Ga–Se system

100 accepted literature values from 1 paper(s) (experimental 73, model 27); 0 calculated phase diagram(s).

Data: JSON · CSV · interactive explorer · phases (9) · papers (bibliography) · Markdown

Accepted values by evidence class
Evidence class	Values
experimental	73
model	27

Accepted values by property group
Property group	Values
invariant reaction	58
formation	16
heat capacity / entropy / enthalpy	26

Convex hulls: Materials Project DFT hull · OQMD DFT hull

Invariant reactions (literature)

Invariant reactions reported in the literature for the Ga–Se system (58)
T (K)	Reaction / phases	Compositions (mole fraction)	Class	Source	Location
1293	congruent melting: α-Ga2Se3 -> L	α-Ga2Se3: Se 0.6; L: Se 0.6	experimental	[1] Zheng 2008 cites Klemm 1934 doi	Table 2, p. 5, row 32 report
1293	congruent melting: α-Ga2Se3 -> L	α-Ga2Se3: Se 0.6; L: Se 0.6	experimental	[1] Zheng 2008 cites Rustamov 1965	Table 2, p. 5, row 34 report
1291	congruent melting: α-Ga2Se3 -> L	α-Ga2Se3: Se 0.606; L: Se 0.606	experimental	[1] Zheng 2008 cites Shtanov 1998	Table 2, p. 5, row 41 report
1283	congruent melting: α-Ga2Se3 -> L	α-Ga2Se3: Se 0.6004; L: Se 0.599	model	[1] Zheng 2008	Table 2, p. 5, row 42 report
1283	congruent melting: α-Ga2Se3 -> L	α-Ga2Se3: Se 0.6; L: Se 0.6	experimental	[1] Zheng 2008 cites Palatnik 1965	Table 2, p. 5, row 33 report
1283	congruent melting: α-Ga2Se3 -> L	α-Ga2Se3: Se 0.6; L: Se 0.6	experimental	[1] Zheng 2008 cites Mikkelsen 1981 doi	Table 2, p. 5, row 39 report
1283	congruent melting: α-Ga2Se3 -> L	α-Ga2Se3: Se 0.6; L: Se 0.6	experimental	[1] Zheng 2008 cites Ollitraut-Fichet 1980	Table 2, p. 5, row 38 report
1283	congruent melting: α-Ga2Se3 -> L	α-Ga2Se3: Se 0.6; L: Se 0.6	experimental	[1] Zheng 2008 cites Palatnik 1966	Table 2, p. 5, row 35 report
1283	congruent melting: α-Ga2Se3 -> L	α-Ga2Se3: Se 0.6; L: Se 0.6	experimental	[1] Zheng 2008 cites Dieleman 1971 doi	Table 2, p. 5, row 36 report
1280	congruent melting: α-Ga2Se3 -> L	α-Ga2Se3: Se 0.6; L: Se 0.6	experimental	[1] Zheng 2008 cites Dieleman 1982	Table 2, p. 5, row 40 report
1280	critical point: L -> L1 + L2	L: Se 0.253	model	[1] Zheng 2008	Table 2, p. 5, row 4 report
1279	critical point: L -> L1 + L2	L: Se 0.243	experimental	[1] Zheng 2008 cites Ollitraut-Fichet 1980	Table 2, p. 5, row 2 report
1278	congruent melting: α-Ga2Se3 -> L	α-Ga2Se3: Se 0.6; L: Se 0.6	experimental	[1] Zheng 2008 cites Suzuki 1974 doi	Table 2, p. 5, row 37 report
1268	critical point: L -> L1 + L2	L: Se 0.23	experimental	[1] Zheng 2008 cites Suzuki 1974 doi	Table 2, p. 5, row 1 report
1267	critical point: L -> L1 + L2	L: Se 0.24	experimental	[1] Zheng 2008 cites Dieleman 1982	Table 2, p. 5, row 3 report
1233	congruent melting: GaSe -> L	GaSe: Se 0.5; L: Se 0.5	experimental	[1] Zheng 2008 cites Rustamov 1965	Table 2, p. 5, row 16 report
1233	congruent melting: GaSe -> L	GaSe: Se 0.5; L: Se 0.5	experimental	[1] Zheng 2008 cites Klemm 1934 doi	Table 2, p. 5, row 15 report
