Ag–In system

50 accepted literature values from 2 paper(s) (experimental 35, model 15); 6 calculated phase diagram(s). 12 further extracted value(s) not accepted by the reader-agreement checks are only in the JSON/CSV.

Data: JSON · CSV · interactive explorer · interactive phase diagram · phases (9) · papers (bibliography) · Markdown

Accepted values by evidence class
Evidence class	Values
experimental	35
model	15

Accepted values by property group
Property group	Values
invariant reaction	43
phase transition	7

Calculated phase diagrams

Binary phase diagrams calculated with pycalphad 0.11.2 from the SGTE binary collection (Hallstedt 2025, CC BY 4.0). Evidence class: model.

Assessments with a calculated phase diagram
TDB file	Assessment	SHA-256	Links
AgIn-01Che-LB.tdb	P.-Y. Chevalier, E. Fischer, unpublished, Thermodata, 2001.	`4a54fce02faf2be33720e1ad4f7814b3af0abfcb083f44028ac2a25425acd9d8`	viewer · TDB · JSON
AgIn-01Mos.tdb	Z. Moser, W. Gasior, J. Pstrus, W. Zakulski, I. Ohnuma, X.J. Liu, Y. Inohana, K. Ishida, J. Electron. Mater., 30, 1120-28(2001). doi:10.1007/s11664-001-0138-4	`8135d127623e0a9013d8029e11addf46d43b24e1ec934005661f5597a0377f6d`	viewer · TDB · JSON
AgIn-12Gie.tdb	W. Gierlotka, J. Electron. Mater., 41, 86-108(2012). doi:10.1007/s11664-011-1757-z	`2d44091621ab6487acdd987b8a85c922a12657311bfeb987b529323d1cdd15c5`	viewer · TDB · JSON
AgIn-18Muz.tdb	C.P. Muzzillo, T. Anderson, J. Mater. Sci., 53, 6893-6910(2018). doi:10.1007/s10853-018-1999-8	`c7853514773b1fdba4937525e737d4b9481d4c2e173df43539aa645b7b12db3b`	viewer · TDB · JSON
AgIn-19Fis.tdb	E. Fischer, K. Gajavalli, G. Mikaelian, P. Benigni, J. Rogez, A. Decreton, M. Barrachin, Calphad, 64, 292-305(2019). doi:10.1016/j.calphad.2019.01.001	`4cca7ad748e801ffd31af18a3ee8dc141526869f2a465276cb689d1d48fee71f`	viewer · TDB · JSON
AgIn-98Kor.tdb	T.-M. Korhonen, J.K. Kivilahti, J. Electron. Mater., 27, 149-58(1998). doi:10.1007/s11664-998-0205-1	`4c8fd91ba6cf605ce7d3e75ea4083b0bd14cdd84879b05dc05cb92f028af15c5`	viewer · TDB · JSON

