Ge–Li system

311 accepted literature values from 2 paper(s) (experimental 236, model 60, DFT 8, unspecified 7); 2 calculated phase diagram(s). 36 further extracted value(s) not accepted by the reader-agreement checks are only in the JSON/CSV.

Data: JSON · CSV · interactive explorer · interactive phase diagram · phases (16) · papers (bibliography) · Markdown

Accepted values by evidence class
Evidence class	Values
experimental	236
model	60
DFT	8
unspecified	7

Accepted values by property group
Property group	Values
invariant reaction	71
phase transition	2
formation	29
activity / EMF / Gibbs energy	209

Calculated phase diagrams

Binary phase diagrams calculated with pycalphad 0.11.2 from the SGTE binary collection (Hallstedt 2025, CC BY 4.0). Evidence class: model.

Assessments with a calculated phase diagram
TDB file	Assessment	SHA-256	Links
GeLi-18Wan.tdb	S. Wang, Y. Du, Y. Peng, P. Zhou, X. Yuan, S. Liu, J. Phase Equilib. Diffus., 39, 315-23(2018). doi:10.1007/s11669-018-0632-5	`5eb8811b38c848dac3d3c2d886984a789eb4d77974b4203feb3f86fda1ed8c19`	viewer · TDB · JSON
GeLi-22Gie.tdb	W. Gierlotka, A. Debski, M. Zabrocki, A. Goral, W. Gasior, J. Chem. Thermodyn., 175, 106883(2022). doi:10.1016/j.jct.2022.106883	`ce9879aaebef3c3cca842c50a6a2df1d996510f02c5880caf8dfcda8f67fb47d`	viewer · TDB · JSON

Calculated three-phase invariants (model, mole fraction of the second component)
TDB file	T (K)	Phases at the invariant
GeLi-18Wan.tdb	1019.74	GE6LI14 (x(Li) 0.7) + LIQUID (x(Li) 0.70549) + GE4LI13 (x(Li) 0.76471)
GeLi-18Wan.tdb	1019.74	GE6LI14 (x(Li) 0.7) + LIQUID (x(Li) 0.70538) + GE4LI13 (x(Li) 0.76471)
GeLi-18Wan.tdb	1019.74	GE6LI14 (x(Li) 0.7) + LIQUID (x(Li) 0.7057) + GE4LI13 (x(Li) 0.76471)
GeLi-18Wan.tdb	1011.45	LIQUID (x(Li) 0.67038) + GE4LI9 (x(Li) 0.69231) + GE6LI14 (x(Li) 0.7)
GeLi-18Wan.tdb	990.13	GE4LI13 (x(Li) 0.76471) + GE4LI15_D86 (x(Li) 0.78947) + LIQUID (x(Li) 0.84034)
GeLi-18Wan.tdb	990.13	GE4LI13 (x(Li) 0.76471) + GE4LI15_D86 (x(Li) 0.78947) + LIQUID (x(Li) 0.8402)
GeLi-18Wan.tdb	890.12	GE4LI15_D86 (x(Li) 0.78947) + GELI4 (x(Li) 0.80392) + LIQUID (x(Li) 0.89429)
GeLi-18Wan.tdb	890.12	GE4LI15_D86 (x(Li) 0.78947) + GELI4 (x(Li) 0.80392) + LIQUID (x(Li) 0.89423)
GeLi-18Wan.tdb	890.12	GE4LI15_D86 (x(Li) 0.78947) + GELI4 (x(Li) 0.80392) + LIQUID (x(Li) 0.89413)
GeLi-18Wan.tdb	798.26	LIQUID (x(Li) 0.53507) + GE7LI12 (x(Li) 0.63158) + GE4LI9 (x(Li) 0.69231)
GeLi-18Wan.tdb	797.93	GELI (x(Li) 0.5) + LIQUID (x(Li) 0.53482) + GE7LI12 (x(Li) 0.63158)
GeLi-18Wan.tdb	797.93	GELI (x(Li) 0.5) + LIQUID (x(Li) 0.53483) + GE7LI12 (x(Li) 0.63158)
GeLi-18Wan.tdb	791.72	GELI4 (x(Li) 0.80392) + GE4LI17 (x(Li) 0.80952) + LIQUID (x(Li) 0.93117)
GeLi-18Wan.tdb	791.72	GELI4 (x(Li) 0.80392) + GE4LI17 (x(Li) 0.80952) + LIQUID (x(Li) 0.9311)
GeLi-18Wan.tdb	791.72	GELI4 (x(Li) 0.80392) + GE4LI17 (x(Li) 0.80952) + LIQUID (x(Li) 0.93124)
GeLi-18Wan.tdb	791.2	DIAMOND_A4 (x(Li) 0) + LIQUID (x(Li) 0.44511) + GELI (x(Li) 0.5)
GeLi-18Wan.tdb	784.69	DIAMOND_A4 (x(Li) 0) + GE12LI7 (x(Li) 0.36842) + GELI (x(Li) 0.5)
GeLi-18Wan.tdb	670.84	GE4LI15_D86 (x(Li) 0.78947) + GELI4 (x(Li) 0.80392) + GE4LI17 (x(Li) 0.80952)
GeLi-18Wan.tdb	453.33	GE4LI17 (x(Li) 0.80952) + LIQUID (x(Li) 0.99953) + BCC_A2 (x(Li) 1)
GeLi-18Wan.tdb	453.33	GE4LI17 (x(Li) 0.80952) + LIQUID (x(Li) 0.99954) + BCC_A2 (x(Li) 1)
GeLi-22Gie.tdb	1033.56	GE3LI7 (x(Li) 0.7) + LIQUID (x(Li) 0.73852) + GE2LI7 (x(Li) 0.77778)
GeLi-22Gie.tdb	1033.55	GE3LI7 (x(Li) 0.7) + LIQUID (x(Li) 0.73875) + GE2LI7 (x(Li) 0.77778)
GeLi-22Gie.tdb	1033.55	GE3LI7 (x(Li) 0.7) + LIQUID (x(Li) 0.73884) + GE2LI7 (x(Li) 0.77778)
GeLi-22Gie.tdb	1018.15	LIQUID (x(Li) 0.64185) + GE4LI9 (x(Li) 0.69231) + GE3LI7 (x(Li) 0.7)
GeLi-22Gie.tdb	977.48	GE2LI7 (x(Li) 0.77778) + GE4LI15_D86 (x(Li) 0.78947) + LIQUID (x(Li) 0.85599)
GeLi-22Gie.tdb	977.48	GE2LI7 (x(Li) 0.77778) + GE4LI15_D86 (x(Li) 0.78947) + LIQUID (x(Li) 0.85582)
GeLi-22Gie.tdb	900.21	GE4LI15_D86 (x(Li) 0.78947) + GELI4 (x(Li) 0.80377) + LIQUID (x(Li) 0.89319)
GeLi-22Gie.tdb	900.21	GE4LI15_D86 (x(Li) 0.78947) + GELI4 (x(Li) 0.80377) + LIQUID (x(Li) 0.8931)
GeLi-22Gie.tdb	900.21	GE4LI15_D86 (x(Li) 0.78947) + GELI4 (x(Li) 0.80377) + LIQUID (x(Li) 0.89292)
GeLi-22Gie.tdb	812.8	DIAMOND_A4 (x(Li) 0) + LIQUID (x(Li) 0.49446) + GELI (x(Li) 0.5)
GeLi-22Gie.tdb	812.8	DIAMOND_A4 (x(Li) 0) + LIQUID (x(Li) 0.49408) + GELI (x(Li) 0.5)
GeLi-22Gie.tdb	808.16	LIQUID (x(Li) 0.53669) + GE7LI12 (x(Li) 0.63158) + GE4LI9 (x(Li) 0.69231)
GeLi-22Gie.tdb	808.16	LIQUID (x(Li) 0.53669) + GE7LI12 (x(Li) 0.63158) + GE4LI9 (x(Li) 0.69231)
GeLi-22Gie.tdb	805.5	GELI (x(Li) 0.5) + LIQUID (x(Li) 0.53476) + GE7LI12 (x(Li) 0.63158)
GeLi-22Gie.tdb	805.5	GELI (x(Li) 0.5) + LIQUID (x(Li) 0.53476) + GE7LI12 (x(Li) 0.63158)
GeLi-22Gie.tdb	795.07	GELI4 (x(Li) 0.80377) + GE4LI17 (x(Li) 0.80952) + LIQUID (x(Li) 0.93574)
GeLi-22Gie.tdb	795.07	GELI4 (x(Li) 0.80377) + GE4LI17 (x(Li) 0.80952) + LIQUID (x(Li) 0.9357)
GeLi-22Gie.tdb	795.07	GELI4 (x(Li) 0.80377) + GE4LI17 (x(Li) 0.80952) + LIQUID (x(Li) 0.93584)
GeLi-22Gie.tdb	784.34	DIAMOND_A4 (x(Li) 0) + GE12LI7 (x(Li) 0.36842) + GELI (x(Li) 0.5)
GeLi-22Gie.tdb	672.9	GE4LI15_D86 (x(Li) 0.78947) + GELI4 (x(Li) 0.80377) + GE4LI17 (x(Li) 0.80952)
GeLi-22Gie.tdb	453.5	GE4LI17 (x(Li) 0.80952) + LIQUID (x(Li) 0.99982) + BCC_A2 (x(Li) 1)
GeLi-22Gie.tdb	453.5	GE4LI17 (x(Li) 0.80952) + LIQUID (x(Li) 0.99982) + BCC_A2 (x(Li) 1)