1223	congruent melting: GaSe -> L	GaSe: Se 0.5; L: Se 0.5	experimental	[1] Zheng 2008 cites Palatnik 1966	Table 2, p. 5, row 17 report
1218	congruent melting: GaSe -> L	GaSe: Se 0.5; L: Se 0.5	experimental	[1] Zheng 2008 cites Ollitraut-Fichet 1980	Table 2, p. 5, row 20 report
1211	congruent melting: GaSe -> L	GaSe: Se 0.5; L: Se 0.5	experimental	[1] Zheng 2008 cites Suzuki 1974 doi	Table 2, p. 5, row 19 report
1211	congruent melting: GaSe -> L	GaSe: Se 0.5; L: Se 0.5	experimental	[1] Zheng 2008 cites Dieleman 1971 doi	Table 2, p. 5, row 18 report
1210	congruent melting: GaSe -> L	GaSe: Se 0.5; L: Se 0.5	model	[1] Zheng 2008	Table 2, p. 5, row 23 report
1210	congruent melting: GaSe -> L	GaSe: Se 0.482; L: Se 0.482	experimental	[1] Zheng 2008 cites Shtanov 1998	Table 2, p. 5, row 22 report
1210	congruent melting: GaSe -> L	GaSe: Se 0.5; L: Se 0.5	experimental	[1] Zheng 2008 cites Dieleman 1982	Table 2, p. 5, row 21 report
1190	monotectic: L1 + L2 -> GaSe	L1: Se 0.075; L2: Se 0.455; GaSe: Se 0.5	experimental	[1] Zheng 2008 cites Dieleman 1982	Table 2, p. 5, row 7 report
1188	monotectic: L1 + L2 -> GaSe	L1: Se 0.055; L2: Se 0.44; GaSe: Se 0.5	experimental	[1] Zheng 2008 cites Suzuki 1974 doi	Table 2, p. 5, row 5 report
1187	monotectic: L1 + L2 -> GaSe	L1: Se 0.082; L2: Se 0.42; GaSe: Se 0.5	experimental	[1] Zheng 2008 cites Ollitraut-Fichet 1980	Table 2, p. 5, row 6 report
1185	other: GaSe + α-Ga2Se3 -> L	GaSe: Se 0.5; α-Ga2Se3: Se 0.6; L: Se 0.55	experimental	[1] Zheng 2008 cites Rustamov 1965	Table 2, p. 5, row 24 report
1185	monotectic: L1 + L2 -> GaSe	L1: Se 0.078; L2: Se 0.412; GaSe: Se 0.5	model	[1] Zheng 2008	Table 2, p. 5, row 9 report
1185	monotectic: L1 + L2 -> GaSe	GaSe: Se 0.48	experimental	[1] Zheng 2008 cites Shtanov 1998	Table 2, p. 5, row 8 report
1163	other: GaSe + α-Ga2Se3 -> L	GaSe: Se 0.5; α-Ga2Se3: Se 0.595; L: Se 0.554	model	[1] Zheng 2008	Table 2, p. 5, row 31 report
1163	other: GaSe + α-Ga2Se3 -> L	GaSe: Se 0.5; α-Ga2Se3: Se 0.6; L: Se 0.55	experimental	[1] Zheng 2008 cites Ollitraut-Fichet 1980	Table 2, p. 5, row 28 report
1162	other: GaSe + α-Ga2Se3 -> L	GaSe: Se 0.5; α-Ga2Se3: Se 0.6; L: Se 0.551	experimental	[1] Zheng 2008 cites Dieleman 1982	Table 2, p. 5, row 29 report
1161	other: GaSe + α-Ga2Se3 -> L	GaSe: Ga 0.5, Se 0.5; α-Ga2Se3: Ga 0.4, Se 0.6; L: Se 0.56	experimental	[1] Zheng 2008 cites Shtanov 1998	Table 2, p. 5, row 30 report
1160	other: GaSe + α-Ga2Se3 -> L	GaSe: Se 0.5; α-Ga2Se3: Se 0.594; L: Se 0.551	experimental	[1] Zheng 2008 cites Dieleman 1971 doi	Table 2, p. 5, row 26 report
1157	other: GaSe + α-Ga2Se3 -> L	GaSe: Se 0.5; α-Ga2Se3: Se 0.6; L: Se 0.55	experimental	[1] Zheng 2008 cites Suzuki 1974 doi	Table 2, p. 5, row 27 report
1153	other: GaSe + α-Ga2Se3 -> L	GaSe: Se 0.5; α-Ga2Se3: Se 0.5976; L: Se 0.554	experimental	[1] Zheng 2008 cites Palatnik 1966	Table 2, p. 5, row 25 report