Calculated three-phase invariants (model, mole fraction of the second component)
TDB file	T (K)	Phases at the invariant
AgIn-01Che-LB.tdb	977.82	FCC_A1 (x(In) 0.1866) + BCC_A2 (x(In) 0.22525) + LIQUID (x(In) 0.27791)
AgIn-01Che-LB.tdb	946.69	FCC_A1 (x(In) 0.19227) + HCP_A3 (x(In) 0.22402) + BCC_A2 (x(In) 0.23093)
AgIn-01Che-LB.tdb	933.35	HCP_A3 (x(In) 0.25156) + BCC_A2 (x(In) 0.25293) + LIQUID (x(In) 0.32913)
AgIn-01Che-LB.tdb	477.7	AG2IN_D83 (x(In) 0.33333) + HCP_A3 (x(In) 0.41961) + LIQUID (x(In) 0.92573)
AgIn-01Che-LB.tdb	477.7	AG2IN_D83 (x(In) 0.33333) + HCP_A3 (x(In) 0.41964) + LIQUID (x(In) 0.92594)
AgIn-01Che-LB.tdb	458.25	AG3IN_L12 (x(In) 0.25) + HCP_A3 (x(In) 0.25596) + AG2IN_D83 (x(In) 0.33333)
AgIn-01Che-LB.tdb	443.76	FCC_A1 (x(In) 0.19981) + HCP_A3 (x(In) 0.23289) + AG3IN_L12 (x(In) 0.25)
AgIn-01Che-LB.tdb	439.19	AG2IN_D83 (x(In) 0.33333) + AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.95054)
AgIn-01Che-LB.tdb	439.18	AG2IN_D83 (x(In) 0.33333) + AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.95042)
AgIn-01Che-LB.tdb	439.18	AG2IN_D83 (x(In) 0.33333) + AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.95041)
AgIn-01Che-LB.tdb	414.6	AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.96734) + TETRAGONAL_A6 (x(In) 1)
AgIn-01Che-LB.tdb	414.6	AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.96734) + TETRAGONAL_A6 (x(In) 1)
AgIn-01Mos.tdb	948.41	FCC_A1 (x(In) 0.19811) + HCP_A3 (x(In) 0.24204) + LIQUID (x(In) 0.30105)
AgIn-01Mos.tdb	467.94	AG2IN_D83 (x(In) 0.32) + HCP_A3 (x(In) 0.35928) + LIQUID (x(In) 0.93854)
AgIn-01Mos.tdb	467.94	AG2IN_D83 (x(In) 0.32) + HCP_A3 (x(In) 0.35928) + LIQUID (x(In) 0.93848)
AgIn-01Mos.tdb	439.02	AG2IN_D83 (x(In) 0.32) + AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.95452)
AgIn-01Mos.tdb	439.02	AG2IN_D83 (x(In) 0.32) + AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.95438)
AgIn-01Mos.tdb	439.02	AG2IN_D83 (x(In) 0.32) + AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.95462)
AgIn-01Mos.tdb	417.64	AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.97484) + TETRAGONAL_A6 (x(In) 1)
AgIn-01Mos.tdb	417.64	AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.97498) + TETRAGONAL_A6 (x(In) 1)
AgIn-01Mos.tdb	417.64	AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.97507) + TETRAGONAL_A6 (x(In) 1)
AgIn-12Gie.tdb	949.14	FCC_A1 (x(In) 0.21106) + HCP_A3 (x(In) 0.24334) + LIQUID (x(In) 0.31225)
AgIn-12Gie.tdb	472.96	AG2IN_D83 (x(In) 0.3379) + HCP_A3 (x(In) 0.37285) + LIQUID (x(In) 0.93454)
AgIn-12Gie.tdb	448.95	AG2IN_D83 (x(In) 0.33808) + AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.94633)
AgIn-12Gie.tdb	415.17	AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.97216) + TETRAGONAL_A6 (x(In) 1)
AgIn-12Gie.tdb	415.17	AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.97219) + TETRAGONAL_A6 (x(In) 1)