Convex hulls: Materials Project DFT hull · OQMD DFT hull · CALPHAD hull GeLi-18Wan

Invariant reactions (literature)

Invariant reactions reported in the literature for the Ge–Li system (71)
T (K)	Reaction / phases	Compositions (mole fraction)	Class	Source	Location
1034	eutectic: Liquid -> Ge3Li7 + Ge2Li7	L: Li 0.738; Ge3Li7: Ge 0.3, Li 0.7; Ge2Li7: Ge 0.222222, Li 0.777778	model	[1] Gierlotka 2022	Table 11, p. 9, row 1 report
1019.75	L = Li14Ge6 + Li13Ge4	Li14Ge6: Li 0.7; Li13Ge4: Li 0.764706	model	[2] Wang 2018	Table 4, p. 7, row 40 report
1019	Liquid + Ge3Li7 -> Ge4Li9	L: Li 0.64; Ge3Li7: Ge 0.3, Li 0.7; Ge4Li9: Ge 0.307692, Li 0.692308	model	[1] Gierlotka 2022	Table 11, p. 9, row 2 report
1015.95	L = Li14Ge6 + Li13Ge4	Li14Ge6: Li 0.7; Li13Ge4: Li 0.764706	model	[2] Wang 2018	Table 4, p. 7, row 39 report
1013.15	L + Li14Ge6 = Li9Ge4	Li14Ge6: Li 0.7; Li9Ge4: Li 0.692308	experimental	[2] Wang 2018 cites Gruttner 1982	Table 4, p. 7, row 6 report
1013	Liquid + Ge3Li7 -> Ge4Li9	Ge3Li7: Ge 0.3, Li 0.7; Ge4Li9: Ge 0.307692, Li 0.692308	unspecified	[1] Gierlotka 2022 cites Gruttner 1982	Table 11, p. 9, row 5 report
1012.35	L + Li14Ge6 = Li9Ge4	Li14Ge6: Li 0.7; Li9Ge4: Li 0.692308	model	[2] Wang 2018	Table 4, p. 7, row 41 report
1012	Liquid + Ge3Li7 -> Ge4Li9	L: Li 0.682; Ge3Li7: Ge 0.3, Li 0.7; Ge4Li9: Ge 0.307692, Li 0.692308	model	[1] Gierlotka 2022 cites modeled stoichiometry of the phases based on Gruttner [23] description whereas this work adopts ab initio findings	Table 11, p. 9, row 3 report
1011.55	L + Li14Ge6 = Li9Ge4	Li14Ge6: Li 0.7; Li9Ge4: Li 0.692308	model	[2] Wang 2018	Table 4, p. 7, row 42 report
1011	Liquid + Ge3Li7 -> Ge4Li9	L: Li 0.67; Ge3Li7: Ge 0.3, Li 0.7; Ge4Li9: Ge 0.307692, Li 0.692308	model	[1] Gierlotka 2022 cites modeled stoichiometry of the phases based on Gruttner [23] description whereas this work adopts ab initio findings	Table 11, p. 9, row 4 report
1003.15	L = Li14Ge6 + Li13Ge4	Li14Ge6: Li 0.7; Li13Ge4: Li 0.764706	experimental	[2] Wang 2018 cites Gruttner 1982	Table 4, p. 7, row 3 report
995.05	L + Li13Ge4 = Li15Ge4	Li13Ge4: Li 0.764706; Li15Ge4: Li 0.789474	model	[2] Wang 2018	Table 4, p. 7, row 43 report
995	Liquid + Ge2Li7 -> Ge4Li15	L: Li 0.837; Ge2Li7: Ge 0.222222, Li 0.777778; Ge4Li15: Ge 0.210526, Li 0.789474	model	[1] Gierlotka 2022 cites modeled stoichiometry of the phases based on Gruttner [23] description whereas this work adopts ab initio findings	Table 11, p. 9, row 7 report
994	Liquid + Ge2Li7 -> Ge4Li15	L: Li 0.841; Ge2Li7: Ge 0.222222, Li 0.777778; Ge4Li15: Ge 0.210526, Li 0.789474	model	[1] Gierlotka 2022 cites modeled stoichiometry of the phases based on Gruttner [23] description whereas this work adopts ab initio findings	Table 11, p. 9, row 8 report
989.75	L + Li13Ge4 = Li15Ge4	Li13Ge4: Li 0.764706; Li15Ge4: Li 0.789474	model	[2] Wang 2018	Table 4, p. 7, row 44 report
977	Liquid + Ge2Li7 -> Ge4Li15	L: Li 0.858; Ge2Li7: Ge 0.222222, Li 0.777778; Ge4Li15: Ge 0.210526, Li 0.789474	model	[1] Gierlotka 2022	Table 11, p. 9, row 6 report
963.15	L = Li13Ge4 + Li15Ge4	Li13Ge4: Li 0.764706; Li15Ge4: Li 0.789474	experimental	[2] Wang 2018 cites Gruttner 1982	Table 4, p. 7, row 10 report
913.15	L + Li15Ge4 = Li4Ge	Li15Ge4: Li 0.789474; Li4Ge: Li 0.8	experimental	[2] Wang 2018 cites Gruttner 1982	Table 4, p. 7, row 14 report
901	Liquid + Ge5Li14 -> GeLi4.096	L: Li 0.894; GeLi4.096: Ge 0.196232, Li 0.803768	model	[1] Gierlotka 2022	Table 11, p. 9, row 9 report
900.15	L + Li15Ge4 = Li4.1Ge	Li15Ge4: Li 0.789474; Li4.1Ge: Li 0.803922	experimental	[2] Wang 2018 cites Zeilinger 2014 doi	Table 4, p. 7, row 13 report
900	Liquid + Ge5Li14 -> GeLi4.096	GeLi4.096: Ge 0.196232, Li 0.803768	experimental	[1] Gierlotka 2022 cites Zeilinger 2014 doi	Table 11, p. 9, row 12 report
897.45	L + Li15Ge4 = Li4.1Ge	Li15Ge4: Li 0.789474; Li4.1Ge: Li 0.803922	model	[2] Wang 2018	Table 4, p. 7, row 45 report
897	Liquid + Ge5Li14 -> GeLi4.096	L: Li 0.891; GeLi4.096: Ge 0.196232, Li 0.803768	model	[1] Gierlotka 2022 cites modeled stoichiometry of the phases based on Gruttner [23] description whereas this work adopts ab initio findings	Table 11, p. 9, row 10 report
888.15	L + Li15Ge4 = Li4.1Ge	Li15Ge4: Li 0.789474; Li4.1Ge: Li 0.803922	model	[2] Wang 2018	Table 4, p. 7, row 46 report
888	Liquid + Ge5Li14 -> GeLi4.096	L: Li 0.895; GeLi4.096: Ge 0.196232, Li 0.803768	model	[1] Gierlotka 2022 cites modeled stoichiometry of the phases based on Gruttner [23] description whereas this work adopts ab initio findings	Table 11, p. 9, row 11 report
811	Liquid + Ge4Li9 -> Ge3Li7	L: Li 0.527; Ge4Li9: Ge 0.307692, Li 0.692308; Ge3Li7: Ge 0.3, Li 0.7	model	[1] Gierlotka 2022	Table 11, p. 9, row 13 report
810	eutectic: Liquid -> GeLi + Diamond_A4	L: Li 0.483; GeLi: Ge 0.5, Li 0.5	model	[1] Gierlotka 2022	Table 11, p. 9, row 18 report
809	eutectic: Liquid -> GeLi + Ge7Li12	L: Li 0.522; GeLi: Ge 0.5, Li 0.5; Ge7Li12: Ge 0.368421, Li 0.631579	model	[1] Gierlotka 2022	Table 11, p. 9, row 22 report
803.15	L = (Ge) + LiGe	(Ge): Li 0; LiGe: Li 0.5	experimental	[2] Wang 2018 cites Gruttner 1982	Table 4, p. 7, row 17 report
803	eutectic: Liquid -> GeLi + Diamond_A4	GeLi: Ge 0.5, Li 0.5	unspecified	[1] Gierlotka 2022 cites Gruttner 1982	Table 11, p. 9, row 21 report
801.15	L + Li9Ge4 = Li12Ge7	Li9Ge4: Li 0.692308; Li12Ge7: Li 0.631579	experimental	[2] Wang 2018 cites Pell 1957 doi	Table 4, p. 7, row 28 report
801	Liquid + Ge4Li9 -> Ge3Li7	Ge4Li9: Ge 0.307692, Li 0.692308; Ge3Li7: Ge 0.3, Li 0.7	experimental	[1] Gierlotka 2022 cites Pell 1957 doi	Table 11, p. 9, row 17 report
798.15	L + Li9Ge4 = Li12Ge7	Li9Ge4: Li 0.692308; Li12Ge7: Li 0.631579	model	[2] Wang 2018	Table 4, p. 7, row 54 report
798	Liquid + Ge4Li9 -> Ge3Li7	L: Li 0.535; Ge4Li9: Ge 0.307692, Li 0.692308; Ge3Li7: Ge 0.3, Li 0.7	model	[1] Gierlotka 2022 cites modeled stoichiometry of the phases based on Gruttner [23] description whereas this work adopts ab initio findings	Table 11, p. 9, row 15 report
798	eutectic: Liquid -> GeLi + Ge7Li12	L: Li 0.535; GeLi: Ge 0.5, Li 0.5; Ge7Li12: Ge 0.368421, Li 0.631579	model	[1] Gierlotka 2022 cites modeled stoichiometry of the phases based on Gruttner [23] description whereas this work adopts ab initio findings	Table 11, p. 9, row 24 report