1004	polymorphic: β-Ga2Se3 -> α-Ga2Se3	β-Ga2Se3: Se 0.6; α-Ga2Se3: Se 0.6	experimental	[1] Zheng 2008 cites Muhsin 2003	Table 2, p. 5, row 49 report
1003	polymorphic: β-Ga2Se3 -> α-Ga2Se3	β-Ga2Se3: Se 0.6; α-Ga2Se3: Se 0.6	experimental	[1] Zheng 2008 cites Ollitraut-Fichet 1980	Table 2, p. 5, row 45 report
1003	polymorphic: β-Ga2Se3 -> α-Ga2Se3	β-Ga2Se3: Se 0.6; α-Ga2Se3: Se 0.6	experimental	[1] Zheng 2008 cites Mikkelsen 1981 doi	Table 2, p. 5, row 46 report
994	polymorphic: β-Ga2Se3 -> α-Ga2Se3	β-Ga2Se3: Se 0.6; α-Ga2Se3: Se 0.6	experimental	[1] Zheng 2008 cites Muhsin 2003	Table 2, p. 5, row 48 report
968	polymorphic: β-Ga2Se3 -> α-Ga2Se3	β-Ga2Se3: Se 0.605; α-Ga2Se3: Se 0.605	experimental	[1] Zheng 2008 cites Dieleman 1982	Table 2, p. 5, row 47 report
967	polymorphic: β-Ga2Se3 -> α-Ga2Se3	β-Ga2Se3: Se 0.6; α-Ga2Se3: Se 0.6	model	[1] Zheng 2008	Table 2, p. 5, row 50 report
918	peritectic: β-Ga2Se3 + α-Ga2Se3 -> L	β-Ga2Se3: Se 0.607; α-Ga2Se3: Se 0.61	experimental	[1] Zheng 2008 cites Dieleman 1982	Table 2, p. 5, row 51 report
918	peritectic: β-Ga2Se3 + α-Ga2Se3 -> L	β-Ga2Se3: Se 0.6; α-Ga2Se3: Se 0.61; L: Se 0.983	model	[1] Zheng 2008	Table 2, p. 5, row 52 report
898	eutectoid: GaSe + α-Ga2Se3 -> β-Ga2Se3	GaSe: Se 0.5; α-Ga2Se3: Se 0.599; β-Ga2Se3: Se 0.602	experimental	[1] Zheng 2008 cites Dieleman 1982	Table 2, p. 5, row 43 report
898	eutectoid: GaSe + α-Ga2Se3 -> β-Ga2Se3	GaSe: Se 0.5; α-Ga2Se3: Se 0.593; β-Ga2Se3: Se 0.6	model	[1] Zheng 2008	Table 2, p. 5, row 44 report
494	other: β-Ga2Se3 + Se -> L	β-Ga2Se3: Se 0.6; Se: Se 1; L: Se 1	model	[1] Zheng 2008	Table 2, p. 5, row 58 report
493	other: β-Ga2Se3 + Se -> L	β-Ga2Se3: Se 0.6; Se: Se 1; L: Se 1	experimental	[1] Zheng 2008 cites Suzuki 1974 doi	Table 2, p. 5, row 55 report
493	other: β-Ga2Se3 + Se -> L	β-Ga2Se3: Se 0.6; Se: Se 1; L: Se 1	experimental	[1] Zheng 2008 cites Ollitraut-Fichet 1980	Table 2, p. 5, row 56 report
493	other: β-Ga2Se3 + Se -> L	β-Ga2Se3: Se 0.6; Se: Se 1; L: Se 1	experimental	[1] Zheng 2008 cites Rustamov 1965	Table 2, p. 5, row 53 report
493	other: β-Ga2Se3 + Se -> L	β-Ga2Se3: Se 0.6; Se: Se 1; L: Se 1	experimental	[1] Zheng 2008 cites Dieleman 1982	Table 2, p. 5, row 57 report
478	other: β-Ga2Se3 + Se -> L	β-Ga2Se3: Se 0.6024; Se: Se 1; L: Se 1	experimental	[1] Zheng 2008 cites Palatnik 1966	Table 2, p. 5, row 54 report
303	other: Ga + GaSe -> L	Ga: Se 0; GaSe: Se 0.5; L: Se 0	experimental	[1] Zheng 2008 cites Dieleman 1982	Table 2, p. 5, row 13 report
303	other: Ga + GaSe -> L	Ga: Se 0; GaSe: Se 0.5; L: Se 0	experimental	[1] Zheng 2008 cites Rustamov 1965	Table 2, p. 5, row 10 report
303	other: Ga + GaSe -> L	Ga: Se 0; GaSe: Se 0.5; L: Se 0	experimental	[1] Zheng 2008 cites Ollitraut-Fichet 1980	Table 2, p. 5, row 12 report
303	other: Ga + GaSe -> L	Ga: Se 0; GaSe: Se 0.5; L: Se 0	model	[1] Zheng 2008	Table 2, p. 5, row 14 report
303	other: Ga + GaSe -> L	Ga: Se 0; GaSe: Se 0.5; L: Se 0	experimental	[1] Zheng 2008 cites Suzuki 1974 doi	Table 2, p. 5, row 11 report