AgIn-18Muz.tdb	981.81	FCC_A1 (x(In) 0.19129) + BCC_A2 (x(In) 0.24048) + LIQUID (x(In) 0.28346)
AgIn-18Muz.tdb	939.45	FCC_A1 (x(In) 0.21057) + HCP_A3 (x(In) 0.24283) + BCC_A2 (x(In) 0.25375)
AgIn-18Muz.tdb	933.98	HCP_A3 (x(In) 0.25506) + BCC_A2 (x(In) 0.26405) + LIQUID (x(In) 0.33185)
AgIn-18Muz.tdb	477.41	AG9IN4_D83 (x(In) 0.33621) + HCP_A3 (x(In) 0.37265) + LIQUID (x(In) 0.93226)
AgIn-18Muz.tdb	438.98	AG9IN4_D83 (x(In) 0.33622) + AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.95121)
AgIn-18Muz.tdb	414.09	AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.97019) + TETRAGONAL_A6 (x(In) 1)
AgIn-18Muz.tdb	414.09	AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.97027) + TETRAGONAL_A6 (x(In) 1)
AgIn-19Fis.tdb	965.97	FCC_A1 (x(In) 0.19271) + BCC_A2 (x(In) 0.23241) + LIQUID (x(In) 0.29591)
AgIn-19Fis.tdb	937.95	FCC_A1 (x(In) 0.20342) + HCP_A3 (x(In) 0.2353) + BCC_A2 (x(In) 0.24193)
AgIn-19Fis.tdb	932.71	HCP_A3 (x(In) 0.24927) + BCC_A2 (x(In) 0.25479) + LIQUID (x(In) 0.33246)
AgIn-19Fis.tdb	478.52	AG3IN_L12 (x(In) 0.25) + HCP_A3 (x(In) 0.26002) + AG2IN_D83 (x(In) 0.33333)
AgIn-19Fis.tdb	477.63	AG2IN_D83 (x(In) 0.33333) + HCP_A3 (x(In) 0.41382) + LIQUID (x(In) 0.92898)
AgIn-19Fis.tdb	477.63	AG2IN_D83 (x(In) 0.33333) + HCP_A3 (x(In) 0.41385) + LIQUID (x(In) 0.92918)
AgIn-19Fis.tdb	460.03	FCC_A1 (x(In) 0.19951) + HCP_A3 (x(In) 0.23094) + AG3IN_L12 (x(In) 0.25)
AgIn-19Fis.tdb	439.22	AG2IN_D83 (x(In) 0.33333) + AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.95205)
AgIn-19Fis.tdb	439.22	AG2IN_D83 (x(In) 0.33333) + AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.95184)
AgIn-19Fis.tdb	439.22	AG2IN_D83 (x(In) 0.33333) + AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.95217)
AgIn-19Fis.tdb	413.62	AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.96751) + TETRAGONAL_A6 (x(In) 1)
AgIn-19Fis.tdb	413.62	AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.96767) + TETRAGONAL_A6 (x(In) 1)
AgIn-98Kor.tdb	926.59	FCC_A1 (x(In) 0.1972) + HCP_A3 (x(In) 0.23529) + LIQUID (x(In) 0.33016)
AgIn-98Kor.tdb	475.58	AG2IN_D83 (x(In) 0.33333) + HCP_A3 (x(In) 0.41941) + LIQUID (x(In) 0.91711)
AgIn-98Kor.tdb	475.58	AG2IN_D83 (x(In) 0.33333) + HCP_A3 (x(In) 0.41941) + LIQUID (x(In) 0.91702)
AgIn-98Kor.tdb	440.17	AG2IN_D83 (x(In) 0.33333) + AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.94205)
AgIn-98Kor.tdb	440.17	AG2IN_D83 (x(In) 0.33333) + AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.94174)
AgIn-98Kor.tdb	440.17	AG2IN_D83 (x(In) 0.33333) + AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.94225)
AgIn-98Kor.tdb	413.27	AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.96739) + TETRAGONAL_A6 (x(In) 1)
AgIn-98Kor.tdb	413.27	AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.96759) + TETRAGONAL_A6 (x(In) 1)
AgIn-98Kor.tdb	413.27	AGIN2_C16 (x(In) 0.66667) + LIQUID (x(In) 0.96778) + TETRAGONAL_A6 (x(In) 1)