797.95	L = Li12Ge7 + LiGe	Li12Ge7: Li 0.631579; LiGe: Li 0.5	model	[2] Wang 2018	Table 4, p. 7, row 56 report
795.45	L = (Ge) + LiGe	(Ge): Li 0; LiGe: Li 0.5	model	[2] Wang 2018	Table 4, p. 7, row 47 report
795	eutectic: Liquid -> GeLi + Diamond_A4	L: Li 0.462; GeLi: Ge 0.5, Li 0.5	model	[1] Gierlotka 2022 cites modeled stoichiometry of the phases based on Gruttner [23] description whereas this work adopts ab initio findings	Table 11, p. 9, row 19 report
794.15	L + Li4.1Ge = Li17Ge4	Li4.1Ge: Li 0.803922; Li17Ge4: Li 0.809524	experimental	[2] Wang 2018 cites Zeilinger 2014 doi	Table 4, p. 7, row 20 report
794	Liquid + GeLi4.096 -> Ge4Li17	L: Li 0.936; GeLi4.096: Ge 0.196232, Li 0.803768; Ge4Li17: Ge 0.190476, Li 0.809524	model	[1] Gierlotka 2022	Table 11, p. 9, row 26 report
794	Liquid + GeLi4.096 -> Ge4Li17	GeLi4.096: Ge 0.196232, Li 0.803768; Ge4Li17: Ge 0.190476, Li 0.809524	unspecified	[1] Gierlotka 2022 cites Gruttner 1982	Table 11, p. 9, row 29 report
791.45	L + Li4.1Ge = Li17Ge4	Li4.1Ge: Li 0.803922; Li17Ge4: Li 0.809524	model	[2] Wang 2018	Table 4, p. 7, row 50 report
791.25	L + Li4.1Ge = Li17Ge4	Li4.1Ge: Li 0.803922; Li17Ge4: Li 0.809524	model	[2] Wang 2018	Table 4, p. 7, row 49 report
791.15	L = (Ge) + LiGe	(Ge): Li 0; LiGe: Li 0.5	model	[2] Wang 2018	Table 4, p. 7, row 48 report
791	eutectic: Liquid -> GeLi + Diamond_A4	L: Li 0.455; GeLi: Ge 0.5, Li 0.5	model	[1] Gierlotka 2022 cites modeled stoichiometry of the phases based on Gruttner [23] description whereas this work adopts ab initio findings	Table 11, p. 9, row 20 report
789	Liquid + GeLi4.096 -> Ge4Li17	L: Li 0.94; GeLi4.096: Ge 0.196232, Li 0.803768; Ge4Li17: Ge 0.190476, Li 0.809524	model	[1] Gierlotka 2022 cites modeled stoichiometry of the phases based on Gruttner [23] description whereas this work adopts ab initio findings	Table 11, p. 9, row 27 report
789	Liquid + GeLi4.096 -> Ge4Li17	L: Li 0.93; GeLi4.096: Ge 0.196232, Li 0.803768; Ge4Li17: Ge 0.190476, Li 0.809524	model	[1] Gierlotka 2022 cites modeled stoichiometry of the phases based on Gruttner [23] description whereas this work adopts ab initio findings	Table 11, p. 9, row 28 report
783.35	(Ge) + LiGe = Li7Ge12	(Ge): Li 0; LiGe: Li 0.5; Li7Ge12: Li 0.368421	model	[2] Wang 2018	Table 4, p. 7, row 52 report
783.15	(Ge) + LiGe = Li7Ge12	(Ge): Li 0; LiGe: Li 0.5; Li7Ge12: Li 0.368421	experimental	[2] Wang 2018 cites Gruttner 1982	Table 4, p. 7, row 24 report
783.15	L + Li9Ge4 = Li12Ge7	Li9Ge4: Li 0.692308; Li12Ge7: Li 0.631579	experimental	[2] Wang 2018 cites Gruttner 1982	Table 4, p. 7, row 27 report
783	Liquid + Ge4Li9 -> Ge3Li7	Ge4Li9: Ge 0.307692, Li 0.692308; Ge3Li7: Ge 0.3, Li 0.7	unspecified	[1] Gierlotka 2022 cites Gruttner 1982	Table 11, p. 9, row 16 report
782.65	L + Li9Ge4 = Li12Ge7	Li9Ge4: Li 0.692308; Li12Ge7: Li 0.631579	model	[2] Wang 2018	Table 4, p. 7, row 53 report
782	Liquid + Ge4Li9 -> Ge3Li7	L: Li 0.57; Ge4Li9: Ge 0.307692, Li 0.692308; Ge3Li7: Ge 0.3, Li 0.7	model	[1] Gierlotka 2022 cites modeled stoichiometry of the phases based on Gruttner [23] description whereas this work adopts ab initio findings	Table 11, p. 9, row 14 report
773.15	L = Li12Ge7 + LiGe	Li12Ge7: Li 0.631579; LiGe: Li 0.5	experimental	[2] Wang 2018 cites Gruttner 1982	Table 4, p. 7, row 31 report
773	eutectic: Liquid -> GeLi + Ge7Li12	GeLi: Ge 0.5, Li 0.5; Ge7Li12: Ge 0.368421, Li 0.631579	unspecified	[1] Gierlotka 2022 cites Gruttner 1982	Table 11, p. 9, row 25 report
769.35	L = Li12Ge7 + LiGe	Li12Ge7: Li 0.631579; LiGe: Li 0.5	model	[2] Wang 2018	Table 4, p. 7, row 55 report
769	eutectic: Liquid -> GeLi + Ge7Li12	L: Li 0.564; GeLi: Ge 0.5, Li 0.5; Ge7Li12: Ge 0.368421, Li 0.631579	model	[1] Gierlotka 2022 cites modeled stoichiometry of the phases based on Gruttner [23] description whereas this work adopts ab initio findings	Table 11, p. 9, row 23 report
673.15	Li4.1Ge = Li15Ge4 + Li17Ge4	Li4.1Ge: Li 0.803922; Li15Ge4: Li 0.789474; Li17Ge4: Li 0.809524	model	[2] Wang 2018	Table 4, p. 7, row 58 report
673.15	Li4.1Ge = Li15Ge4 + Li17Ge4	Li4.1Ge: Li 0.803922; Li15Ge4: Li 0.789474; Li17Ge4: Li 0.809524	experimental	[2] Wang 2018 cites Zeilinger 2014 doi	Table 4, p. 7, row 34 report
673	GeLi4.096 -> Ge4Li17 + Ge4Li15	GeLi4.096: Ge 0.196232, Li 0.803768; Ge4Li17: Ge 0.190476, Li 0.809524; Ge4Li15: Ge 0.210526, Li 0.789474	model	[1] Gierlotka 2022	Table 11, p. 9, row 30 report
673	GeLi4.096 -> Ge4Li17 + Ge4Li15	GeLi4.096: Ge 0.196232, Li 0.803768; Ge4Li17: Ge 0.190476, Li 0.809524; Ge4Li15: Ge 0.210526, Li 0.789474	model	[1] Gierlotka 2022 cites modeled stoichiometry of the phases based on Gruttner [23] description whereas this work adopts ab initio findings	Table 11, p. 9, row 31 report
673	GeLi4.096 -> Ge4Li17 + Ge4Li15	GeLi4.096: Ge 0.196232, Li 0.803768; Ge4Li17: Ge 0.190476, Li 0.809524; Ge4Li15: Ge 0.210526, Li 0.789474	unspecified	[1] Gierlotka 2022 cites Gruttner 1982	Table 11, p. 9, row 33 report
454	eutectic: Liquid -> Ge4Li17 + BCC_A2	L: Li 0.999; Ge4Li17: Ge 0.190476, Li 0.809524	model	[1] Gierlotka 2022 cites modeled stoichiometry of the phases based on Gruttner [23] description whereas this work adopts ab initio findings	Table 11, p. 9, row 35 report
453.75	L = Li17Ge4 + (Li)	Li17Ge4: Li 0.809524	model	[2] Wang 2018	Table 4, p. 7, row 59 report
453.65	L = Li17Ge4 + (Li)	Li17Ge4: Li 0.809524	experimental	[2] Wang 2018 cites Dadd 1981	Table 4, p. 7, row 38 report
453.5	eutectic: Liquid -> Ge4Li17 + BCC_A2	Ge4Li17: Ge 0.190476, Li 0.809524	experimental	[1] Gierlotka 2022 cites Dadd 1981	Table 11, p. 9, row 38 report
453.45	L = Li17Ge4 + (Li)	Li17Ge4: Li 0.809524	model	[2] Wang 2018	Table 4, p. 7, row 60 report
453.15	L = Li17Ge4 + (Li)	Li17Ge4: Li 0.809524	experimental	[2] Wang 2018 cites Gruttner 1982	Table 4, p. 7, row 37 report
453	eutectic: Liquid -> Ge4Li17 + BCC_A2	Ge4Li17: Ge 0.190476, Li 0.809524	unspecified	[1] Gierlotka 2022 cites Gruttner 1982	Table 11, p. 9, row 37 report
453	eutectic: Liquid -> Ge4Li17 + BCC_A2	L: Li 0.999; Ge4Li17: Ge 0.190476, Li 0.809524	model	[1] Gierlotka 2022 cites modeled stoichiometry of the phases based on Gruttner [23] description whereas this work adopts ab initio findings	Table 11, p. 9, row 36 report
450	eutectic: Liquid -> Ge4Li17 + BCC_A2	L: Li 0.997; Ge4Li17: Ge 0.190476, Li 0.809524	model	[1] Gierlotka 2022	Table 11, p. 9, row 34 report

