The bismuth-oxygen system

D. Risold, B. Hallstedt, L. J. Gauckler, H. L. Lukas, S. G. Fries

Journal of Phase Equilibria 16 (3) 223 (1995) · Springer Science and Business Media LLC

DOI: 10.1007/bf02667306

Data: JSON record · id doi:10.1007/bf02667306 · metadata: crossref

Roles in ORCHID

• read by ORCHID (values extracted): 86 released values
• assessment behind a TDB file: BiO-95Ris-LB.tdb (Bi–O)
• original evaluation behind an assessed (handbook) diagram: Bi–O

Systems

Bi–O

Evidence in ORCHID

86 values read from this paper (81 accepted), from 4 tables and 2 text passages.

ESPEI datasets derived: 6 (experimental/BI-O/BiO-95Ris-LB.cpm-00.json …).

Phase-registry phases citing it: phase:bi-o:a7-rhombohedral, phase:bi-o:bi2o3-alpha, phase:bi-o:bi2o3-c1, phase:bi-o:gas, phase:bi-o:ion, phase:bi-o:o2gas

Assessed phase-assemblage records citing it: 10.

Availability

Read by ORCHID: yes (values_extracted, full_text_screened_for_origin). Open-access licence (Crossref license field): none deposited. Crossref is-referenced-by count: 98 (retrieved 2026-10-23).

Relations

Cited by (Crossref reference lists) (6)

• The SGTE collection of binary datasets (2025) [crossref_reference_list]
• Calculation of phase diagrams: Calphad (1996) [crossref_reference_list]
• Thermodynamic Assessment of the Bismuth–Strontium–Oxygen Oxide System (1997) [crossref_reference_list]
• Experimental Phase Diagram Study and Thermodynamic Optimization of the Ag‐Bi‐O System (1999) [crossref_reference_list]
• Thermodynamic Optimization of the Silver—Bismuth—Strontium—Calcium—Copper—Oxygen (Ag‐Bi‐Sr‐Ca‐Cu‐O) System (2000) [crossref_reference_list]
• On the coupled growth of oxide phases during internal oxidation of Ag–Sn–Bi alloys (2012) [crossref_reference_list]

References (Crossref, publisher-deposited) (13)

• Über Wismutoxide. III. Die Kristallstruktur der Hochtemperaturmodifikation von Wismut(III)‐oxid (δ‐Bi₂O₃) (1962) [crossref_reference_list]
• Über Wismutoxide. VI. Überein Wismut (III)‐oxid mit höherem Sauerstoffgehalt (β‐Modifikation) (1964) [crossref_reference_list]
• Thermodynamic assessment of the copper-oxygen system (1994) [crossref_reference_list]
• Free energy of formation of Bi2O3 (1971) [crossref_reference_list]
• Diffusivity, activity and solubility of oxygen in liquid bismuth (1980) [crossref_reference_list]
• SGTE data for pure elements (1991) [crossref_reference_list]
• Phase transformations and electrical properties of bismuth sesquioxide (1969) [crossref_reference_list]
• Enthalpy and entropy increments above 298.degree.K. for bismuth(III) bromide, bismuth(III) oxide, thallium(III) oxide, and thallium(I) oxide (1967) [crossref_reference_list]
• Free Energy of Formation of Bi[sub 2]O[sub 3], Sb[sub 2]O[sub 3], and TeO[sub 2] from EMF Measurements (1973) [crossref_reference_list]
• Activity Measurements of Liquid Ag-Bi Alloys by an EMF Method Using a Zirconia Electrolyte (1991) [crossref_reference_list]
• Activity of Liquid Tl-Bi Alloys Measured by an EMF Method Using Zirconia Electrolyte (1992) [crossref_reference_list]
• Heat of formation of trisodium orthophosphate, trisodium orthoarsenate, the oxides of antimony, bismuth trioxide; and fourth paper on the heat of combination of acidic oxides with sodium oxide (1909) [crossref_reference_list]
• Heats of transformations in bismuth oxide by differential thermal analysis (1965) [crossref_reference_list]

