S–Sn system

23 accepted literature values from 1 paper(s) (experimental 16, model 7); 0 calculated phase diagram(s). 5 further extracted value(s) not accepted by the reader-agreement checks are only in the JSON/CSV.

Data: JSON · CSV · interactive explorer · phases (13) · papers (bibliography) · Markdown

Accepted values by evidence class
Evidence class	Values
experimental	16
model	7

Accepted values by property group
Property group	Values
invariant reaction	23

Convex hulls: Materials Project DFT hull · OQMD DFT hull

Invariant reactions (literature)

Invariant reactions reported in the literature for the S–Sn system (23)
T (K)	Reaction / phases	Compositions (mole fraction)	Class	Source	Location
1150	congruent melting: Tm for beta-SnS	beta-SnS: S 0.5	model	[1] Lindwall 2016	Table 1, p. 4, row 23 report
1137	L2 <=> L1 + beta-SnS	L2: S 0.48; L1: S 0.075; beta-SnS: S 0.5, Sn 0.5	experimental	[1] Lindwall 2016 cites ref. 22	Table 1, p. 4, row 7 report
1137	L2 <=> L1 + beta-SnS	L2: S 0.48; beta-SnS: S 0.5, Sn 0.5	experimental	[1] Lindwall 2016 cites ref. 12	Table 1, p. 4, row 8 report
1137	L2 <=> L1 + beta-SnS	L2: S 0.465; L1: S 0.071; beta-SnS: S 0.5	model	[1] Lindwall 2016	Table 1, p. 4, row 3 report
1133	L2 <=> L1 + beta-SnS	beta-SnS: S 0.5	experimental	[1] Lindwall 2016 cites ref. Moh 1969	Table 1, p. 4, row 6 report
1132	L2 <=> SnS2 + L3	L2: S 0.698; SnS2: S 0.6667; L3: S 0.982	model	[1] Lindwall 2016	Table 1, p. 4, row 19 report
1131	L2 <=> L1 + beta-SnS	beta-SnS: S 0.5	experimental	[1] Lindwall 2016 cites ref. Karakhanova 1966	Table 1, p. 4, row 5 report
1128	L2 <=> L1 + beta-SnS	beta-SnS: S 0.5	experimental	[1] Lindwall 2016 cites ref. Ridge 1943	Table 1, p. 4, row 4 report
1114	L2 <=> SnS2 + L3	L2: S 0.7; SnS2: S 0.6667; L3: S 0.98	experimental	[1] Lindwall 2016 cites ref. Moh 1969	Table 1, p. 4, row 20 report
1033	L2 + SnS2 <=> Sn2S3	SnS2: S 0.666667, Sn 0.333333; Sn2S3: S 0.6, Sn 0.4	experimental	[1] Lindwall 2016 cites ref. Christensen 1958	Table 1, p. 4, row 17 report
1031	L2 + SnS2 <=> Sn2S3	L2: S 0.591; SnS2: S 0.6667; Sn2S3: S 0.6	model	[1] Lindwall 2016	Table 1, p. 4, row 15 report
1031	L2 + SnS2 <=> Sn2S3	L2: S 0.59; SnS2: S 0.6667; Sn2S3: S 0.6	experimental	[1] Lindwall 2016 cites ref. Karakhanova 1966	Table 1, p. 4, row 18 report
1018	L2 + SnS2 <=> Sn2S3	L2: S 0.565; SnS2: S 0.6667; Sn2S3: S 0.6	experimental	[1] Lindwall 2016 cites ref. Moh 1969	Table 1, p. 4, row 16 report
1013	L2 <=> beta-SnS + Sn2S3	L2: S 0.556; beta-SnS: S 0.5; Sn2S3: S 0.6	experimental	[1] Lindwall 2016 cites ref. Moh 1969	Table 1, p. 4, row 11 report
1011	L2 <=> beta-SnS + Sn2S3	beta-SnS: S 0.5; Sn2S3: S 0.6, Sn 0.4	experimental	[1] Lindwall 2016 cites ref. Csillag 1979	Table 1, p. 4, row 12 report
978	L2 <=> beta-SnS + Sn2S3	beta-SnS: S 0.5; Sn2S3: S 0.6, Sn 0.4	experimental	[1] Lindwall 2016 cites ref. Christensen 1958	Table 1, p. 4, row 10 report
967	L2 <=> beta-SnS + Sn2S3	L2: S 0.55; beta-SnS: S 0.5, Sn 0.5; Sn2S3: S 0.6	experimental	[1] Lindwall 2016 cites ref. Schol 1961	Table 1, p. 4, row 14 report
967	L2 <=> beta-SnS + Sn2S3	L2: S 0.557; beta-SnS: S 0.5; Sn2S3: S 0.6	model	[1] Lindwall 2016	Table 1, p. 4, row 9 report
967	L2 <=> beta-SnS + Sn2S3	L2: S 0.55; beta-SnS: S 0.5, Sn 0.5; Sn2S3: S 0.57	experimental	[1] Lindwall 2016 cites ref. Karakhanova 1966	Table 1, p. 4, row 13 report
505	L1 <=> betaSn + alpha-SnS	betaSn: S 0; alpha-SnS: S 0.5	model	[1] Lindwall 2016	Table 1, p. 4, row 1 report
504	L1 <=> betaSn + alpha-SnS	alpha-SnS: S 0.5	experimental	[1] Lindwall 2016 cites ref. Chang 1986	Table 1, p. 4, row 2 report
388	L3 <=> SnS2 + betaS	L3: S 1; SnS2: S 0.6667; betaS: S 1; βS: S 1	model	[1] Lindwall 2016	Table 1, p. 4, row 21 report
385	L3 <=> SnS2 + betaS	SnS2: S 0.6667	experimental	[1] Lindwall 2016 cites ref. Moh 1969	Table 1, p. 4, row 22 report

Sources

Reporting papers the values were read from (a value cited from another work names that work in its row).

Greta Lindwall, ShunLi Shang, Neal R. Kelly, Tim Anderson, Zi-Kui Liu, Thermodynamics of the S–Sn system: Implication for synthesis of earth abundant photovoltaic absorber materials, Solar Energy 125, 314-323 (2016). doi:10.1016/j.solener.2015.12.013

Please cite

R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23735569
R. Arróyave, J. Saal, D. Shin, ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD) (version 2026.10), Zenodo (2026). doi:10.5281/zenodo.23735891
R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0); B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file. Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_hulls_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Hulls: binary convex hulls (Materials Project, OQMD, assessed CALPHAD)}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735891},
  url       = {https://doi.org/10.5281/zenodo.23735891}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}