Formation enthalpies

Literature values in kJ/mol-atom where the per-atom basis is known. DFT columns: the lowest-energy entry at the same composition (Materials Project 2026.04.13, OQMD v1.8; different energy references, never averaged), from dft_parity.json.

Enthalpies of formation, Ge–Li system (29)
Phase	Compound	Value	T (K)	Class	MP DFT (kJ/mol-atom)	OQMD DFT (kJ/mol-atom)	Source	Location
Ge12Li7		-26.664 kJ/mol-atom	0	model			[1] Gierlotka 2022 cites modeled stoichiometry of the phases based on Gruttner [23] description whereas this work adopts ab initio findings	Table 10, p. 8, row 4 report
Ge12Li7		-22.4 kJ/mol-atom	298.15	experimental			[1] Gierlotka 2022	Table 4, p. 4, row 2 report
Ge12Li7		-22.4 kJ/mol-atom ± 1.3	298.15	experimental			[1] Gierlotka 2022	Table 4, p. 4, row 16 report
Ge12Li7		-21.9 kJ/mol-atom ± 1.3	298.15	experimental			[1] Gierlotka 2022	Table 10, p. 8, row 2 report
Ge12Li7		-20.819 kJ/mol-atom	0	model			[1] Gierlotka 2022	Table 10, p. 8, row 3 report
Ge12Li7		-20.006 kJ/mol-atom	0	DFT			[1] Gierlotka 2022	Table 10, p. 8, row 1 report
Ge2Li7	Ge2Li7	-37.531 kJ/mol-atom	0	model	-30.764 (mp-aaaabrvq)	-32.508 (oqmd-1908167)	[1] Gierlotka 2022	Table 10, p. 8, row 19 report
Ge2Li7		-31.164 kJ/mol-atom	0	DFT			[1] Gierlotka 2022	Table 10, p. 8, row 18 report
Ge3Li7	Ge3Li7	-35.913 kJ/mol-atom	0	model		-34.859 (oqmd-1797094)	[1] Gierlotka 2022	Table 10, p. 8, row 17 report
Ge3Li7		-34.957 kJ/mol-atom	0	DFT			[1] Gierlotka 2022	Table 10, p. 8, row 16 report
Ge4Li15	Ge4Li15	-37.954 kJ/mol-atom	0	model	-31.616 (mp-aaaaacqj)	-32.315 (oqmd-8013)	[1] Gierlotka 2022	Table 10, p. 8, row 21 report
Ge4Li15		-32.024 kJ/mol-atom	0	DFT			[1] Gierlotka 2022	Table 10, p. 8, row 20 report
Ge4Li17	Ge4Li17	-33.465 kJ/mol-atom	0	model		-30.291 (oqmd-686163)	[1] Gierlotka 2022 cites modeled stoichiometry of the phases based on Gruttner [23] description whereas this work adopts ab initio findings	Table 10, p. 8, row 24 report
Ge4Li17	Ge4Li17	-29.878 kJ/mol-atom	0	model		-30.291 (oqmd-686163)	[1] Gierlotka 2022	Table 10, p. 8, row 23 report
Ge4Li17		-29.858 kJ/mol-atom	0	DFT			[1] Gierlotka 2022	Table 10, p. 8, row 22 report
Ge4Li9	Ge4Li9	-37.789 kJ/mol-atom	0	model	-33.572 (mp-aaafekwf)	-34.257 (oqmd-4751)	[1] Gierlotka 2022 cites modeled stoichiometry of the phases based on Gruttner [23] description whereas this work adopts ab initio findings	Table 10, p. 8, row 15 report
Ge4Li9	Ge4Li9	-35.845 kJ/mol-atom	0	model	-33.572 (mp-aaafekwf)	-34.257 (oqmd-4751)	[1] Gierlotka 2022	Table 10, p. 8, row 14 report
Ge4Li9		-33.919 kJ/mol-atom	0	DFT			[1] Gierlotka 2022	Table 10, p. 8, row 13 report
Ge7Li12	Ge7Li12	-36.407 kJ/mol-atom	0	model	-30.866 (mp-aaacqzll)		[1] Gierlotka 2022 cites modeled stoichiometry of the phases based on Gruttner [23] description whereas this work adopts ab initio findings	Table 10, p. 8, row 12 report
Ge7Li12	Ge7Li12	-33.782 kJ/mol-atom	0	model	-30.866 (mp-aaacqzll)		[1] Gierlotka 2022	Table 10, p. 8, row 11 report
Ge7Li12	Ge7Li12	-33.4 kJ/mol-atom	298.15	experimental	-30.866 (mp-aaacqzll)		[1] Gierlotka 2022	Table 4, p. 4, row 10 report
Ge7Li12	Ge7Li12	-33.4 kJ/mol-atom ± 1.9	298.15	experimental	-30.866 (mp-aaacqzll)		[1] Gierlotka 2022	Table 4, p. 4, row 20 report
Ge7Li12	Ge7Li12	-32.6 kJ/mol-atom	298.15	experimental	-30.866 (mp-aaacqzll)		[1] Gierlotka 2022	Table 4, p. 4, row 11 report
Ge7Li12	Ge7Li12	-32.2 kJ/mol-atom ± 1.9	298.15	experimental	-30.866 (mp-aaacqzll)		[1] Gierlotka 2022	Table 10, p. 8, row 10 report
Ge7Li12		-32.131 kJ/mol-atom	0	DFT			[1] Gierlotka 2022	Table 10, p. 8, row 9 report
GeLi	GeLi	-33.637 kJ/mol-atom	0	model	-27.093 (mp-aaaaaorm)	-27.619 (oqmd-7668)	[1] Gierlotka 2022 cites modeled stoichiometry of the phases based on Gruttner [23] description whereas this work adopts ab initio findings	Table 10, p. 8, row 8 report
GeLi	GeLi	-28.25 kJ/mol-atom	0	model	-27.093 (mp-aaaaaorm)	-27.619 (oqmd-7668)	[1] Gierlotka 2022	Table 10, p. 8, row 7 report
GeLi		-27.542 kJ/mol-atom	0	DFT			[1] Gierlotka 2022	Table 10, p. 8, row 5 report
GeLi	GeLi	-25.5 kJ/mol-atom ± 1.6	298.15	experimental	-27.093 (mp-aaaaaorm)	-27.619 (oqmd-7668)	[1] Gierlotka 2022	Table 10, p. 8, row 6 report