Cites (values carry this citation) (11)

• Free energy of formation of Bi2O3 (1971) — 5 values [orchid_extraction]
• Free Energy of Formation of Bi[sub 2]O[sub 3], Sb[sub 2]O[sub 3], and TeO[sub 2] from EMF Measurements (1973) — 4 values [orchid_extraction]
• Activity Measurements of Liquid Ag-Bi Alloys by an EMF Method Using a Zirconia Electrolyte (1991) — 4 values [orchid_extraction]
• Activity of Liquid Tl-Bi Alloys Measured by an EMF Method Using Zirconia Electrolyte (1992) — 4 values [orchid_extraction]
• Diffusivity, activity and solubility of oxygen in liquid bismuth (1980) — 3 values [orchid_extraction]
• Enthalpy and entropy increments above 298.degree.K. for bismuth(III) bromide, bismuth(III) oxide, thallium(III) oxide, and thallium(I) oxide (1967) — 2 values [orchid_extraction]
• Heat of formation of trisodium orthophosphate, trisodium orthoarsenate, the oxides of antimony, bismuth trioxide; and fourth paper on the heat of combination of acidic oxides with sodium oxide (1909) — 2 values [orchid_extraction]
• Heats of transformations in bismuth oxide by differential thermal analysis (1965) — 2 values [orchid_extraction]
• Über Wismutoxide. III. Die Kristallstruktur der Hochtemperaturmodifikation von Wismut(III)‐oxid (δ‐Bi₂O₃) (1962) — 1 values [orchid_extraction]
• Über Wismutoxide. VI. Überein Wismut (III)‐oxid mit höherem Sauerstoffgehalt (β‐Modifikation) (1964) — 1 values [orchid_extraction]
• Phase transformations and electrical properties of bismuth sesquioxide (1969) — 1 values [orchid_extraction]

Reproduced by handbook diagrams (1)

• handbook:okamoto-2010:BI-O [okamoto_handbook_source_line]

TDB files modelling its system (2)

• tdb:BiO-95Ris-LB.tdb [sgte_tdb_header]
• tdb:BiO-95Ris-LB.tdb [orchid_literature_model_link]

Data papers used (11)

• Free energy of formation of Bi2O3 (1971) — 5 values [orchid_extraction]
• Free Energy of Formation of Bi[sub 2]O[sub 3], Sb[sub 2]O[sub 3], and TeO[sub 2] from EMF Measurements (1973) — 4 values [orchid_extraction]
• Activity Measurements of Liquid Ag-Bi Alloys by an EMF Method Using a Zirconia Electrolyte (1991) — 4 values [orchid_extraction]
• Activity of Liquid Tl-Bi Alloys Measured by an EMF Method Using Zirconia Electrolyte (1992) — 4 values [orchid_extraction]
• Diffusivity, activity and solubility of oxygen in liquid bismuth (1980) — 3 values [orchid_extraction]
• Enthalpy and entropy increments above 298.degree.K. for bismuth(III) bromide, bismuth(III) oxide, thallium(III) oxide, and thallium(I) oxide (1967) — 2 values [orchid_extraction]
• Heat of formation of trisodium orthophosphate, trisodium orthoarsenate, the oxides of antimony, bismuth trioxide; and fourth paper on the heat of combination of acidic oxides with sodium oxide (1909) — 2 values [orchid_extraction]
• Heats of transformations in bismuth oxide by differential thermal analysis (1965) — 2 values [orchid_extraction]
• Über Wismutoxide. III. Die Kristallstruktur der Hochtemperaturmodifikation von Wismut(III)‐oxid (δ‐Bi₂O₃) (1962) — 1 values [orchid_extraction]
• Über Wismutoxide. VI. Überein Wismut (III)‐oxid mit höherem Sauerstoffgehalt (β‐Modifikation) (1964) — 1 values [orchid_extraction]
• Phase transformations and electrical properties of bismuth sesquioxide (1969) — 1 values [orchid_extraction]