2013) [crossref_reference_list]
• Thermodynamic assessment of the Bi-alkali metal (Li, Na, K, Rb) systems using the modified quasichemical model for the liquid phase (2014) [crossref_reference_list]
• Thermodynamic description of the Bi–Cs and Bi–Tm system supported by first-principles calculations (2015) [crossref_reference_list]
• Calorimetric measurement of the intermetallic compounds Cr3Ga and CrGa4 and thermodynamic assessment of the (Cr–Ga) system (2005) [crossref_reference_list]
• Thermodynamic assessments of the Bi–Nd and Bi–Tm systems (2010) [crossref_reference_list]
• Thermodynamic assessment of the Bi–K binary system (2012) [crossref_reference_list]
• Thermodynamic assessment of the Bi–Rb binary system (2013) [crossref_reference_list]
• Thermodynamic basis and related phase equilibria for Bi–Li and Bi–Na binary systems (2013) [crossref_reference_list]
• Thermodynamic assessment of the Bi–Er and the Bi–Dy systems (2013) [crossref_reference_list]
• Thermodynamic optimization of Bi-Ni binary system (2011) [crossref_reference_list]
• Synthesis and Characterization of the “Metallic Salts” A₅Pn₄ (A = K, Rb, Cs and Pn = As, Sb, Bi) with Isolated Zigzag Tetramers of Pn₄^4- and an Extra Delocalized Electron (2001) [crossref_reference_list]
• Synthesis and Characterization of A₃Bi₂ (A = K, Rb, Cs) with Isolated Diatomic Dianion of Bismuth, [Bi₂]²^-, and an Extra Delocalized Electron (2000) [crossref_reference_list]
• Calorical properties of equiatomic alloy of rubidium-bismuth system in the temperature range 293–1175 K (2019) [crossref_reference_list]
• Crystallography and magnetism of the heavy-fermion compound YbBiPt (1994) [crossref_reference_list]
• Efficient iterative schemes for <i>ab initio</i> total-energy calculations using a plane-wave basis set (1996) [crossref_reference_list]
• From ultrasoft pseudopotentials to the projector augmented-wave method (1999) [crossref_reference_list]
• Generalized Gradient Approximation Made Simple (1996) [crossref_reference_list]
• X-ray study of the alkali metals at low temperatures (1956) [crossref_reference_list]
• Electromotive Force Measurements in Molten Rb‐Bi Alloys with a Rubidium β″‐Alumina Electrolyte (1988) [crossref_reference_list]

Cites (values carry this citation) (11)

• Thermodynamic basis and related phase equilibria for Bi–Li and Bi–Na binary systems (2013) — 17 values [orchid_extraction]
• Thermodynamic assessment of the Bi-alkali metal (Li, Na, K, Rb) systems using the modified quasichemical model for the liquid phase (2014) — 15 values [orchid_extraction]
• Electromotive Force Measurements in Molten Rb‐Bi Alloys with a Rubidium β″‐Alumina Electrolyte (1988) — 9 values [orchid_extraction]
• Das Verhalten der Alkalimetalle zu Halbmetallen. IV. Die Systeme des Kaliums, Rubidiums und Caesiums mit Wismut (1961) — 8 values [orchid_extraction]
• Alkalimetallbismutide ABi und ABi₂ (A = K, Rb, Cs) — Synthesen, Kristallstrukturen, Eigenschaften (2004) — 7 values [orchid_extraction]
• The Bi-Rb (bismuth-rubidium) system (1993) — 7 values [orchid_extraction]
• Synthesis and Characterization of the “Metallic Salts” A₅Pn₄ (A = K, Rb, Cs and Pn = As, Sb, Bi) with Isolated Zigzag Tetramers of Pn₄^4- and an Extra Delocalized Electron (2001) — 6 values [orchid_extraction]
• Synthesis and Characterization of A₃Bi₂ (A = K, Rb, Cs) with Isolated Diatomic Dianion of Bismuth, [Bi₂]²^-, and an Extra Delocalized Electron (2000) — 6 values [orchid_extraction]
• Crystallography and magnetism of the heavy-fermion compound YbBiPt (1994) — 2 values [orchid_extraction]
• Calorical properties of equiatomic alloy of rubidium-bismuth system in the temperature range 293–1175 K (2019) — 1 values [orchid_extraction]
• X-ray study of the alkali metals at low temperatures (1956) — 1 values [orchid_extraction]

TDB files modelling its system (2)

• tdb:BiRb-22Dzi.tdb [orchid_literature_model_link]
• tdb:BiRb-22Dzi.tdb [sgte_tdb_header]

Reassesses (cites an earlier assessment of the same system) (1)

• Thermodynamic assessment of the Bi–Rb binary system (2013) [citation+same-system]

Data papers used (11)

• Thermodynamic basis and related phase equilibria for Bi–Li and Bi–Na binary systems (2013) — 17 values [orchid_extraction]
• Thermodynamic assessment of the Bi-alkali metal (Li, Na, K, Rb) systems using the modified quasichemical model for the liquid phase (2014) — 15 values [orchid_extraction]
• Electromotive Force Measurements in Molten Rb‐Bi Alloys with a Rubidium β″‐Alumina Electrolyte (1988) — 9 values [orchid_extraction]
• Das Verhalten der Alkalimetalle zu Halbmetallen. IV. Die Systeme des Kaliums, Rubidiums und Caesiums mit Wismut (1961) — 8 values [orchid_extraction]
• Alkalimetallbismutide ABi und ABi₂ (A = K, Rb, Cs) — Synthesen, Kristallstrukturen, Eigenschaften (2004) — 7 values [orchid_extraction]
• The Bi-Rb (bismuth-rubidium) system (1993) — 7 values [orchid_extraction]
• Synthesis and Characterization of the “Metallic Salts” A₅Pn₄ (A = K, Rb, Cs and Pn = As, Sb, Bi) with Isolated Zigzag Tetramers of Pn₄^4- and an Extra Delocalized Electron (2001) — 6 values [orchid_extraction]
• Synthesis and Characterization of A₃Bi₂ (A = K, Rb, Cs) with Isolated Diatomic Dianion of Bismuth, [Bi₂]²^-, and an Extra Delocalized Electron (2000) — 6 values [orchid_extraction]
• Crystallography and magnetism of the heavy-fermion compound YbBiPt (1994) — 2 values [orchid_extraction]
• Calorical properties of equiatomic alloy of rubidium-bismuth system in the temperature range 293–1175 K (2019) — 1 values [orchid_extraction]
• X-ray study of the alkali metals at low temperatures (1956) — 1 values [orchid_extraction]