Other properties

Phase transition (2)

Phase transition, Ge–Li system
Property	Value	T (K)	Phases / composition	Class	Source	Location	Quote
Phase transition	803.15 K	803.15	Li4Ge(ht) = Li4Ge(rt) Li4Ge(ht): Li 0.8; Li4Ge(rt): Li 0.8	experimental	[2] Wang 2018 cites Gruttner 1982	Table 4, p. 7, row 21 report
Phase transition	993.15 K	993.15	L = Li15Ge4 L: Li 0.789474; Li15Ge4: Li 0.789474	experimental	[2] Wang 2018 cites Gruttner 1982	Table 4, p. 7, row 9 report

Activity / EMF / Gibbs energy (209)

Activity / EMF / Gibbs energy, Ge–Li system
Property	Value	T (K)	Phases / composition	Class	Source	Location
EMF	565.3 mV ± 0.1	634	(Ge) alloy: Ge 0.972, Li 0.028	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 7 report
EMF	1398.2 mV ± 0.1	634	(Ge) alloy: Ge 0.997, Li 0.003	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 1 report
EMF	1007.5 mV ± 0.1	634	(Ge) alloy: Ge 0.994, Li 0.006	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 2 report
EMF	688.9 mV ± 0.1	634	(Ge) alloy: Ge 0.985, Li 0.015	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 4 report
EMF	538.7 mV ± 0.1	634	(Ge) alloy: Ge 0.968, Li 0.032	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 8 report
EMF	523.6 mV ± 0.1	634	(Ge) alloy: Ge 0.964, Li 0.036	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 9 report
EMF	606 mV ± 0.1	634	(Ge) alloy: Ge 0.976, Li 0.024	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 6 report
EMF	646.2 mV ± 0.1	634	(Ge) alloy: Ge 0.981, Li 0.019	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 5 report
EMF	739.4 mV ± 0.1	634	(Ge) alloy: Ge 0.989, Li 0.011	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 3 report
EMF	521 mV ± 0.1	634	(Ge) + Ge12Li7 alloy: Ge 0.637, Li 0.363	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 38 report
EMF	526.8 mV ± 0.1	634	(Ge) + Ge12Li7 alloy: Ge 0.924, Li 0.076	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 16 report
EMF	525.8 mV ± 0.1	634	(Ge) + Ge12Li7 alloy: Ge 0.956, Li 0.044	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 10 report
EMF	524.6 mV ± 0.1	634	(Ge) + Ge12Li7 alloy: Ge 0.793, Li 0.207	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 29 report
EMF	524.7 mV ± 0.1	634	(Ge) + Ge12Li7 alloy: Ge 0.687, Li 0.313	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 35 report
EMF	524.5 mV ± 0.1	634	(Ge) + Ge12Li7 alloy: Ge 0.739, Li 0.261	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 32 report
EMF	527.4 mV ± 0.1	634	(Ge) + Ge12Li7 alloy: Ge 0.839, Li 0.161	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 26 report
EMF	526.5 mV ± 0.1	634	(Ge) + Ge12Li7 alloy: Ge 0.826, Li 0.174	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 27 report
EMF	522.9 mV ± 0.1	634	(Ge) + Ge12Li7 alloy: Ge 0.654, Li 0.346	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 37 report
EMF	523.2 mV ± 0.1	634	(Ge) + Ge12Li7 alloy: Ge 0.671, Li 0.329	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 36 report
EMF	525.6 mV ± 0.1	634	(Ge) + Ge12Li7 alloy: Ge 0.81, Li 0.19	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 28 report
EMF	525.6 mV ± 0.1	634	(Ge) + Ge12Li7 alloy: Ge 0.946, Li 0.054	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 12 report
EMF	525.7 mV ± 0.1	634	(Ge) + Ge12Li7 alloy: Ge 0.721, Li 0.279	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 33 report
EMF	526.8 mV ± 0.1	634	(Ge) + Ge12Li7 alloy: Ge 0.913, Li 0.087	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 18 report
EMF	523.6 mV ± 0.1	634	(Ge) + Ge12Li7 alloy: Ge 0.762, Li 0.238	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 31 report
EMF	525.6 mV ± 0.1	634	(Ge) + Ge12Li7 alloy: Ge 0.952, Li 0.048	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 11 report
EMF	525.5 mV ± 0.1	634	(Ge) + Ge12Li7 alloy: Ge 0.703, Li 0.297	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 34 report
EMF	527.1 mV ± 0.1	634	(Ge) + Ge12Li7 alloy: Ge 0.88, Li 0.12	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 23 report
EMF	526.6 mV ± 0.1	634	(Ge) + Ge12Li7 alloy: Ge 0.907, Li 0.093	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 19 report
EMF	526.3 mV ± 0.1	634	(Ge) + Ge12Li7 alloy: Ge 0.897, Li 0.103	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 21 report
EMF	525.6 mV ± 0.1	634	(Ge) + Ge12Li7 alloy: Ge 0.935, Li 0.065	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 14 report
EMF	527 mV ± 0.1	634	(Ge) + Ge12Li7 alloy: Ge 0.868, Li 0.132	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 24 report
EMF	527.1 mV ± 0.1	634	(Ge) + Ge12Li7 alloy: Ge 0.891, Li 0.109	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 22 report
EMF	520.7 mV ± 0.1	634	(Ge) + Ge12Li7 alloy: Ge 0.929, Li 0.071	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 15 report
EMF	523.9 mV ± 0.1	634	(Ge) + Ge12Li7 alloy: Ge 0.777, Li 0.223	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 30 report
EMF	525.8 mV ± 0.1	634	(Ge) + Ge12Li7 alloy: Ge 0.941, Li 0.059	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 13 report
EMF	526.6 mV ± 0.1	634	(Ge) + Ge12Li7 alloy: Ge 0.902, Li 0.098	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 20 report
EMF	526.6 mV ± 0.1	634	(Ge) + Ge12Li7 alloy: Ge 0.918, Li 0.082	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 17 report
EMF	527.4 mV ± 0.1	634	(Ge) + Ge12Li7 alloy: Ge 0.854, Li 0.146	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 25 report
EMF	516.1 mV ± 0.1	634	Ge12Li7 + GeLi alloy: Ge 0.593, Li 0.407	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 43 report
EMF	520.6 mV ± 0.1	634	Ge12Li7 + GeLi alloy: Ge 0.622, Li 0.378	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 41 report
EMF	521 mV ± 0.1	634	Ge12Li7 + GeLi alloy: Li 0.368421	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 40 report
EMF	507.5 mV ± 0.1	634	Ge12Li7 + GeLi alloy: Ge 0.561, Li 0.439	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 45 report
EMF	520.1 mV ± 0.1	634	Ge12Li7 + GeLi alloy: Ge 0.607, Li 0.393	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 42 report
EMF	504.5 mV ± 0.1	634	Ge12Li7 + GeLi alloy: Ge 0.546, Li 0.454	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 46 report
EMF	492.9 mV ± 0.1	634	Ge12Li7 + GeLi alloy: Ge 0.53, Li 0.47	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 47 report
EMF	511.4 mV ± 0.1	634	Ge12Li7 + GeLi alloy: Ge 0.576, Li 0.424	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 44 report
EMF	432.5 mV ± 0.1	634	Ge12Li7 + GeLi alloy: Ge 0.516, Li 0.484	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 48 report
EMF	162.9 mV ± 0.1	634	Ge2Li7 alloy: Ge 0.213, Li 0.787	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 84 report
EMF	177.1 mV ± 0.1	634	Ge2Li7 alloy: Ge 0.222, Li 0.778	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 82 report
EMF	174 mV ± 0.1	634	Ge2Li7 alloy: Ge 0.218, Li 0.782	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 83 report
EMF	208.8 mV ± 0.1	634	Ge3Li7 alloy: Ge 0.3, Li 0.7	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 69 report