Formation enthalpies

Literature values in kJ/mol-atom where the per-atom basis is known. DFT columns: the lowest-energy entry at the same composition (Materials Project 2026.04.13, OQMD v1.8; different energy references, never averaged), from dft_parity.json.

Enthalpies of formation, Ga–Se system (16)
Phase	Compound	Value	T (K)	Class	MP DFT (kJ/mol-atom)	OQMD DFT (kJ/mol-atom)	Source	Location
GaSe	GaSe	-79.496 kJ/mol-atom	298.15	model	-79.831 (mp-aaaaaqug)	-57.465 (oqmd-1971260)	[1] Zheng 2008 cites Mills 1974	Table 3, p. 6, row 4 report
GaSe	GaSe	-79.496 kJ/mol-atom	298.15	experimental	-79.831 (mp-aaaaaqug)	-57.465 (oqmd-1971260)	[1] Zheng 2008 cites Mamedov 1969	Table 3, p. 6, row 3 report
GaSe	GaSe	-79.496 kJ/mol-atom	298.15	model	-79.831 (mp-aaaaaqug)	-57.465 (oqmd-1971260)	[1] Zheng 2008 cites Barin 1995 doi	Table 3, p. 6, row 5 report
GaSe	GaSe	-78.9705 kJ/mol-atom	298.15	model	-79.831 (mp-aaaaaqug)	-57.465 (oqmd-1971260)	[1] Zheng 2008	Table 3, p. 6, row 7 report
GaSe	GaSe	-78.85 kJ/mol-atom	298.15	experimental	-79.831 (mp-aaaaaqug)	-57.465 (oqmd-1971260)	[1] Zheng 2008 cites Zavrazhnov 2003	Table 3, p. 6, row 6 report
GaSe	GaSe	-73.22 kJ/mol-atom	298.15	experimental	-79.831 (mp-aaaaaqug)	-57.465 (oqmd-1971260)	[1] Zheng 2008 cites Hahn 1956 doi	Table 3, p. 6, row 1 report
GaSe	GaSe	-71.75 kJ/mol-atom	298.15	experimental	-79.831 (mp-aaaaaqug)	-57.465 (oqmd-1971260)	[1] Zheng 2008 cites Kh 1968	Table 3, p. 6, row 2 report
β-Ga2Se3	Ga2Se3	-92.048 kJ/mol-atom	298.15	experimental	-83.763 (mp-aaaaabzo)	-57.081 (oqmd-2169176)	[1] Zheng 2008 cites Gadzhiev 1961	Table 3, p. 6, row 9 report
β-Ga2Se3	Ga2Se3	-87.864 kJ/mol-atom	298.15	experimental	-83.763 (mp-aaaaabzo)	-57.081 (oqmd-2169176)	[1] Zheng 2008 cites Hahn 1956 doi	Table 3, p. 6, row 8 report
β-Ga2Se3	Ga2Se3	-81.7554 kJ/mol-atom	298.15	experimental	-83.763 (mp-aaaaabzo)	-57.081 (oqmd-2169176)	[1] Zheng 2008 cites Mamedov 1969	Table 3, p. 6, row 12 report
β-Ga2Se3	Ga2Se3	-81.7554 kJ/mol-atom	298.15	model	-83.763 (mp-aaaaabzo)	-57.081 (oqmd-2169176)	[1] Zheng 2008 cites Barin 1995 doi	Table 3, p. 6, row 14 report
β-Ga2Se3	Ga2Se3	-81.7554 kJ/mol-atom	298.15	model	-83.763 (mp-aaaaabzo)	-57.081 (oqmd-2169176)	[1] Zheng 2008 cites Mills 1974	Table 3, p. 6, row 13 report
β-Ga2Se3	Ga2Se3	-81.002 kJ/mol-atom	298.15	experimental	-83.763 (mp-aaaaabzo)	-57.081 (oqmd-2169176)	[1] Zheng 2008 cites Mamedov 1969	Table 3, p. 6, row 12 report
β-Ga2Se3	Ga2Se3	-79.7396 kJ/mol-atom	298.15	model	-83.763 (mp-aaaaabzo)	-57.081 (oqmd-2169176)	[1] Zheng 2008	Table 3, p. 6, row 15 report
β-Ga2Se3	Ga2Se3	-75.312 kJ/mol-atom	298.15	experimental	-83.763 (mp-aaaaabzo)	-57.081 (oqmd-2169176)	[1] Zheng 2008 cites Effendiev 1965	Table 3, p. 6, row 10 report
β-Ga2Se3	Ga2Se3	-73.722 kJ/mol-atom	298.15	experimental	-83.763 (mp-aaaaabzo)	-57.081 (oqmd-2169176)	[1] Zheng 2008 cites Sharifov 1967	Table 3, p. 6, row 11 report

