Thermodynamic description of the Bi–Cs and Bi–Tm system supported by first-principles calculations

Y. Djaballah, A. Said Amer, Ş. Uğur, G. Uğur, A. Hidoussi, A. Belgacem-Bouzida

Calphad 48 72-78 (2015) · Elsevier BV

DOI: 10.1016/j.calphad.2014.11.002

Data: JSON record · id doi:10.1016/j.calphad.2014.11.002 · metadata: crossref

Roles in ORCHID

• read by ORCHID (values extracted): 135 released values
• assessment behind a TDB file: BiCs-15Dja.tdb (Bi–Cs), BiTm-15Dja.tdb (Bi–Tm)

Systems

Bi, Cs, Tm, Bi–Cs, Bi–Tm

Evidence in ORCHID

135 values read from this paper (133 accepted), from 4 tables and 2 text passages.

ESPEI datasets derived: 16 (derived/invariant-brackets/BI-CS/BiCs-15Dja.zpf-00.json …).

Phase-registry phases citing it: phase:bi-cs:a7-rhombohedral, phase:bi-cs:bcc-a2, phase:bi-cs:bi2cs-c15, phase:bi-cs:bi2cs3, phase:bi-cs:bi4cs5, phase:bi-cs:bics3-d03, phase:bi-cs:fcc-a1, phase:bi-cs:hcp-a3, phase:bi-cs:liquid, phase:bi-tm:a7-rhombohedral, phase:bi-tm:bcc-a2, phase:bi-tm:bi3tm5, phase:bi-tm:bitm-b1, phase:bi-tm:fcc-a1, phase:bi-tm:hcp-a3, phase:bi-tm:liquid

Availability

Read by ORCHID: yes (values_extracted). Open-access licence (Crossref license field): none deposited. Crossref is-referenced-by count: 14 (retrieved 2026-10-23).

Relations

Cited by (Crossref reference lists) (4)

• Thermodynamic Study of Er-Bi and Er-Te Systems by Combination of First-Principles Calculations and the CALPHAD Method (2022) [crossref_reference_list]
• Thermodynamic Reassessment of the Bi-Rb System Supported by Ab-Initio Calculations (2022) [crossref_reference_list]
• The SGTE collection of binary datasets (2025) [crossref_reference_list]
• Thermodynamic properties of fission products (Pr, Ce, Er) in liquid bismuth by thermodynamic assessment (2017) [crossref_reference_list]

References (Crossref, publisher-deposited) (30)

• Das Verhalten der Alkalimetalle zu Halbmetallen. IV. Die Systeme des Kaliums, Rubidiums und Caesiums mit Wismut (1961) [crossref_reference_list]
• Alkalimetallbismutide ABi und ABi₂ (A = K, Rb, Cs) — Synthesen, Kristallstrukturen, Eigenschaften (2004) [crossref_reference_list]
• The Bi-Cs (Bismuth-Cesium) system (1991) [crossref_reference_list]
• Contribution to the evaluation of rare earth alloy systems (1993) [crossref_reference_list]
• Contribution to the thermochemistry of rare earth pnictides: The Sm-Bi system (1993) [crossref_reference_list]
• Rare-earth bismuthides (1975) [crossref_reference_list]
• Enthalpies of formation of liquid and solid binary alloys of lead, antimony and bismuth with rare earth elements (1984) [crossref_reference_list]
• Heats of formation of gadolinium—bismuth alloys (1980) [crossref_reference_list]
• The Thermo-Calc databank system (1985) [crossref_reference_list]
• SGTE data for pure elements (1991) [crossref_reference_list]
• Phase diagrams and thermodynamic properties of rare earth-bismuth systems (1996) [crossref_reference_list]
• Thermodynamic assessments of the Bi–Lu and Lu–Sb systems (2011) [crossref_reference_list]
• Thermodynamic assessment of the Gd–Bi and the Ho–Bi systems (2013) [crossref_reference_list]
• Thermodynamic assessment of the Bi-alkali metal (Li, Na, K, Rb) systems using the modified quasichemical model for the liquid phase (2014) [crossref_reference_list]
• Calorimetric measurement of the intermetallic compounds Cr3Ga and CrGa4 and thermodynamic assessment of the (Cr–Ga) system (2005) [crossref_reference_list]
• Thermodynamic assessments of the Bi–Nd and Bi–Tm systems (2010) [crossref_reference_list]
• Thermodynamic assessment of the Bi–K binary system (2012) [crossref_reference_list]
• Thermodynamic assessment of the Bi–Rb binary system (2013) [crossref_reference_list]
• Thermodynamic basis and related phase equilibria for Bi–Li and Bi–Na binary systems (2013) [crossref_reference_list]
• Thermodynamic assessment of the Bi–Er and the Bi–Dy systems (2013) [crossref_reference_list]
• Thermodynamic optimization of Bi-Ni binary system (2011) [crossref_reference_list]
• Synthesis and Characterization of the “Metallic Salts” A₅Pn₄ (A = K, Rb, Cs and Pn = As, Sb, Bi) with Isolated Zigzag Tetramers of Pn₄^4- and an Extra Delocalized Electron (2001) [crossref_reference_list]
• Synthesis and Characterization of A₃Bi₂ (A = K, Rb, Cs) with Isolated Diatomic Dianion of Bismuth, [Bi₂]²^-, and an Extra Delocalized Electron (2000) [crossref_reference_list]
• Phase Relations and Properties of Alloys in the Tm–Bi System (2003) [crossref_reference_list]
• Location of deuterium and its interaction with magnetic order in HCP thulium: a neutron diffraction study (1983) [crossref_reference_list]
• Special points for Brillouin-zone integrations (1976) [crossref_reference_list]
• Crystallography and magnetism of the heavy-fermion compound YbBiPt (1994) [crossref_reference_list]
• Efficient iterative schemes for <i>ab initio</i> total-energy calculations using a plane-wave basis set (1996) [crossref_reference_list]
• From ultrasoft pseudopotentials to the projector augmented-wave method (1999) [crossref_reference_list]
• X-ray study of the alkali metals at low temperatures (1956) [crossref_reference_list]