EMF	183.2 mV ± 0.1	634	Ge3Li7 + Ge2Li7 alloy: Ge 0.26, Li 0.74	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 75 report
EMF	183.1 mV ± 0.1	634	Ge3Li7 + Ge2Li7 alloy: Ge 0.254, Li 0.746	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 76 report
EMF	183.2 mV ± 0.1	634	Ge3Li7 + Ge2Li7 alloy: Ge 0.237, Li 0.763	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 79 report
EMF	183.4 mV ± 0.1	634	Ge3Li7 + Ge2Li7 alloy: Ge 0.242, Li 0.758	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 78 report
EMF	186.4 mV ± 0.1	634	Ge3Li7 + Ge2Li7 alloy: Ge 0.248, Li 0.752	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 77 report
EMF	184.3 mV ± 0.1	634	Ge3Li7 + Ge2Li7 alloy: Ge 0.266, Li 0.734	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 74 report
EMF	182.7 mV ± 0.1	634	Ge3Li7 + Ge2Li7 alloy: Ge 0.227, Li 0.773	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 81 report
EMF	183.1 mV ± 0.1	634	Ge3Li7 + Ge2Li7 alloy: Ge 0.232, Li 0.768	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 80 report
EMF	182.6 mV ± 0.1	634	Ge3Li7 + Ge2Li7 alloy: Ge 0.28, Li 0.72	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 72 report
EMF	185.8 mV ± 0.1	634	Ge3Li7 + Ge2Li7 alloy: Ge 0.273, Li 0.727	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 73 report
EMF	182.3 mV ± 0.1	634	Ge3Li7 + Ge2Li7 alloy: Ge 0.287, Li 0.713	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 71 report
EMF	133.2 mV ± 0.1	634	Ge4Li17 alloy: Ge 0.198, Li 0.802	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 89 report
EMF	72.5 mV ± 0.1	634	Ge4Li17 alloy: Ge 0.191, Li 0.809	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 91 report
EMF	156.4 mV ± 0.1	634	Ge4Li17 alloy: Ge 0.201, Li 0.799	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 88 report
EMF	156 mV ± 0.1	634	Ge4Li17 alloy: Ge 0.205, Li 0.795	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 87 report
EMF	156.1 mV ± 0.1	634	Ge4Li17 alloy: Ge 0.209, Li 0.791	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 86 report
EMF	89.2 mV ± 0.1	634	Ge4Li17 alloy: Ge 0.194, Li 0.806	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 90 report
EMF	253.9 mV ± 0.1	634	Ge4Li9 alloy: Ge 0.308, Li 0.692	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 67 report
EMF	407.2 mV ± 0.1	634	Ge7Li12 alloy: Ge 0.368, Li 0.632	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 60 report
EMF	401.3 mV ± 0.1	634	Ge7Li12 alloy: Ge 0.363, Li 0.637	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 61 report
EMF	377.9 mV ± 0.1	634	Ge7Li12 + Ga4Li9 alloy: Ge 0.335, Li 0.665	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 64 report
EMF	388.1 mV ± 0.1	634	Ge7Li12 + Ga4Li9 alloy: Ge 0.353, Li 0.647	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 62 report
EMF	341 mV ± 0.1	634	Ge7Li12 + Ga4Li9 alloy: Ge 0.326, Li 0.674	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 65 report
EMF	385.8 mV ± 0.1	634	Ge7Li12 + Ga4Li9 alloy: Ge 0.344, Li 0.656	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 63 report
EMF	426.6 mV ± 0.1	634	GeLi alloy: Ge 0.5, Li 0.5	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 50 report
EMF	424.7 mV ± 0.1	634	GeLi + Ge7Li12 alloy: Ge 0.472, Li 0.528	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 52 report
EMF	422.1 mV ± 0.1	634	GeLi + Ge7Li12 alloy: Ge 0.396, Li 0.604	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 57 report
EMF	424.3 mV ± 0.1	634	GeLi + Ge7Li12 alloy: Ge 0.455, Li 0.545	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 53 report
EMF	423.1 mV ± 0.1	634	GeLi + Ge7Li12 alloy: Ge 0.411, Li 0.589	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 56 report
EMF	424.3 mV ± 0.1	634	GeLi + Ge7Li12 alloy: Ge 0.44, Li 0.56	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 54 report
EMF	410.1 mV ± 0.1	634	GeLi + Ge7Li12 alloy: Ge 0.385, Li 0.615	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 58 report
EMF	424.9 mV ± 0.1	634	GeLi + Ge7Li12 alloy: Ge 0.489, Li 0.511	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 51 report
EMF	424 mV ± 0.1	634	GeLi + Ge7Li12 alloy: Ge 0.426, Li 0.574	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 55 report
EMF	55.9 mV ± 0.1	634	L alloy: Ge 0.175, Li 0.825	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 97 report
EMF	51.6 mV ± 0.1	634	L alloy: Ge 0.173, Li 0.827	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 98 report
EMF	56.6 mV ± 0.1	634	L alloy: Ge 0.181, Li 0.819	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 95 report
EMF	55.2 mV ± 0.1	634	L alloy: Ge 0.188, Li 0.812	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 93 report
EMF	53.9 mV ± 0.1	634	L alloy: Ge 0.185, Li 0.815	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 94 report
EMF	57.2 mV ± 0.1	634	L alloy: Ge 0.178, Li 0.822	experimental	[1] Gierlotka 2022	Table 5, p. 5, row 96 report
EMF	614 mV ± 0.1	807	(Ge) alloy: Ge 0.93, Li 0.07	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 2 report
EMF	526.8 mV ± 0.1	807	(Ge) alloy: Ge 0.909, Li 0.091	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 3 report
EMF	643.1 mV ± 0.1	807	(Ge) alloy: Ge 0.966, Li 0.034	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 1 report
EMF	524.2 mV ± 0.1	807	(Ge) + L alloy: Ge 0.7, Li 0.3	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 10 report
EMF	523.2 mV ± 0.1	807	(Ge) + L alloy: Ge 0.8, Li 0.2	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 7 report
EMF	524.1 mV ± 0.1	807	(Ge) + L alloy: Ge 0.65, Li 0.35	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 12 report
EMF	523.5 mV ± 0.1	807	(Ge) + L alloy: Ge 0.6, Li 0.4	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 14 report
EMF	523.7 mV ± 0.1	807	(Ge) + L alloy: Ge 0.625, Li 0.375	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 13 report
EMF	524 mV ± 0.1	807	(Ge) + L alloy: Ge 0.725, Li 0.275	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 9 report
EMF	523.9 mV ± 0.1	807	(Ge) + L alloy: Ge 0.875, Li 0.125	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 4 report
EMF	522.9 mV ± 0.1	807	(Ge) + L alloy: Ge 0.849, Li 0.151	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 5 report
EMF	522.2 mV ± 0.1	807	(Ge) + L alloy: Ge 0.75, Li 0.25	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 8 report
EMF	523.2 mV ± 0.1	807	(Ge) + L alloy: Ge 0.825, Li 0.175	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 6 report
EMF	524.3 mV ± 0.1	807	(Ge) + L alloy: Ge 0.675, Li 0.325	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 11 report
EMF	129 mV ± 0.1	807	Ge3Li7 alloy: Ge 0.3, Li 0.7	experimental	[1] Gierlotka 2022 cites modeled stoichiometry of the phases based on Gruttner [23] description whereas this work adopts ab initio findings	Table 6, p. 6, row 44 report
EMF	101.6 mV ± 0.1	807	Ge3Li7 + Ge2Li7 alloy: Ge 0.255, Li 0.745	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 51 report