Convex hulls: Materials Project DFT hull · OQMD DFT hull · CALPHAD hull AgIn-01Che-LB · CALPHAD hull AgIn-01Mos · CALPHAD hull AgIn-12Gie · CALPHAD hull AgIn-18Muz · CALPHAD hull AgIn-98Kor

Invariant reactions (literature)

Invariant reactions reported in the literature for the Ag–In system (43)
T (K)	Reaction / phases	Compositions (mole fraction)	Class	Source	Location
983	L + α -> β	L: In 0.194; α: In 0.286; β: In 0.242	model	[1] Muzzillo 2018 cites Gierlotka 2012 doi	Table 1, p. 3, row 6 report
968	L + α -> β	L: In 0.208; α: In 0.311; β: In 0.264	experimental	[1] Muzzillo 2018 cites Campbell 1970 doi	Table 1, p. 3, row 3 report
967.1	L + α -> β	L: In 0.204; α: In 0.3; β: In 0.249	model	[1] Muzzillo 2018	Table 1, p. 3, row 7 report
967	L + α -> β	L: In 0.21; α: In 0.3; β: In 0.25	experimental	[1] Muzzillo 2018 cites Moser 2001 doi	Table 1, p. 3, row 4 report
966.1	L + α -> β	L: In 0.19; α: In 0.282; β: In 0.249	experimental	[1] Muzzillo 2018 cites Bahari 2009 doi	Table 1, p. 3, row 5 report
966	L + α -> β	L: In 0.183; α: In 0.283; β: In 0.239	experimental	[1] Muzzillo 2018 cites Hellner 1951	Table 1, p. 3, row 2 report
966	L + α -> β	L: In 0.188; α: In 0.29; β: In 0.239	experimental	[1] Muzzillo 2018 cites Weibke 1935 doi	Table 1, p. 3, row 1 report
944.5	α + β -> ζ	α: In 0.192; β: In 0.233; ζ: In 0.228	experimental	[1] Muzzillo 2018 cites Bahari 2009 doi	Table 1, p. 3, row 12 report
944	α + β -> ζ	α: In 0.209; β: In 0.265; ζ: In 0.25	experimental	[1] Muzzillo 2018 cites Moser 2001 doi	Table 1, p. 3, row 11 report
943	α + β -> ζ	α: In 0.204; β: In 0.275; ζ: In 0.262	experimental	[1] Muzzillo 2018 cites Campbell 1970 doi	Table 1, p. 3, row 10 report
940	α + β -> ζ	α: In 0.186; β: In 0.237; ζ: In 0.231	experimental	[1] Muzzillo 2018 cites Weibke 1935 doi	Table 1, p. 3, row 8 report
940	α + β -> ζ	α: In 0.181; β: In 0.237; ζ: In 0.231	experimental	[1] Muzzillo 2018 cites Hellner 1951	Table 1, p. 3, row 9 report
935.8	α + β -> ζ	α: In 0.221; β: In 0.26; ζ: In 0.251	model	[1] Muzzillo 2018	Table 1, p. 3, row 14 report
935.7	α + β -> ζ	α: In 0.221; β: In 0.26; ζ: In 0.251	model	[1] Muzzillo 2018 cites Gierlotka 2012 doi	Table 1, p. 3, row 13 report
934.4	β -> L + ζ	β: In 0.261; L: In 0.253; ζ: In 0.316	experimental	[1] Muzzillo 2018 cites Bahari 2009 doi	Table 1, p. 3, row 19 report
934	β -> L + ζ	β: In 0.264; L: In 0.255; ζ: In 0.332	model	[1] Muzzillo 2018 cites Gierlotka 2012 doi	Table 1, p. 3, row 20 report
934	β -> L + ζ	β: In 0.264; L: In 0.255; ζ: In 0.332	model	[1] Muzzillo 2018	Table 1, p. 3, row 21 report
933	β -> L + ζ	β: In 0.3; L: In 0.28; ζ: In 0.325	experimental	[1] Muzzillo 2018 cites Moser 2001 doi	Table 1, p. 3, row 18 report
933	β -> L + ζ	β: In 0.247; L: In 0.242; ζ: In 0.311	experimental	[1] Muzzillo 2018 cites Hellner 1951	Table 1, p. 3, row 16 report
933	β -> L + ζ	β: In 0.322; L: In 0.298; ζ: In 0.336	experimental	[1] Muzzillo 2018 cites Campbell 1970 doi	Table 1, p. 3, row 17 report
933	β -> L + ζ	β: In 0.247; L: In 0.242; ζ: In 0.317	experimental	[1] Muzzillo 2018 cites Weibke 1935 doi	Table 1, p. 3, row 15 report