Other properties

Heat capacity / entropy / enthalpy (26)

Heat capacity / entropy / enthalpy, Ga–Se system
Property	Value	T (K)	Phases / composition	Class	Source	Location
Entropy printed: S°298	35.085 J/mol-atom/K	298.15	GaSe alloy: Se 0.5	model	[1] Zheng 2008	Table 4, p. 6, row 9 report
Entropy printed: S°298	35.145 J/mol-atom/K	298.15	GaSe alloy: Se 0.5	experimental	[1] Zheng 2008 cites Mamedov 1967	Table 4, p. 6, row 1 report
Entropy printed: S°298	35.125 J/mol-atom/K	298.15	GaSe alloy: Se 0.5	experimental	[1] Zheng 2008 cites Mamedov 1970	Table 4, p. 6, row 3 report
Entropy printed: S°298	35.115 J/mol-atom/K	298.15	GaSe alloy: Se 0.5	model	[1] Zheng 2008 cites Rymkevich 1975	Table 4, p. 6, row 6 report
Entropy printed: S°298	35.085 J/mol-atom/K	298.15	GaSe alloy: Se 0.5	experimental	[1] Zheng 2008 cites Tyurin 2004	Table 4, p. 6, row 8 report
Entropy printed: S°298	35.125 J/mol-atom/K	298.15	GaSe alloy: Se 0.5	experimental	[1] Zheng 2008 cites Kerimov 1971	Table 4, p. 6, row 4 report
Entropy printed: S°298	34.45 J/mol-atom/K	298.15	GaSe alloy: Se 0.5	experimental	[1] Zheng 2008 cites Abbasov 1969	Table 4, p. 6, row 2 report
Entropy printed: S°298	33.95 J/mol-atom/K	298.15	GaSe alloy: Se 0.5	experimental	[1] Zheng 2008 cites Zavrazhnov 2003	Table 4, p. 6, row 7 report
Entropy printed: S°298	35.1455 J/mol-atom/K	298.15	GaSe alloy: Se 0.5	model	[1] Zheng 2008 cites Mills 1974	Table 4, p. 6, row 5 report
Entropy printed: S°298	36.14 J/mol-atom/K	298.15	β-Ga2Se3 alloy: Se 0.6	model	[1] Zheng 2008	Table 4, p. 6, row 14 report
Entropy printed: S°298	36.652 J/mol-atom/K	298.15	β-Ga2Se3 alloy: Se 0.6	experimental	[1] Zheng 2008 cites Mamedov 1969	Table 4, p. 6, row 10 report
Entropy printed: S°298	36.08 J/mol-atom/K	298.15	β-Ga2Se3 alloy: Se 0.6	experimental	[1] Zheng 2008 cites Tyurin 2005 doi	Table 4, p. 6, row 13 report
Entropy printed: S°298	35.9824 J/mol-atom/K	298.15	β-Ga2Se3 alloy: Se 0.6	model	[1] Zheng 2008 cites Mills 1974	Table 4, p. 6, row 11 report
Entropy printed: S°298	35.9824 J/mol-atom/K	298.15	β-Ga2Se3 alloy: Se 0.6	model	[1] Zheng 2008 cites Barin 1995 doi	Table 4, p. 6, row 12 report
Heat capacity printed: Cp°298	48.32 J/mol (basis unstated)/K	298.15	GaSe alloy: Se 0.5	experimental	[1] Zheng 2008 cites Zavrazhnov 2004 doi	Table 5, p. 7, row 6 report
Heat capacity printed: Cp°298	47.89 J/mol (basis unstated)/K	298.15	GaSe alloy: Se 0.5	model	[1] Zheng 2008	Table 5, p. 7, row 7 report