EMF	101.5 mV ± 0.1	807	Ge3Li7 + Ge2Li7 alloy: Ge 0.245, Li 0.755	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 52 report
EMF	101.7 mV ± 0.1	807	Ge3Li7 + Ge2Li7 alloy: Ge 0.288, Li 0.712	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 47 report
EMF	101.5 mV ± 0.1	807	Ge3Li7 + Ge2Li7 alloy: Ge 0.265, Li 0.735	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 50 report
EMF	100.5 mV ± 0.1	807	Ge3Li7 + Ge2Li7 alloy: Ge 0.235, Li 0.765	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 53 report
EMF	101.1 mV ± 0.1	807	Ge3Li7 + Ge2Li7 alloy: Ge 0.285, Li 0.715	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 48 report
EMF	101.4 mV ± 0.1	807	Ge3Li7 + Ge2Li7 alloy: Ge 0.275, Li 0.725	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 49 report
EMF	100.9 mV ± 0.1	807	Ge3Li7 + Ge2Li7 alloy: Ge 0.29, Li 0.71	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 46 report
EMF	100.1 mV ± 0.1	807	Ge3Li7 + Ge2Li7 alloy: Ge 0.295, Li 0.705	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 45 report
EMF	34.4 mV ± 0.1	807	Ge4Li15 + GeLi4.096 alloy: Ge 0.2, Li 0.8	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 60 report
EMF	40 mV ± 0.1	807	Ge4Li15 + GeLi4.096 alloy: Ge 0.204, Li 0.796	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 59 report
EMF	196.9 mV ± 0.1	807	Ge7Li12 + Ge4Li9 alloy: Ge 0.34, Li 0.66	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 38 report
EMF	196.7 mV ± 0.1	807	Ge7Li12 + Ge4Li9 alloy: Ge 0.32, Li 0.68	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 40 report
EMF	197 mV ± 0.1	807	Ge7Li12 + Ge4Li9 alloy: Ge 0.33, Li 0.67	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 39 report
EMF	196.8 mV ± 0.1	807	Ge7Li12 + Ge4Li9 alloy: Ge 0.35, Li 0.65	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 37 report
EMF	195.5 mV ± 0.1	807	Ge7Li12 + Ge4Li9 alloy: Ge 0.31, Li 0.69	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 41 report
EMF	196.6 mV ± 0.1	807	Ge7Li12 + Ge4Li9 alloy: Ge 0.36, Li 0.64	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 36 report
EMF	16.9 mV ± 0.1	807	GeLi4.096 + L alloy: Ge 0.144, Li 0.856	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 70 report
EMF	17.8 mV ± 0.1	807	GeLi4.096 + L alloy: Ge 0.159, Li 0.841	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 68 report
EMF	15.9 mV ± 0.1	807	GeLi4.096 + L alloy: Ge 0.13, Li 0.87	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 72 report
EMF	16.3 mV ± 0.1	807	GeLi4.096 + L alloy: Ge 0.152, Li 0.848	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 69 report
EMF	16.1 mV ± 0.1	807	GeLi4.096 + L alloy: Ge 0.137, Li 0.863	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 71 report
EMF	522.5 mV ± 0.1	807	L alloy: Ge 0.575, Li 0.425	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 15 report
EMF	410.3 mV ± 0.1	807	L alloy: Ge 0.49, Li 0.51	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 22 report
EMF	485.8 mV ± 0.1	807	L alloy: Ge 0.54, Li 0.46	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 17 report
EMF	441.9 mV ± 0.1	807	L alloy: Ge 0.51, Li 0.49	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 20 report
EMF	499.1 mV ± 0.1	807	L alloy: Ge 0.55, Li 0.45	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 16 report
EMF	426.3 mV ± 0.1	807	L alloy: Ge 0.5, Li 0.5	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 21 report
EMF	457.1 mV ± 0.1	807	L alloy: Ge 0.52, Li 0.48	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 19 report
EMF	471.6 mV ± 0.1	807	L alloy: Ge 0.53, Li 0.47	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 18 report
EMF	392.4 mV ± 0.1	807	L + Ge7Li12 alloy: Ge 0.41, Li 0.59	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 30 report
EMF	393.9 mV ± 0.1	807	L + Ge7Li12 alloy: Ge 0.46, Li 0.54	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 25 report
EMF	393.4 mV ± 0.1	807	L + Ge7Li12 alloy: Ge 0.44, Li 0.56	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 27 report
EMF	393.2 mV ± 0.1	807	L + Ge7Li12 alloy: Ge 0.43, Li 0.57	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 28 report
EMF	394.2 mV ± 0.1	807	L + Ge7Li12 alloy: Ge 0.48, Li 0.52	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 23 report
EMF	391.6 mV ± 0.1	807	L + Ge7Li12 alloy: Ge 0.4, Li 0.6	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 31 report
EMF	394 mV ± 0.1	807	L + Ge7Li12 alloy: Ge 0.47, Li 0.53	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 24 report
EMF	393.7 mV ± 0.1	807	L + Ge7Li12 alloy: Ge 0.45, Li 0.55	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 26 report
EMF	392.9 mV ± 0.1	807	L + Ge7Li12 alloy: Ge 0.42, Li 0.58	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 29 report
EMF	73.7 mV ± 0.1	807	UNKNOWN alloy: Ge 0.225, Li 0.775	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 54 report
EMF	177.2 mV ± 0.1	807	UNKNOWN alloy: Ge 0.305, Li 0.695	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 43 report
EMF	21.4 mV ± 0.1	807	UNKNOWN alloy: Ge 0.173, Li 0.827	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 66 report
EMF	389.9 mV ± 0.1	807	UNKNOWN alloy: Ge 0.39, Li 0.61	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 32 report
EMF	347.7 mV ± 0.1	807	UNKNOWN alloy: Ge 0.38, Li 0.62	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 33 report
EMF	28.6 mV ± 0.1	807	UNKNOWN alloy: Ge 0.18, Li 0.82	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 65 report
EMF	32.7 mV ± 0.1	807	UNKNOWN alloy: Ge 0.195, Li 0.805	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 62 report
EMF	32 mV ± 0.1	807	UNKNOWN alloy: Ge 0.186, Li 0.814	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 64 report
EMF	48.2 mV ± 0.1	807	UNKNOWN alloy: Ge 0.21, Li 0.79	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 58 report
EMF	19.3 mV ± 0.1	807	UNKNOWN alloy: Ge 0.166, Li 0.834	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 67 report
EMF	243.6 mV ± 0.1	807	UNKNOWN alloy: Ge 0.37, Li 0.63	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 34 report
EMF	33.2 mV ± 0.1	807	UNKNOWN alloy: Ge 0.192, Li 0.808	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 63 report
EMF	48.1 mV ± 0.1	807	UNKNOWN alloy: Ge 0.215, Li 0.785	experimental	[1] Gierlotka 2022	Table 6, p. 6, row 56 report
EMF	781.7 mV ± 0.1	841	(Ge) alloy: Ge 0.989, Li 0.011	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 7 report
EMF	535.5 mV ± 0.1	841	(Ge) alloy: Ge 0.968, Li 0.032	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 19 report
EMF	828.8 mV ± 0.1	841	(Ge) alloy: Ge 0.993, Li 0.007	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 5 report
EMF	759 mV ± 0.1	841	(Ge) alloy: Ge 0.987, Li 0.013	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 8 report
EMF	586.6 mV ± 0.1	841	(Ge) alloy: Ge 0.979, Li 0.021	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 13 report
EMF	1810.3 mV ± 0.1	841	(Ge) alloy: Ge 1, Li 0	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 1 report
EMF	533.8 mV ± 0.1	841	(Ge) alloy: Ge 0.966, Li 0.034	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 20 report