Cites (values carry this citation) (13)

• Das Verhalten der Alkalimetalle zu Halbmetallen. IV. Die Systeme des Kaliums, Rubidiums und Caesiums mit Wismut (1961) — 10 values [orchid_extraction]
• The Bi-Cs (Bismuth-Cesium) system (1991) — 8 values [orchid_extraction]
• Rare-earth bismuthides (1975) — 6 values [orchid_extraction]
• Thermodynamic assessments of the Bi–Nd and Bi–Tm systems (2010) — 6 values [orchid_extraction]
• Phase diagrams and thermodynamic properties of rare earth-bismuth systems (1996) — 4 values [orchid_extraction]
• Phase Relations and Properties of Alloys in the Tm–Bi System (2003) — 4 values [orchid_extraction]
• Alkalimetallbismutide ABi und ABi₂ (A = K, Rb, Cs) — Synthesen, Kristallstrukturen, Eigenschaften (2004) — 3 values [orchid_extraction]
• Synthesis and Characterization of the “Metallic Salts” A₅Pn₄ (A = K, Rb, Cs and Pn = As, Sb, Bi) with Isolated Zigzag Tetramers of Pn₄^4- and an Extra Delocalized Electron (2001) — 3 values [orchid_extraction]
• Synthesis and Characterization of A₃Bi₂ (A = K, Rb, Cs) with Isolated Diatomic Dianion of Bismuth, [Bi₂]²^-, and an Extra Delocalized Electron (2000) — 3 values [orchid_extraction]
• Location of deuterium and its interaction with magnetic order in HCP thulium: a neutron diffraction study (1983) — 3 values [orchid_extraction]
• Crystallography and magnetism of the heavy-fermion compound YbBiPt (1994) — 3 values [orchid_extraction]
• X-ray study of the alkali metals at low temperatures (1956) — 3 values [orchid_extraction]
• Enthalpies of formation of liquid and solid binary alloys of lead, antimony and bismuth with rare earth elements (1984) — 2 values [orchid_extraction]

TDB files modelling its system (4)

• tdb:BiCs-15Dja.tdb [orchid_literature_model_link]
• tdb:BiCs-15Dja.tdb [sgte_tdb_header]
• tdb:BiTm-15Dja.tdb [orchid_literature_model_link]
• tdb:BiTm-15Dja.tdb [sgte_tdb_header]

Reassesses (cites an earlier assessment of the same system) (1)

• Thermodynamic assessments of the Bi–Nd and Bi–Tm systems (2010) [citation+same-system]

Data papers used (13)

• Das Verhalten der Alkalimetalle zu Halbmetallen. IV. Die Systeme des Kaliums, Rubidiums und Caesiums mit Wismut (1961) — 10 values [orchid_extraction]
• The Bi-Cs (Bismuth-Cesium) system (1991) — 8 values [orchid_extraction]
• Rare-earth bismuthides (1975) — 6 values [orchid_extraction]
• Thermodynamic assessments of the Bi–Nd and Bi–Tm systems (2010) — 6 values [orchid_extraction]
• Phase diagrams and thermodynamic properties of rare earth-bismuth systems (1996) — 4 values [orchid_extraction]
• Phase Relations and Properties of Alloys in the Tm–Bi System (2003) — 4 values [orchid_extraction]
• Alkalimetallbismutide ABi und ABi₂ (A = K, Rb, Cs) — Synthesen, Kristallstrukturen, Eigenschaften (2004) — 3 values [orchid_extraction]
• Synthesis and Characterization of the “Metallic Salts” A₅Pn₄ (A = K, Rb, Cs and Pn = As, Sb, Bi) with Isolated Zigzag Tetramers of Pn₄^4- and an Extra Delocalized Electron (2001) — 3 values [orchid_extraction]
• Synthesis and Characterization of A₃Bi₂ (A = K, Rb, Cs) with Isolated Diatomic Dianion of Bismuth, [Bi₂]²^-, and an Extra Delocalized Electron (2000) — 3 values [orchid_extraction]
• Location of deuterium and its interaction with magnetic order in HCP thulium: a neutron diffraction study (1983) — 3 values [orchid_extraction]
• Crystallography and magnetism of the heavy-fermion compound YbBiPt (1994) — 3 values [orchid_extraction]
• X-ray study of the alkali metals at low temperatures (1956) — 3 values [orchid_extraction]
• Enthalpies of formation of liquid and solid binary alloys of lead, antimony and bismuth with rare earth elements (1984) — 2 values [orchid_extraction]