478.3	ζ -> L + γ-Ag9In4	ζ: In 0.387; L: In 0.95; γ-Ag9In4: In 0.332	experimental	[1] Muzzillo 2018 cites Bahari 2009 doi	Table 1, p. 3, row 31 report
478	ζ -> L + γ-Ag9In4	ζ: In 0.476; L: In 0.353; γ-Ag9In4: In 0.928	experimental	[1] Muzzillo 2018 cites Campbell 1970 doi	Table 1, p. 3, row 30 report
477.4	ζ -> L + γ-Ag9In4	ζ: In 0.373; L: In 0.932; γ-Ag9In4: In 0.336	model	[1] Muzzillo 2018	Table 1, p. 3, row 33 report
477	ζ -> L + γ-Ag9In4	L: In 0.925; γ-Ag9In4: In 0.319	experimental	[1] Muzzillo 2018 cites Hellner 1951	Table 1, p. 3, row 29 report
477	ζ -> L + γ-Ag9In4	L: In 0.928; γ-Ag9In4: In 0.322	experimental	[1] Muzzillo 2018 cites Weibke 1935 doi	Table 1, p. 3, row 28 report
474.1	α + ζ -> α'	α: In 0.204; ζ: In 0.251; α': In 0.243	experimental	[1] Muzzillo 2018 cites Bahari 2009 doi	Table 1, p. 3, row 37 report
473	ζ -> L + γ-Ag9In4	ζ: In 0.373; L: In 0.338; γ-Ag9In4: In 0.935	model	[1] Muzzillo 2018 cites Gierlotka 2012 doi	Table 1, p. 3, row 32 report
460	α + ζ -> α'	α: In 0.193; ζ: In 0.254; α': In 0.245	experimental	[1] Muzzillo 2018 cites Campbell 1970 doi	Table 1, p. 3, row 36 report
460	ζ -> α + α'	ζ: In 0.245; α: In 0.182; α': In 0.254	experimental	[1] Muzzillo 2018 cites Hellner 1951	Table 1, p. 3, row 35 report
460	ζ -> α + α'	ζ: In 0.248; α: In 0.186; α': In 0.256	experimental	[1] Muzzillo 2018 cites Weibke 1935 doi	Table 1, p. 3, row 34 report
451.7	L + γ-Ag9In4 -> AgIn2	L: In 0.338; γ-Ag9In4: In 0.945; AgIn2: In 0.67	model	[1] Muzzillo 2018 cites Gierlotka 2012 doi	Table 1, p. 3, row 42 report
443.3	L + γ-Ag9In4 -> AgIn2	L: In 0.968; γ-Ag9In4: In 0.332; AgIn2: In 0.667	experimental	[1] Muzzillo 2018 cites Bahari 2009 doi	Table 1, p. 3, row 41 report
439	L + γ-Ag9In4 -> AgIn2	L: In 0.951; γ-Ag9In4: In 0.336; AgIn2: In 0.667	model	[1] Muzzillo 2018	Table 1, p. 3, row 43 report
439	L + γ-Ag9In4 -> AgIn2	L: In 0.355; γ-Ag9In4: In 0.955; AgIn2: In 0.667	experimental	[1] Muzzillo 2018 cites Campbell 1970 doi	Table 1, p. 3, row 40 report
439	L + γ-Ag9In4 -> AgIn2	L: In 0.951; γ-Ag9In4: In 0.319; AgIn2: In 0.731	experimental	[1] Muzzillo 2018 cites Hellner 1951	Table 1, p. 3, row 39 report
439	L + γ-Ag9In4 -> AgIn2	L: In 0.953; γ-Ag9In4: In 0.321; AgIn2: In 0.737	experimental	[1] Muzzillo 2018 cites Weibke 1935 doi	Table 1, p. 3, row 38 report
418.7	eutectic: L -> AgIn2 + In	L: In 0.99; AgIn2: In 0.667; In: In 1	experimental	[1] Muzzillo 2018 cites Bahari 2009 doi	Table 1, p. 3, row 47 report
417	eutectic: L -> AgIn2 + In	L: In 0.977; AgIn2: In 0.667; In: In 1	experimental	[1] Muzzillo 2018 cites Campbell 1970 doi	Table 1, p. 3, row 46 report
415.6	eutectic: L -> AgIn2 + In	L: In 0.973; AgIn2: In 0.67; In: In 1	model	[1] Muzzillo 2018 cites Gierlotka 2012 doi	Table 1, p. 3, row 48 report
414.1	eutectic: L -> AgIn2 + In	L: In 0.97; AgIn2: In 0.667; In: In 1	model	[1] Muzzillo 2018	Table 1, p. 3, row 49 report
414	eutectic: L -> AgIn2 + In	L: In 0.97; AgIn2: In 0.742; In: In 1	experimental	[1] Muzzillo 2018 cites Weibke 1935 doi	Table 1, p. 3, row 44 report
414	eutectic: L -> AgIn2 + In	L: In 0.962; AgIn2: In 0.738; In: In 1	experimental	[1] Muzzillo 2018 cites Hellner 1951	Table 1, p. 3, row 45 report