EMF	541.7 mV ± 0.1	841	(Ge) alloy: Ge 0.969, Li 0.031	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 18 report
EMF	625.5 mV ± 0.1	841	(Ge) alloy: Ge 0.982, Li 0.018	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 11 report
EMF	602.5 mV ± 0.1	841	(Ge) alloy: Ge 0.98, Li 0.02	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 12 report
EMF	578.6 mV ± 0.1	841	(Ge) alloy: Ge 0.977, Li 0.023	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 14 report
EMF	540.3 mV ± 0.1	841	(Ge) alloy: Ge 0.973, Li 0.027	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 16 report
EMF	860.5 mV ± 0.1	841	(Ge) alloy: Ge 0.994, Li 0.006	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 4 report
EMF	912 mV ± 0.1	841	(Ge) alloy: Ge 0.996, Li 0.004	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 3 report
EMF	1215.7 mV ± 0.1	841	(Ge) alloy: Ge 0.998, Li 0.002	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 2 report
EMF	722.4 mV ± 0.1	841	(Ge) alloy: Ge 0.986, Li 0.014	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 9 report
EMF	536.2 mV ± 0.1	841	(Ge) alloy: Ge 0.972, Li 0.028	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 17 report
EMF	533.1 mV ± 0.1	841	(Ge) alloy: Ge 0.965, Li 0.035	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 21 report
EMF	665.7 mV ± 0.1	841	(Ge) alloy: Ge 0.984, Li 0.016	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 10 report
EMF	554 mV ± 0.1	841	(Ge) alloy: Ge 0.975, Li 0.025	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 15 report
EMF	800.7 mV ± 0.1	841	(Ge) alloy: Ge 0.991, Li 0.009	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 6 report
EMF	530.9 mV ± 0.1	841	(Ge) + L alloy: Ge 0.929, Li 0.071	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 35 report
EMF	532.6 mV ± 0.1	841	(Ge) + L alloy: Ge 0.956, Li 0.044	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 26 report
EMF	531.5 mV ± 0.1	841	(Ge) + L alloy: Ge 0.941, Li 0.059	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 32 report
EMF	530.7 mV ± 0.1	841	(Ge) + L alloy: Ge 0.884, Li 0.116	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 43 report
EMF	532.5 mV ± 0.1	841	(Ge) + L alloy: Ge 0.961, Li 0.039	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 23 report
EMF	530.8 mV ± 0.1	841	(Ge) + L alloy: Ge 0.919, Li 0.081	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 37 report
EMF	530.6 mV ± 0.1	841	(Ge) + L alloy: Ge 0.906, Li 0.094	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 40 report
EMF	531.1 mV ± 0.1	841	(Ge) + L alloy: Ge 0.938, Li 0.062	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 33 report
EMF	532.1 mV ± 0.1	841	(Ge) + L alloy: Ge 0.95, Li 0.05	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 30 report
EMF	529 mV ± 0.1	841	(Ge) + L alloy: Ge 0.813, Li 0.187	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 52 report
EMF	530.7 mV ± 0.1	841	(Ge) + L alloy: Ge 0.915, Li 0.085	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 38 report
EMF	529.6 mV ± 0.1	841	(Ge) + L alloy: Ge 0.835, Li 0.165	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 49 report
EMF	530.5 mV ± 0.1	841	(Ge) + L alloy: Ge 0.875, Li 0.125	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 44 report
EMF	532.3 mV ± 0.1	841	(Ge) + L alloy: Ge 0.951, Li 0.049	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 29 report
EMF	532.7 mV ± 0.1	841	(Ge) + L alloy: Ge 0.963, Li 0.037	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 22 report
EMF	530.6 mV ± 0.1	841	(Ge) + L alloy: Ge 0.901, Li 0.099	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 41 report
EMF	529.9 mV ± 0.1	841	(Ge) + L alloy: Ge 0.851, Li 0.149	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 47 report
EMF	532.4 mV ± 0.1	841	(Ge) + L alloy: Ge 0.958, Li 0.042	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 25 report
EMF	529.5 mV ± 0.1	841	(Ge) + L alloy: Ge 0.828, Li 0.172	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 50 report
EMF	529.3 mV ± 0.1	841	(Ge) + L alloy: Ge 0.82, Li 0.18	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 51 report
EMF	531 mV ± 0.1	841	(Ge) + L alloy: Ge 0.892, Li 0.108	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 42 report
EMF	530.8 mV ± 0.1	841	(Ge) + L alloy: Ge 0.924, Li 0.076	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 36 report
EMF	532.1 mV ± 0.1	841	(Ge) + L alloy: Ge 0.948, Li 0.052	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 31 report
EMF	532.5 mV ± 0.1	841	(Ge) + L alloy: Ge 0.955, Li 0.045	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 27 report
EMF	529.7 mV ± 0.1	841	(Ge) + L alloy: Ge 0.843, Li 0.157	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 48 report
EMF	530.4 mV ± 0.1	841	(Ge) + L alloy: Ge 0.859, Li 0.141	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 46 report
EMF	531 mV ± 0.1	841	(Ge) + L alloy: Ge 0.933, Li 0.067	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 34 report
EMF	532.4 mV ± 0.1	841	(Ge) + L alloy: Ge 0.96, Li 0.04	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 24 report
EMF	530.5 mV ± 0.1	841	(Ge) + L alloy: Ge 0.867, Li 0.133	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 45 report
EMF	532.4 mV ± 0.1	841	(Ge) + L alloy: Ge 0.953, Li 0.047	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 28 report
EMF	530.7 mV ± 0.1	841	(Ge) + L alloy: Ge 0.91, Li 0.09	experimental	[1] Gierlotka 2022	Table 7, p. 6, row 39 report

Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

W. Gierlotka, A. Dębski, M. Zabrocki, A. Góral, W. Gąsior, Phase diagram, thermodynamic studies, and ab-initio calculations of the Ge-Li system, The Journal of Chemical Thermodynamics 175, 106883 (2022). doi:10.1016/j.jct.2022.106883
Shimin Wang, Yong Du, Yingbiao Peng, Peng Zhou, Xiaoming Yuan, Shuhong Liu, A Thermodynamic Assessment of the Li-Ge System, J. Phase Equilib. Diffus. 39, 315-323 (2018). doi:10.1007/s11669-018-0632-5

Please cite

R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23735569
R. Arróyave, J. Saal, D. Shin, ORCHID-Diagrams: calculated binary phase diagrams (version 2026.10), Zenodo (2026). doi:10.5281/zenodo.23735859
R. Arróyave, J. Saal, D. Shin, ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD) (version 2026.10), Zenodo (2026). doi:10.5281/zenodo.23735891
R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file; A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0). Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_phase_diagrams_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Diagrams: calculated binary phase diagrams}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735859},
  url       = {https://doi.org/10.5281/zenodo.23735859}
}

@misc{orchid_hulls_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD)}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735891},
  url       = {https://doi.org/10.5281/zenodo.23735891}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}