Heat capacity printed: Cp°298	48.49 J/mol (basis unstated)/K	298.15	GaSe alloy: Se 0.5	experimental	[1] Zheng 2008 cites Mamedov 1967	Table 5, p. 7, row 1 report
Heat capacity printed: Cp°298	47.79 J/mol (basis unstated)/K	298.15	GaSe alloy: Se 0.5	experimental	[1] Zheng 2008 cites Okhotin 1998	Table 5, p. 7, row 4 report
Heat capacity printed: Cp°298	47.21 J/mol (basis unstated)/K	298.15	GaSe alloy: Se 0.5	model	[1] Zheng 2008 cites Rymkevich 1975	Table 5, p. 7, row 3 report
Heat capacity printed: Cp°298	47.67 J/mol (basis unstated)/K	298.15	GaSe alloy: Se 0.5	experimental	[1] Zheng 2008 cites Tyurin 2004	Table 5, p. 7, row 5 report
Heat capacity printed: Cp°298	48.51 J/mol (basis unstated)/K	298.15	GaSe alloy: Se 0.5	model	[1] Zheng 2008 cites Mills 1974	Table 5, p. 7, row 2 report
Heat capacity printed: Cp°298	115.8 J/mol (basis unstated)/K	298.15	β-Ga2Se3 alloy: Se 0.6	experimental	[1] Zheng 2008 cites Zavrazhnov 2004 doi	Table 5, p. 7, row 10 report
Heat capacity printed: Cp°298	120.8 J/mol (basis unstated)/K	298.15	β-Ga2Se3 alloy: Se 0.6	experimental	[1] Zheng 2008 cites Tyurin 2005 doi	Table 5, p. 7, row 11 report
Heat capacity printed: Cp°298	115.8 J/mol (basis unstated)/K	298.15	β-Ga2Se3 alloy: Se 0.6	model	[1] Zheng 2008	Table 5, p. 7, row 12 report
Heat capacity printed: Cp°298	116.3 J/mol (basis unstated)/K	298.15	β-Ga2Se3 alloy: Se 0.6	model	[1] Zheng 2008 cites Mills 1974	Table 5, p. 7, row 9 report
Heat capacity printed: Cp°298	117.57 J/mol (basis unstated)/K	298.15	β-Ga2Se3 alloy: Se 0.6	experimental	[1] Zheng 2008 cites Gadzhiev 1961	Table 5, p. 7, row 8 report

Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

F. Zheng, J.Y. Shen, Y.Q. Liu, W.K. Kim, M.Y. Chu, M. Ider et al., Thermodynamic optimization of the Ga–Se system, Calphad 32, 432-438 (2008). doi:10.1016/j.calphad.2008.03.004

Please cite

R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23735569
R. Arróyave, J. Saal, D. Shin, ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD) (version 2026.10), Zenodo (2026). doi:10.5281/zenodo.23735891
R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file. Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_hulls_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD)}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735891},
  url       = {https://doi.org/10.5281/zenodo.23735891}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}