Other properties

Phase transition (7)

Phase transition, Ag–In system
Property	Value	T (K)	Phases / composition	Class	Source	Location	Quote
Phase transition	477 K	477	other	model	[2] Fischer 2019	p. 15 report	The optimization based on the experimental points from Weibke and Eggers [59] for the (Ag2In + hcp) silver rich domain leads to a symmetric shape, the hcp composition reaches 42 at.% In at the metatectic temperature of 477 K.
Phase transition	557.4 K	557.4	ζ -> γ-Ag9In4 ζ: In 0.327; γ-Ag9In4: In 0.327	experimental	[1] Muzzillo 2018 cites Bahari 2009 doi	Table 1, p. 3, row 25 report
Phase transition	570 K	570	ζ -> γ-Ag9In4 ζ: In 0.342; γ-Ag9In4: In 0.342	experimental	[1] Muzzillo 2018 cites Campbell 1970 doi	Table 1, p. 3, row 24 report
Phase transition	570.9 K	570.9	ζ -> γ-Ag9In4 ζ: In 0.318; γ-Ag9In4: In 0.318	model	[1] Muzzillo 2018	Table 1, p. 3, row 27 report
Phase transition	572 K	572	ζ -> γ-Ag9In4 ζ: In 0.314; γ-Ag9In4: In 0.314	experimental	[1] Muzzillo 2018 cites Hellner 1951	Table 1, p. 3, row 23 report
Phase transition	574 K	574	ζ -> γ-Ag9In4 ζ: In 0.317; γ-Ag9In4: In 0.317	experimental	[1] Muzzillo 2018 cites Weibke 1935 doi	Table 1, p. 3, row 22 report
Phase transition	577.1 K	577.1	ζ -> γ-Ag9In4 ζ: In 0.33; γ-Ag9In4: In 0.33	model	[1] Muzzillo 2018 cites Gierlotka 2012 doi	Table 1, p. 3, row 26 report

Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

Christopher P. Muzzillo, Tim Anderson, Thermodynamic assessment of Ag–Cu–In, J Mater Sci 53, 6893-6910 (2018). doi:10.1007/s10853-018-1999-8
E. Fischer, K. Gajavalli, G. Mikaelian, P. Benigni, J. Rogez, A. Decreton et al., Experimental study and thermodynamic modelling of the Ag-Cd-In system, Calphad 64, 292-305 (2019). doi:10.1016/j.calphad.2019.01.001

Please cite

R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23735569
R. Arróyave, J. Saal, D. Shin, ORCHID-Diagrams: calculated binary phase diagrams (version 2026.10), Zenodo (2026). doi:10.5281/zenodo.23735859
R. Arróyave, J. Saal, D. Shin, ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD) (version 2026.10), Zenodo (2026). doi:10.5281/zenodo.23735891
R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0). Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_phase_diagrams_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Diagrams: calculated binary phase diagrams}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735859},
  url       = {https://doi.org/10.5281/zenodo.23735859}
}

@misc{orchid_hulls_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD)}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735891},
  url       = {https://doi.org/10.5281/zenodo.23735891}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}